AR090331A1 - Arilpirrolidinas pesticidas - Google Patents
Arilpirrolidinas pesticidasInfo
- Publication number
- AR090331A1 AR090331A1 ARP130100817A ARP130100817A AR090331A1 AR 090331 A1 AR090331 A1 AR 090331A1 AR P130100817 A ARP130100817 A AR P130100817A AR P130100817 A ARP130100817 A AR P130100817A AR 090331 A1 AR090331 A1 AR 090331A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- amino
- haloalkyl
- haloalkoxy
- alkoxy
- Prior art date
Links
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 14
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 12
- 125000004641 (C1-C12) haloalkyl group Chemical group 0.000 abstract 11
- 125000000217 alkyl group Chemical group 0.000 abstract 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 8
- -1 nitro, cyano, hydroxy, mercapto, amino Chemical group 0.000 abstract 8
- 229910052739 hydrogen Inorganic materials 0.000 abstract 6
- 239000001257 hydrogen Substances 0.000 abstract 6
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 abstract 5
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 5
- 125000001188 haloalkyl group Chemical group 0.000 abstract 5
- 125000000623 heterocyclic group Chemical group 0.000 abstract 5
- 150000002431 hydrogen Chemical class 0.000 abstract 5
- 125000004643 (C1-C12) haloalkoxy group Chemical group 0.000 abstract 4
- 125000003282 alkyl amino group Chemical group 0.000 abstract 4
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 4
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 abstract 4
- 125000005347 halocycloalkyl group Chemical group 0.000 abstract 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract 4
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000004647 alkyl sulfenyl group Chemical group 0.000 abstract 3
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 3
- 125000000304 alkynyl group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 3
- 125000004440 haloalkylsulfinyl group Chemical group 0.000 abstract 3
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical group 0.000 abstract 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 2
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 2
- BPFZRKQDXVZTFD-UHFFFAOYSA-N disulfur decafluoride Chemical compound FS(F)(F)(F)(F)S(F)(F)(F)(F)F BPFZRKQDXVZTFD-UHFFFAOYSA-N 0.000 abstract 2
- 125000004992 haloalkylamino group Chemical group 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052717 sulfur Chemical group 0.000 abstract 2
- 239000011593 sulfur Chemical group 0.000 abstract 2
- 241000239223 Arachnida Species 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 abstract 1
- 241000237852 Mollusca Species 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 abstract 1
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 1
- 125000004461 halocycloalkylalkyl group Chemical group 0.000 abstract 1
- 244000000013 helminth Species 0.000 abstract 1
- 238000003898 horticulture Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- RESCIWUZWYWXFH-UHFFFAOYSA-N pentafluorosulfanylamine Chemical compound NS(F)(F)(F)(F)F RESCIWUZWYWXFH-UHFFFAOYSA-N 0.000 abstract 1
- 125000000464 thioxo group Chemical group S=* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D207/10—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/12—Oxygen or sulfur atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Veterinary Medicine (AREA)
- Agronomy & Crop Science (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pharmacology & Pharmacy (AREA)
- Tropical Medicine & Parasitology (AREA)
- General Chemical & Material Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Medicinal Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyrrole Compounds (AREA)
Abstract
Reivindicación 1: Compuestos de la fórmula (1), en donde R¹ es alquilo C₁₋₁₂, cicloalquilo C₃₋₈, haloalquilo C₁₋₁₂, halocicloalquilo C₃₋₈; R² es oxo y/o tioxo y n es 1 ó 2, si la línea de trazos en la fórmula (1) representa un enlace, de modo que R² está unido mediante un enlace doble al anillo de pirrolidina; o R² independientemente es halógeno, nitro, ciano, hidroxi, mercapto, amino, alquilo C₁₋₁₂, haloalquilo C₁₋₁₂, alcoxi C₁₋₁₂, haloalcoxi C₁₋₁₂, alquilsulfenilo C₁₋₁₂, alquilsulfinilo C₁₋₁₂, alquilsulfonilo C₁₋₁₂, haloalquilsulfenilo C₁₋₁₂, haloalquilsulfinilo C₁₋₁₂, haloalquilsulfonilo C₁₋₁₂, pentafluoruro de azufre, alcoxi C₁₋₁₂-carbonilo, haloalcoxi C₁₋₁₂-carbonilo, alcoxi C₁₋₁₂-carboniloxi o haloalcoxi C₁₋₁₂-carboniloxi, n es 1 ó 2, si la línea de trazos en la fórmula (1) no tiene significado, de modo que R² está unido mediante un enlace simple al anillo de pirrolidina; A es C-X³ o nitrógeno; X¹, X², X³ y X⁴ cada uno independientemente son hidrógeno, halógeno, nitro, ciano, hidroxi, mercapto, amino, alquilo C₁₋₁₂, haloalquilo C₁₋₁₂, alcoxi C₁₋₁₂, haloalcoxi C₁₋₁₂, alquilsulfenilo C₁₋₁₂, alquilsulfinilo C₁₋₁₂, alquilsulfonilo C₁₋₁₂, haloalquilsulfenilo C₁₋₁₂, haloalquilsulfinilo C₁₋₁₂, haloalquilsulfonilo C₁₋₁₂, alquilamino C₁₋₁₂, di(alquil C₁₋₁₂)amino, haloalquilamino C₁₋₁₂, di(haloalquil C₁₋₁₂)amino, (alquil C₁₋₁₂)(haloalquil C₁₋₁₂)amino o pentafluoruro de azufre; B¹ es C-Y¹ o nitrógeno; B³ es C-Y³ o nitrógeno; B⁴ es C-Y⁴ o nitrógeno; Y¹, Y³ e Y⁴ cada uno independientemente son hidrógeno, halógeno, nitro, ciano, hidroxi, mercapto, amino, alquilo C₁₋₁₂, haloalquilo C₁₋₁₂, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alcoxi C₁₋₁₂, haloalcoxi C₁₋₁₂, alquilsulfenilo C₁₋₁₂, alquilsulfinilo C₁₋₁₂, alquilsulfonilo C₁₋₁₂, haloalquilsulfenilo C₁₋₁₂, haloalquilsulfinilo C₁₋₁₂, haloalquilsulfonilo C₁₋₁₂, alquilamino C₁₋₁₂, di(alquil C₁₋₁₂)amino, haloalquilamino C₁₋₁₂, di(haloalquil C₁₋₁₂)amino, (alquil C₁₋₁₂)(haloalquil C₁₋₁₂)amino, pentafluoruro de azufre, arilo o heterociclilo; R³ es hidrógeno, ciano, hidroxi, mercapto, amino, alquilo C₁₋₁₂, haloalquilo C₁₋₁₂, alquenilo C₂₋₁₂, haloalquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquil C₁₋₁₂-carbonilo, haloalquil C₁₋₁₂-carbonilo, alcoxi C₁₋₁₂-carbonilo o haloalcoxi C₁₋₁₂-carbonilo, alcoxi C₁₋₁₂-alquilo C₁₋₁₂, o ciano-alquilo C₁₋₁₂; R⁶ es hidrógeno o alquilo C₁₋₆; R⁷ es hidrógeno, o alquilo C₁₋₁₂, cianoalquilo C₁₋₁₂ y haloalquilo C₁₋₁₂ opcionalmente sustituidos, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₁₂ y halocicloalquil C₃₋₈-alquilo C₁₋₁₂ opcionalmente sustituidos, alquenilo C₂₋₁₂, haloalquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alcoxi C₁₋₁₂, haloalcoxi C₁₋₁₂, alcoxi C₁₋₁₂-alquilo C₁₋₁₂, haloalcoxi C₁₋₁₂-alquilo C₁₋₁₂, alquil C₁₋₁₂-S-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S-alquilo C₁₋₁₂, alquil C₁₋₁₂-S(O)-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S(O)-alquilo C₁₋₁₂, alquil C₁₋₁₂-S(O)₂-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S(O)₂-alquilo C₁₋₁₂, amino, alquilamino C₁₋₁₂, di(alquil C₁₋₁₂)amino, haloalquilamino C₁₋₁₂, di(haloalquil C₁₋₁₂)amino, (alquil C₁₋₁₂)(haloalquil C₁₋₁₂)amino, arilo y aril-alquilo C₁₋₁₂ opcionalmente sustituidos, un grupo heterocíclico opcionalmente sustituido, alquilo C₁₋₁₂ sustituido con un grupo heterocíclico, alquil C₁₋₁₂-carbonilo, haloalquil C₁₋₁₂-carbonilo o (R⁸)(R⁹)N-CO-; R⁸ y R⁹ cada uno independientemente son hidrógeno, ciano, hidroxi, amino, alquilo C₁₋₁₂, haloalquilo C₁₋₁₂, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₁₂, halocicloalquil C₃₋₈-alquilo C₁₋₁₂, alquenilo C₂₋₁₂, haloalquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alcoxi C₁₋₁₂, haloalcoxi C₁₋₁₂, alcoxi C₁₋₁₂-alquilo C₁₋₁₂, haloalcoxi C₁₋₁₂-alquilo C₁₋₁₂, alquil C₁₋₁₂-S-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S-alquilo C₁₋₁₂, alquil C₁₋₁₂-S(O)-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S(O)-alquilo C₁₋₁₂, alquil C₁₋₁₂-S(O)₂-alquilo C₁₋₁₂, haloalquil C₁₋₁₂-S(O)₂-alquilo C₁₋₁₂, alquilsulfonilo C₁₋₁₂, haloalquilsulfonilo C₁₋₁₂, alquilamino C₁₋₁₂, di(alquil C₁₋₁₂)amino, haloalquil C₁₋₁₂-amino, di(haloalquil C₁₋₁₂)amino, (alquil C₁₋₁₂)(haloalquil C₁₋₁₂)amino, cianoalquilo C₁₋₁₂, ciano-cicloalquilo C₃₋₈, arilo, aril-alquilo C₁₋₁₂, un grupo heterocíclico o alquilo C₁₋₁₂ sustituido con un grupo heterocíclico; W es oxígeno o azufre; E es oxígeno, azufre o un grupo alcanodiilo C₁₋₃ cuyo grupo puede estar opcionalmente sustituido con 1 ó 2 grupos alquilo C₁₋₆. Reivindicación 12: Uso de los compuestos de acuerdo con cualquiera de las reivindicaciones 1 a 7 para controlar insectos, arácnidos, helmintos, nemátodos y moluscos que se encuentran en la agricultura, en la horticultura, en la producción animal, en bosques, en jardines y en instalaciones de ocio, en la protección de productos almacenados y de materiales y en el sector de higiene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12159494 | 2012-03-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR090331A1 true AR090331A1 (es) | 2014-11-05 |
Family
ID=47844396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130100817A AR090331A1 (es) | 2012-03-14 | 2013-03-13 | Arilpirrolidinas pesticidas |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9206122B2 (es) |
| EP (1) | EP2825532A1 (es) |
| JP (1) | JP2015515454A (es) |
| CN (1) | CN104321317B (es) |
| AR (1) | AR090331A1 (es) |
| BR (1) | BR112014021674A2 (es) |
| TW (1) | TW201400452A (es) |
| WO (1) | WO2013135724A1 (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107835803A (zh) | 2015-05-13 | 2018-03-23 | 拜耳作物科学股份公司 | 杀昆虫的芳基吡咯烷、其制备方法及其作为试剂用于防治动物害虫的用途 |
| CN115136957B (zh) * | 2021-03-30 | 2024-04-16 | 江苏食叶草农业开发有限公司 | 一种食叶草种植用除草剂及其制备方法 |
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-
2013
- 2013-03-12 CN CN201380014040.5A patent/CN104321317B/zh not_active Expired - Fee Related
- 2013-03-12 TW TW102108571A patent/TW201400452A/zh unknown
- 2013-03-12 BR BR112014021674A patent/BR112014021674A2/pt not_active IP Right Cessation
- 2013-03-12 US US14/384,840 patent/US9206122B2/en not_active Expired - Fee Related
- 2013-03-12 EP EP13708503.1A patent/EP2825532A1/en not_active Withdrawn
- 2013-03-12 WO PCT/EP2013/055042 patent/WO2013135724A1/en not_active Ceased
- 2013-03-12 JP JP2014561425A patent/JP2015515454A/ja active Pending
- 2013-03-13 AR ARP130100817A patent/AR090331A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW201400452A (zh) | 2014-01-01 |
| WO2013135724A1 (en) | 2013-09-19 |
| EP2825532A1 (en) | 2015-01-21 |
| CN104321317B (zh) | 2016-09-21 |
| CN104321317A (zh) | 2015-01-28 |
| US20150025253A1 (en) | 2015-01-22 |
| BR112014021674A2 (pt) | 2019-09-24 |
| US9206122B2 (en) | 2015-12-08 |
| JP2015515454A (ja) | 2015-05-28 |
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