ZA976998B - 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process - Google Patents
3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization processInfo
- Publication number
- ZA976998B ZA976998B ZA976998A ZA976998A ZA976998B ZA 976998 B ZA976998 B ZA 976998B ZA 976998 A ZA976998 A ZA 976998A ZA 976998 A ZA976998 A ZA 976998A ZA 976998 B ZA976998 B ZA 976998B
- Authority
- ZA
- South Africa
- Prior art keywords
- polymerization process
- metal complexes
- containing metal
- olefin polymerization
- substituted cyclopentadienyl
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 title 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2376896P | 1996-08-08 | 1996-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA976998B true ZA976998B (en) | 1999-02-08 |
Family
ID=21817090
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA976998A ZA976998B (en) | 1996-08-08 | 1997-08-06 | 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
| ZA976999A ZA976999B (en) | 1996-08-08 | 1997-08-06 | 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA976999A ZA976999B (en) | 1996-08-08 | 1997-08-06 | 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP1021454A1 (cs) |
| JP (1) | JP2000516608A (cs) |
| KR (1) | KR20000029853A (cs) |
| CN (1) | CN1231668A (cs) |
| AR (1) | AR009034A1 (cs) |
| AU (1) | AU716659B2 (cs) |
| BR (1) | BR9711115A (cs) |
| CA (1) | CA2262377A1 (cs) |
| CO (1) | CO4870709A1 (cs) |
| CZ (1) | CZ42499A3 (cs) |
| HU (1) | HUP9904148A3 (cs) |
| ID (1) | ID18005A (cs) |
| NO (1) | NO990546L (cs) |
| NZ (1) | NZ333877A (cs) |
| PL (1) | PL331526A1 (cs) |
| RU (1) | RU2196776C2 (cs) |
| SA (1) | SA97180735B1 (cs) |
| SK (1) | SK15299A3 (cs) |
| TR (1) | TR199900589T2 (cs) |
| WO (1) | WO1998006728A1 (cs) |
| ZA (2) | ZA976998B (cs) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI971565A7 (fi) * | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
| DE19809159A1 (de) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Metallorganische Verbindungen |
| US6326493B1 (en) * | 1999-01-25 | 2001-12-04 | Chisso Corporation | Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers |
| JP2002543208A (ja) | 1999-04-29 | 2002-12-17 | ザ ダウ ケミカル カンパニー | ビス（ｎ、ｎ−ジヒドロカルビルアミノ）置換シクロペンタジエン及びそれらの金属錯体 |
| DE60001557T2 (de) | 1999-05-13 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Metallkomplexe mit heteroatom-enthaltende brücke für olefinpolymerisationsverfahren |
| DE60001558T2 (de) | 1999-05-13 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Di- und tri-heteroatom-substituierte metall-indenylkomplexe |
| DE60020968T2 (de) | 1999-06-04 | 2006-05-11 | Dow Global Technologies, Inc., Midland | Borsubstituierte cyclopentadiene und metallkomplexe dieser liganden |
| CA2646567A1 (en) * | 1999-12-10 | 2001-06-14 | Dow Global Technologies Inc. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| EP1253158A1 (en) * | 1999-12-10 | 2002-10-30 | Dow Global Technologies Inc. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| ATE430753T1 (de) | 2000-01-18 | 2009-05-15 | Basell Polyolefine Gmbh | Ligand für einen metallocenkatalysator für die polymerisation von propylen und dessen herstellungsverfahren |
| GB0001232D0 (en) * | 2000-01-19 | 2000-03-08 | Borealis Polymers Oy | Polymerisation catalysts |
| EP1248806A1 (en) * | 2000-01-19 | 2002-10-16 | Borealis Technology Oy | Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins |
| JP4062929B2 (ja) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| ATE403684T1 (de) * | 2002-03-14 | 2008-08-15 | Dow Global Technologies Inc | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren |
| US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
| RU2373592C1 (ru) * | 2006-09-11 | 2009-11-20 | Асахи Касеи Кабусики Кайся | Полимерный электролит, способ его получения и электрохимический элемент |
| RU2549541C2 (ru) | 2009-07-28 | 2015-04-27 | Юнивейшн Текнолоджиз, Ллк | Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией |
| WO2012036164A1 (ja) * | 2010-09-15 | 2012-03-22 | 株式会社日本触媒 | 熱潜在性重合開始剤として用い得る組成物 |
| CN102101897B (zh) * | 2010-12-24 | 2013-02-06 | 上海化工研究院 | 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用 |
| US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
| CN107107025A (zh) | 2015-01-06 | 2017-08-29 | Scg化学有限公司 | SiO2层状双氢氧化物微球及它们的制备方法 |
| KR102010630B1 (ko) * | 2016-01-20 | 2019-08-13 | 한화토탈 주식회사 | 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법 |
| GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
| US10870716B2 (en) * | 2017-03-23 | 2020-12-22 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods for preparing and using the same |
| KR102643986B1 (ko) | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| KR102714698B1 (ko) | 2019-02-28 | 2024-10-10 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| WO2020174346A1 (ko) | 2019-02-28 | 2020-09-03 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| EP3865522A4 (en) | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | POLYETHYLENE AND CHLORINATED POLYETHYLENE THEREOF |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| ATE198207T1 (de) * | 1992-08-03 | 2001-01-15 | Targor Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene |
| DE4406964A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme |
| DE4406963A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem |
-
1997
- 1997-07-28 CN CN97198208A patent/CN1231668A/zh active Pending
- 1997-07-28 KR KR1019997001015A patent/KR20000029853A/ko not_active Withdrawn
- 1997-07-28 AU AU39647/97A patent/AU716659B2/en not_active Ceased
- 1997-07-28 PL PL97331526A patent/PL331526A1/xx unknown
- 1997-07-28 RU RU99104650/04A patent/RU2196776C2/ru not_active IP Right Cessation
- 1997-07-28 SK SK152-99A patent/SK15299A3/sk not_active Application Discontinuation
- 1997-07-28 HU HU9904148A patent/HUP9904148A3/hu unknown
- 1997-07-28 WO PCT/US1997/013171 patent/WO1998006728A1/en not_active Ceased
- 1997-07-28 TR TR1999/00589T patent/TR199900589T2/xx unknown
- 1997-07-28 JP JP10509760A patent/JP2000516608A/ja active Pending
- 1997-07-28 CZ CZ99424A patent/CZ42499A3/cs unknown
- 1997-07-28 EP EP97937033A patent/EP1021454A1/en not_active Withdrawn
- 1997-07-28 CA CA002262377A patent/CA2262377A1/en not_active Abandoned
- 1997-07-28 BR BR9711115A patent/BR9711115A/pt not_active IP Right Cessation
- 1997-07-28 NZ NZ333877A patent/NZ333877A/xx unknown
- 1997-08-06 ZA ZA976998A patent/ZA976998B/xx unknown
- 1997-08-06 ZA ZA976999A patent/ZA976999B/xx unknown
- 1997-08-07 ID IDP972749A patent/ID18005A/id unknown
- 1997-08-08 AR ARP970103616A patent/AR009034A1/es not_active Application Discontinuation
- 1997-08-08 CO CO97045592A patent/CO4870709A1/es unknown
- 1997-12-24 SA SA97180735A patent/SA97180735B1/ar unknown
-
1999
- 1999-02-05 NO NO990546A patent/NO990546L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU3964797A (en) | 1998-03-06 |
| JP2000516608A (ja) | 2000-12-12 |
| EP1021454A1 (en) | 2000-07-26 |
| KR20000029853A (ko) | 2000-05-25 |
| NO990546D0 (no) | 1999-02-05 |
| CZ42499A3 (cs) | 1999-07-14 |
| CA2262377A1 (en) | 1998-02-19 |
| NZ333877A (en) | 2000-08-25 |
| WO1998006728A1 (en) | 1998-02-19 |
| AR009034A1 (es) | 2000-03-08 |
| BR9711115A (pt) | 1999-08-17 |
| HUP9904148A2 (hu) | 2000-03-28 |
| SA97180735B1 (ar) | 2006-10-08 |
| ID18005A (id) | 1998-02-19 |
| CO4870709A1 (es) | 1999-12-27 |
| CN1231668A (zh) | 1999-10-13 |
| SK15299A3 (en) | 2000-03-13 |
| TR199900589T2 (xx) | 1999-07-21 |
| ZA976999B (en) | 1999-02-08 |
| AU716659B2 (en) | 2000-03-02 |
| PL331526A1 (en) | 1999-07-19 |
| HUP9904148A3 (en) | 2003-03-28 |
| NO990546L (no) | 1999-03-29 |
| RU2196776C2 (ru) | 2003-01-20 |
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