ATE115596T1 - Verfahren zur herstellung von epoxyendgruppen enthaltenden polyoxazolidonen sowie von elektrischen laminaten daraus. - Google Patents
Verfahren zur herstellung von epoxyendgruppen enthaltenden polyoxazolidonen sowie von elektrischen laminaten daraus.Info
- Publication number
- ATE115596T1 ATE115596T1 AT90909068T AT90909068T ATE115596T1 AT E115596 T1 ATE115596 T1 AT E115596T1 AT 90909068 T AT90909068 T AT 90909068T AT 90909068 T AT90909068 T AT 90909068T AT E115596 T1 ATE115596 T1 AT E115596T1
- Authority
- AT
- Austria
- Prior art keywords
- polyoxazolidones
- manufacture
- percent
- containing epoxy
- electrical laminates
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000004593 Epoxy Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 2
- WDGCBNTXZHJTHJ-UHFFFAOYSA-N 2h-1,3-oxazol-2-id-4-one Chemical group O=C1CO[C-]=N1 WDGCBNTXZHJTHJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0036—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/003—Polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/28—Di-epoxy compounds containing acyclic nitrogen atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/02—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/12—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2363/00—Epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Thermal Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Resins (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Paints Or Removers (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898912952A GB8912952D0 (en) | 1989-06-06 | 1989-06-06 | Epoxy-terminated polyoxazolidones,process for the preparation thereof and electrical laminates made from the epoxy-terminated polyoxazolidones |
| SG9590553 | 1995-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE115596T1 true ATE115596T1 (de) | 1994-12-15 |
Family
ID=26295443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT90909068T ATE115596T1 (de) | 1989-06-06 | 1990-05-25 | Verfahren zur herstellung von epoxyendgruppen enthaltenden polyoxazolidonen sowie von elektrischen laminaten daraus. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5112932A (de) |
| EP (1) | EP0478606B1 (de) |
| JP (1) | JP2859956B2 (de) |
| KR (1) | KR0160755B1 (de) |
| AT (1) | ATE115596T1 (de) |
| AU (1) | AU628596B2 (de) |
| BR (1) | BR9007428A (de) |
| CA (1) | CA2018265A1 (de) |
| DE (1) | DE69015188T2 (de) |
| DK (1) | DK0478606T3 (de) |
| ES (1) | ES2067030T3 (de) |
| GB (1) | GB8912952D0 (de) |
| NZ (1) | NZ233933A (de) |
| WO (1) | WO1990015089A1 (de) |
Families Citing this family (124)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3322909B2 (ja) * | 1991-08-15 | 2002-09-09 | 旭化成エポキシ株式会社 | エポキシ樹脂組成物 |
| JP3290449B2 (ja) | 1991-08-19 | 2002-06-10 | 旭化成エポキシ株式会社 | エポキシ樹脂組成物 |
| JP3345687B2 (ja) | 1991-12-06 | 2002-11-18 | 日本ペイント株式会社 | オキサゾリドン環含有水性樹脂および塗料 |
| DE4223630A1 (de) * | 1992-07-17 | 1994-01-20 | Siemens Ag | Oxazolidinonstrukturen aufweisende präpolymere Epoxidharzmischung |
| DE4223632A1 (de) | 1992-07-17 | 1994-01-20 | Siemens Ag | Verfahren zur Herstellung einer flammwidrig eingestellten Epoxidharzformmasse |
| DE4223622A1 (de) * | 1992-07-17 | 1994-01-20 | Siemens Ag | Oxazolidinonstrukturen aufweisende präpolymere Epoxidharzmischung |
| JP3355658B2 (ja) | 1992-08-13 | 2002-12-09 | 旭化成エポキシ株式会社 | エポキシ樹脂組成物 |
| US5314983A (en) * | 1992-11-09 | 1994-05-24 | Enichem S.P.A. | Process for curing polymerizable liquid compositions based on polyisocyanates and epoxides |
| US5290903A (en) * | 1992-11-09 | 1994-03-01 | Norton Company | Composite abrasive wheels |
| CA2115533C (en) * | 1994-02-11 | 2002-06-18 | Hiroshi Uchida | Urethane modified epoxy resin compositions |
| US5545697A (en) * | 1994-02-14 | 1996-08-13 | Ciba-Geigy Corporation | Urethane modified epoxy resin compositions |
| US5480958A (en) | 1994-09-21 | 1996-01-02 | Air Products And Chemicals, Inc. | Polyepoxide resins incorporating epoxy terminated urethanes as tougheners |
| KR19990021907A (ko) * | 1995-05-24 | 1999-03-25 | 디어터 크리스트, 베르너 뵈켈 | 할로겐을 함유하지 않는 난연성 에폭시수지 성형재료 |
| US5686541A (en) * | 1995-11-14 | 1997-11-11 | National Science Council | Modification of epoxy resins with urethane prepolymer for electronic encapsulation |
| GB2315490B (en) * | 1996-07-22 | 2001-02-07 | Dow Deutschland Inc | Improved curing catalysts for curing epoxy resins |
| DE69829465T2 (de) * | 1997-03-27 | 2006-02-09 | Mitsubishi Rayon Co., Ltd. | Epoxidharzzusammensetzung für faserverstärkte kunststoffe, prepeg, und daraus hergestellter schlauchförmiger formkörper |
| US6353080B1 (en) | 1997-06-26 | 2002-03-05 | The Dow Chemical Company | Flame retardant epoxy resin composition |
| GB9817799D0 (en) | 1998-08-14 | 1998-10-14 | Dow Deutschland Inc | Viscosity modifier for thermosetting resin compositioning |
| GB9827367D0 (en) | 1998-12-11 | 1999-02-03 | Dow Deutschland Inc | Adhesive resin composition |
| KR101148353B1 (ko) | 2004-05-28 | 2012-05-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 내인화성 할로겐 무함유 중합체의 제조에 유용한 인 함유화합물 |
| KR100866653B1 (ko) * | 2004-06-29 | 2008-11-04 | 아사히 가세이 케미칼즈 가부시키가이샤 | 난연성 에폭시 수지 조성물 |
| KR100856186B1 (ko) * | 2005-04-07 | 2008-09-03 | 아사히 가세이 케미칼즈 가부시키가이샤 | 에폭시 수지 조성물 |
| EP1818044A1 (de) | 2005-11-25 | 2007-08-15 | DSMIP Assets B.V. | Kosmetische Zusammensetzung enthaltend ein Polymer mit Oxazolidongruppen |
| BRPI0621083A2 (pt) * | 2005-12-22 | 2011-11-29 | Dow Global Technologies Inc | composição de resina epóxi curável contendo halogênio, artigo compósito reforçado com fibra, componente de circuito elétrico, processo para produzir um artigo revestido, pré- impregnado, laminado, placa de circuito impresso (pcb), processo para preparar um artigo revestido com resina, e artigo revestido com resina |
| BRPI0810290A2 (pt) * | 2007-05-09 | 2014-11-04 | Dow Global Technologies Inc | "processo para curar uma composição termofixa, composição termofixa e processo para formar um compósito." |
| KR20100024936A (ko) * | 2007-05-16 | 2010-03-08 | 다우 글로벌 테크놀로지스 인크. | 난연성 조성물 |
| KR101467609B1 (ko) | 2007-06-20 | 2014-12-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 온도 변화에 대한 민감도가 매우 낮은 충돌 내구성 에폭시 접착제 |
| KR20100058521A (ko) * | 2007-08-02 | 2010-06-03 | 다우 글로벌 테크놀로지스 인크. | 열경화된 완충재 |
| CN101802037A (zh) * | 2007-09-11 | 2010-08-11 | 陶氏环球技术公司 | 熔融粘结的环氧泡沫体涂敷用的异氰酸酯改性的环氧树脂 |
| CN101878239B (zh) * | 2007-09-28 | 2014-06-18 | 陶氏环球技术有限责任公司 | 环氧树脂配制物 |
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| CN101878101A (zh) | 2007-11-29 | 2010-11-03 | 陶氏环球技术公司 | 可微波加热的单乙烯基芳族聚合物 |
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| US7947785B2 (en) * | 2009-05-21 | 2011-05-24 | New Jersey Institute Of Technology | Polyoxazolidones derived from bisanhydrohexitols |
| KR100929380B1 (ko) * | 2009-06-18 | 2009-12-02 | 주식회사 신아티앤씨 | 난연성 폴리에폭시 화합물의 제조방법 |
| CN106832224A (zh) | 2009-06-22 | 2017-06-13 | 蓝立方知识产权有限责任公司 | 环氧树脂的硬化剂组合物 |
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| JP5715638B2 (ja) | 2009-11-05 | 2015-05-13 | ダウ グローバル テクノロジーズ エルエルシー | ケトオキシムでキャップされたエラストマー強化剤を含む構造用エポキシ樹脂系接着剤 |
| CN105713179A (zh) | 2009-11-12 | 2016-06-29 | 陶氏环球技术有限责任公司 | 聚噁唑烷酮树脂 |
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| BR112012028252A2 (pt) | 2010-06-29 | 2016-08-02 | Dow Global Technologies Llc | composição de catalisador termo-ativável, adesivo de epóxi monocomponente e processo para preparar um catalisador de amina |
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| US3305494A (en) * | 1963-04-12 | 1967-02-21 | Baker Chem Co J T | Oxazolidonyl sulfones and method of making same |
| US3334110A (en) * | 1965-08-16 | 1967-08-01 | Baker Chem Co J T | Method for preparing epoxyoxazolidinones |
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| US3471442A (en) * | 1967-02-02 | 1969-10-07 | American Cyanamid Co | Process for the preparation of thermoplastic polymers prepared by reacting diepoxide monomers with aromatic diisocyanates |
| US3694406A (en) * | 1970-07-31 | 1972-09-26 | Us Air Force | Preparation of polyoxazolidones |
| US3767624A (en) * | 1971-12-27 | 1973-10-23 | Dow Chemical Co | Oxazolidinone modified epoxy novolac resin |
| JPS5231000B2 (de) * | 1972-11-29 | 1977-08-11 | ||
| JPS5315757B2 (de) * | 1973-08-31 | 1978-05-26 | ||
| JPS57131219A (en) * | 1981-02-06 | 1982-08-14 | Sumitomo Bakelite Co Ltd | Thermosetting resin composition |
| ZA839459B (en) * | 1982-12-30 | 1985-08-28 | Mobil Oil Corp | Polyoxazolidone powder coating compositions |
| DE3323122A1 (de) * | 1983-06-27 | 1985-05-23 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur herstellung von reaktionsharzformstoffen |
| FR2549277B1 (fr) * | 1983-07-13 | 1985-10-25 | Alsthom Atlantique | Procede d'isolation par impregnation d'un bobinage electrique, et vernis sans solvant stabilise utilisable dans ce procede |
| GB8412900D0 (en) * | 1984-05-21 | 1984-06-27 | Secr Defence | Thermosetting resin compositions |
| DE3720759A1 (de) * | 1987-06-24 | 1989-01-05 | Bayer Ag | Oxazolidongruppen enthaltende epoxidharze |
-
1989
- 1989-06-06 GB GB898912952A patent/GB8912952D0/en active Pending
-
1990
- 1990-05-25 JP JP2508802A patent/JP2859956B2/ja not_active Expired - Lifetime
- 1990-05-25 AT AT90909068T patent/ATE115596T1/de active
- 1990-05-25 DK DK90909068.0T patent/DK0478606T3/da active
- 1990-05-25 BR BR909007428A patent/BR9007428A/pt not_active IP Right Cessation
- 1990-05-25 EP EP90909068A patent/EP0478606B1/de not_active Expired - Lifetime
- 1990-05-25 ES ES90909068T patent/ES2067030T3/es not_active Expired - Lifetime
- 1990-05-25 WO PCT/US1990/002973 patent/WO1990015089A1/en not_active Ceased
- 1990-05-25 DE DE69015188T patent/DE69015188T2/de not_active Expired - Lifetime
- 1990-05-25 AU AU58291/90A patent/AU628596B2/en not_active Ceased
- 1990-06-01 US US07/531,963 patent/US5112932A/en not_active Expired - Lifetime
- 1990-06-05 CA CA002018265A patent/CA2018265A1/en not_active Abandoned
- 1990-06-05 NZ NZ233933A patent/NZ233933A/en unknown
-
1991
- 1991-12-06 KR KR1019910701786A patent/KR0160755B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2067030T3 (es) | 1995-03-16 |
| BR9007428A (pt) | 1992-07-21 |
| US5112932A (en) | 1992-05-12 |
| WO1990015089A1 (en) | 1990-12-13 |
| JPH04506678A (ja) | 1992-11-19 |
| AU628596B2 (en) | 1992-09-17 |
| DK0478606T3 (da) | 1995-05-15 |
| CA2018265A1 (en) | 1990-12-06 |
| DE69015188D1 (de) | 1995-01-26 |
| JP2859956B2 (ja) | 1999-02-24 |
| GB8912952D0 (en) | 1989-07-26 |
| EP0478606A1 (de) | 1992-04-08 |
| EP0478606A4 (en) | 1992-05-13 |
| EP0478606B1 (de) | 1994-12-14 |
| KR920701289A (ko) | 1992-08-11 |
| DE69015188T2 (de) | 1995-05-04 |
| AU5829190A (en) | 1991-01-07 |
| NZ233933A (en) | 1993-05-26 |
| KR0160755B1 (en) | 1999-01-15 |
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