ATE137247T1 - Addition von alkylaluminium zum verbessern eines metallocenkatalysators - Google Patents

Addition von alkylaluminium zum verbessern eines metallocenkatalysators

Info

Publication number
ATE137247T1
ATE137247T1 AT90870175T AT90870175T ATE137247T1 AT E137247 T1 ATE137247 T1 AT E137247T1 AT 90870175 T AT90870175 T AT 90870175T AT 90870175 T AT90870175 T AT 90870175T AT E137247 T1 ATE137247 T1 AT E137247T1
Authority
AT
Austria
Prior art keywords
catalyst
metallocene catalyst
improve
ionic
addition
Prior art date
Application number
AT90870175T
Other languages
English (en)
Inventor
John A Ewen
Michael J Elder
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23661319&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE137247(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fina Technology filed Critical Fina Technology
Application granted granted Critical
Publication of ATE137247T1 publication Critical patent/ATE137247T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT90870175T 1989-10-30 1990-10-09 Addition von alkylaluminium zum verbessern eines metallocenkatalysators ATE137247T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41922289A 1989-10-30 1989-10-30

Publications (1)

Publication Number Publication Date
ATE137247T1 true ATE137247T1 (de) 1996-05-15

Family

ID=23661319

Family Applications (1)

Application Number Title Priority Date Filing Date
AT90870175T ATE137247T1 (de) 1989-10-30 1990-10-09 Addition von alkylaluminium zum verbessern eines metallocenkatalysators

Country Status (9)

Country Link
US (2) US5519100A (de)
EP (1) EP0426638B2 (de)
JP (1) JP2939321B2 (de)
KR (1) KR100196613B1 (de)
CN (2) CN1037686C (de)
AT (1) ATE137247T1 (de)
CA (1) CA2027122C (de)
DE (1) DE69026679T3 (de)
ES (1) ES2086397T5 (de)

Families Citing this family (226)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
IE904007A1 (en) * 1989-11-08 1991-05-08 Mount Isa Mines Condensation of metal vapours in a fluidized bed
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
DE69130320T2 (de) * 1990-07-24 1999-04-08 Mitsui Chemicals Inc Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
EP0548274B1 (de) * 1990-09-14 1996-02-28 Exxon Chemical Patents Inc. Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität
EP0513380B2 (de) † 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Verfahren zur herstellung von olefinpolymeren
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
TW300901B (de) 1991-08-26 1997-03-21 Hoechst Ag
TW309523B (de) * 1991-11-30 1997-07-01 Hoechst Ag
CA2105555C (en) * 1992-01-06 2003-12-30 Brian W. S. Kolthammer Improved catalyst composition
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
BE1005957A5 (fr) 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
US5434116A (en) 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
EP0587440A3 (de) * 1992-09-10 1995-03-08 Nippon Oil Co Ltd Katalysatorbestandteil für Olefinpolymerisation und Olefinpolymerisationsverfahren unter Anwendung derselben.
US5461127A (en) * 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
ES2136132T3 (es) * 1992-10-05 1999-11-16 Exxon Chemical Patents Inc Procedimiento de polimerizacion que emplea un sistema catalizador con productividad mejorada.
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
BE1006438A3 (fr) * 1992-12-17 1994-08-30 Solvay Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
GB9226905D0 (en) 1992-12-24 1993-02-17 Wellcome Found Pharmaceutical preparation
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
BE1006880A3 (fr) 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
JP3189175B2 (ja) * 1993-07-02 2001-07-16 出光興産株式会社 芳香族ビニル化合物共重合体の製造方法
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
FI945959L (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
DE69506821T2 (de) * 1994-04-11 1999-06-10 Mitsui Chemicals, Inc., Tokio/Tokyo Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
DE69511023T2 (de) * 1994-04-11 2000-01-27 Mitsui Chemicals, Inc. Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
DE4424227A1 (de) 1994-07-09 1996-01-11 Hoechst Ag Organometallverbindung
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
DE4434640C1 (de) 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
DE4436113A1 (de) 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
EP0710663A1 (de) 1994-11-01 1996-05-08 Japan Polyolefins Co., Ltd. Borenthaltende Verbindung, sein Polymer, diese Polymer und ein Metallocen enthaltender Katalysator und ein Verfahren zur Herstellung eines Polyolefins
CA2183650C (en) * 1994-12-20 2006-01-03 Toshiyuki Tsutsui Process for preparing ethylene polymer and ethylene polymer
CN1076282C (zh) 1995-03-02 2001-12-19 三井化学株式会社 聚丙烯复合膜
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
WO1997010296A1 (en) 1995-09-13 1997-03-20 Mitsui Petrochemical Industries, Ltd. Resin composition and use thereof
JP3176932B2 (ja) * 1995-10-18 2001-06-18 チッソ株式会社 オレフィン(共)重合体組成物とその製造方法及びオレフィン(共)重合用触媒とその製造方法
DE19546501A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
DE19546500A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Verfahren zur Herstellung eines Cycloolefincopolymeren
AR005066A1 (es) 1995-12-15 1999-04-07 Union Carbide Chem Plastic Un procedimiento para hacer un homopolimero, copolimero o terpolimero de polietileno con ramificacion de cadena larga, una composicion de polietilenoasi obtenida y un articulo de pelicula o moldeado por inyeccion que comprende dicha composicion.
DE19549352A1 (de) * 1995-12-22 1997-06-26 Gerhard Edwin Herberich Übergangsmetallverbindung der Formel Ln Am MXK (M=Metall der Gruppe IIIb oder Vb) und Verfahren zur Herstellung der Verbindung sowie Verwendung der Verbindung als Katalysatorkomponente bei der Polymerisation von Olefinen
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
US6231804B1 (en) 1997-04-02 2001-05-15 Chisso Corporation Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
US6025407A (en) * 1997-10-30 2000-02-15 Occidental Chemical Corporation Photo-polymerization of vinyl chloride using metallocene catalysts
FI980342A0 (fi) * 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
US6300433B1 (en) * 1998-10-23 2001-10-09 Exxonmobil Chemical Patents Inc. Olefin copolymerization process with bridged hafnocenes
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
JP2000351813A (ja) 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6291386B1 (en) * 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
JP3808243B2 (ja) 1999-07-27 2006-08-09 三井化学株式会社 軟質樹脂組成物
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
KR100854012B1 (ko) 2000-01-26 2008-08-26 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체
CN1128168C (zh) 2000-03-31 2003-11-19 三井化学株式会社 聚烯烃组合物的制备方法
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US6635733B2 (en) 2000-05-23 2003-10-21 Chisso Corporation Elastomeric polypropylene
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
TW541318B (en) 2000-07-04 2003-07-11 Mitsui Chemicals Inc Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
EP1296993B1 (de) 2000-07-06 2005-01-26 Basf Aktiengesellschaft Metallverbindungen und ihre verwendung zur polymerisation von olefinen
EP1241194B1 (de) 2000-07-26 2013-09-04 Mitsui Chemicals, Inc. Polymer und verfahren zu dessen herstellung
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
US20020156207A1 (en) 2000-09-07 2002-10-24 Junichi Imuta Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
KR100844062B1 (ko) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
ATE337343T1 (de) 2001-04-30 2006-09-15 Grace W R & Co Geträgerte dualübergangsmetallkatalysatorsysteme
KR100540049B1 (ko) 2001-04-30 2006-01-20 더블유.알. 그레이스 앤드 캄파니-콘. 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
WO2002088196A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
KR100880476B1 (ko) 2001-04-30 2009-01-28 더블유.알. 그레이스 앤드 캄파니-콘. 크롬 지지체-응집물을 사용하는 배위 촉매 시스템 및 그의제조방법
US7220801B2 (en) 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
JP3865314B2 (ja) 2001-10-19 2007-01-10 旭化成ケミカルズ株式会社 オレフィンの重合方法
DE10211386A1 (de) 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
ATE377033T1 (de) 2002-07-31 2007-11-15 Exxonmobil Chem Patents Inc Silanvernetztes polyethylen
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
ATE395379T1 (de) 2002-09-05 2008-05-15 Exxonmobil Chem Patents Inc Schrumpffolie
EP1539866B1 (de) 2002-09-05 2011-01-05 ExxonMobil Chemical Patents Inc. Stretchfoliewickelverfahren
KR100456396B1 (ko) * 2002-09-17 2004-11-10 삼성전자주식회사 반도체 소자 테스트 장치의 프로브 팁 샌딩 제어방법 및샌딩 제어장치
EP2465879B1 (de) 2002-09-27 2019-04-24 Mitsui Chemicals, Inc. Verbrückte Metallocenverbindung zur Olefinpolymerisierung und Verfahren zur Polymerisierung von Olefin unter Verwendung davon
US7253132B2 (en) 2002-10-23 2007-08-07 Mitsui Chemicals, Inc. Magnesium-containing carrier components and application thereof to olefin polymerization
DE10251513A1 (de) 2002-11-04 2004-05-19 Basf Ag Übergangsmetallkatalysatoren für (Co)Polymerisation von olefinischen Monomeren
KR101087179B1 (ko) 2003-03-28 2011-11-25 미쓰이 가가쿠 가부시키가이샤 폴리올레핀 수지 조성물
DE602005017243D1 (de) 2004-01-28 2009-12-03 Idemitsu Kosan Co Inpolymerisierung
EP1661921B1 (de) 2004-11-26 2019-07-17 Mitsui Chemicals, Inc. Synthetische Schmieröle und Schmierölzusammensetzung deren
WO2006068308A1 (ja) * 2004-12-22 2006-06-29 Mitsui Chemicals, Inc. プロピレン系重合体、該重合体を含む組成物及びこれらから得られる成形体
JP5438256B2 (ja) 2006-11-17 2014-03-12 三井化学株式会社 ポリプロピレン系樹脂フィルムおよびその用途
EP2275457B1 (de) 2005-05-18 2016-11-23 Mitsui Chemicals, Inc. Zusammensetzung auf Basis von Propylenpolymer und die davon geformte Produkte, Platte, Folie, Laminate und Vliesstoffe
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
CA2615982C (en) 2005-07-19 2012-02-21 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US20070225423A1 (en) * 2005-10-07 2007-09-27 Mitsui Chemicals, Inc. Process for producing blow molded product by blow molding
US20070080483A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
CN101316699A (zh) 2005-10-26 2008-12-03 陶氏环球技术公司 多层、预拉伸的弹性制品
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
CN101003595B (zh) 2006-01-18 2010-12-15 住友化学株式会社 制备乙烯-α-烯烃-多烯无规共聚物的方法
EP1992649A4 (de) * 2006-02-15 2009-04-22 Mitsui Chemicals Inc Ethylenharz und dieses umfassender blasformkörper
EP1992658A4 (de) * 2006-02-15 2011-04-06 Mitsui Chemicals Inc Spannungsrissbeständigkeitsmodifikator und spannungsrissbeständigkeitsmodifizierte harzzusammensetzung damit
WO2007105483A1 (ja) 2006-03-10 2007-09-20 Mitsui Chemicals, Inc. インフレーション成形による成形体の製造方法
US20090166911A1 (en) 2006-03-27 2009-07-02 Mitsui Chemicals, Inc. Process for Producing Molded Article by T-Die Molding
JP2007261201A (ja) 2006-03-29 2007-10-11 Mitsui Chemicals Inc ブロー成形による成形体の製造方法
EP2002955A4 (de) 2006-03-30 2009-09-16 Mitsui Chemicals Inc Verfahren zur herstellung eines geformten objekts durch spritzgiessen
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
EP2050771B1 (de) 2006-07-31 2020-07-15 Mitsui Chemicals, Inc. Folie oder laminat, umfassend ethylenharz oder ethylenharzzusammensetzung
CA2666807C (en) 2006-10-20 2012-05-29 Mitsui Chemicals, Inc. Copolymer, lubricating oil viscosity modifier, and lubricating oil composition
DE102006057822A1 (de) 2006-12-06 2008-06-26 Basell Poliolefine Italia S.R.L. Mehrschichtiges Verbundmaterial mit inhärent latentem Schutz gegenüber Verformung unter Temperatureinwirkung als Ausgleich des Bi-Metalleffektes
DE102006060459A1 (de) * 2006-12-19 2008-06-26 Basell Poliolefine Italia S.R.L. Mehrschichtiges Verbundmaterial mit mindestens einer Glasschicht
JPWO2008075717A1 (ja) 2006-12-19 2010-04-15 三井化学株式会社 オレフィン重合用固体状触媒、オレフィン重合方法及び該重合方法によって得られるオレフィン重合体粒子
US20100028578A1 (en) * 2007-01-16 2010-02-04 Prime Polymer Co., Ltd. Blow molding ethylene resin composition and blow molded article therefrom
CN101679702B (zh) 2007-06-14 2012-07-04 三井化学株式会社 热塑性弹性体组合物
JP5226973B2 (ja) 2007-06-15 2013-07-03 三井化学株式会社 エチレン系共重合体、該共重合体を含む組成物ならびにその用途
CN101687776B (zh) 2007-07-04 2015-07-01 三井化学株式会社 过渡金属配位化合物、含有该化合物的烯烃聚合用催化剂以及在该催化剂存在下进行的烯烃聚合物的制造方法
WO2009066689A1 (ja) 2007-11-19 2009-05-28 Mitsui Chemicals, Inc. 架橋メタロセン化合物およびそれを用いたオレフィン重合用触媒、ならびに該触媒を用いて得られるエチレン系重合体
DE102007057606A1 (de) 2007-11-28 2009-06-04 Basell Polyolefine Gmbh Modular aufgebaute Rotationstrommel für Elektro- und Haushaltsgeräte
CA2709566A1 (en) * 2007-12-17 2009-06-25 Gliamed, Inc. Stem-like cells and method for reprogramming adult mammalian somatic cells
EP2275493B1 (de) 2008-03-27 2013-02-27 Mitsui Chemicals, Inc. Harzzusammensetzung und verwendung davon
CN104059283B (zh) 2008-03-31 2017-04-12 三井化学株式会社 树脂组合物和熔融袋
JP5754940B2 (ja) 2008-08-19 2015-07-29 三井化学株式会社 混合触媒によるプロピレン重合体の製造方法
US20100317711A1 (en) * 2008-12-17 2010-12-16 Gliamed, Inc. Stem-like cells and method for reprogramming adult mammalian somatic cells
WO2010123033A1 (ja) 2009-04-21 2010-10-28 三井化学株式会社 オレフィン重合体の製造方法
EP2440564A4 (de) 2009-06-11 2014-07-09 Grace W R & Co Verfahren zur herstellung von aluminoxan und katalysatoren mit in diesem verfahren hergestelltem aluminoxan
US9017593B2 (en) 2009-06-16 2015-04-28 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
EP2450361B1 (de) 2009-07-01 2017-10-25 Mitsui Chemicals, Inc. Organometallische verbindungen und verfahren zu ihrer herstellung
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
WO2011011124A1 (en) 2009-07-23 2011-01-27 Exxonmobil Chemical Patents Inc. Polypropylene-based elastomer coating compositions
EP2467253B1 (de) 2009-08-18 2018-02-21 Basell Poliolefine Italia S.r.l. Gehäuse für stromzellen in elektrisch betriebenen fahrzeugen
WO2011020582A1 (en) 2009-08-18 2011-02-24 Basell Polyolefine Gmbh Plastic fuel container for motor bikes or automotive hybrid cars
WO2011053406A1 (en) 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
KR101411182B1 (ko) 2009-12-21 2014-06-23 미쓰이 가가쿠 가부시키가이샤 신디오택틱 α-올레핀 중합체의 제조방법
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
CN103154123B (zh) 2010-10-15 2016-01-27 埃克森美孚化学专利公司 聚丙烯-基粘合剂组合物
JP6457716B2 (ja) 2011-01-14 2019-01-23 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用
EP2711380A4 (de) 2011-05-18 2014-11-05 Mitsui Chemicals Inc Propylencopolymer und propylencopolymerzusammensetzung, form und schaumstoff dafür sowie verfahren zur herstellung dieser form und dieses schaumstoffs
SG11201401125WA (en) 2011-10-10 2014-04-28 Exxonmobil Res & Eng Co Low viscosity engine oil compositions
JP5769821B2 (ja) 2011-12-27 2015-08-26 三井化学株式会社 4−メチル−1−ペンテン(共)重合体組成物、該組成物からなるフィルムおよび中空成形体
CN104024326B (zh) 2011-12-28 2016-11-23 三井化学株式会社 乙烯类聚合物组合物和由其得到的成形体
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
KR101609500B1 (ko) 2012-03-21 2016-04-05 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체의 제조 방법
EP2833415B1 (de) 2012-03-28 2018-05-02 Mitsui Chemicals, Inc. Dichtmaterial für solarzellen und solarzellenmodul
CN102796008A (zh) * 2012-07-05 2012-11-28 河南颖泰化工有限责任公司 一种mea生产中排放气体回收再利用的工艺
EP2902419B1 (de) 2012-09-25 2020-08-19 Mitsui Chemicals, Inc. Verfahren zur herstellung eines olefinpolymers und olefinpolymer
SG10201706412TA (en) 2012-09-25 2017-09-28 Mitsui Chemicals Inc Transition Metal Compound, Olefin Polymerization Catalyst, And Olefin Polymer Production Process
KR101394943B1 (ko) 2012-11-19 2014-05-14 대림산업 주식회사 에틸렌과 알파-올레핀의 공중합체 및 그 제조방법
EP2960270B1 (de) 2013-02-20 2017-12-20 Prime Polymer Co., Ltd. Biaxial gestreckte folie und ethylenpolymerzusammensetzung
JP6204973B2 (ja) 2013-02-27 2017-09-27 三井化学株式会社 オレフィン多量化用触媒および該触媒存在下で行うオレフィン多量体の製造方法
EP2975069B1 (de) 2013-03-12 2018-09-05 Mitsui Chemicals, Inc. Verfahren zur herstellung von olefinpolymer und katalysator zur olefinpolymerisation
US10093838B2 (en) 2013-10-18 2018-10-09 Mitsui Chemicals, Inc. Adhesive including ethylene⋅α-olefin copolymer
CN105916888B (zh) 2014-02-13 2018-03-16 三井化学株式会社 乙烯/α‑烯烃共聚物的制造方法
BR112016016900B8 (pt) 2014-02-13 2022-05-17 Mitsui Chemicals Inc Copolímero de etileno-alfa-olefina-polieno não conjugado, artigo moldado, composição, método de fabricação deste copolímero, composição para uma junta de vedação, junta de vedação, composição para formação de uma mangueira e mangueira
WO2015122495A1 (ja) 2014-02-14 2015-08-20 三井化学株式会社 エチレン・α-オレフィン・非共役ポリエン共重合体、その製造方法ならびに用途
BR112016018907B1 (pt) 2014-02-28 2021-07-06 Mitsui Chemicals, Inc método para a produção de um produto reticulado, artigo moldado laminado, copolímero de etileno (a) e composição de copolímero de etileno
WO2015147186A1 (ja) 2014-03-28 2015-10-01 三井化学株式会社 オレフィン系樹脂およびその製造方法
US9771448B2 (en) 2014-03-28 2017-09-26 Mitsui Chemicals, Inc. Olefin-based resin, method for producing same and propylene-based resin composition
JP6618891B2 (ja) 2014-03-28 2019-12-11 三井化学株式会社 エチレン/α−オレフィン共重合体および潤滑油
KR101970078B1 (ko) 2014-09-10 2019-04-17 미쓰이 가가쿠 가부시키가이샤 윤활유 조성물
CN106715487B (zh) 2014-09-11 2021-02-26 三井化学株式会社 包含来源于1-丁烯的构成单元的烯烃(共)聚合物的制造方法
WO2016093266A1 (ja) 2014-12-09 2016-06-16 三井化学株式会社 プロピレン系樹脂組成物
CN107429011B (zh) 2015-03-20 2020-06-19 三井化学株式会社 热塑性弹性体组合物及其制造方法
CN107428956B (zh) 2015-03-20 2022-05-17 三井化学株式会社 热塑性弹性体组合物、其用途、其制造方法、乙烯-α-烯烃-非共轭多烯共聚物及其用途
EP3279256A4 (de) 2015-03-31 2018-12-19 Mitsui Chemicals, Inc. Harzzusammensetzung und verwendung davon
US20180320102A1 (en) 2015-11-09 2018-11-08 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oils, additive composition for lubricating oils, and lubricating oil compositions
CA3004086C (en) 2015-12-16 2020-06-02 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions
CN108698383A (zh) 2016-03-04 2018-10-23 三井化学株式会社 层叠体及其用途
WO2017172102A1 (en) 2016-03-31 2017-10-05 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
CN110072981B (zh) 2017-01-16 2022-02-25 三井化学株式会社 汽车齿轮用润滑油组合物
JP6792649B2 (ja) 2017-02-20 2020-11-25 三井化学株式会社 積層体
US20190358928A1 (en) 2017-02-20 2019-11-28 Mitsui Chemicals, Inc. Laminate
JP2020524733A (ja) 2017-06-22 2020-08-20 エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company メチルパラフィン含有炭化水素流体に基づく低粘度潤滑油
KR20200026953A (ko) 2017-07-06 2020-03-11 미쓰이 가가쿠 가부시키가이샤 올레핀 다량화용 촉매 및 그 촉매 존재하에서 행하는 올레핀 다량체의 제조 방법
CN111132988B (zh) 2017-09-28 2023-06-20 尤尼威蒂恩技术有限责任公司 环状有机化合物和茂金属的合成
KR102520290B1 (ko) 2018-03-20 2023-04-10 미쓰이 가가쿠 가부시키가이샤 에틸렌·α-올레핀·비공액 폴리엔 공중합체, 그의 제조 방법 및 용도
WO2020060690A1 (en) 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US12091536B2 (en) 2018-12-04 2024-09-17 Mitsui Chemicals, Inc. Resin composition containing 4-methyl-1-pentene copolymer, and film for capacitors
WO2020189676A1 (ja) 2019-03-19 2020-09-24 三井化学株式会社 プロピレン系樹脂組成物、成形体およびプロピレン重合体
CN113574139A (zh) 2019-03-26 2021-10-29 三井化学株式会社 润滑油组合物及其制造方法
KR20210141610A (ko) 2019-03-26 2021-11-23 미쓰이 가가쿠 가부시키가이샤 자동차 변속기유용 윤활유 조성물 및 그의 제조 방법
EP3950901A4 (de) 2019-03-26 2022-08-17 Mitsui Chemicals, Inc. Schmierölzusammensetzung für brennkraftmaschinen und verfahren zu deren herstellung
WO2020194549A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 潤滑油組成物およびその製造方法
CN113574140A (zh) 2019-03-26 2021-10-29 三井化学株式会社 工业齿轮用润滑油组合物及其制造方法
WO2020194546A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 内燃機関用潤滑油組成物およびその製造方法
KR20210139407A (ko) 2019-03-26 2021-11-22 미쓰이 가가쿠 가부시키가이샤 그리스 조성물 및 그의 제조 방법
CN113574145A (zh) 2019-03-26 2021-10-29 三井化学株式会社 压缩机油用润滑油组合物及其制造方法
CN113574142A (zh) 2019-03-26 2021-10-29 三井化学株式会社 液压油用润滑油组合物及其制造方法
WO2020194548A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 自動車ギア用潤滑油組成物およびその製造方法
JP7297054B2 (ja) 2019-03-29 2023-06-23 三井化学株式会社 樹脂組成物
US12344731B2 (en) 2019-08-08 2025-07-01 Prime Polymer Co., Ltd Propylene polymer composition and shaped article
US20220298087A1 (en) 2019-08-09 2022-09-22 Exxonmobil Chemical Patents Inc. Processes for producing poly alpha olefins and method of analysis and apparatuses therefor
EP4010308A1 (de) 2019-08-09 2022-06-15 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von poly-alpha-olefinen und vorrichtungen dafür
KR102707199B1 (ko) 2019-10-07 2024-09-13 미쓰이 가가쿠 가부시키가이샤 에틸렌·α-올레핀 공중합체 조성물 및 그 용도
EP4051656A1 (de) 2019-10-28 2022-09-07 ExxonMobil Chemical Patents Inc. Dimer-selektive metallocen-katalysatoren, nicht-aromatische kohlenwasserstoff-lösliche aktivatoren und verfahren zum produzieren von poly-alpha-olefin-oligmeren mit ihnen
EP4417648A1 (de) 2019-10-29 2024-08-21 Mitsui Chemicals, Inc. Ethylencopolymerzusammensetzung und verwendung davon
JP7341256B2 (ja) 2020-01-30 2023-09-08 三井化学株式会社 ポリアミド組成物
US20230365794A1 (en) 2020-10-06 2023-11-16 Mitsui Chemicals, Inc. Resin composition
EP4279547A4 (de) 2021-01-18 2024-12-11 Mitsui Chemicals, Inc. Wässrige dispersionszusammensetzung, verfahren zur herstellung der wässrigen dispersionszusammensetzung und säuremodifiziertes ethylen-alpha-olefin-copolymer
JP7621455B2 (ja) 2021-03-05 2025-01-24 三井化学株式会社 熱可塑性エラストマー組成物
EP4316834A4 (de) 2021-03-31 2025-03-26 Mitsui Chemicals, Inc. Ethylen-a-olefin-copolymer, thermoplastische harzzusammensetzung und film
EP4316833A4 (de) 2021-03-31 2025-03-26 Mitsui Chemicals, Inc. Ethylen-a-olefin-copolymer, thermoplastische harzzusammensetzung, film und laminat
EP4317215A4 (de) 2021-03-31 2025-04-09 Mitsui Chemicals, Inc. Ethylenharzzusammensetzung und formkörper
KR20230160903A (ko) 2021-05-20 2023-11-24 미쓰이 가가쿠 가부시키가이샤 수지 조성물, 및 그 용도 및 제조 방법
US20240352253A1 (en) 2021-11-16 2024-10-24 Mitsui Chemicals, Inc. Resin composition and use thereof
JP7793753B2 (ja) 2022-03-17 2026-01-05 三井化学株式会社 熱可塑性樹脂組成物
EP4501979A4 (de) 2022-03-24 2026-03-11 Mitsui Chemicals Inc Ethylen/alpha-olefin/5-vinyl-2-norbornen-copolymer, zusammensetzung mit diesem copolymer und vernetzter körper
JP7818082B2 (ja) 2022-06-27 2026-02-19 三井化学株式会社 環状オレフィン系共重合体の製造方法、環状オレフィン系共重合体、架橋体、フィルムまたはシート、積層体、回路基板、電子機器およびプリプレグ
EP4545577A1 (de) 2022-06-27 2025-04-30 Mitsui Chemicals, Inc. Verfahren zur herstellung einer lackartigen cyclischen olefincopolymerzusammensetzung, cyclische olefincopolymerzusammensetzung, vernetztes produkt, film oder folie, laminat, leiterplatte, elektronische vorrichtung und prepreg
WO2024195445A1 (ja) 2023-03-23 2024-09-26 三井化学株式会社 水系潤滑剤組成物
EP4685217A1 (de) 2023-03-23 2026-01-28 Mitsui Chemicals, Inc. Wässrige schmiermittelzusammensetzung
EP4716678A1 (de) 2023-05-22 2026-04-01 ExxonMobil Technology and Engineering Company Verfahren zur aktivierung von metallocenkatalysatoren in einem reaktor zur erhöhung der katalysatorproduktivität bei der pao-herstellung
CN119371579B (zh) * 2023-07-26 2026-03-17 中国石油天然气集团有限公司 茂金属催化剂体系、聚异丁烯及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3756998A (en) * 1968-10-14 1973-09-04 Union Carbide Corp L catalysts polymerization of olefins using supported pi arenechromium tricarbony
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
CA1238145A (en) * 1982-09-30 1988-06-14 Kenneth W. Powers Modified lewis acid catalyzed polymerization
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
EP0426637B2 (de) * 1989-10-30 2001-09-26 Fina Technology, Inc. Herstellung von Metallocenkatalysatoren für Olefinpolymerisation

Also Published As

Publication number Publication date
ES2086397T5 (es) 2005-07-16
CA2027122C (en) 2002-12-10
CN1037686C (zh) 1998-03-11
EP0426638B1 (de) 1996-04-24
US5519100A (en) 1996-05-21
CN1037685C (zh) 1998-03-11
CN1051365A (zh) 1991-05-15
DE69026679T2 (de) 1996-09-26
US5614457A (en) 1997-03-25
CN1111641A (zh) 1995-11-15
JPH03207704A (ja) 1991-09-11
EP0426638A3 (en) 1991-08-07
KR100196613B1 (ko) 1999-06-15
EP0426638B2 (de) 2005-03-02
EP0426638A2 (de) 1991-05-08
JP2939321B2 (ja) 1999-08-25
DE69026679D1 (de) 1996-05-30
DE69026679T3 (de) 2005-10-06
CA2027122A1 (en) 1991-05-01
ES2086397T3 (es) 1996-07-01
KR910007974A (ko) 1991-05-30

Similar Documents

Publication Publication Date Title
DE69026679D1 (de) Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators
DE69026907D1 (de) Metallocenkatalysator mit Lewissäure und Alkylaluminium
PL288591A1 (en) Method of obtaining a supported ionic catalyst
RU94046276A (ru) Способ получения этиленового полимера
ATE122060T1 (de) Verfahren zur polymerisation von olefinen und katalysator für olefinpolymerisation.
RU92016448A (ru) Катализаторы на основе алюминия и свободного моноциклопентадиенилов для полимеризации олефинов
NO903866L (no) Ny baererkatalysator for polymerisasjonen av etylen.
FI882869A0 (fi) Menetelmä olefiinien kaasufaasipolymerointia varten tarkoitetun, huokoiseen metallioksidikantajaan kiinnitetyn katalyyttikomponentin käsittelemiseksi ja tällä tavoin saadun katalyytin käyttö olefiinien polymerointiin
DE69309386D1 (de) Titaniumkatalysatorbestandteil für Ethylenpolymerisation, Ethylenpolymerisationkatalysator und Verfahren zur Ethylenpolymerisation unter Anwendung desselben
YU48428B (sh) Katalitički sastavi i katalitički postupci
HUT60295A (en) Catalyst bonded to a carrier for the polymerization of ethylene and copolymerization of ethylene with apha-olefins, as well as process for applying the catalyst
IT1275812B1 (it) Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine
MX9702453A (es) Proceso de polimerizacion de olefina proquiral sindiotactica.
BR8405141A (pt) Processo para producao,em suspensao em um hidrocarboneto liquido e em unico estagio de polimerizacao,de polimeros de etileno ou copolimeros de etileno com alfa-olefinas,e sistema catalitico para uso do mesmo
FI99243B (fi) Menetelmä olefiinien polymeroimiseksi
NO902028D0 (no) Fremgangsmaate for hydrogenering av polymerer.
ES2066091T3 (es) Catalizador de polimerizacion, procedimiento y mejora.
GB2114583B (en) Olefin polymerisation catalysts, methods for the production thereof and use in the polymerisation of olefins
DE68915456D1 (de) Katalysator und verfahren zur polymerisierung von olefinen.
FI873012A7 (fi) Menetelmä olefiinien polymeroinnissa käytetyn rakenteeltaan sfäärisen katalysaattorin käsittelemiseksi, saatavan katalysaattorin käyttö olefiinen polymeroinnissa
DE3685971D1 (de) Verfahren zur herstellung von ethylenpolymeren.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties