ATE498636T1 - Verfahren zur herstellung eines bimodalen polyolefins und folien daraus - Google Patents

Verfahren zur herstellung eines bimodalen polyolefins und folien daraus

Info

Publication number
ATE498636T1
ATE498636T1 AT03794469T AT03794469T ATE498636T1 AT E498636 T1 ATE498636 T1 AT E498636T1 AT 03794469 T AT03794469 T AT 03794469T AT 03794469 T AT03794469 T AT 03794469T AT E498636 T1 ATE498636 T1 AT E498636T1
Authority
AT
Austria
Prior art keywords
producing
film
bimodal polyolefin
bimodal
polyolefin
Prior art date
Application number
AT03794469T
Other languages
English (en)
Inventor
Chi-I Kuo
Laughlin Mccullough
Pradeep Shirodkar
Fred Ehrman
Porter Shannon
Robert Santana
Steven Ackerman
Daniel Oneil
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Application granted granted Critical
Publication of ATE498636T1 publication Critical patent/ATE498636T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Catalysts (AREA)
AT03794469T 2002-09-04 2003-08-12 Verfahren zur herstellung eines bimodalen polyolefins und folien daraus ATE498636T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US40843002P 2002-09-04 2002-09-04
US10/368,818 US6875828B2 (en) 2002-09-04 2003-02-18 Bimodal polyolefin production process and films therefrom
PCT/US2003/025281 WO2004022607A1 (en) 2002-09-04 2003-08-12 Bimodal polyolefin production process and films therefrom

Publications (1)

Publication Number Publication Date
ATE498636T1 true ATE498636T1 (de) 2011-03-15

Family

ID=31981174

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03794469T ATE498636T1 (de) 2002-09-04 2003-08-12 Verfahren zur herstellung eines bimodalen polyolefins und folien daraus

Country Status (17)

Country Link
US (3) US6875828B2 (de)
EP (1) EP1546212B1 (de)
JP (1) JP2005538216A (de)
KR (1) KR100625162B1 (de)
CN (1) CN1305912C (de)
AR (2) AR041153A1 (de)
AT (1) ATE498636T1 (de)
AU (1) AU2003259802B2 (de)
BR (1) BR0314339A (de)
CA (1) CA2497676A1 (de)
DE (1) DE60336069D1 (de)
EG (1) EG23481A (de)
MX (1) MXPA05002474A (de)
PL (1) PL375267A1 (de)
RU (1) RU2315776C2 (de)
TW (1) TW200422301A (de)
WO (1) WO2004022607A1 (de)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US7172987B2 (en) 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
ATE447575T1 (de) * 2003-04-23 2009-11-15 Merck & Co Inc Selektive spirocyclische glucocorticoid-rezeptor- modulatoren
US7410926B2 (en) 2003-12-30 2008-08-12 Univation Technologies, Llc Polymerization process using a supported, treated catalyst system
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
SG151301A1 (en) * 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation
NZ549262A (en) * 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7858706B2 (en) * 2004-03-17 2010-12-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
EP1731537A1 (de) * 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
DE602005011421D1 (de) * 2005-06-30 2009-01-15 Borealis Tech Oy Überzug-Schicht für Energie- oder Kommunikationskabel
DE102005035477A1 (de) * 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
US7393916B2 (en) * 2005-11-01 2008-07-01 Univation Technologies, Llc Method of reducing gels in polyolefins
US7595364B2 (en) * 2005-12-07 2009-09-29 Univation Technologies, Llc High density polyethylene
CN100432115C (zh) * 2006-08-18 2008-11-12 中国科学院长春应用化学研究所 一种由催化剂共混体系制备双峰分子量分布聚乙烯的方法
US8288078B2 (en) * 2007-01-24 2012-10-16 Tokyo Ohka Kogyo Co., Ltd. Photosensitive resin composition, and pattern formation method using the same
EP1950241A1 (de) 2007-01-25 2008-07-30 Borealis Technology Oy Multimodale Polyethylenzusammensetzung
DE102007014621A1 (de) 2007-03-23 2008-09-25 Innogel Ag Verfahren zur Herstellung von Molekulargewichtsverteilungen mit kurzkettigem Anteil mittels Post-Reaktor Extrusion
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂
BRPI0705994A2 (pt) * 2007-10-19 2009-10-06 Braskem Sa processo de preparação de suporte catalìtico e catalisadores bimetálicos suportados para a produção de homopolìmeros e copolìmeros de etileno com alfa-olefinas de alto e ultra alto peso molecular e com ampla distribuição de peso molecular em processos em lama, massa e fase gás e os produtos assim obtidos
TW200936619A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US8318872B2 (en) * 2007-12-18 2012-11-27 Univation Technologies, Llc Method for controlling bimodal catalyst activity during polymerization
EP2516485B1 (de) * 2009-12-22 2015-02-25 Basell Polyolefine GmbH Verfahren zur herstellung eines multimodalen polyolefinpolymers mit verbesserter wasserstoffentfernung
KR20130026531A (ko) 2010-02-22 2013-03-13 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법
US9284394B2 (en) 2010-11-26 2016-03-15 Basell Polyolefine Gmbh Polyethylene polymerisation in gas phase reactor
EA027509B1 (ru) 2011-07-08 2017-08-31 Тотал Ресерч & Технолоджи Фелай Металлоцен-катализированный полиэтилен
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
CN102504058B (zh) * 2011-11-10 2014-04-02 上海化工研究院 用于生产宽分子量分布聚乙烯的复合催化剂及制法和应用
ES2588513T5 (es) * 2012-06-26 2024-03-05 Ineos Europe Ag Composición de película
CN102887968B (zh) * 2012-10-19 2014-03-19 河北工业大学 合成宽/双峰聚乙烯的非茂双金属催化体系及其应用
WO2014078919A1 (pt) 2012-11-26 2014-05-30 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metaloceno suportado e polímero de etileno com distribuição de massa molar ampla ou bimodal
WO2014106143A1 (en) 2012-12-28 2014-07-03 Univation Technologies, Llc Supported catalyst with improved flowability
WO2014123598A1 (en) 2013-02-07 2014-08-14 Univation Technologies, Llc Preparation of polyolefin
JP6360549B2 (ja) 2013-03-15 2018-07-18 ユニベーション・テクノロジーズ・エルエルシー オレフィン重合触媒用の三座窒素系配位子
CN105143280B (zh) 2013-03-15 2017-06-13 尤尼威蒂恩技术有限责任公司 催化剂的配体
EP3287473B1 (de) 2013-06-05 2019-10-16 Univation Technologies, LLC Schutz von phenolgruppen
ES2568615T3 (es) * 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
CN105017626B (zh) * 2014-04-15 2018-03-23 中国石化扬子石油化工有限公司 一种乙烯‑α‑烯烃共聚物、其制造方法及其应用
WO2016198273A1 (en) * 2015-06-10 2016-12-15 Borealis Ag Multimodal copolymer of ethylene and at least two alpha-olefin comonomers and final articles made thereof
CN115141300A (zh) 2015-07-08 2022-10-04 切弗朗菲利浦化学公司 乙烯共聚物和包含其的制品
US9845367B2 (en) 2015-09-24 2017-12-19 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9758599B2 (en) 2015-09-24 2017-09-12 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9540457B1 (en) 2015-09-24 2017-01-10 Chevron Phillips Chemical Company Lp Ziegler-natta—metallocene dual catalyst systems with activator-supports
WO2017069854A1 (en) * 2015-10-22 2017-04-27 Exxonmobil Chemical Patents Inc. Catalysts for the formation of multimodal polymers
WO2018106388A1 (en) 2016-12-05 2018-06-14 Exxonmobil Chemical Patents Inc. Broad orthogonal distribution metallocene polyethylenes for films
EP3692079B1 (de) 2017-10-06 2024-09-04 ExxonMobil Chemical Patents Inc. Polyethylenextrudate und verfahren zur herstellung derselben
EP3749707A1 (de) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Verbesserte verarbeitbarkeit von lldpe durch zusatz von hochdichtem polyethylen mit ultrahohem molekulargewicht
US20220289586A1 (en) * 2019-08-05 2022-09-15 Indian Institute Of Technology, Jodhpur A hydrogen-annealed bimetallic oxide and implementations thereof
BR112022004186A2 (pt) * 2019-09-26 2022-05-31 Univation Tech Llc Composição de homopolímero de polietileno bimodal, métodos para fazer a composição de homopolímero de polietileno bimodal, para fabricar um artigo fabricado, para fazer um filme extrudado e para proteger um material sensível à umidade e/ou sensível ao oxigênio, formulação, artigo fabricado, filme extrudado, e, embalagem vedada

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US52453A (en) * 1866-02-06 Improvement in rulers
US4525678A (en) * 1982-07-06 1985-06-25 Texas Instruments Incorporated Monolithic low noise common-gate amplifier
DE3678024D1 (de) 1985-03-26 1991-04-18 Mitsui Petrochemical Ind Fluessiges statisches ethylencopolymer, verfahren zur herstellung und anwendung desselben.
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4740550A (en) * 1986-06-18 1988-04-26 Shell Oil Company Multistage copolymerization process
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
TW218884B (de) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5693583A (en) 1991-06-10 1997-12-02 Mobil Oil Corporation High activity polyethylene catalysts which produce bimodal or trimodal product molecular weight distributions
CA2071706C (en) 1991-06-20 1996-09-17 Junichi Imuta Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5602067A (en) 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
ES2156153T3 (es) 1993-06-15 2001-06-16 Idemitsu Kosan Co Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.
DE4332009A1 (de) 1993-09-21 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Organometallfluoriden
US5614456A (en) 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
EP0664301A1 (de) 1994-01-24 1995-07-26 Dainichiseika Color & Chemicals Mfg. Co. Ltd. Chitosanderivate, Verfahren zu ihrer Herstellung sowie kosmetische Mittel auf der Basis von dieser Derivaten
EP0779837B1 (de) 1994-09-08 2001-08-01 Mobil Oil Corporation Katalytische kontrolle der molekulargewichtsverteilung eines breit/bimodalen harzes in einem einzigen katalytischen reaktor
US5525678A (en) 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
EP0857179A1 (de) 1995-08-18 1998-08-12 Basell Polyolefine GmbH Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
US6486089B1 (en) * 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
US5693727A (en) 1996-06-06 1997-12-02 Union Carbide Chemicals & Plastics Technology Corporation Method for feeding a liquid catalyst to a fluidized bed polymerization reactor
WO1998002247A1 (en) 1996-07-15 1998-01-22 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US6180736B1 (en) 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
EP0960144B1 (de) 1997-02-17 2002-05-29 Bayer Aktiengesellschaft Neues kalalysatorsystem, dessen verwendung zur polymerisation von dienen in lösung, suspension und gasphase und verwendung der somit herstellbaren dienkautschuke
FI111848B (fi) * 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
US6051525A (en) 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6001766A (en) * 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
US6136747A (en) 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
US6632901B2 (en) 1998-08-21 2003-10-14 Univation Technologies, Llc Polymerization process using an improved bulky ligand metallocene-type catalyst system
US6433203B1 (en) 1998-11-20 2002-08-13 Basell Technology Company Bv Bridged metallocenes, preparation, use in catalytic systems
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
US6420298B1 (en) * 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
ATE316984T1 (de) 1999-09-27 2006-02-15 Dow Global Technologies Inc Expandierte anionen enthaltende geträgertes katalysatorsystem
WO2001030861A1 (en) * 1999-10-22 2001-05-03 Univation Technologies, Llc Catalyst compositions, methods of polymerization, and polymers therefrom
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
DE10006538C2 (de) 2000-02-15 2002-11-28 Forsch Pigmente Und Lacke E V Verfahren zur Beschichtung von Partikeln mit LCST-Polymeren
US6306718B1 (en) * 2000-04-26 2001-10-23 Dallas Semiconductor Corporation Method of making polysilicon resistor having adjustable temperature coefficients
US6605675B2 (en) * 2000-12-04 2003-08-12 Univation Technologies, Llc Polymerization process
AU1790702A (en) * 2000-12-04 2002-06-18 Univaton Technologies Llc Polimerization process

Also Published As

Publication number Publication date
AU2003259802B2 (en) 2007-01-11
JP2005538216A (ja) 2005-12-15
CA2497676A1 (en) 2004-03-18
TW200422301A (en) 2004-11-01
US6943134B2 (en) 2005-09-13
PL375267A1 (en) 2005-11-28
AR041153A1 (es) 2005-05-04
EP1546212A4 (de) 2006-07-05
US6875828B2 (en) 2005-04-05
AR060201A2 (es) 2008-06-04
CN1305912C (zh) 2007-03-21
RU2005109916A (ru) 2006-01-20
MXPA05002474A (es) 2005-05-27
DE60336069D1 (de) 2011-03-31
US20050054799A1 (en) 2005-03-10
BR0314339A (pt) 2005-07-05
EP1546212A1 (de) 2005-06-29
RU2315776C2 (ru) 2008-01-27
AU2003259802A1 (en) 2004-03-29
WO2004022607A1 (en) 2004-03-18
CN1678640A (zh) 2005-10-05
EG23481A (en) 2005-11-26
US20040044154A1 (en) 2004-03-04
EP1546212B1 (de) 2011-02-16
KR100625162B1 (ko) 2006-09-18
US20050038210A1 (en) 2005-02-17
KR20050057145A (ko) 2005-06-16

Similar Documents

Publication Publication Date Title
ATE498636T1 (de) Verfahren zur herstellung eines bimodalen polyolefins und folien daraus
DE60317814D1 (de) Vorrichtung und verfahren zur abscheidung eines oxidfilms
DE60334480D1 (de) Atmungsaktive elastische mehrlagige folie und verfahren zur herstellung einer atmungsaktiven elastischen mehrlagigen folie
ATE427978T1 (de) Verfahren zur herstellung von thermoplastischen vulkanisaten und thermoplastischen vulkanisaten
ATE463471T1 (de) Verfahren und vorrichtung zur herstellung eines hydraulisch abgebundenen porenkörpers
ATE430704T1 (de) Verpackung aus schrumpffolie und verfahren zur herstellung derselben
DE60305664D1 (de) Vorrichtung und verfahren zur veränderung einer wandaussenschicht
DE60314484D1 (de) Untersuchungsverfahren und Verfahren zur Herstellung einer Vorrichtung
DE60326982D1 (de) Verfahren und vorrichtung zur herstellung von gepufftem teig extrudat
DE60315144D1 (de) Mikrolautsprecher und verfahren zur herstellung eines solchen mikrolautsprechers
DE502004003727D1 (de) Träger zur aufnahme eines gegenstandes sowie verfahren zur herstellung eines trägers
DE60304174D1 (de) Verfahren und vorrichtung zur herstellung eines luftreifens
DE60320461D1 (de) Haftklebeband und verfahren zur linsenformbearbeitung
DE50301055D1 (de) Kühlbares bauteil und verfahren zur herstellung einer durchtrittsöffnung in einem kühlbarem bauteil
DE50306521D1 (de) Schichtsystem und Verfahren zur Herstellung eines Schichtsystems
DE60305590D1 (de) Vorrichtung und Verfahren zur Herstellung eines Bauteils aus einem Metall-Keramik-Komposit
DE60335337D1 (de) Vorrichtung und Verfahren zur Herstellung von dünnen Schichten
DE60333840D1 (de) Geformte absorbierende auflagen und verfahren zur dessen herstellung
DE602004007783D1 (de) Verfahren zur herstellung eines schichtkörpers
DE60332905D1 (de) Verfahren zur Herstellung eines Kobaltsilizidfilms und zur Herstellung einer einen Kobaltsilizidfilm enthaltenden Halbleitervorrichtung
DE60321969D1 (de) Verfahren und vorrichtung zur herstellung eines reifenbestandteiles
ATE406992T1 (de) Verfahren und vorrichtung zur herstellung von kunststoffprofilen
DE60327364D1 (de) Verfahren und vorrichtung zur herstellung von verpackungen
DE502004007497D1 (de) Verfahren und vorrichtung zur herstellung eines strukturierten blechbandes
DE602004019835D1 (de) Träger und Verfahren zur Herstellung eines Trägers

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties