AR030084A1 - CATALIZADOR APROPIADO PARA LA OBTENCION DE NITRILOS, PROCEDIMIENTO PARA SU OBTENCIoN Y PROCEDIMIENTOS PARA LA OBTENCION DE NITRILOS - Google Patents

CATALIZADOR APROPIADO PARA LA OBTENCION DE NITRILOS, PROCEDIMIENTO PARA SU OBTENCIoN Y PROCEDIMIENTOS PARA LA OBTENCION DE NITRILOS

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Publication number
AR030084A1
AR030084A1 ARP010103646A AR030084A1 AR 030084 A1 AR030084 A1 AR 030084A1 AR P010103646 A ARP010103646 A AR P010103646A AR 030084 A1 AR030084 A1 AR 030084A1
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AR
Argentina
Prior art keywords
aryl
alkyl
cycloalkyl
different
heteroaryl
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English (en)
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of AR030084A1 publication Critical patent/AR030084A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4866—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the ester moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4875—Esters with hydroxy aryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Catalizador que contiene un complejo de níquel (0) con un ligando de la formula (1) Y1 û E1-X ûE2 ûY2 (1) en donde X significa arileno o heteroarileno, pudiendo el grupo arileno o heteroarileno llevar uno, dos, tres o más sustituyentes seleccionados entre alquilo, cicloalquilo, arilo, alcoxi, cicloalquiloxi, acilo, ariloxi, halogeno, trifluorometilo, nitro ciano, carboxilo o NZ1Z2, donde Z1 y Z2 pueden ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo, pudiendo el grupo arileno o heteroarileno estar uno a dos veces anelado con cicloalquilo, arilo, heterocicloalquilo y/o heteroarilo, donde los grupos cicloalquilo, arilo, heterocicloalquilo o heteroarilo pueden llevar uno, dos o tres sustituyentes seleccionados entre alquilo, cicloalquilo, arilo, alcoxi, cicloalquiloxi, acilo, ariloxi, halogeno, trifluormetilo, nitro, ciano, carboxilo o NZ3Z4, donde Z3 y Z4 pueden ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo, E1, E2 significan independientemente O o NZ5, donde Z5 significa alquilo, arilo, heteroarilo o SiZ6Z7Z8, pudiendo los grupos alquilo, arilo o heteroarilo llevar uno, dos o tres sustituyentes, seleccionados entre alquilo, cicloalquilo, arilo, alcoxi, cicloalquiloxi, acilo, ariloxi, halogeno, trifluormetilo, nitro, ciano, carboxilo o NZ9Z10, donde Z9 y Z10 pueden ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo y pudiendo Z6-, Z7 y Z8 ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo, Y1, Y2 pueden ser idénticos o diferentes y significan independientemente un radical de las formulas (2) o (3). Donde E3, E4, E5, E6 pueden ser idénticos o diferentes y pueden representar, independientemente, un enlace químico o, independientemente, O o NZ11, donde Z11 significa alquilo, arilo, heteroarilo, o SiZ12Z13Z14, pudiendo los grupos alquilo, arilo o heteroarilo llevar uno, dos o tres sustituyentes seleccionados entre alquilo, cicloalquilo, arilo, alcoxi, cicloalquiloxi, acilo, ariloxi, halogeno, trifluorometilo, nitro, ciano, carboxilo o NZ15Z16, donde Z15 y Z16 pueden ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo, y donde Z12, Z13, Z14 pueden ser idénticos o diferentes y significar alquilo, cicloalquilo o arilo; R1 y R2 pueden ser idénticos o diferentes y significar independientemente un grupo cicloalquilo, arilo heterocicloalquilo o heteroarilo, pudiendo el grupo llevar cada vez uno dos o tres sustituyentes seleccionados entre alquilo, alcoxi, halogeno, nitro, ciano o carboxilo; R3 representa junto con una parte del sistema ûE5-P-E6, al que está unido, un heterociclo de 5, 6, 7 u 8 miembros, que eventualmente puede estar anelado adicionalmente uno, dos o tres veces con cicloalquilo, arilo o heteroarilo, pudiendo los grupos anelados llevar cada vez uno, dos o tres sustituyentes seleccionados entre alquilo, alcoxi, halogeno, nitro, ciano o carboxilo; o las sales o mezclas de los mismos. Procedimiento para la obtencion de los catalizadores anteriores, en donde se hace reaccionar por lo menos un compuesto de la formula (1) con: a) níquel o b) un compuesto de níquel, en presencia de un reductor, o c) un complejo de níquel (0) en un diluyente inerte líquido. Procedimiento para la obtencion de mezclas de mononitrilos monoolefínicos con 5 átomos de carbono con enlaces C=C y CsN- no conjugados por hidrocianuracion catalítica de butadieno o una mezcla de hidrocarburo que contiene 1,3-butadieno, en donde la hidrocianuracion se realiza en presencia del catalizador descripto. Procedimiento para la obtencion de adipodinitrilo, en donde se somete la mezcla de mononitrilos con 5 átomos de carbono, eventualmente tras elaboracion ulterior y/o isomerizacion ulterior, en presencia de un catalizador segun lo descripto a una hidrocianuracion catalítica. Uso de catalizadores que comprenden ligandos de la formula (1) para la hidrocianuracion y/o isomerizacion de posicion y de doble enlace de olefinas.
ARP010103646 2000-08-02 2001-07-31 CATALIZADOR APROPIADO PARA LA OBTENCION DE NITRILOS, PROCEDIMIENTO PARA SU OBTENCIoN Y PROCEDIMIENTOS PARA LA OBTENCION DE NITRILOS AR030084A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2000138037 DE10038037A1 (de) 2000-08-02 2000-08-02 Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen

Publications (1)

Publication Number Publication Date
AR030084A1 true AR030084A1 (es) 2003-08-13

Family

ID=7651302

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP010103646 AR030084A1 (es) 2000-08-02 2001-07-31 CATALIZADOR APROPIADO PARA LA OBTENCION DE NITRILOS, PROCEDIMIENTO PARA SU OBTENCIoN Y PROCEDIMIENTOS PARA LA OBTENCION DE NITRILOS

Country Status (4)

Country Link
AR (1) AR030084A1 (es)
AU (1) AU2001282012A1 (es)
DE (1) DE10038037A1 (es)
WO (1) WO2002013964A2 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10136488A1 (de) 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
FR2842196B1 (fr) * 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
US7786349B2 (en) 2003-04-09 2010-08-31 Bayer Bioscience N.V. Methods and means for increasing the tolerance of plants to stress conditions
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE102004004718A1 (de) 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
ES2532982T3 (es) 2005-10-18 2015-04-06 Invista Technologies S.À.R.L. Proceso de preparación de 3-aminopentanonitrilo
WO2007109005A2 (en) 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
WO2007131699A2 (en) 2006-05-12 2007-11-22 Bayer Bioscience N.V. Novel stress-related microrna molecules and uses thereof
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
EP2146930A2 (en) 2007-05-14 2010-01-27 INVISTA Technologies S.à.r.l. High efficiency reactor and process
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
WO2009091771A2 (en) 2008-01-15 2009-07-23 Invista Technologies S.A R.L Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
CN102471218B (zh) 2009-08-07 2014-11-05 因温斯特技术公司 用于形成二酯的氢化并酯化
CN103080119B (zh) 2010-09-07 2015-04-08 因温斯特技术公司 用于制备镍金属的镍组合物和镍配合物

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Publication number Priority date Publication date Assignee Title
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
TW213465B (es) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
IN187044B (es) * 1995-01-27 2002-01-05 Du Pont
ZA986369B (en) * 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.

Also Published As

Publication number Publication date
WO2002013964A2 (de) 2002-02-21
WO2002013964A3 (de) 2002-07-18
DE10038037A1 (de) 2002-04-18
AU2001282012A1 (en) 2002-02-25

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