ATE169936T1 - Herstellung von polyolefinen mit lankettiger verzweigung nach einem gasphaseverfahren - Google Patents
Herstellung von polyolefinen mit lankettiger verzweigung nach einem gasphaseverfahrenInfo
- Publication number
- ATE169936T1 ATE169936T1 AT94309546T AT94309546T ATE169936T1 AT E169936 T1 ATE169936 T1 AT E169936T1 AT 94309546 T AT94309546 T AT 94309546T AT 94309546 T AT94309546 T AT 94309546T AT E169936 T1 ATE169936 T1 AT E169936T1
- Authority
- AT
- Austria
- Prior art keywords
- gas phase
- phase process
- lang
- polyolefins
- production
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title 1
- 125000004429 atom Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000004122 cyclic group Chemical group 0.000 abstract 2
- -1 polyethylene Polymers 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17127293A | 1993-12-21 | 1993-12-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE169936T1 true ATE169936T1 (de) | 1998-09-15 |
Family
ID=22623168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT94309546T ATE169936T1 (de) | 1993-12-21 | 1994-12-20 | Herstellung von polyolefinen mit lankettiger verzweigung nach einem gasphaseverfahren |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0659773B2 (de) |
| JP (1) | JP2895408B2 (de) |
| AT (1) | ATE169936T1 (de) |
| AU (1) | AU697056B2 (de) |
| BR (1) | BR9405192A (de) |
| CA (1) | CA2138572C (de) |
| DE (1) | DE69412576T3 (de) |
| ES (1) | ES2122179T5 (de) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6538080B1 (en) | 1990-07-03 | 2003-03-25 | Bp Chemicals Limited | Gas phase polymerization of olefins |
| US5710224A (en) * | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
| US5525695A (en) * | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
| DK1134238T3 (da) * | 1994-04-07 | 2005-11-28 | Innovene Europ Ltd | Copolymerer |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| BR9602268A (pt) * | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Processo para a produção de polietileno e polietileno |
| CZ290641B6 (cs) * | 1995-12-18 | 2002-09-11 | Univation Technologies Llc | Způsob kontinuální výroby polymeru v plynné fázi reaktoru s fluidním ložem |
| US6114477A (en) * | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
| JPH09309926A (ja) | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
| ATE212648T1 (de) * | 1996-05-17 | 2002-02-15 | Bp Chem Int Ltd | Polyolefinzusammensetzung, deren molekulargewichtsmaximum sich in dem teil der zusammensetzung mit dem höheren comonomergehalt befindet |
| US6211310B1 (en) | 1997-06-05 | 2001-04-03 | Union Carbide Chemicals & Plastics Technology Corporation | Manufacture of stereoregular polymers |
| US5693727A (en) * | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| US6759499B1 (en) | 1996-07-16 | 2004-07-06 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process with alkyl-substituted metallocenes |
| US6180736B1 (en) | 1996-12-20 | 2001-01-30 | Exxon Chemical Patents Inc | High activity metallocene polymerization process |
| US6114457A (en) * | 1997-02-07 | 2000-09-05 | Exxon Chemical Patents Inc. | High melt strength polyethylene compositions |
| US6355757B2 (en) | 1997-02-14 | 2002-03-12 | Exxonmobil Chemical Patents, Inc. | Processing olefin copolymers |
| US6420507B1 (en) | 1997-05-01 | 2002-07-16 | The Dow Chemical Company | Olefin polymers prepared with substituted indenyl containing metal complexes |
| NL1006346C2 (nl) * | 1997-06-18 | 1998-12-21 | Dsm Nv | Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen. |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US6677265B1 (en) | 1997-12-08 | 2004-01-13 | Albemarle Corporation | Process of producing self-supported catalysts |
| GB9800245D0 (en) * | 1998-01-07 | 1998-03-04 | Bp Chem Int Ltd | Novel polymers |
| EP1098934A1 (de) | 1998-07-01 | 2001-05-16 | Exxon Chemical Patents Inc. | Elastische mischung mit kristallpolymeren und kristallisierbaren polymeren des propens |
| MXPA01004337A (es) | 1998-11-02 | 2002-04-24 | Pont Dow Elastomers L L C Du | Interpolimeros de alfa-olefina/etileno que disminuyen el esfuerzo cortante. |
| WO2000050466A1 (en) * | 1999-02-22 | 2000-08-31 | Borealis Technology Oy | Olefin polymerisation process |
| SK5492002A3 (en) * | 1999-10-22 | 2002-12-03 | Univation Tech Llc | Start up methods for multiple catalyst systems |
| ATE485319T1 (de) | 2001-04-12 | 2010-11-15 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von propylen und ethylen in lösung |
| US6825293B1 (en) | 2001-08-20 | 2004-11-30 | Nova Chemicals (International) S.A. | Polymer control through co-catalyst |
| SG147306A1 (en) | 2001-11-06 | 2008-11-28 | Dow Global Technologies Inc | Isotactic propylene copolymers, their preparation and use |
| US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| US7579407B2 (en) | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| WO2005028584A1 (en) | 2003-08-19 | 2005-03-31 | Dow Global Technologies Inc. | Interpolymers suitable for use in hot melt adhesives and processes to prepare same |
| US7309741B2 (en) | 2004-06-01 | 2007-12-18 | Nova Chemicals (International) S.A. | Polyolefin blends and pipe |
| US7211535B2 (en) | 2004-10-29 | 2007-05-01 | Nova Chemicals Corporation | Enhanced polyolefin catalyst |
| US7323523B2 (en) | 2004-12-07 | 2008-01-29 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
| US7321015B2 (en) | 2004-12-07 | 2008-01-22 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
| EP1964860B1 (de) * | 2005-12-19 | 2017-07-05 | Tosoh Corporation | Ethylenpolymer, katalysator zur herstellung von ethylenpolymer und verfahren zur herstellung von ethylenpolymer |
| JP2007177168A (ja) * | 2005-12-28 | 2007-07-12 | Nippon Polyethylene Kk | ポリエチレン系フィルム及びその積層フィルム並びにそれらから形成される包装用袋体 |
| JP5174333B2 (ja) * | 2006-07-31 | 2013-04-03 | 三井化学株式会社 | 積層体用樹脂組成物および積層体 |
| JP5014701B2 (ja) * | 2006-07-31 | 2012-08-29 | 三井化学株式会社 | 肉厚フィルムおよびその製造方法ならびにその用途 |
| JP2008031385A (ja) * | 2006-07-31 | 2008-02-14 | Mitsui Chemicals Inc | 熱可塑性樹脂用改質材および樹脂組成物 |
| KR101096836B1 (ko) * | 2006-07-31 | 2011-12-22 | 가부시키가이샤 프라임 폴리머 | 에틸렌계 수지 또는 에틸렌계 수지 조성물로 이루어지는 필름 또는 적층체 |
| CN101868471A (zh) | 2007-11-19 | 2010-10-20 | 三井化学株式会社 | 交联茂金属化合物以及使用其的烯烃聚合用催化剂、以及使用该催化剂得到的乙烯系聚合物 |
| CN103038264A (zh) * | 2010-04-05 | 2013-04-10 | 陶氏环球技术有限责任公司 | 用于以冷凝的和超-冷凝的模式聚合含有高分子量部分的基于烯烃的聚合物的方法 |
| CN106279485B (zh) | 2011-03-30 | 2018-10-02 | 日本聚乙烯株式会社 | 乙烯类聚合物、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法 |
| CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2742461C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
| US8796409B2 (en) | 2011-10-04 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene |
| WO2013052273A2 (en) * | 2011-10-04 | 2013-04-11 | Exxonmobil Chemical Patents Inc. | Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene |
| US9309337B2 (en) | 2012-04-02 | 2016-04-12 | Exxonmobil Research And Engineering Company | Branched saturated hydrocarbon polymers as extensional rheology modifiers without impacting shear properties |
| US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
| CA2797620C (en) | 2012-12-03 | 2019-08-27 | Nova Chemicals Corporation | Controlling resin properties in a gas phase polymerization process |
| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
| CA2890606C (en) | 2015-05-07 | 2022-07-19 | Nova Chemicals Corporation | Process for polymerization using dense and spherical ziegler-natta type catalyst |
| CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
| CA2900772C (en) | 2015-08-20 | 2022-07-12 | Nova Chemicals Corporation | Method for altering melt flow ratio of ethylene polymers |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY107639A (en) * | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5317036A (en) † | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
-
1994
- 1994-12-20 CA CA002138572A patent/CA2138572C/en not_active Expired - Fee Related
- 1994-12-20 DE DE69412576T patent/DE69412576T3/de not_active Expired - Fee Related
- 1994-12-20 AU AU81524/94A patent/AU697056B2/en not_active Ceased
- 1994-12-20 JP JP6334655A patent/JP2895408B2/ja not_active Expired - Lifetime
- 1994-12-20 AT AT94309546T patent/ATE169936T1/de not_active IP Right Cessation
- 1994-12-20 EP EP94309546A patent/EP0659773B2/de not_active Expired - Lifetime
- 1994-12-20 ES ES94309546T patent/ES2122179T5/es not_active Expired - Lifetime
- 1994-12-21 BR BR9405192A patent/BR9405192A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE69412576T3 (de) | 2002-05-29 |
| ES2122179T5 (es) | 2002-12-01 |
| ES2122179T3 (es) | 1998-12-16 |
| BR9405192A (pt) | 1995-08-01 |
| JPH07252311A (ja) | 1995-10-03 |
| DE69412576T2 (de) | 1998-12-24 |
| CA2138572C (en) | 1999-08-24 |
| EP0659773A1 (de) | 1995-06-28 |
| AU8152494A (en) | 1995-06-29 |
| EP0659773B2 (de) | 2001-12-05 |
| JP2895408B2 (ja) | 1999-05-24 |
| AU697056B2 (en) | 1998-09-24 |
| DE69412576D1 (de) | 1998-09-24 |
| CA2138572A1 (en) | 1995-06-22 |
| EP0659773B1 (de) | 1998-08-19 |
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Legal Events
| Date | Code | Title | Description |
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