WO2024259720A1 - Adhésif thermofusible de polyuréthane durcissable à l'humidité ayant une résistance à vert améliorée à basses températures - Google Patents

Adhésif thermofusible de polyuréthane durcissable à l'humidité ayant une résistance à vert améliorée à basses températures Download PDF

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Publication number
WO2024259720A1
WO2024259720A1 PCT/CN2023/102002 CN2023102002W WO2024259720A1 WO 2024259720 A1 WO2024259720 A1 WO 2024259720A1 CN 2023102002 W CN2023102002 W CN 2023102002W WO 2024259720 A1 WO2024259720 A1 WO 2024259720A1
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Prior art keywords
adhesive composition
composition according
adhesive
isocyanate
polyol
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PCT/CN2023/102002
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English (en)
Inventor
Peng TONG
Martin Schmider
Weng TEPELMANN
Elyes Jendoubi
Weiming Zhang
Sven Rosenau
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Sika Technology AG
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Sika Technology AG
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Priority to PCT/CN2023/102002 priority Critical patent/WO2024259720A1/fr
Priority to CN202380097678.3A priority patent/CN121263495A/zh
Publication of WO2024259720A1 publication Critical patent/WO2024259720A1/fr
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/20—Compositions for hot melt adhesives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/354—Applications of adhesives in processes or use of adhesives in the form of films or foils for automotive applications
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane

Definitions

  • the invention relates to reactive polyurethane hot-melt adhesives having improved initial strength at low temperatures and to use of the adhesives for bonding of substrates in production of white goods, automotive vehicles, and electronic devices.
  • Hot-melt adhesives are solvent free adhesives, which are solid at room temperature, and which are applied to the substrate to be bonded in form of a melt. After cooling the adhesive solidifies and forms an adhesive bond with the substrate through physically occurring bonding.
  • Conventional hot-melt adhesives are non-reactive adhesives, which soften again upon heating and are, therefore, not suitable to be used at elevated temperatures.
  • Reactive hot-melt adhesives contain polymers with reactive groups that enable chemical curing of the adhesive, for example, by crosslinking of the polymer chains. Due to the chemically cured polymer matrix reactive hot-melt adhesives do not soften upon heating and these adhesives are, therefore, suitable for use also at elevated temperatures.
  • the chemical curing of the polymers can be initiated, for example, by heating or exposing the adhesive composition to water, such as atmospheric moisture.
  • Moisture curing hot-melt adhesives typically contain polymers functionalized with isocyanate or silane groups, which enables crosslinking of the polymer chains upon contact with atmospheric moisture.
  • Moisture curing polyurethane hot-melt adhesives consist mainly of isocyanate-functional polyurethane polymers, which have been obtained by reacting suitable polyols, typically polyester and/or polyether polyols, with polyisocyanates, where the reaction is conducted at a molar excess of isocyanate (NCO) groups over hydroxyl (OH) groups.
  • the adhesive composition is cured by reaction of the residual isocyanate groups with water, which results in various chain extension and/or crosslinking reactions of the polymers.
  • a fully cured polyurethane hot-melt adhesive comprises urea and/or urethane bonds and, depending on the starting materials used for providing the
  • a crosslinked hot-melt adhesive does not remelt when subjected to heating and therefore, typically has a very good heat-stability.
  • PUR-HMAs are widely used in white goods and automotive industry for sealing and bonding.
  • Typical substrates include coated glass and metal panels, which exhibit high thermal conductivity. After having been applied on the substrate as a melt, a PUR-HMA will solidify to establish the green strength.
  • Some PUR-RHM adhesives exhibit a rather slow build-up of adhesive bonding strength.
  • the State-of-the-Art PUR-HMAs have been found out to have exceptionally poor wetting performance at low temperatures occurring during winter months, which can be a significant disadvantage in industrial applications.
  • the object of the present invention is to provide an adhesive composition, which overcomes or at least mitigates the disadvantages of the prior art moisture curable polyurethane hot-melt adhesives as discussed above.
  • the cured adhesive composition should also preferably have a low viscosity at typical application temperatures of hot-melt adhesives and a relatively long open time.
  • an adhesive composition comprising at least one isocyanate-functional polyurethane polymer P obtained by reacting:
  • At least one polyether polyol PO2 At least one polyether polyol PO2
  • At least one polyisocyanate PI At least one polyisocyanate PI
  • adhesive composition further comprises:
  • At least one tackifying resin TR At least one tackifying resin TR.
  • the subject of the present invention is an adhesive composition comprising at least one isocyanate-functional polyurethane polymer P obtained by reacting:
  • At least one polyether polyol PO2 At least one polyether polyol PO2
  • At least one polyisocyanate PI At least one polyisocyanate PI
  • adhesive composition further comprises:
  • At least one tackifying resin TR At least one tackifying resin TR.
  • poly in substance designations such as “polyol” or “polyisocyanate” refers to substances which in formal terms contain two or more per molecule of the functional group that occurs in their designation.
  • a polyol for example, is a compound having two or more hydroxyl groups
  • a polyisocyanate is a compound having two or more isocyanate groups.
  • polymer designates a collective of chemically uniform macromolecules produced by a polyreaction (polymerization, polyaddition, polycondensation) where the macromolecules differ with respect to their degree of polymerization, molecular weight, and chain length.
  • the term also comprises derivatives of said collective of macromolecules resulting from polyreactions, that is, compounds which are obtained by reactions such as, for example, additions or substitutions, of functional groups in predetermined macromolecules and which may be chemically uniform or chemically non-uniform.
  • polyurethane polymer designates polymers prepared by the so called diisocyanate polyaddition process. These also include those polymers which are virtually or entirely free from urethane groups. Examples of polyurethane polymers are polyether-polyurethanes, polyester-polyurethanes, polyether-polyureas, polyureas, polyester-polyureas, polyisocyanurates and polycarbodiimides.
  • isocyanate-functional polyurethane polymer designates polyurethane polymers comprising one or more unreacted isocyanate groups.
  • the polyurethane prepolymers can be obtained by reacting excess of polyisocyanates with polyols and they are polyisocyanates themselves.
  • the terms “isocyanate-functional polyurethane polymer” and “polyurethane prepolymer” are used interchangeably.
  • molecular weight refers to the molar mass (g/mol) of a molecule or a part of a molecule, also referred to as “moiety” .
  • average molecular weight refers to number average molecular weight (M n ) or to weight average molecular weight (M w ) of an oligomeric or polymeric mixture of molecules or moieties.
  • the molecular weight may be determined by gel permeation chromatography (GPC) using polystyrene as standard, styrene-divinylbenzene gel with porosity of 100 Angstrom, 1000 Angstrom and 10000 Angstrom as the column and, depending on the molecule, tetrahydrofurane as a solvent, at 35°C, or 1, 2, 4 ⁇ trichlorobenzene as a solvent, at 160 °C.
  • GPC gel permeation chromatography
  • average OH-functionality designates the average number of hydroxyl (OH) groups per molecule.
  • the average OH-functionality of a compound can be calculated based on the number average molecular weight (M n ) and the hydroxyl number of the compound.
  • M n number average molecular weight
  • the hydroxyl number of a compound can be determined by using method as defined in DIN 53 240-2 standard.
  • open time designates the length of a time period during which an adhesive applied to a surface of a substrate is still able to form an adhesive bond after being contacted with another substrate.
  • the “amount of at least one component X” in a composition for example “the amount of the at least one polyol” refers in the present document to the sum of the individual amounts of all polyols contained in the composition.
  • the at least one polyol is a polyester polyol and the composition comprises 20 wt. -%of at least one polyol
  • the sum of the amounts of all polyester polyols contained in the composition equals 20 wt. -%.
  • room temperature refers to a temperature of ca. 23 °C.
  • the adhesive composition is preferably a hot-melt adhesive composition, more preferably a one-component hot-melt adhesive composition.
  • the term “one-component composition” refers in context of the present invention to a composition in which all constituents of the composition are stored in a mixture in the same container or compartment.
  • the adhesive composition comprises at least one isocyanate-functional polyurethane polymer P obtained by reacting a polyol composition with at least one polyisocyanate PI.
  • the “polyol composition” is understood to comprise all polyols that are used for obtaining the at least one isocyanate-functional polyurethane polymer P.
  • the adhesive composition comprises at least one styrene block copolymer SC.
  • Suitable styrene block copolymers include, particularly, block copolymers containing polystyrene polyisoprene blocks and/or polybutadiene blocks. These materials are generally available as pure triblock copolymers, also known as SIS and SBS block copolymers, and as diblock copolymers (SI and SB block copolymers) . Furthermore, styrene block copolymers are also commercially available as mixtures of diblock and triblock copolymers. Suitable styrene block copolymers can have a linear, radial, or star structure, the linear structure being especially preferred.
  • the at least one styrene block copolymer SC comprises at least one styrene isoprene diblock (SI) and/or triblock (SIS) copolymer and/or at least one styrene-butadiene diblock (SB) and/or triblock (SBS) copolymer, preferably at least one styrene isoprene diblock (SI) and/or triblock (SIS) copolymer.
  • Suitable SI, SIS, SB, and SBS block copolymers are commercially available, for example from TSRC/Dexco under the trade name of such as 4000-series, and from Kraton Polymers under the trade name of D-series.
  • the at least one styrene block copolymer SC has:
  • polystyrene content of not more than 55 wt. -%, more preferably not more than 45 wt.-%and/or
  • melt flow rate determined according to ASTM D1238 (200 °C/5 kg) of not more than 100 g/10 min, more preferably not more than 50 g/10 min and/or
  • polystyrene content of a block copolymer refers here to a weight percentage of styrene or polystyrene in the block copolymer and is based on the total weight of the block copolymer.
  • the adhesive composition further comprises at least one tackifying resin TR.
  • tackifying resin designates in the present document resins that in general enhance the adhesion and/or tackiness of an adhesive composition.
  • tackiness designates in the present document the property of a substance of being sticky or adhesive by simple contact. The tackiness can be measured, for example, as a loop tack.
  • Preferred tackifying resins are tackifying at a temperature of 25°C
  • Suitable tackifying resins include natural resins, synthetic resins and chemically modified natural resins.
  • Suitable natural resins and chemically modified natural resins include rosins, rosin esters, phenolic modified rosin esters, and terpene resins.
  • rosin is to be understood to include gum rosin, wood rosin, tall oil rosin, distilled rosin, and modified rosins, for example dimerized, hydrogenated, maleated and/or polymerized versions of any of these rosins.
  • Suitable terpene resins include copolymers and terpolymers of natural terpenes, such as styrene/terpene and alpha methyl styrene/terpene resins; polyterpene resins generally resulting from the polymerization of terpene hydrocarbons, such as the bicyclic monoterpene known as pinene, in the presence of Friedel-Crafts catalysts at moderately low temperatures; hydrogenated polyterpene resins; and phenolic modified terpene resins including hydrogenated derivatives thereof.
  • natural terpenes such as styrene/terpene and alpha methyl styrene/terpene resins
  • polyterpene resins generally resulting from the polymerization of terpene hydrocarbons, such as the bicyclic monoterpene known as pinene, in the presence of Friedel-Crafts catalysts at moderately low temperatures
  • hydrogenated polyterpene resins and phenolic modified
  • synthetic resin refers to compounds obtained from the controlled chemical reactions such as polyaddition or polycondensation between well-defined reactants that do not themselves have the characteristic of resins.
  • Monomers that may be polymerized to synthesize the synthetic resins may include aliphatic monomer, cycloaliphatic monomer, aromatic monomer, or mixtures thereof.
  • Aliphatic monomers can include C 4 , C 5 , and C 6 paraffins, olefins, and conjugated diolefins.
  • aliphatic monomer or cycloaliphatic monomer examples include butadiene, isobutylene, 1, 3-pentadiene, 1, 4-pentadiene, cyclopentane, 1-pentene, 2-pentene, 2-methyl-1-pentene, 2-methyl-2-butene, 2-methyl-2-pentene, isoprene, cyclohexane, 1-3-hexadiene, 1-4-hexadiene, cyclopentadiene, dicyclopentadiene, and terpenes.
  • Aromatic monomer can include C 8 , C 9 , and C 10 aromatic monomer. Examples of aromatic monomer include styrene, indene, derivatives of styrene, derivatives of indene, coumarone, and combinations thereof.
  • Particularly suitable synthetic resins include synthetic resins made by polymerizing mixtures of unsaturated monomers that are obtained as by-products of cracking of natural gas liquids, gas oil, or petroleum naphthas. Such synthetic resins obtained from petroleum-based feedstocks are also characterized as “petroleum resins” or “hydrocarbon resins” . These include also pure monomer aromatic resins, which are made by polymerizing aromatic monomer feedstocks that have been purified to eliminate color causing contaminants and to precisely control the composition of the product.
  • Tackifying hydrocarbon resins typically have a relatively low average molecular weight (M n ) , such in the range of 250 –5000 g/mol and a glass transition temperature of above 0°C, preferably equal to or higher than 15°C, more preferably equal to or higher than 30°C.
  • M n average molecular weight
  • suitable hydrocarbon resins for use as the tackifying resin TR include, for example, C5 aliphatic hydrocarbon resins, mixed C5/C9 aliphatic/aromatic hydrocarbon resins, aromatic modified C5 aliphatic hydrocarbon resins, cycloaliphatic hydrocarbon resins, mixed C5 aliphatic/cycloaliphatic hydrocarbon resins, mixed C9 aromatic/cycloaliphatic hydrocarbon resins, mixed C5 aliphatic/cycloaliphatic/C9 aromatic hydrocarbon resins, aromatic modified cycloaliphatic hydrocarbon resins, C9 aromatic hydrocarbon resins, polyterpene resins, and copolymers and terpolymers of natural terpenes as well hydrogenated versions of the aforementioned hydrocarbon resins.
  • the notations "C5" and “C9” indicate that the monomers from which the resins are made are predominantly hydrocarbons having 4-6 and 8-10 carbon atoms, respectively.
  • the term “hydrogenated” includes fully, substantially, and at least partially hydrogenated resins. Partially hydrogenated resins may have a hydrogenation level, for example, of 50%, 70%, or 90%.
  • the at least one tackifying resin TR is a non-functionalized tackifying resin.
  • non-functionalized tackifying resin designates tackifying resins which are not chemically modified so as to contain functional groups such as epoxy, silane, sulfonate, amide, or anhydride groups.
  • the at least one tackifying resin TR has:
  • M n a number average molecular weight (M n ) in the range of 150 –5000 g/mol, preferably 250 –3500 g/mol, more preferably 250 –3000 g/mol, even more preferably 250 –2500 g/mol and/or
  • T g glass transition temperature determined by dynamical mechanical analysis (DMA) as the peak of the measured loss modulus (G” ) curve using an applied frequency of 1 Hz and a strain level of 0.1%of at or above 0 °C, preferably at or above 10 °C, more preferably at or above 15 °C, even more preferably at or above 20 °C.
  • DMA dynamical mechanical analysis
  • the at least one tackifying resin TR is a hydrocarbon resin.
  • Suitable hydrocarbon resins are commercially available, for example, under the trade name of series, Plus, Extra, and STS (all from Cray Valley) ; under the trade name of 1000 series, 2000 series, and 5000 series (all from Exxon Mobile Chemical) ; under the trade name of T series, TT series, TD series, TL series, TN series, TK series, and TV series (all from Novares GmbH) ; and under the trade name of and (all from Eastman Chemicals) .
  • the mass ratio of the amount of the at least one styrene block copolymer SC to the amount of the at least one tackifying resin TR is not more than 2, preferably not more than 1.5, especially 0.1 –2, preferably 0.5 –1.5, more preferably 0.6 –1.25.
  • Adhesive composition comprising the styrene block copolymer SC and the tackifying resin TR in amounts falling within the above cited ranges were surprising found out to exhibit particularly high green (initial) strengths at low temperatures, especially at below 5 °C.
  • the sum of the proportions of the at least one styrene block copolymer SC and the at least one tackifying resin TR makes up 5 –30 wt. -%, preferably 10 –25 wt. -%, more preferably 10 –20 wt. -%, still more preferably 12.5 –20 wt. -%, of the total weight of the adhesive composition.
  • the polyol composition a) comprises the at least one polyester polyol PO1.
  • Suitable compounds for use as the at least one polyester polyol PO1 include crystalline, partially crystalline, and amorphous, polyester polyols. These can be obtained by reacting dihydric and trihydric, preferably dihydric, alcohols, for example, 1, 2-ethanediol, diethylene glycol, triethylene glycol, 1, 2-propanediol, 1, 3-propanediol, dipropylene glycol, 1, 4-butanediol, 1, 5-pentanediol, 1, 6-hexanediol, 1, 8-octanediol, 1, 10-decanediol, 1, 12-dodecanediol, dimer fatty alcohol, neopentyl glycol, glycerol, 1, 1, 1-trimethylolpropane or mixtures of the aforesaid alcohols, with organic dicarboxylic acids or tricarboxylic acids, preferably dicarboxylic acids, or their anhydrides
  • polyester polyols include those obtained by reacting adipic acid, sebacic acid or dodecanedicarboxylic acid as dicarboxylic acid and hexanediol or neopentyl glycol as dihydric alcohol. Further examples of suitable polyester polyols include polyester polyols of oleochemical origin.
  • Polyester polyols of this type may be prepared, for example, by complete ring opening of epoxidized triglycerides of a fat mixture comprising at least partially olefinically unsaturated fatty acids, with one or more alcohols having 1-12 carbon atoms, and by subsequent partial transesterification of the triglyceride derivatives to give alkyl ester polyols having 1-12 carbon atoms in the alkyl radical.
  • Particularly suitable crystalline and partially crystalline polyester polyols include adipic acid/hexanediol polyester and dodecanedicarboxylic acid/hexanediol polyesters.
  • the at least one polyester polyol PO1 is at 25 °C solid polyester polyol, preferably having:
  • Suitable at 25 °C solid polyester polyols are commercially available, for example, under the trade name 7300-series (from Evonik Industries) .
  • the proportion of the at least one polyester polyol PO1 makes up 5 –35 wt. -%, preferably 10 –30 wt. -%, more preferably 10 –25 wt. -%, still more preferably 15 –25 wt. -%, of the total weight of the adhesive composition.
  • the polyol composition a) further comprises at least one polyether polyol PO2.
  • Suitable polyether polyols also known as polyoxyalkylene polyols, for use as the at least one polyether polyol PO2 include polymerization products of ethylene oxide, 1, 2-propylene oxide, 1, 2-or 2, 3-butylene oxide, tetrahydrofuran or mixtures thereof, optionally polymerized by means of a starter molecule having two or more active hydrogen atoms, such as, for example, water, ammonia or compounds having two or more OH-or NH-groups such as 1, 2-ethanediol, 1, 2-and 1, 3-propanediol, neopentyl glycol, diethylene glycol, triethylene glycol, isomeric dipropylene glycols and tripropylene glycols, isomeric butanediols, pentanediols, hexanediols, heptanediols, octanediols, nonanediols, de
  • Use can be made both of polyoxyalkylene polyols which have a low degree of unsaturation (measured according to ASTM D-2849-69 and expressed as milliequivalents of unsaturation per gram of polyol (meq/g) ) , produced for example by means of double metal cyanide complex catalysts (DMC catalysts) , and of polyoxyalkylene polyols having a relatively high degree of unsaturation, produced for example by means of anionic catalysts such as NaOH, KOH or alkali metal alkoxides.
  • DMC catalysts double metal cyanide complex catalysts
  • Particularly suitable polyether polyols include polyoxyalkylene diols or poly-oxyalkylene triols, especially polyoxyethylene diols or polyoxyethylene triols.
  • polyoxyalkylene diols or polyoxyalkylene triols are particularly polyoxypropylene diols and triols, having a number average molecular weight (M n ) in the range of 1000 –30000 g/mol, and also polyoxypropylene diols and triols having a number average molecular weight (M n ) of 400 –8000 g/mol.
  • Suitable polyether polyols are commercially available, for example, under the trade name of and (all from Covestro) .
  • the at least one polyether polyol PO2 is a at 25 °C liquid polyether polyol, preferably having:
  • the proportion of the at least one polyether polyol PO2 makes up 15 –45 wt. -%, preferably 20 –40 wt. -%, more preferably 20 –35 wt. -%, still more preferably 25 –35 wt. -%, of the total weight of the adhesive composition.
  • Suitable compounds to be used as the at least one polyisocyanate PI include, for example, aliphatic, cyclo-aliphatic, and aromatic polyisocyanates, especially diisocyanates, particularly monomeric diisocyanates.
  • diisocyanates particularly monomeric diisocyanates.
  • Non-monomeric diisocyanates such as oligomeric and polymeric products of monomeric diisocyanates, for example adducts of monomeric diisocyanates are also suitable but the use of monomeric diisocyanates is preferred.
  • the term “monomer” designates a molecule having at least one polymerizable group.
  • a monomeric di-or polyisocyanate contains particularly no urethane groups.
  • oligomers, or polymer products of diisocyanate monomers such as adducts of monomeric diisocyanates are not monomeric diisocyanates.
  • An isocyanate is called “aliphatic” when its isocyanate group is directly bound to an aliphatic, cycloaliphatic or arylaliphatic moiety. The corresponding functional group is therefore called an aliphatic isocyanate group.
  • An isocyanate is called “aromatic” when its isocyanate group is directly bound to an aromatic moiety. The corresponding functional group is therefore called an aromatic isocyanate group.
  • the at least one polyisocyanate PI is a diisocyanate, preferably a monomeric diisocyanate, more preferably a monomeric diisocyanate having a number average molecular weight (M n ) determined by gel permeation chromatography (GPC) using polystyrene as standard of not more than 1000 g/mol, preferably not more than 500 g/mol, more preferably not more than 400 g/mol.
  • M n number average molecular weight
  • the monomeric diisocyanate is selected from the group consisting of 4, 4 ‘-, 2, 4'-, and 2, 2'-diphenylmethane diisocyanate and mixtures of these isomers (MDI) , 2, 4-and 2, 6-tolylene diisocyanate and mixtures of these isomers (TDI) , 1, 6-hexamethylene diisocyanate (HDI) , and 1-isocyanato-3, 3, 5-trimethyl-5-isocyanatomethylcyclohexane (IPDI) .
  • MDI 4, 4 ‘-, 2, 4'-, and 2, 2'-diphenylmethane diisocyanate and mixtures of these isomers
  • TDI 2, 4-and 2, 6-tolylene diisocyanate and mixtures of these isomers
  • HDI 1, 6-hexamethylene diisocyanate
  • IPDI 1-isocyanato-3, 3, 5-trimethyl-5-isocyanatomethylcyclohexane
  • the monomeric diisocyanate is selected from the group consisting of MDI and IPDI.
  • Suitable monomeric diisocyanates are commercially available, for example, under the trade name of (from BASF) and Desmodur (from Covestro) .
  • the adhesive composition further comprises:
  • At least one poly (meth) acrylate AC At least one poly (meth) acrylate AC.
  • (meth) acrylate designates in the context of the present invention methacrylate or acrylate.
  • poly (meth) acrylate refers to homopolymers, copolymers, and higher interpolymers of an (meth) acrylate monomer with one or more further (meth) acrylate monomers and/or with one or more further monomers.
  • the (meth) acrylate monomers do not contain further functional groups such as hydroxyl-and/or carboxyl groups.
  • (meth) acrylate monomers containing further functional groups, particularly hydroxyl-groups, can be used in combination with (meth) acrylate monomers without further functional groups.
  • Suitable (meth) acrylate monomers include, for example, alkyl (meth) acrylates, such as methyl acrylate, methyl methacrylate, ethyl acrylate, n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-heptyl acrylate, n-octyl acrylate, n-octyl methacrylate, n-nonyl acrylate, lauryl acrylate, stearyl acrylate, behenyl acrylate, and their branched isomers, as for example isobutyl acrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isooctyl acrylate, isooctyl methacrylate, and also cyclohexyl methacrylate, isobornyl
  • Suitable (meth) acrylate monomers with further functional groups include, for example, hydroxyl group containing (meth) acrylate monomers, such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxybutyl butyl (meth) acrylate, 2-hydroxy-hexyl (meth) acrylate, 6-hydroxy hexyl (meth) acrylate, 8- hydroxyoctyl (meth) acrylate, 10-hydroxydecyl (meth) acrylate, 12-hydroxylauryl (meth) acrylate.
  • hydroxyl group containing (meth) acrylate monomers such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 4-
  • Suitable comonomers for the synthesis of the at least one poly (meth) acrylate AC include vinyl compounds, such as ethylenically unsaturated hydrocarbons with functional groups, vinyl esters, vinyl halides, vinylidene halides, nitriles of ethylenically unsaturated hydrocarbons, phosphoric acid esters, and zinc salts of (meth) acrylic acid.
  • vinyl compounds such as ethylenically unsaturated hydrocarbons with functional groups, vinyl esters, vinyl halides, vinylidene halides, nitriles of ethylenically unsaturated hydrocarbons, phosphoric acid esters, and zinc salts of (meth) acrylic acid.
  • Suitable comonomers include, for example, maleic anhydride, styrene, styrenic compounds, acrylonitriles, vinyl acetate, vinyl propionate, vinyl chloride, (meth) acrylic acid, beta-acryloyloxypropionic acid, vinylacetic acid, fumaric acid, crotonic acid, aconitic acid, trichloroacrylic acid, itaconic acid, and maleic acid, and amides thereof.
  • maleic anhydride styrene, styrenic compounds, acrylonitriles, vinyl acetate, vinyl propionate, vinyl chloride, (meth) acrylic acid, beta-acryloyloxypropionic acid, vinylacetic acid, fumaric acid, crotonic acid, aconitic acid, trichloroacrylic acid, itaconic acid, and maleic acid, and amides thereof.
  • Especially suitable poly (meth) acrylates include, for example, homopolymers and copolymers obtained by free radical polymerization of one or more (meth) acrylate monomers optionally in combination with one or more hydroxyl-functional (meth) acrylate monomer and/or at least one further comonomer.
  • Suitable poly (meth) acrylates are commercially available, for example, under the trade name of AC, such as AC 1420, AC 1520, AC 1631, AC 1620, AC 1630, AC 1632, AC 1750, AC 1920, AC 4830, and AC 2740 (all from Evonik Industries) .
  • AC such as AC 1420, AC 1520, AC 1631, AC 1620, AC 1630, AC 1632, AC 1750, AC 1920, AC 4830, and AC 2740 (all from Evonik Industries) .
  • the at least one poly (meth) acrylate AC has
  • M w weight average molecular weight determined by gel permeation chromatography (GPC) using polystyrene as standard of at least 15000 g/mol, preferably at least 25000 g/mol and/or
  • T g glass transition temperature
  • the proportion of the at least one poly (meth) acrylate AC makes up 5 –35 wt. -%, preferably 10 –30 wt. -%, more preferably 15 –30 wt. -%, still more preferably 15 –25 wt. -%, of the total weight of the adhesive composition.
  • the at least one poly (meth) acrylate AC comprises at least one first poly (meth) acrylate AC1, preferably having a weight average molecular weight (M w ) determined by gel permeation chromatography (GPC) using polystyrene as standard of not more than 100000 g/mol, more preferably not more than 75000 g/mol, and/or at least one second poly (meth) acrylate AC2, preferably having a weight average molecular weight (M w ) determined by gel permeation chromatography (GPC) using polystyrene as standard of at least 115000 g/mol, more preferably at least 135000 g/mol.
  • GPC gel permeation chromatography
  • the expression “the at least one component X comprises at least one component XN” such as “the at least one poly (meth) acrylate AC comprises at least one poly (meth) acrylate AC1” is understood to mean in the context of the present disclosure that a composition comprises one or more poly (meth) acrylate AC1 as representatives of the at least one poly (meth) acrylate AC.
  • the at least one poly (meth) acrylate AC comprises the at least one first poly (meth) acrylate AC1 and the at least one second poly (meth) acrylate AC2, wherein the mass ratio of the amount of the at least one first poly (meth) acrylate AC1 to the amount at least one second poly (meth) acrylate AC2 is preferably at least 0.3, preferably at least 0.5, particularly 0.4 –2, preferably 0.7 –2, more preferably 1 –2.
  • the at least one isocyanate-functional polyurethane polymer P has an average isocyanate functionality of not more than 3.5, preferably not more than 3.0.
  • the term “average NCO-functionality” designates in the present disclosure the average number of isocyanate (NCO) groups per molecule.
  • the average NCO functionality of a compound can be determined by using the method as defined in ISO 14896-2006 standard method A.
  • the at least one isocyanate-functional polyurethane polymer P has an average isocyanate functionality of 1.1 –3.5, preferably 1.5 –3, more preferably 1.8 –2.5.
  • the proportion of the at least one isocyanate-functional polyurethane polymer P makes up at least 35 wt. -%, preferably at least 45 wt. -%, of the total weight of the adhesive composition.
  • the at least one isocyanate-functional polyurethane polymer P makes up 40 –75 wt. -%, preferably 50 –70 wt. -%, more preferably 55 –70 wt. -%, still more preferably 55 –65 wt. -%, of the total weight of the adhesive composition.
  • the adhesive composition further comprises at least one catalyst CA that catalyzes the reactions of isocyanate groups with water.
  • Suitable catalysts include metal-based catalysts such as dialkyltin complexes, particularly dibutyltin (IV) or dioctyltin (IV) carboxylates or acetoacetonates, such as dibutyltindilaurate (DBTDL) , dibutyltindiacetylacetonate, dioctyltindilaurate (DOTDL) , further bismuth (III) complexes such as bismuthoctoate or bismuthneodecanoate, zinc (II) complexes, such as zincoctoate or zincneodecanoate, and zirconium (IV) com-plexes, such as zirconiumoctoate or zirconiumneodecanoate.
  • metal-based catalysts such as dialkyltin complexes, particularly dibutyltin (IV) or dioctyltin (IV) carboxylates or acetoacetonates, such as dibuty
  • Suitable catalysts include compounds containing amine groups such as, dimorpholinodialkylethers and/or dimorpholino substituted polyalkylene glycols, for example 2, 2'-dimorpholinodiethyl ether and 1, 4-diazabicyclo [2.2.2] -octane. Combinations of two or more catalysts may also be used, preferred combinations including of one or more metal-catalysts with one or more morpholine amine compounds.
  • the proportion of the at least one catalyst CA makes up 0.005 –2.00 wt. -%, preferably 0.05 –1.00 wt. -%, of the total weight of the adhesive composition.
  • the adhesive composition of the present invention can further comprise auxiliary substances and additives, for example, those selected from the group consisting of fillers, plasticizers, adhesion promoters, UV absorption agents, UV and heat stabilizers, flame retardants, optical brighteners, pigments, dyes, and desiccants.
  • auxiliary substances and additives for example, those selected from the group consisting of fillers, plasticizers, adhesion promoters, UV absorption agents, UV and heat stabilizers, flame retardants, optical brighteners, pigments, dyes, and desiccants.
  • Suitable fillers include inorganic and organic fillers, especially natural, ground or precipitated calcium carbonates, optionally coated with fatty acids or fatty acid esters, especially stearic acid, baryte (heavy spar) , talcs, quartz flours, quartz sand, dolomites, wollastonites, kaolins, calcined kaolins, mica (potassium aluminum silicate) , molecular sieves, aluminum oxides, aluminum hydroxides, magnesium hydroxide, silicas including finely divided silicas from pyrolysis processes, industrially produced carbon blacks, graphite, metal powders such as aluminum, copper, iron, silver, steel, polyvinylchloride powder, and hollow spheres.
  • fatty acids or fatty acid esters especially stearic acid, baryte (heavy spar) , talcs, quartz flours, quartz sand, dolomites, wollastonites, kaolins, calcined kaolins, mica (pot
  • the total amount of such auxiliary substances and additives preferably makes up not more than 15 wt. -%, more preferably not more than 10 wt. -%, of the total weight of the adhesive composition.
  • the adhesive composition is obtained by a method comprising steps of:
  • step B) Adding to the mixture obtained from step A) the at least one isocyanate PI and conducting reaction, optionally in the presence of one or more catalysts, wherein the molar ratio between isocyanate groups (NCO) and hydroxyl groups (OH) is at least 1.1, preferably at least 1.3, to obtain a reaction mixture comprising the at least one isocyanate-functional polyurethane polymer P.
  • NCO isocyanate groups
  • OH hydroxyl groups
  • the adhesive composition of the present invention is a moisture-curing adhesive composition, i.e., the adhesive composition can be cured by contacting the composition with water, especially with atmospheric moisture.
  • the adhesive composition of the present invention has good workability under typical application conditions of hot-melt adhesives, particularly at temperatures in the range of 95 –200 °C, meaning that at the application temperature the adhesive has sufficiently low viscosity to enable application to a substrate in a molten state.
  • the adhesive composition also develops a high initial strength immediately after the application to a substrate upon cooling even before the initiation of the crosslinking reaction with water, particularly with atmospheric moisture.
  • the adhesive composition has a viscosity at a temperature of 130 °C of not more than 75000 mPa ⁇ s, preferably not more than 50000 mPa ⁇ s, more preferably not more than 30000 mPa ⁇ s.
  • the viscosity at temperature of 130 °C can be measured using a conventional viscometer at 5 revolutions per minute, for example by using a Brookfield DV-2 viscometer with a spindle No. 27, preferably with a Thermosel System for temperature control.
  • the adhesive composition has a softening point measured by Ring and Ball method according to 4625-1: 2020 standard in the range of 45 –115 °C, preferably 50 –105 °C, more preferably 55 –95 °C.
  • Another aspect of the present invention is use of the adhesive composition of the present invention for bonding of substrates in production of white goods, automotive vehicles, and electronic devices.
  • a further aspect of the present invention is a method for producing the adhesive of the present invention, the method comprising steps of:
  • step B) Adding to the mixture obtained from step A) the at least one isocyanate PI and conducting reaction, optionally in the presence of one or more catalysts, wherein the molar ratio between isocyanate groups and hydroxyl groups is at least 1.1, preferably at least 1.3, to obtain a reaction mixture comprising the at least one isocyanate-functional polyurethane polymer P.
  • the NCO/OH ratio in step B) of the method is not greater than 3.5, preferably not greater than 3.0, more preferably not greater than 2.75, particularly 1.3 –2.75, preferably 1.5 –2.5.
  • step B) will convert substantially all the hydroxyl groups of the polyol composition a) , for example at least 95 %, preferably at least 99 %, of the hydroxyl groups of the polyol a) composition.
  • the starting mixture provided in step A) is dehydrated under vacuum at a temperature of at or above 120 °C before conducting step B) .
  • the reaction in step B) may be carried out according to conventional methods used for preparation of isocyanate-functional polyurethane polymers.
  • the reaction may, for example, be carried out at temperatures in the range of 50 –160 °C, preferably 60 –120 °C, optionally in the presence of a catalyst.
  • the reaction time depends on the temperature employed, but may, for example, be in the range of from 30 minutes to 6 hours, particularly from 30 minutes to 3 hours, preferably from 30 minutes to 1.5 hours.
  • Suitable catalysts used in the reaction of step B) include, for example, metal catalysts, such as (from Vertellus Performance Materials Inc. ) , and tin catalysts.
  • the at least one styrene block copolymer SC and the at least one tackifying resin TR are added into the reactor in step A) as a pre-mixed batch. Providing these components as a pre-mixed batch may reduce separation of the styrene block copolymer SC from the polyol composition in step A) .
  • the at least one poly (meth) acrylate AC if present in the adhesive composition, can be added before, during, of after conducing step B) of the method.
  • the at least one poly (meth) acrylate AC is dissolved in the polyol composition a) before, during, or after conducting step A) of the method.
  • a still further aspect of the present invention is a method for adhesively bonding a first substrate to a second substrate, the method comprising steps of:
  • the first and second substrates can be sheet-like articles having first and second major surfaces defined by peripheral edges and defining a thickness there between or three-dimensional shaped articles.
  • the adhesive composition is heated to a temperature above the softening point of the adhesive composition and applied to the surface of the first substrate in molten state using any conventional technique, for example, by using slot die coating, roller coating, extrusion coating, calendar coating, or spray coating.
  • the adhesive composition can be applied to the surface of the first substrate with a coating weight of, for example, 25 –750 g/m 2 , preferably 35 –500 g/m 2 , more preferably 45 –350 g/m 2 , even more preferably 50 –250 g/m 2 .
  • the adhesive composition develops a certain initial adhesive strength by physical curing, i.e., upon cooling.
  • the chemical curing reactions may begin already during the application of the adhesive composition on the surface of the first substrate.
  • majority of the chemical curing occurs after the application of adhesive, particularly, after the applied adhesive film has been contacted with the surface of the second substrate.
  • the first and second substrates can be composed of any conventional material including polymeric material, metal, painted metal, glass, wood, wood derived materials such as natural fiber polypropylene (NFPP) , and fiber materials.
  • Suitable polymeric materials include, for example, polyethylene (PE) , in particular high density polyethylene (HDPE) , polypropylene (PP) , glass-fiber reinforced polypropylene (GFPP) , polyvinyl chloride (PVC) , polyethylene terephthalate (PET) , polystyrene (PS) , polycarbonate (PC) , polymethylmethacrylate (PMMA) , acrylonitrile butadiene styrene (ABS) , polyamide (PA) , and combinations thereof.
  • PE polyethylene
  • HDPE high density polyethylene
  • PP polypropylene
  • GFPP glass-fiber reinforced polypropylene
  • PVC polyvinyl chloride
  • PET polyethylene terephthalate
  • PS polystyrene
  • the first and second substrates can be composed of a single layer or of multiple layers of different types of materials.
  • the layer (s) composed of polymeric materials can further contain additives such as fillers, plasticizers, flame retardants, thermal stabilizers, antioxidants, pigments, dyes, and biocides.
  • a still further aspect of the present invention is a composite element obtainable by using the method for adhesively bonding a first substrate to a second substrate of the present invention.
  • the polyols (PO1, PO2) and the poly (meth) acrylates (AC2, AC3) were charged into a stainless-steel reactor.
  • the mixture was kept under vacuum with stirring at 140 °C for 120 minutes to dewater the components and to obtain a homogeneously mixed mixture.
  • the styrene block copolymer (SC) and the tackifying resin (TR) were then added to the mixture, either as separate components or as a pre-mixed batch (Batch) .
  • the polyisocyanate (PI) was then added to the mixture under a nitrogen blanket.
  • the thus obtained starting mixture was reacted with stirring for 60 minutes under vacuum at a temperature of 140 °C to obtain a reaction product containing the isocyanate-functional polyurethane polymer.
  • the obtained adhesive composition was stored at room temperature under exclusion of moisture.
  • the adhesive compositions were characterized using the following measurement methods.
  • the sample adhesive composition provided in a sealed tube was preheated in an oven at a temperature of 130 °C for a time period of 30 minutes. After the heating, a sample of 12.3 g of the adhesive composition was weighted and placed in a disposable sleeve to a viscometer. The viscosity was measured at temperature of 130 °C at 5 revolutions per minute using a Brookfield DV-2 viscometer with a spindle No. 27 equipped with a Thermosel system. The values obtained with 20 minutes of tempering at the measurement temperature and five minutes of measurement were recorded as representative viscosities.
  • the sample adhesive composition provided in a sealed tube was first preheated in an oven to at temperature of 110 °C for a time period of 30 minutes. After the heating, a sample of 20 g of the molten adhesive was applied with a doctor blade to surface of a silicone paper strip (B700 white, Laufenberg &Sohn KG) placed on a heating plate.
  • the silicone paper strip had dimensions of 30 cm x 10 cm and the adhesive was applied as a film having a thickness of 500 ⁇ m and dimensions of 30 cm x 6 cm.
  • the silicone paper strip and the doctor blade were heated to a temperature of 110 °C with the heating plate.
  • the silicone paper strip was removed from the heating plate and placed (with the adhesive film facing upwards) on a sheet of plywood at room temperature (23 °C) and the time was recorded as the starting point of the measurement. Every 10 seconds a short strip of silicone coated paper having dimensions of 10 cm x 1 cm and formed in a roll (non-siliconized surface facing outwards) was placed on the adhesive film and then slowly removed to separate the strip from the adhesive film. The procedure was repeated until the paper strip could not be removed from the adhesive film without damaging the paper strip or the adhesive film. The time interval between the starting point of the measurement and the last sampling point was recorded as the open time (in seconds) of the adhesive composition
  • the adhesive was kept in an oven at 130 °C for more than 30 min to ensure the adhesive was provided in a molten state. After the heating, a sample of the molten adhesive was applied on the surface of a metal substrate having dimensions of 9 cm x 2 cm x 5 mm. The adhesive was applied as a coating film having dimensions of 2.5 cm x 1 cm and a thickness of 1 mm.
  • a second metal substrate having same dimensions as the first metal substrate was positioned over the first metal substrate along the edge of the adhesive film to form a test composite element.
  • the second metal substrate was pressed firmly against the first metal substrate to remove air from adhesive bond.
  • a weigh of 150 g was placed on the top surface of the second metal substrate. Any adhesive squeezed out from the joint was trimmed off with a knife.
  • Lap shear strength (LSS) of the test composite element was measured according to EN 1465 standard using a material testing apparatus (Zwick Z 020) and a test speed 10 mm/min. The lap shear strengths were measure with test composite elements, which had been stored for 3/6/10/20/30 minutes after the bonding of the first substrate with the second substrate to investigate the green (initial) adhesive bond strength obtained with the tested adhesive composition.
  • a first set of measurements were conducted with substrates, which had been stored at normal room temperature (RT) before assembling the composite elements.
  • the low temperature LSS results were obtained using substrates that were stored for one hour at a temperature of 0 °C.
  • the values for low temperature LSS results describe the green strength in comparison with the values obtained by using substrates stored at normal room temperature on a scale of 0 to 10, wherein 0 depicts worse performance and 10 the best performance.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention concerne une composition adhésive comprenant au moins un polymère de polyuréthane à fonctionnalité isocyanate P obtenu par réaction : a) d'une composition de polyol comprenant a1) au moins un polyester polyol PO1 et a2) au moins un polyéther polyol PO2, et b) au moins un polyisocyanate PI, la composition adhésive comprenant en outre : c) au moins un copolymère séquencé de styrène SC et d) au moins une résine collante TR.
PCT/CN2023/102002 2023-06-23 2023-06-23 Adhésif thermofusible de polyuréthane durcissable à l'humidité ayant une résistance à vert améliorée à basses températures Pending WO2024259720A1 (fr)

Priority Applications (2)

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PCT/CN2023/102002 WO2024259720A1 (fr) 2023-06-23 2023-06-23 Adhésif thermofusible de polyuréthane durcissable à l'humidité ayant une résistance à vert améliorée à basses températures
CN202380097678.3A CN121263495A (zh) 2023-06-23 2023-06-23 具有改进的低温下初始强度的可湿固化聚氨酯热熔粘合剂

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Citations (6)

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JP2015052090A (ja) * 2013-09-09 2015-03-19 積水フーラー株式会社 湿気硬化型ホットメルト接着剤
JP2015196768A (ja) * 2014-04-01 2015-11-09 積水フーラー株式会社 湿気硬化型ホットメルト接着剤
CN108431068A (zh) * 2015-12-23 2018-08-21 Sika技术股份公司 基于高耐热聚丙烯酸酯的聚氨酯热熔粘合剂
CN110256648A (zh) * 2013-01-25 2019-09-20 汉高股份有限及两合公司 包含可持续生产的原料的湿气固化聚氨酯组合物
CN110691804A (zh) * 2017-05-30 2020-01-14 汉高股份有限及两合公司 湿固化型热熔粘合剂
CN114846107A (zh) * 2019-12-17 2022-08-02 汉高股份有限及两合公司 聚氨酯热熔粘合剂组合物和它的制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110256648A (zh) * 2013-01-25 2019-09-20 汉高股份有限及两合公司 包含可持续生产的原料的湿气固化聚氨酯组合物
JP2015052090A (ja) * 2013-09-09 2015-03-19 積水フーラー株式会社 湿気硬化型ホットメルト接着剤
JP2015196768A (ja) * 2014-04-01 2015-11-09 積水フーラー株式会社 湿気硬化型ホットメルト接着剤
CN108431068A (zh) * 2015-12-23 2018-08-21 Sika技术股份公司 基于高耐热聚丙烯酸酯的聚氨酯热熔粘合剂
CN110691804A (zh) * 2017-05-30 2020-01-14 汉高股份有限及两合公司 湿固化型热熔粘合剂
CN114846107A (zh) * 2019-12-17 2022-08-02 汉高股份有限及两合公司 聚氨酯热熔粘合剂组合物和它的制备方法

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