AT38330B - Method for the representation of Santalo ethers. - Google Patents
Method for the representation of Santalo ethers.Info
- Publication number
- AT38330B AT38330B AT38330DA AT38330B AT 38330 B AT38330 B AT 38330B AT 38330D A AT38330D A AT 38330DA AT 38330 B AT38330 B AT 38330B
- Authority
- AT
- Austria
- Prior art keywords
- ethers
- santalo
- representation
- santalol
- parts
- Prior art date
Links
- 150000002170 ethers Chemical class 0.000 title claims 2
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 claims 2
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 229940100198 alkylating agent Drugs 0.000 claims 1
- 239000002168 alkylating agent Substances 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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die Benzollösung mit kalter verdünnter Natronlauge und dann mit Wasser gewaschen. Nach dem Trocknen der Lösung über Chlorkalzium wird das Benzol abgetrieben und der Rantalylphenyl- äther durch fraktionierte Destillation im Vakuum gereinigt. Das neue Produkt bildet ein gelbliches dickes 01 von mildem Geschmack, das unter einem Druck von 20 ww bei 232 bis 2410 siedet. ist fast unlöslich in Wasser, löslich in Alkohol, Äther und Chloroform.
Beispiel 7 : 156 Teile Menthol werden in 500 Teilen Xylol gelöst und durch Erhitzen mit 23 Teilen Natrium in die Natriumverbindung verwandelt. Man fügt darauf 238,5 Teile Santaly'-
EMI2.1
Benzol abgetrieben und der Rückstand im Vakuum destilliert. Der Santalylmenthyläther bildet einen farblosen dicken Syrup von mildem Geschmack und schwach aromatischen Geruch. Er
EMI2.2
selbstzurVerwendunggelangen.
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<Desc / Clms Page number 2>
the benzene solution was washed with cold dilute sodium hydroxide solution and then with water. After the solution has been dried over calcium chloride, the benzene is driven off and the rantalylphenyl ether is purified by fractional distillation in vacuo. The new product forms a yellowish, thick oil with a mild taste that boils at 232 to 2410 under a pressure of 20 ww. is almost insoluble in water, soluble in alcohol, ether and chloroform.
Example 7: 156 parts of menthol are dissolved in 500 parts of xylene and converted into the sodium compound by heating with 23 parts of sodium. 238.5 parts of Santaly'-
EMI2.1
Driven off benzene and the residue distilled in vacuo. The santalyl menthyl ether forms a colorless, thick syrup with a mild taste and a faintly aromatic odor. He
EMI2.2
get to use yourself.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1907202352D DE202352C (en) | 1907-03-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT38330B true AT38330B (en) | 1909-08-10 |
Family
ID=5771044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT38330D AT38330B (en) | 1907-03-16 | 1908-10-10 | Method for the representation of Santalo ethers. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT38330B (en) |
-
1908
- 1908-10-10 AT AT38330D patent/AT38330B/en active
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