ATE165611T1 - Verfahren zur herstellung eines polyesterharzschaumstoffes - Google Patents

Verfahren zur herstellung eines polyesterharzschaumstoffes

Info

Publication number
ATE165611T1
ATE165611T1 AT93102832T AT93102832T ATE165611T1 AT E165611 T1 ATE165611 T1 AT E165611T1 AT 93102832 T AT93102832 T AT 93102832T AT 93102832 T AT93102832 T AT 93102832T AT E165611 T1 ATE165611 T1 AT E165611T1
Authority
AT
Austria
Prior art keywords
polyester resin
producing
resin foam
foam sheet
crystallinity
Prior art date
Application number
AT93102832T
Other languages
English (en)
Inventor
Norio Amano
Takeshi Taki
Takaaki Hirai
Original Assignee
Sekisui Plastics
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27547787&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE165611(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP63302233A external-priority patent/JPH02150434A/ja
Priority claimed from JP366989A external-priority patent/JPH02251543A/ja
Priority claimed from JP1088633A external-priority patent/JP2528514B2/ja
Priority claimed from JP1088300A external-priority patent/JPH0688301B2/ja
Priority claimed from JP25004989A external-priority patent/JPH0698982B2/ja
Priority claimed from JP27304989A external-priority patent/JPH03134037A/ja
Application filed by Sekisui Plastics filed Critical Sekisui Plastics
Application granted granted Critical
Publication of ATE165611T1 publication Critical patent/ATE165611T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0012Combinations of extrusion moulding with other shaping operations combined with shaping by internal pressure generated in the material, e.g. foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
    • B65D1/22Boxes or like containers with side walls of substantial depth for enclosing contents
    • B65D1/26Thin-walled containers, e.g. formed by deep-drawing operations
    • B65D1/28Thin-walled containers, e.g. formed by deep-drawing operations formed of laminated material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/20Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535Five-membered rings
    • C08K5/1539Cyclic anhydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0264Polyester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/704Crystalline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08Dimensions, e.g. volume
    • B32B2309/10Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105Thickness
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1376Foam or porous material containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • Y10T428/249991Synthetic resin or natural rubbers
    • Y10T428/249992Linear or thermoplastic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Emergency Medicine (AREA)
  • Ceramic Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Table Devices Or Equipment (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
AT93102832T 1988-12-01 1989-12-01 Verfahren zur herstellung eines polyesterharzschaumstoffes ATE165611T1 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP63302233A JPH02150434A (ja) 1988-12-01 1988-12-01 ポリエステル系樹脂発泡体の製造法
JP366989A JPH02251543A (ja) 1989-01-12 1989-01-12 ポリエステル系樹脂発泡体の製造法
JP1088633A JP2528514B2 (ja) 1989-04-06 1989-04-06 熱可塑性ポリエステル系樹脂発泡シ―ト
JP1088300A JPH0688301B2 (ja) 1989-04-07 1989-04-07 耐熱性熱可塑性ポリエステル系樹脂発泡体の製造法
JP25004989A JPH0698982B2 (ja) 1989-09-25 1989-09-25 食品容器
JP27304989A JPH03134037A (ja) 1989-10-20 1989-10-20 熱可塑性ポリエステル系樹脂発泡体の製造方法

Publications (1)

Publication Number Publication Date
ATE165611T1 true ATE165611T1 (de) 1998-05-15

Family

ID=27547787

Family Applications (4)

Application Number Title Priority Date Filing Date
AT93102832T ATE165611T1 (de) 1988-12-01 1989-12-01 Verfahren zur herstellung eines polyesterharzschaumstoffes
AT93102839T ATE163442T1 (de) 1988-12-01 1989-12-01 Polyesterharzschaumstoffbahn
AT89312548T ATE136562T1 (de) 1988-12-01 1989-12-01 Verfahren zur herstellung eines polyesterharzschaumstoffes
AT93102840T ATE155757T1 (de) 1988-12-01 1989-12-01 Verfahren zur herstellung eines lebensmittelbehälters

Family Applications After (3)

Application Number Title Priority Date Filing Date
AT93102839T ATE163442T1 (de) 1988-12-01 1989-12-01 Polyesterharzschaumstoffbahn
AT89312548T ATE136562T1 (de) 1988-12-01 1989-12-01 Verfahren zur herstellung eines polyesterharzschaumstoffes
AT93102840T ATE155757T1 (de) 1988-12-01 1989-12-01 Verfahren zur herstellung eines lebensmittelbehälters

Country Status (9)

Country Link
US (1) US5000991B2 (de)
EP (4) EP0547032B2 (de)
KR (2) KR0118112B1 (de)
AT (4) ATE165611T1 (de)
AU (2) AU635230B2 (de)
CA (1) CA2004300C (de)
DE (4) DE68928659T2 (de)
ES (4) ES2112344T5 (de)
SG (1) SG46581A1 (de)

Families Citing this family (112)

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EP0536517A3 (en) * 1991-10-07 1993-06-02 Staeger & Co. Ag Plastic container produced by deep drawing
IT1252223B (it) * 1991-12-16 1995-06-05 M & G Ricerche Spa Resine poliestere cellulari e loro procedimento di preparazione
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US5229432A (en) * 1992-11-24 1993-07-20 E. I. Du Pont De Nemours And Company High melt strength pet polymers for foam applications and methods relating thereto
US5348984A (en) * 1993-01-28 1994-09-20 Sealed Air Corporation Expandable composition and process for extruded thermoplastic foams
US5288764A (en) * 1993-01-29 1994-02-22 Amoco Corporation Increased throughput in foaming and other melt fabrication of polyester
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JP3015628B2 (ja) * 1993-06-30 2000-03-06 日本プレストン株式会社 転写型化粧シートとその製造方法
IL110514A0 (en) * 1993-10-04 1994-10-21 Eastman Chem Co Concentrates for improving polyester compositions and a method for preparing such compositions
SE502080C2 (sv) * 1993-11-30 1995-08-07 Plm Ab Förpackningsmaterial, sätt att framställa detta, behållare bestående av sådant material samt användning av materialet för framställning av behållare
JPH07179736A (ja) * 1993-12-24 1995-07-18 Kanegafuchi Chem Ind Co Ltd 高溶融粘弾性発現性樹脂組成物およびそれを用いた芳香族ポリエステル系樹脂発泡体の製造法
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KR100363291B1 (ko) 1994-12-27 2003-05-09 세키스이가세이힝코교가부시키가이샤 열가소성폴리에스테르계수지발포체의연속적제조방법및제조장치
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US5696176A (en) * 1995-09-22 1997-12-09 Eastman Chemical Company Foamable polyester compositions having a low level of unreacted branching agent
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US5661193A (en) * 1996-05-10 1997-08-26 Eastman Chemical Company Biodegradable foamable co-polyester compositions
US6342173B1 (en) 1996-07-11 2002-01-29 Genpak, L.L.C. Method for producing polymer foam using a blowing agent combination
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US5679295A (en) * 1996-07-11 1997-10-21 Genpak Corporation Method for producing polyester foam using a blowing agent combination
US6099924A (en) * 1996-07-22 2000-08-08 Toyo Seikan Daisha, Ltd. Laminate and container made of the same
FI109286B (fi) * 1996-10-17 2002-06-28 Wihuri Oy Muovilaminaatti, menetelmä sen valmistamiseksi ja sen käyttö
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US5922782A (en) * 1997-07-23 1999-07-13 Eastman Chemical Company Foamable copolyesters prepared from divalent metal containing co-ionomers
IT1296878B1 (it) * 1997-12-17 1999-08-02 Sinco Ricerche Spa Schiume di poliestere flessibili
US5985190A (en) 1998-04-28 1999-11-16 Genpak, L.L.C. Method and system for forming low-density polymer foam article
WO1999061283A1 (en) 1998-05-27 1999-12-02 The Dow Chemical Company Vehicle headliner comprised of a thermoformable thermoplastic foam sheet
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ES2104973T3 (es) 1997-10-16
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ATE155757T1 (de) 1997-08-15
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US5000991B2 (en) 2000-07-11
US5000991B1 (en) 1997-09-16
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