ATE163653T1 - Katalysatoren und verfahren zur polymerisierung von olefinen - Google Patents

Katalysatoren und verfahren zur polymerisierung von olefinen

Info

Publication number
ATE163653T1
ATE163653T1 AT95926926T AT95926926T ATE163653T1 AT E163653 T1 ATE163653 T1 AT E163653T1 AT 95926926 T AT95926926 T AT 95926926T AT 95926926 T AT95926926 T AT 95926926T AT E163653 T1 ATE163653 T1 AT E163653T1
Authority
AT
Austria
Prior art keywords
carbon atoms
alkenyl
alkyl
catalysts
arylalkyl
Prior art date
Application number
AT95926926T
Other languages
English (en)
Inventor
Occo Tiziano Dall
Maurizio Galimberti
Luigi Resconi
Enrico Albizzati
Gianni Pennini
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Application granted granted Critical
Publication of ATE163653T1 publication Critical patent/ATE163653T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT95926926T 1994-07-20 1995-07-18 Katalysatoren und verfahren zur polymerisierung von olefinen ATE163653T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941516A IT1273661B (it) 1994-07-20 1994-07-20 Catalizzatori per la polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ATE163653T1 true ATE163653T1 (de) 1998-03-15

Family

ID=11369317

Family Applications (1)

Application Number Title Priority Date Filing Date
AT95926926T ATE163653T1 (de) 1994-07-20 1995-07-18 Katalysatoren und verfahren zur polymerisierung von olefinen

Country Status (25)

Country Link
US (2) US5849653A (de)
EP (1) EP0720627B1 (de)
JP (1) JP3714678B2 (de)
KR (1) KR100356549B1 (de)
CN (1) CN1113899C (de)
AT (1) ATE163653T1 (de)
AU (1) AU695214B2 (de)
BG (1) BG100514A (de)
BR (1) BR9506295A (de)
CA (1) CA2171834A1 (de)
CZ (1) CZ112796A3 (de)
DE (1) DE69501720T2 (de)
ES (1) ES2115391T3 (de)
FI (1) FI961269A7 (de)
HU (1) HU215264B (de)
IL (1) IL114659A (de)
IT (1) IT1273661B (de)
MX (1) MX9601040A (de)
NO (1) NO308904B1 (de)
PL (1) PL313588A1 (de)
RU (1) RU2155774C2 (de)
SK (1) SK49496A3 (de)
TR (1) TR199500876A2 (de)
WO (1) WO1996002580A1 (de)
ZA (1) ZA955988B (de)

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IT1276752B1 (it) 1995-06-20 1997-11-03 Spherilene S P A Ora Montell I Catalizzatori e procedimenti per la polimerizzazione di olefine
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
PT835886E (pt) * 1996-10-09 2004-05-31 Atofina Res Processo para a preparacao e utilizacao de compostos de dicloreto de (bis(indenil)etano)zirconio meso/racemico
KR20000069714A (ko) 1997-10-29 2000-11-25 간디 지오프레이 에이치. 올레핀 중합용 촉매 및 그의 제조방법
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
US6001766A (en) * 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
ES2198098T3 (es) 1998-03-09 2004-01-16 Basell Poliolefine Italia S.P.A. Procedimiento multietapas para la polimerizacion de olefinas.
EP1073521A1 (de) 1998-04-15 2001-02-07 Shell Internationale Researchmaatschappij B.V. Katalysatorsystem zur oligomerisierung von alpha-olefinen
EP0953582A1 (de) * 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
US6555494B2 (en) 1998-10-23 2003-04-29 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6492292B2 (en) 1998-10-23 2002-12-10 Albemarle Corporation Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components
US6462212B1 (en) 1998-10-23 2002-10-08 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6812182B2 (en) 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
ATE388967T1 (de) * 1998-10-27 2008-03-15 Westlake Longview Corp Verfahren zur polymerisierung von olefine; polyethylene, und filme, und gegenstände damit hergestellt
IL142979A0 (en) 1998-11-18 2002-04-21 Basell Technology Co Bv Methylene bridged metallocenes as olefin-polymerization-catalyst components
US6395668B1 (en) 1998-12-15 2002-05-28 Basell Technology Company Bv Catalyst system for olefin polymerization
CN1350552A (zh) 1999-03-09 2002-05-22 巴塞尔技术有限公司 烯烃(共)聚合的多阶段方法
KR20010072229A (ko) 1999-06-04 2001-07-31 간디 지오프레이 에이치. 티타늄 착물의 제조 방법
WO2000075147A1 (en) 1999-06-07 2000-12-14 Basell Technology Company B.V. Preparation of transition-metal-alkyl-complexes carrying a bidentate, dianionic ligand
US6420298B1 (en) 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
KR20020034193A (ko) 1999-09-22 2002-05-08 간디 지오프레이 에이치. 올레핀 중합을 위한 촉매 시스템 및 방법
WO2001053360A1 (en) 2000-01-18 2001-07-26 Basell Technology Company B.V. Process for producing substantially amorphous propylene-based polymers
EP1222216B1 (de) 2000-05-24 2004-12-29 Basell Polyolefine GmbH Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
WO2002024769A2 (en) 2000-09-25 2002-03-28 Basell Technology Company B.V. Process for the preparation of ethylene polymers with a bis-amido titanium compound
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
WO2003000628A1 (en) * 2001-06-20 2003-01-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of oligomers
US7214745B2 (en) * 2001-08-07 2007-05-08 Denki Kagaku Kogyo Kabushiki Kaisha Process for producing polymer
KR20030087670A (ko) * 2002-05-09 2003-11-15 (주)다사테크 회전기계의 비접촉식 전원공급장치
JP2004149761A (ja) * 2002-09-02 2004-05-27 Sumitomo Chem Co Ltd エチレン重合体
RU2355709C2 (ru) * 2004-11-04 2009-05-20 Шеврон Филлипс Кемикал Компани Лп Катализаторы для получения бимодальных смол на основе комбинации хроморганического соединения и металлоцена
TWI555574B (zh) 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
KR102165484B1 (ko) * 2018-05-10 2020-10-14 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
KR102927908B1 (ko) 2020-10-15 2026-02-13 에스케이이노베이션 주식회사 폴리프로필렌의 제조방법

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Also Published As

Publication number Publication date
HUT74321A (en) 1996-12-30
CN1113899C (zh) 2003-07-09
PL313588A1 (en) 1996-07-08
CN1135761A (zh) 1996-11-13
DE69501720D1 (de) 1998-04-09
KR100356549B1 (ko) 2003-02-11
EP0720627B1 (de) 1998-03-04
BG100514A (en) 1997-01-31
HU215264B (hu) 1998-11-30
SK49496A3 (en) 1997-03-05
AU695214B2 (en) 1998-08-06
EP0720627A1 (de) 1996-07-10
FI961269A7 (fi) 1996-05-02
ES2115391T3 (es) 1998-06-16
CZ112796A3 (en) 1996-12-11
JPH09503251A (ja) 1997-03-31
ZA955988B (en) 1996-06-18
TR199500876A2 (tr) 1996-06-21
NO961109D0 (no) 1996-03-19
AU3113595A (en) 1996-02-16
MX9601040A (es) 1997-06-28
IL114659A (en) 2000-06-01
NO308904B1 (no) 2000-11-13
CA2171834A1 (en) 1996-02-01
ITMI941516A0 (it) 1994-07-20
NO961109L (no) 1996-05-15
DE69501720T2 (de) 1998-09-10
BR9506295A (pt) 1997-08-12
HU9601038D0 (en) 1996-06-28
WO1996002580A1 (en) 1996-02-01
JP3714678B2 (ja) 2005-11-09
RU2155774C2 (ru) 2000-09-10
IT1273661B (it) 1997-07-09
US6136932A (en) 2000-10-24
ITMI941516A1 (it) 1996-01-20
IL114659A0 (en) 1995-11-27
FI961269A0 (fi) 1996-03-19
KR960704940A (ko) 1996-10-09
US5849653A (en) 1998-12-15

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