ES2115391T3 - Catalizadores y procedimiento para la polimerizacion de olefinas. - Google Patents

Catalizadores y procedimiento para la polimerizacion de olefinas.

Info

Publication number
ES2115391T3
ES2115391T3 ES95926926T ES95926926T ES2115391T3 ES 2115391 T3 ES2115391 T3 ES 2115391T3 ES 95926926 T ES95926926 T ES 95926926T ES 95926926 T ES95926926 T ES 95926926T ES 2115391 T3 ES2115391 T3 ES 2115391T3
Authority
ES
Spain
Prior art keywords
sup
alkyl
sub
different
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95926926T
Other languages
English (en)
Inventor
Occo Tiziano Dall
Maurizio Galimberti
Luigi Resconi
Enrico Albizzati
Gianni Pennini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2115391T3 publication Critical patent/ES2115391T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE PRESENTAN CATALIZADORES PARA LA POLIMERIZACION DE OLEFINAS QUE CONTIENEN EL PRODUCTO DE REACCION DE: (A) UN COMPUESTO DE CICLOPENTADIENILO EN PUENTE Y/O SUSTITUIDO DE TITANIO, ZIRCONIO O HAFNIO; (B) UN COMPUESTO DE ALUMINIO ORGANOMETALICO DE LA FORMULA (II) AL(CH{SUB,2}CR{SUP,4}R{SUP,5}R{SUP,6}){SUB,W}R{SUP,7}{SUB,Y}H{SUB,Z}, EN DONDE EN LOS GRUPOS (CH{SUB,2}-CR{SUP,4}R{SUP,5}R{SUP,6}), QUE SON IGUALES O DIFERENTES, R{SUP,4} ES UN GRUPO ALQUILO, UNO ALQUENILO O UNO ARILALQUILO QUE TIENE DE 1 A 10 ATOMOS DE CARBONO, R{SUP,5} ES UN GRUPO ALQUILO, UNO ALQUENILO, UNO ARILO, UNO ARILALQUILO O UNO ALQUILARILO QUE TIENE DE 3 A 50 ATOMOS DE CARBONO QUE ES DISTINTO DE UN GRUPO ALQUILO O UNO ALQUENILO LINEAL Y, OPCIONALMENTE, R{SUP,4} Y R{SUP,5} FUSIONADOS ENTRE SI PUEDEN FORMAR UN ANILLO QUE TIENE DE 4 A 6 ATOMOS DE CARBONO, R{SUP,6} ES HIDROGENO O UN GRUPO ALQUILO, UNO ALQUENILO O UNO ARILALQUILO QUE TIENE DE 1 A 10 ATOMOS DE CARBONO. LOS SUSTITUYENTES R{SUP,7}, QUE SON IGUALES O DIFERENTES SONRADICALES DE ALQUILO, ALQUENILO, ARILO, ARIALQUILO O ALQUILARILO QUE CONTIENEN DE 1 A 10 ATOMOS DE CARBONO Y, OPCIONALMENTE, PUEDEN CONTENER ATOMOS DE SI O DE GE, W ES 1, 2 O 3, Z ES 0 O 1, Y = 3-W-Z; Y (C) AGUA. LA RELACION MOLAR DE ALUMINIO/AGUA ES DE 1:1 A 100:1. ESTOS CATALIZADORES PRESENTAN UNA ACTIVIDAD MEJORADA RESPECTO A LOS CATALIZADORES CONOCIDOS EN LOS QUE SE UTILIZA UN COMPUESTO DE ALUMINIO DIFERENTE DE LOS DE LA FORMULA ANTEDICHA.
ES95926926T 1994-07-20 1995-07-18 Catalizadores y procedimiento para la polimerizacion de olefinas. Expired - Lifetime ES2115391T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941516A IT1273661B (it) 1994-07-20 1994-07-20 Catalizzatori per la polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ES2115391T3 true ES2115391T3 (es) 1998-06-16

Family

ID=11369317

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95926926T Expired - Lifetime ES2115391T3 (es) 1994-07-20 1995-07-18 Catalizadores y procedimiento para la polimerizacion de olefinas.

Country Status (25)

Country Link
US (2) US5849653A (es)
EP (1) EP0720627B1 (es)
JP (1) JP3714678B2 (es)
KR (1) KR100356549B1 (es)
CN (1) CN1113899C (es)
AT (1) ATE163653T1 (es)
AU (1) AU695214B2 (es)
BG (1) BG100514A (es)
BR (1) BR9506295A (es)
CA (1) CA2171834A1 (es)
CZ (1) CZ112796A3 (es)
DE (1) DE69501720T2 (es)
ES (1) ES2115391T3 (es)
FI (1) FI961269A7 (es)
HU (1) HU215264B (es)
IL (1) IL114659A (es)
IT (1) IT1273661B (es)
MX (1) MX9601040A (es)
NO (1) NO308904B1 (es)
PL (1) PL313588A1 (es)
RU (1) RU2155774C2 (es)
SK (1) SK49496A3 (es)
TR (1) TR199500876A2 (es)
WO (1) WO1996002580A1 (es)
ZA (1) ZA955988B (es)

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IT1276752B1 (it) 1995-06-20 1997-11-03 Spherilene S P A Ora Montell I Catalizzatori e procedimenti per la polimerizzazione di olefine
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
EP0835886B1 (en) * 1996-10-09 2004-02-25 ATOFINA Research Process for preparing and using meso/racemic-(bis(indenyl)ethane)zirconium dichloride compounds
WO1999021896A1 (en) * 1997-10-29 1999-05-06 Montell Technology Company Bv Catalysts for the polymerization of olefins and process for the preparation thereof
US6559252B1 (en) * 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
US6001766A (en) * 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
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US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
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EP1214364B1 (en) * 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins
DE60109680T2 (de) 2000-01-18 2006-02-02 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
AU6230501A (en) 2000-05-24 2001-12-03 Basell Technology Company B.V. Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
DE60135502D1 (de) 2000-09-25 2008-10-02 Basell Polyolefine Gmbh Verfahren zur herstellung von ethylenpolymeren mit einer bis-amid-titanverbindung
DE60135311D1 (de) 2000-12-22 2008-09-25 Basell Polyolefine Gmbh Katalysatorkomponente fur die polymerisation von olefinen
WO2003000628A1 (en) * 2001-06-20 2003-01-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of oligomers
US7214745B2 (en) * 2001-08-07 2007-05-08 Denki Kagaku Kogyo Kabushiki Kaisha Process for producing polymer
KR20030087670A (ko) * 2002-05-09 2003-11-15 (주)다사테크 회전기계의 비접촉식 전원공급장치
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RU2355709C2 (ru) * 2004-11-04 2009-05-20 Шеврон Филлипс Кемикал Компани Лп Катализаторы для получения бимодальных смол на основе комбинации хроморганического соединения и металлоцена
TWI555574B (zh) 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
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KR102165484B1 (ko) * 2018-05-10 2020-10-14 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
KR102927908B1 (ko) 2020-10-15 2026-02-13 에스케이이노베이션 주식회사 폴리프로필렌의 제조방법

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Also Published As

Publication number Publication date
EP0720627A1 (en) 1996-07-10
CA2171834A1 (en) 1996-02-01
SK49496A3 (en) 1997-03-05
NO961109D0 (no) 1996-03-19
TR199500876A2 (tr) 1996-06-21
US5849653A (en) 1998-12-15
RU2155774C2 (ru) 2000-09-10
KR960704940A (ko) 1996-10-09
MX9601040A (es) 1997-06-28
BR9506295A (pt) 1997-08-12
AU3113595A (en) 1996-02-16
IT1273661B (it) 1997-07-09
HU215264B (hu) 1998-11-30
US6136932A (en) 2000-10-24
IL114659A (en) 2000-06-01
ITMI941516A0 (it) 1994-07-20
CN1135761A (zh) 1996-11-13
KR100356549B1 (ko) 2003-02-11
WO1996002580A1 (en) 1996-02-01
AU695214B2 (en) 1998-08-06
BG100514A (en) 1997-01-31
PL313588A1 (en) 1996-07-08
NO308904B1 (no) 2000-11-13
ZA955988B (en) 1996-06-18
NO961109L (no) 1996-05-15
FI961269A7 (fi) 1996-05-02
HUT74321A (en) 1996-12-30
DE69501720D1 (de) 1998-04-09
DE69501720T2 (de) 1998-09-10
CN1113899C (zh) 2003-07-09
IL114659A0 (en) 1995-11-27
CZ112796A3 (en) 1996-12-11
EP0720627B1 (en) 1998-03-04
JP3714678B2 (ja) 2005-11-09
FI961269A0 (fi) 1996-03-19
JPH09503251A (ja) 1997-03-31
ATE163653T1 (de) 1998-03-15
HU9601038D0 (en) 1996-06-28
ITMI941516A1 (it) 1996-01-20

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