ATE159239T1 - Verfahren zum herstellen von butylacrylat durch direkte veresterung - Google Patents

Verfahren zum herstellen von butylacrylat durch direkte veresterung

Info

Publication number: ATE159239T1
Authority: AT; Austria
Prior art keywords: butanol; butyl acrylate; phase; acrylic acid; acid
Prior art date: 1994-07-28

Application number

AT95401765T

Other languages

English (en)

Inventor

Michel Fauconet

Christian Lacroix

Nathalie Hess

Jacqueline Bessalem

Original Assignee

Atochem Elf Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-07-28

Filing date

1995-07-25

Publication date

1997-11-15

1995-07-25 Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa

1997-11-15 Application granted granted Critical

1997-11-15 Publication of ATE159239T1 publication Critical patent/ATE159239T1/de

Links

CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 title abstract 9
230000032050 esterification Effects 0.000 title abstract 4
238000005886 esterification reaction Methods 0.000 title abstract 4
238000004519 manufacturing process Methods 0.000 title 1
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 18
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 8
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 8
239000012071 phase Substances 0.000 abstract 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 5
239000001117 sulphuric acid Substances 0.000 abstract 5
235000011149 sulphuric acid Nutrition 0.000 abstract 5
239000012074 organic phase Substances 0.000 abstract 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
239000002253 acid Substances 0.000 abstract 3
238000006243 chemical reaction Methods 0.000 abstract 3
230000007062 hydrolysis Effects 0.000 abstract 3
238000006460 hydrolysis reaction Methods 0.000 abstract 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
238000006386 neutralization reaction Methods 0.000 abstract 2
238000004064 recycling Methods 0.000 abstract 2
229910021653 sulphate ion Inorganic materials 0.000 abstract 2
238000005406 washing Methods 0.000 abstract 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
230000000295 complement effect Effects 0.000 abstract 1
238000004821 distillation Methods 0.000 abstract 1
238000000605 extraction Methods 0.000 abstract 1
159000000011 group IA salts Chemical class 0.000 abstract 1
238000000034 method Methods 0.000 abstract 1
230000003472 neutralizing effect Effects 0.000 abstract 1
238000011084 recovery Methods 0.000 abstract 1
230000001172 regenerating effect Effects 0.000 abstract 1
239000002904 solvent Substances 0.000 abstract 1
238000000638 solvent extraction Methods 0.000 abstract 1
239000002699 waste material Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

AT95401765T 1994-07-28 1995-07-25 Verfahren zum herstellen von butylacrylat durch direkte veresterung ATE159239T1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9409371A FR2723089B1 (fr)	1994-07-28	1994-07-28	Procede de fabrication de l'acrylate de butyle par esterification directe

Publications (1)

Publication Number	Publication Date
ATE159239T1 true ATE159239T1 (de)	1997-11-15

Family

ID=9465850

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT95401765T ATE159239T1 (de)	1994-07-28	1995-07-25	Verfahren zum herstellen von butylacrylat durch direkte veresterung

Country Status (14)

Country	Link
US (1)	US5606102A (de)
EP (1)	EP0694524B1 (de)
JP (1)	JP2748337B2 (de)
KR (1)	KR0165609B1 (de)
CN (1)	CN1057291C (de)
AT (1)	ATE159239T1 (de)
CA (1)	CA2154940C (de)
CZ (1)	CZ287264B6 (de)
DE (1)	DE69500874T2 (de)
DK (1)	DK0694524T3 (de)
ES (1)	ES2110819T3 (de)
FR (1)	FR2723089B1 (de)
GR (1)	GR3025861T3 (de)
TW (1)	TW296377B (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19604252A1 (de) *	1996-02-06	1997-08-07	Basf Ag	Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure
DE19604253A1 (de) *	1996-02-06	1997-08-07	Basf Ag	Verfahren zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure
WO1998052904A1 (en) *	1997-05-20	1998-11-26	Union Carbide Chemicals & Plastics Technology Corporation	Processes for refining butylacrylate
DE19648746A1 (de) *	1996-11-25	1998-05-28	Basf Ag	Verfahren zur Herstellung von (Meth)acrylsäureestern
DE19648743A1 (de) *	1996-11-25	1998-05-28	Basf Ag	Verfahren zur Herstellung von (Meth)acrylsäureestern
US5877345A (en) *	1997-02-07	1999-03-02	Rohm And Haas Company	Process for producing butyl acrylate
MY120051A (en) *	1997-07-30	2005-08-30	Mitsubishi Rayon Co	Process for purification of (meth)acrylic acid
FR2822824B1 (fr)	2001-04-02	2005-01-14	Atofina	Procede de fabrication d'acrylate de 2-ethylhexyle comportant une neutralisation par une base du brut
FR2822825B1 (fr) *	2001-04-02	2003-05-16	Atofina	Procede de fabrication d'acrylate de 2-ethylhexyle comportant le lavage a l'eau du brut
JP2006213647A (ja) *	2005-02-03	2006-08-17	Toagosei Co Ltd	未反応アクリル酸の回収方法
DE102005010588A1 (de) *	2005-03-08	2006-05-24	Basf Ag	Verfahren zur Herstellung von Alkylestern der (Meth)acrylsäure
CN1305835C (zh) *	2005-04-12	2007-03-21	天津市天骄化工有限公司	多元醇丙烯酸酯的制备方法
FR2884514B1 (fr) *	2005-04-18	2007-06-22	Arkema Sa	Procede perfectionne de fabrication de (meth) acrylates d'alkyle par esterification directe
DE102005038412A1 (de) *	2005-08-12	2007-02-15	Basf Ag	Verfahren zur Deckung des Bedarfs an Polymerisaten I, die zu wenigstens 90% ihres Gewichtes Acrylsäure, deren Salze und/oder Alkylester der Acrylsäure radikalisch einpolymerisiert enthalten
EP2435541B1 (de)	2009-05-25	2017-10-04	Shell Internationale Research Maatschappij B.V.	Benzinzusammensetzungen
CA2762258A1 (en) *	2009-05-25	2010-12-02	Shell Internationale Research Maatschappij B.V.	Gasoline compositions
TWI488838B (zh) *	2010-09-07	2015-06-21	Toagosei Co Ltd	丙烯酸酯之製造方法及丙烯酸之回收方法
CN102267890B (zh) *	2010-11-16	2014-06-11	中国环境科学研究院	从丙烯酸酯生产废水中萃取回收丙烯酸的方法
JP6241314B2 (ja) *	2014-02-24	2017-12-06	三菱ケミカル株式会社	アクリル酸ブチルの製造方法
KR102079774B1 (ko)	2016-11-25	2020-02-20	주식회사 엘지화학	(메트)아크릴산의 연속 회수 방법 및 장치
EP3366660A1 (de) *	2017-02-24	2018-08-29	Linde Aktiengesellschaft	Verfahren und anlage zur herstellung von olefinen
KR102595882B1 (ko)	2019-09-25	2023-10-30	주식회사 엘지화학	디에스터계 조성물의 제조 시스템 및 제조방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1017522A (en) *	1963-09-26	1966-01-19	Distillers Co Yeast Ltd	Improvements in or relating to the production of butyl acrylate
DE2226829A1 (de) *	1972-06-02	1973-12-20	Knapsack Ag	Verfahren zur herstellung von acrylsaeureestern
DE2323328C2 (de)	1973-05-09	1982-04-01	Basf Ag, 6700 Ludwigshafen	Verfahren zur Abtrennung von Acrylsäure aus einer angesäuerten wäßrigen Butanol-Acrylsäure-Veresterungsablauge
DE2449811C2 (de)	1974-10-19	1983-01-05	Hoechst Ag, 6000 Frankfurt	Verfahren zur kontinuierlichen Herstellung von dibutylätherfreiem n-Butylacrylat
DE4019781A1 (de) *	1990-06-21	1992-01-02	Basf Ag	Verfahren zur herstellung von monoethylenisch ungesaettigten carbonsaeureestern
JP3291754B2 (ja) *	1992-04-13	2002-06-10	住友化学工業株式会社	カルボン酸エステルの製造方法
FR2700767B1 (fr) *	1993-01-27	1995-04-07	Atochem Elf Sa	Procédé perfectionné de fabrication de (méthacrylates d'alkyle par estérification directe.
JP3346822B2 (ja) *	1993-03-31	2002-11-18	三菱化学株式会社	アクリル酸エステル又はメタクリル酸エステルの製造法

1994
- 1994-07-28 FR FR9409371A patent/FR2723089B1/fr not_active Expired - Fee Related
1995
- 1995-07-25 AT AT95401765T patent/ATE159239T1/de not_active IP Right Cessation
- 1995-07-25 DK DK95401765.3T patent/DK0694524T3/da active
- 1995-07-25 ES ES95401765T patent/ES2110819T3/es not_active Expired - Lifetime
- 1995-07-25 DE DE69500874T patent/DE69500874T2/de not_active Expired - Fee Related
- 1995-07-25 EP EP95401765A patent/EP0694524B1/de not_active Expired - Lifetime
- 1995-07-27 CN CN95109453A patent/CN1057291C/zh not_active Expired - Fee Related
- 1995-07-27 CA CA002154940A patent/CA2154940C/fr not_active Expired - Fee Related
- 1995-07-27 US US08/508,133 patent/US5606102A/en not_active Expired - Lifetime
- 1995-07-28 KR KR1019950022947A patent/KR0165609B1/ko not_active Expired - Fee Related
- 1995-07-28 JP JP7212783A patent/JP2748337B2/ja not_active Expired - Fee Related
- 1995-07-28 CZ CZ19951958A patent/CZ287264B6/cs not_active IP Right Cessation
- 1995-09-05 TW TW084109259A patent/TW296377B/zh active
1998
- 1998-01-08 GR GR980400032T patent/GR3025861T3/el unknown

Also Published As

Publication number	Publication date
TW296377B (de)	1997-01-21
EP0694524A1 (de)	1996-01-31
EP0694524B1 (de)	1997-10-15
CA2154940C (fr)	1999-03-30
CA2154940A1 (fr)	1996-01-29
US5606102A (en)	1997-02-25
CN1125219A (zh)	1996-06-26
JP2748337B2 (ja)	1998-05-06
CZ195895A3 (en)	1996-02-14
KR0165609B1 (ko)	1999-03-20
FR2723089A1 (fr)	1996-02-02
JPH0859551A (ja)	1996-03-05
DE69500874T2 (de)	1998-05-07
ES2110819T3 (es)	1998-02-16
GR3025861T3 (en)	1998-04-30
FR2723089B1 (fr)	1996-09-06
CN1057291C (zh)	2000-10-11
DK0694524T3 (da)	1998-06-02
CZ287264B6 (en)	2000-10-11
KR960004312A (ko)	1996-02-23
DE69500874D1 (de)	1997-11-20

Legal Events

Date	Code	Title	Description
1998-07-15	UEP	Publication of translation of european patent specification
2003-04-15	REN	Ceased due to non-payment of the annual fee

Publication	Publication Date	Title
ATE159239T1 (de)	1997-11-15	Verfahren zum herstellen von butylacrylat durch direkte veresterung
US5510514A (en)	1996-04-23	Process for the production of alkyl (meth)acrylates by direct esterification
TW364900B (en)	1999-07-21	Process for producing highly pure terephthalic acid
JPH06287162A (ja)	1994-10-11	アクリル酸エステル又はメタクリル酸エステルの製造法
EP0566047B1 (de)	1997-09-03	Verfahren zum Herstellen von Carbonsäureestern
JPS60191021A (ja)	1985-09-28	ウラン回収方法
KR970704909A (ko)	1997-09-06	에칭폐액의 재이용방법
US6084128A (en)	2000-07-04	Sulfur removal process from an acrylate stream
CN215161034U (zh)	2021-12-14	一种从五金配件清洗废酸中回收磷酸的设备
JPS5520666A (en)	1980-02-14	Sludge recovery method
BR9006053A (pt)	1991-09-24	Processo para a recuperacao de valores de cobalto a partir de uma mistura de acido n-acetiliminodiacetico e um catalisador de cobalto
DE3877813D1 (de)	1993-03-11	Verfahren zur fluessig-fluessig-extraktion von gallium.
JPH10249330A (ja)	1998-09-22	ホウ素含有廃水の処理方法
CN220176822U (zh)	2023-12-15	一种新型丙烯酸甲酯生产装置
JPS5591979A (en)	1980-07-11	Recovering and circulating apparatus for alkaline etching waste solution
US20080183005A1 (en)	2008-07-31	Method For Making Alkyl (Meth) Acrylates by Direct Esterification
CN1250031A (zh)	2000-04-12	氰化贫液除杂工艺
KR20010016238A (ko)	2001-03-05	폐전선으로 부터 수지와 금속구리의 화학적 분리방법
JPH0240605B2 (de)	1990-09-12
SU856543A1 (ru)	1981-08-23	Способ регенерации сильнокислотного катионита
KR950003181A (ko)	1995-02-16	질산과 불산을 함유한 산세폐액의 처리방법
CN109663379A (zh)	2019-04-23	一种节能乙腈法裂解碳五分离方法
JPS5551707A (en)	1980-04-15	Crude phosphoric acid purifying method
PL167390B1 (pl)	1995-08-31	Sposób przerobu ścieków akrylowych