AR060201A2 - Una composicion catalizadora bimetalica - Google Patents
Una composicion catalizadora bimetalicaInfo
- Publication number
- AR060201A2 AR060201A2 ARP070104151A ARP070104151A AR060201A2 AR 060201 A2 AR060201 A2 AR 060201A2 AR P070104151 A ARP070104151 A AR P070104151A AR P070104151 A ARP070104151 A AR P070104151A AR 060201 A2 AR060201 A2 AR 060201A2
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst composition
- bimetal catalyst
- catalyst
- activator
- metallocene
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000012190 activator Substances 0.000 abstract 2
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Una composicion catalizadora bimetálica que comprende un componente catalizador de metaloceno fluorado, un componente catalizador distinto de metaloceno y un activador, los componentes catalizadores y el activador soportados sobre un oxido inorgánico deshidratado a una temperatura de 870sC o mayor.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40843002P | 2002-09-04 | 2002-09-04 | |
| US10/368,818 US6875828B2 (en) | 2002-09-04 | 2003-02-18 | Bimodal polyolefin production process and films therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR060201A2 true AR060201A2 (es) | 2008-06-04 |
Family
ID=31981174
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030103214A AR041153A1 (es) | 2002-09-04 | 2003-09-04 | Proceso de produccion de poliolefinas bimodales y peliculas de las mismas |
| ARP070104151A AR060201A2 (es) | 2002-09-04 | 2007-09-19 | Una composicion catalizadora bimetalica |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030103214A AR041153A1 (es) | 2002-09-04 | 2003-09-04 | Proceso de produccion de poliolefinas bimodales y peliculas de las mismas |
Country Status (17)
| Country | Link |
|---|---|
| US (3) | US6875828B2 (es) |
| EP (1) | EP1546212B1 (es) |
| JP (1) | JP2005538216A (es) |
| KR (1) | KR100625162B1 (es) |
| CN (1) | CN1305912C (es) |
| AR (2) | AR041153A1 (es) |
| AT (1) | ATE498636T1 (es) |
| AU (1) | AU2003259802B2 (es) |
| BR (1) | BR0314339A (es) |
| CA (1) | CA2497676A1 (es) |
| DE (1) | DE60336069D1 (es) |
| EG (1) | EG23481A (es) |
| MX (1) | MXPA05002474A (es) |
| PL (1) | PL375267A1 (es) |
| RU (1) | RU2315776C2 (es) |
| TW (1) | TW200422301A (es) |
| WO (1) | WO2004022607A1 (es) |
Families Citing this family (48)
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|---|---|---|---|---|
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| US7172987B2 (en) * | 2002-12-31 | 2007-02-06 | Univation Technologies, Llc | Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom |
| US7662846B2 (en) * | 2003-04-23 | 2010-02-16 | Merck Sharp & Dohme Corp. | Selective spirocyclic glucocorticoid receptor modulators |
| US7410926B2 (en) * | 2003-12-30 | 2008-08-12 | Univation Technologies, Llc | Polymerization process using a supported, treated catalyst system |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| RU2375381C2 (ru) * | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
| AU2005224259B2 (en) * | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| NZ549262A (en) * | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| EP1731537A1 (en) * | 2005-06-09 | 2006-12-13 | Innovene Manufacturing France SAS | Supported polymerisation catalysts |
| PL1739691T3 (pl) * | 2005-06-30 | 2009-06-30 | Borealis Tech Oy | Zewnętrzne osłony dla kabli elektroenergetycznych lub telekomunikacyjnych |
| DE102005035477A1 (de) * | 2005-07-26 | 2007-02-01 | Basell Polyolefine Gmbh | Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren |
| US7393916B2 (en) * | 2005-11-01 | 2008-07-01 | Univation Technologies, Llc | Method of reducing gels in polyolefins |
| US7595364B2 (en) * | 2005-12-07 | 2009-09-29 | Univation Technologies, Llc | High density polyethylene |
| CN100432115C (zh) * | 2006-08-18 | 2008-11-12 | 中国科学院长春应用化学研究所 | 一种由催化剂共混体系制备双峰分子量分布聚乙烯的方法 |
| WO2008090768A1 (ja) * | 2007-01-24 | 2008-07-31 | Tokyo Ohka Kogyo Co., Ltd. | 感光性樹脂組成物、及びこれを用いたパターン形成方法 |
| EP1950241A1 (en) | 2007-01-25 | 2008-07-30 | Borealis Technology Oy | Multimodal medium density polyethylene polymer composition |
| DE102007014621A1 (de) | 2007-03-23 | 2008-09-25 | Innogel Ag | Verfahren zur Herstellung von Molekulargewichtsverteilungen mit kurzkettigem Anteil mittels Post-Reaktor Extrusion |
| CN101274968B (zh) * | 2007-03-28 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于生产宽分子量分布的聚乙烯的复合催化剂 |
| BRPI0705994A2 (pt) * | 2007-10-19 | 2009-10-06 | Braskem Sa | processo de preparação de suporte catalìtico e catalisadores bimetálicos suportados para a produção de homopolìmeros e copolìmeros de etileno com alfa-olefinas de alto e ultra alto peso molecular e com ampla distribuição de peso molecular em processos em lama, massa e fase gás e os produtos assim obtidos |
| TW200936619A (en) * | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
| RU2479593C2 (ru) * | 2007-12-18 | 2013-04-20 | Юнивейшн Текнолоджиз, Ллк | Способ регулирования активности бимодального катализатора в процессе полимеризации |
| JP5695665B2 (ja) * | 2009-12-22 | 2015-04-08 | バーゼル・ポリオレフィン・ゲーエムベーハー | 改良した水素除去を伴う多峰性ポリオレフィンポリマーの製造方法 |
| CN102770467B (zh) | 2010-02-22 | 2015-07-22 | 尤尼威蒂恩技术有限责任公司 | 催化剂体系和使用该催化剂体系制备聚烯烃产物的方法 |
| CN103221439B (zh) * | 2010-11-26 | 2017-03-22 | 巴塞尔聚烯烃股份有限公司 | 气相反应器中的聚乙烯聚合 |
| HUE046972T2 (hu) | 2011-07-08 | 2020-04-28 | Total Res & Technology Feluy | Metallocén-katalizált polietilén |
| WO2013028283A1 (en) | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Catalyst systems and methods for using same to produce polyolefin products |
| CN102504058B (zh) * | 2011-11-10 | 2014-04-02 | 上海化工研究院 | 用于生产宽分子量分布聚乙烯的复合催化剂及制法和应用 |
| BR112014032628B1 (pt) * | 2012-06-26 | 2021-06-22 | Ineos Europe Ag | Película formada por uma composição de polietileno |
| CN102887968B (zh) * | 2012-10-19 | 2014-03-19 | 河北工业大学 | 合成宽/双峰聚乙烯的非茂双金属催化体系及其应用 |
| EP2923756B1 (en) | 2012-11-26 | 2018-05-30 | Braskem S.A. | Metallocene catalyst supported by hybrid supporting means, process for producing same, polymerization process for producing an ethylene homopolymer or copolymer with broad or bimodal molar mass distribution, use of the supported metallocene catalyst and ethylene polymer with broad or bimodal molar mass distribution |
| ES2918582T3 (es) | 2012-12-28 | 2022-07-19 | Univation Tech Llc | Catalizador soportado con fluidez mejorada |
| EP4223802A3 (en) | 2013-02-07 | 2023-10-25 | Univation Technologies, LLC | Polymerization catalyst |
| WO2014149361A1 (en) | 2013-03-15 | 2014-09-25 | Univation Technologies, Llc | Ligands for catalysts |
| WO2014143421A1 (en) | 2013-03-15 | 2014-09-18 | Univation Technologies, Llc | Tridentate nitrogen based ligands for olefin polymerisation catalysts |
| WO2014197169A1 (en) | 2013-06-05 | 2014-12-11 | Univation Technologies, Llc | Protecting phenol groups |
| ES2568615T3 (es) * | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| CN105017626B (zh) * | 2014-04-15 | 2018-03-23 | 中国石化扬子石油化工有限公司 | 一种乙烯‑α‑烯烃共聚物、其制造方法及其应用 |
| ES2743481T3 (es) * | 2015-06-10 | 2020-02-19 | Borealis Ag | Copolímero multimodal de etileno y al menos dos comonómeros de alfa-olefina y artículos finales hechos del mismo |
| KR102509503B1 (ko) | 2015-07-08 | 2023-03-13 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 활성제-지지체를 구비한 지글러-나타-메탈로센 이중 촉매 시스템 |
| US9758599B2 (en) | 2015-09-24 | 2017-09-12 | Chevron Phillips Chemical Company Lp | Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina |
| US9845367B2 (en) | 2015-09-24 | 2017-12-19 | Chevron Phillips Chemical Company Lp | Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina |
| US9540457B1 (en) | 2015-09-24 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Ziegler-natta—metallocene dual catalyst systems with activator-supports |
| WO2017069854A1 (en) * | 2015-10-22 | 2017-04-27 | Exxonmobil Chemical Patents Inc. | Catalysts for the formation of multimodal polymers |
| US10611867B2 (en) | 2016-12-05 | 2020-04-07 | Exxonmobil Chemical Patents Inc. | Broad orthogonal distribution metallocene polyethylenes for films |
| US11302459B2 (en) | 2017-10-06 | 2022-04-12 | Exxonmobil Chemical Patents Inc. | Polyethylene extrudates and methods of making the same |
| CN111902467B (zh) | 2018-02-05 | 2022-11-11 | 埃克森美孚化学专利公司 | 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性 |
| US20220289586A1 (en) * | 2019-08-05 | 2022-09-15 | Indian Institute Of Technology, Jodhpur | A hydrogen-annealed bimetallic oxide and implementations thereof |
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| FI111848B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| US6001766A (en) * | 1997-12-24 | 1999-12-14 | Mobil Oil Corporation | Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes |
| US6136747A (en) | 1998-06-19 | 2000-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst composition for the production of olefin polymers |
| US6632901B2 (en) * | 1998-08-21 | 2003-10-14 | Univation Technologies, Llc | Polymerization process using an improved bulky ligand metallocene-type catalyst system |
| KR20010034199A (ko) | 1998-11-20 | 2001-04-25 | 간디 지오프레이 에이치. | 다리화 메탈로센, 제조, 촉매계 내에서의 용도 |
| US6303718B1 (en) | 1999-09-17 | 2001-10-16 | Bayer Aktiengesellschaft | Composition based on fluorine-containing metal complexes |
| US6420298B1 (en) * | 1999-08-31 | 2002-07-16 | Exxonmobil Oil Corporation | Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby |
| WO2001023442A1 (en) | 1999-09-27 | 2001-04-05 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| AU767697B2 (en) * | 1999-10-22 | 2003-11-20 | Univation Technologies Llc | Catalyst compositions, methods of polymerization, and polymers therefrom |
| DE10006538C2 (de) | 2000-02-15 | 2002-11-28 | Forsch Pigmente Und Lacke E V | Verfahren zur Beschichtung von Partikeln mit LCST-Polymeren |
| US6306718B1 (en) * | 2000-04-26 | 2001-10-23 | Dallas Semiconductor Corporation | Method of making polysilicon resistor having adjustable temperature coefficients |
| RU2258712C2 (ru) * | 2000-12-04 | 2005-08-20 | Юнивейшн Технолоджиз, Ллс | Способ полимеризации |
| US6605675B2 (en) * | 2000-12-04 | 2003-08-12 | Univation Technologies, Llc | Polymerization process |
-
2003
- 2003-02-18 US US10/368,818 patent/US6875828B2/en not_active Expired - Fee Related
- 2003-08-12 CA CA002497676A patent/CA2497676A1/en not_active Abandoned
- 2003-08-12 AT AT03794469T patent/ATE498636T1/de not_active IP Right Cessation
- 2003-08-12 JP JP2004534281A patent/JP2005538216A/ja not_active Ceased
- 2003-08-12 KR KR1020057003701A patent/KR100625162B1/ko not_active Expired - Fee Related
- 2003-08-12 DE DE60336069T patent/DE60336069D1/de not_active Expired - Lifetime
- 2003-08-12 CN CNB038209705A patent/CN1305912C/zh not_active Expired - Fee Related
- 2003-08-12 WO PCT/US2003/025281 patent/WO2004022607A1/en not_active Ceased
- 2003-08-12 MX MXPA05002474A patent/MXPA05002474A/es active IP Right Grant
- 2003-08-12 BR BR0314339-2A patent/BR0314339A/pt not_active IP Right Cessation
- 2003-08-12 AU AU2003259802A patent/AU2003259802B2/en not_active Ceased
- 2003-08-12 RU RU2005109916/04A patent/RU2315776C2/ru not_active IP Right Cessation
- 2003-08-12 EP EP03794469A patent/EP1546212B1/en not_active Expired - Lifetime
- 2003-08-12 PL PL03375267A patent/PL375267A1/xx unknown
- 2003-09-03 EG EG2003090868A patent/EG23481A/xx active
- 2003-09-04 AR ARP030103214A patent/AR041153A1/es active IP Right Grant
- 2003-09-04 TW TW092124494A patent/TW200422301A/zh unknown
-
2004
- 2004-09-20 US US10/945,462 patent/US6943134B2/en not_active Expired - Fee Related
- 2004-09-20 US US10/945,502 patent/US20050054799A1/en not_active Abandoned
-
2007
- 2007-09-19 AR ARP070104151A patent/AR060201A2/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6875828B2 (en) | 2005-04-05 |
| US20050054799A1 (en) | 2005-03-10 |
| CN1678640A (zh) | 2005-10-05 |
| EG23481A (en) | 2005-11-26 |
| EP1546212B1 (en) | 2011-02-16 |
| US20040044154A1 (en) | 2004-03-04 |
| PL375267A1 (en) | 2005-11-28 |
| US6943134B2 (en) | 2005-09-13 |
| RU2005109916A (ru) | 2006-01-20 |
| RU2315776C2 (ru) | 2008-01-27 |
| DE60336069D1 (de) | 2011-03-31 |
| EP1546212A4 (en) | 2006-07-05 |
| AR041153A1 (es) | 2005-05-04 |
| AU2003259802B2 (en) | 2007-01-11 |
| MXPA05002474A (es) | 2005-05-27 |
| KR100625162B1 (ko) | 2006-09-18 |
| WO2004022607A1 (en) | 2004-03-18 |
| BR0314339A (pt) | 2005-07-05 |
| JP2005538216A (ja) | 2005-12-15 |
| CN1305912C (zh) | 2007-03-21 |
| CA2497676A1 (en) | 2004-03-18 |
| US20050038210A1 (en) | 2005-02-17 |
| ATE498636T1 (de) | 2011-03-15 |
| KR20050057145A (ko) | 2005-06-16 |
| EP1546212A1 (en) | 2005-06-29 |
| AU2003259802A1 (en) | 2004-03-29 |
| TW200422301A (en) | 2004-11-01 |
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