ATE190521T1 - Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen - Google Patents

Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen

Info

Publication number
ATE190521T1
ATE190521T1 AT94202241T AT94202241T ATE190521T1 AT E190521 T1 ATE190521 T1 AT E190521T1 AT 94202241 T AT94202241 T AT 94202241T AT 94202241 T AT94202241 T AT 94202241T AT E190521 T1 ATE190521 T1 AT E190521T1
Authority
AT
Austria
Prior art keywords
olefins
aliphatic hydrocarbons
silicacid
functionalized
catalyst based
Prior art date
Application number
AT94202241T
Other languages
English (en)
Inventor
Mario Gabriele Clerici
Carlo Perego
Angelis Alberto De
Luciano Montanari
Original Assignee
Enitecnologie Spa
Agip Petroli
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enitecnologie Spa, Agip Petroli filed Critical Enitecnologie Spa
Application granted granted Critical
Publication of ATE190521T1 publication Critical patent/ATE190521T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicon Polymers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicon Compounds (AREA)
AT94202241T 1993-08-06 1994-08-01 Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen ATE190521T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Publications (1)

Publication Number Publication Date
ATE190521T1 true ATE190521T1 (de) 2000-04-15

Family

ID=11366796

Family Applications (1)

Application Number Title Priority Date Filing Date
AT94202241T ATE190521T1 (de) 1993-08-06 1994-08-01 Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen

Country Status (19)

Country Link
US (2) US5571762A (de)
EP (1) EP0638363B1 (de)
JP (1) JPH07165414A (de)
KR (1) KR100194230B1 (de)
CN (1) CN1054152C (de)
AT (1) ATE190521T1 (de)
AU (1) AU683661B2 (de)
BR (1) BR9403189A (de)
CA (1) CA2129389A1 (de)
DE (1) DE69423398T2 (de)
DK (1) DK0638363T3 (de)
ES (1) ES2142907T3 (de)
GR (1) GR3032968T3 (de)
HU (1) HU214083B (de)
IT (1) IT1265051B1 (de)
MX (1) MXPA99005011A (de)
PL (2) PL179479B1 (de)
PT (1) PT638363E (de)
RU (1) RU2126295C1 (de)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2729968B1 (fr) * 1995-01-27 1997-04-11 Inst Francais Du Petrole Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres
CN1045305C (zh) * 1995-12-20 1999-09-29 中国石油化工总公司石油化工科学研究院 重整生成油烯烃饱和加氢工艺
DK172907B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til rensning af en carbonhydridstrøm
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
DK123796A (da) * 1996-11-05 1998-05-06 Haldor Topsoe As Fremgangsmåde til fremstilling af carbonhydrid produkt med et højt indhold af middeldistilleret produktfraktionering
EP1140357A4 (de) * 1997-05-07 2002-05-08 George A Olah Fester supersaurer katalysator im nano-massstab mit seitenständigen gruppen fluor-alkyl-sulfonischer, fluor- oder perfluor-alkylsulfonischer säure
WO1999008960A1 (fr) * 1997-08-20 1999-02-25 Asahi Kasei Kogyo Kabushiki Kaisha Corps spherique poreux
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6277342B1 (en) * 1999-08-23 2001-08-21 Air Products And Chemicals, Inc. Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers
KR100642775B1 (ko) * 2000-06-17 2006-11-13 주식회사 엘지이아이 김치냉장고의 숙성제어방법 및 장치
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030018970A1 (en) * 2001-07-19 2003-01-23 Digeo, Inc. Object representation of television programs within an interactive television system
WO2005021468A1 (en) 2003-07-15 2005-03-10 Grt, Inc. Hydrocarbon synthesis
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US8329603B2 (en) * 2003-09-16 2012-12-11 Uop Llc Isoparaffin-olefin alkylation
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20070098619A1 (en) * 2005-10-27 2007-05-03 Harmer Mark A Porous microcomposite of fluorinated sulfonic acid and a network of silica
AU2007212493B2 (en) 2006-02-03 2012-09-27 Grt, Inc. Separation of light gases from halogens
US7579510B2 (en) 2006-02-03 2009-08-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
SG192538A1 (en) 2008-07-18 2013-08-30 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN117943003A (zh) * 2024-01-29 2024-04-30 西北工业大学 一种超疏水强酸磁性催化剂及其制备方法和应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1020590A (en) * 1973-05-21 1977-11-08 Gulf Research And Development Company Hydrogen fluoride alkylation of iso-paraffins in the presence of trifluoromethanesulfonic acid
US3970721A (en) * 1975-03-24 1976-07-20 Texaco Inc. Alkylation process for production of motor fuels utilizing sulfuric acid catalyst with trifluoromethane sulfonic acid
IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
US4636488A (en) * 1985-08-12 1987-01-13 Uop Inc. Novel motor fuel alkylation catalyst and process for the use thereof
US4847223A (en) * 1988-04-08 1989-07-11 Concordia University Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene
IT1226550B (it) * 1988-07-29 1991-01-24 Enichem Anic Spa Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo.
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5245100A (en) * 1989-12-18 1993-09-14 Haldor Topsoe, S.A. Alkylation process
US5179052A (en) * 1991-03-04 1993-01-12 Texaco Chemical Company One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts
EP0539277B1 (de) * 1991-10-25 1996-01-10 Institut Francais Du Petrole Verwendung von einem Katalysator zur Alkylierung von Paraffinen
CA2099359C (en) * 1992-08-27 1999-06-15 Alan D. Eastman Alkylation catalyst regeneration
US5233119A (en) * 1992-11-09 1993-08-03 Phillips Petroleum Company Alkylation process and catalyst therefor

Also Published As

Publication number Publication date
PT638363E (pt) 2000-06-30
BR9403189A (pt) 1995-04-11
PL179947B1 (pl) 2000-11-30
ES2142907T3 (es) 2000-05-01
DK0638363T3 (da) 2000-07-24
ITMI931796A0 (it) 1993-08-06
KR100194230B1 (ko) 1999-06-15
RU94028658A (ru) 1996-06-20
RU2126295C1 (ru) 1999-02-20
CN1054152C (zh) 2000-07-05
HU214083B (en) 1997-12-29
CA2129389A1 (en) 1995-02-07
IT1265051B1 (it) 1996-10-28
DE69423398T2 (de) 2000-11-02
AU683661B2 (en) 1997-11-20
HU9402296D0 (en) 1994-09-28
KR950005781A (ko) 1995-03-20
PL179479B1 (pl) 2000-09-29
EP0638363B1 (de) 2000-03-15
AU6885394A (en) 1995-02-16
GR3032968T3 (en) 2000-07-31
US5571762A (en) 1996-11-05
MXPA99005011A (es) 2004-08-31
DE69423398D1 (de) 2000-04-20
JPH07165414A (ja) 1995-06-27
HUT71951A (en) 1996-02-28
CN1108293A (zh) 1995-09-13
US5659105A (en) 1997-08-19
ITMI931796A1 (it) 1995-02-06
EP0638363A1 (de) 1995-02-15
PL304574A1 (en) 1995-02-20

Similar Documents

Publication Publication Date Title
DE69423398D1 (de) Katalysator auf der Basis von funktionalisierte Kieselsaüre und Verfahren zur Alkylierung von aliphatischen Kohlenwasserstoffen mit Olefinen
DE69423237D1 (de) Verfahren zur herstellung eines katalysators für die polymerisation von olefinen
BR8404278A (pt) Processo para polimerizar acidos carboxilicos olefinicamente insaturados
MX165925B (es) Produccion de olefinas ligeras
BR9000416A (pt) Catalisadores para polimerizacao de olefinas
DE3575418D1 (de) Verfahren zur reinigung von methacrylsaeure.
ATE89308T1 (de) Verfahren zur herstellung von olefinen.
BR8305246A (pt) Processo para polimerizacao de acidos carboxilicos olefinicamente insaturados
BR9303478A (pt) Processo para desativacao de um catalisador de elemento de transicao de ziegler-natta empregado em reacoes de polimerizacao de olefinas
ATE90946T1 (de) Verfahren zur verringerung der schmelzfluessigkeit von olefinpolymerprodukten.
ATE120167T1 (de) Verfahren zur umlagerung von geminalen allylischen dihalogenverbindungen.
DE3873000D1 (de) Verfahren zur herstellung von oligomeren aus olefinen unter verwendung eines modifizierten mordenit-katalysators.
ATE26287T1 (de) Verfahren zur herstellung von halbester-addukt modifizierten polymerpolyolen.
ATE147715T1 (de) Verfahren zur herstellung eines alkylsubstituierten kohlenwasserstoffes
ATA447580A (de) Verfahren zur herstellung eines katalysators fuer die polymerisation von olefinen
ATE29022T1 (de) Verfahren zur valenzisomerisierung von olefinen.
ATE85600T1 (de) Verfahren zur herstellung von nabumeton.
ATE45946T1 (de) Verfahren zur herstellung von dialkyldisulfiden.
ATE178062T1 (de) Verfahren zur herstellung von chromanen
DE68913612D1 (de) Verfahren zur Olefinpolymerisation Gasphasen-Wirbelbettreaktor mit Zuführung einer Organo-Metallverbindung.
ATE80602T1 (de) Verfahren zur herstellung von hydroxybiphenylen.
MX9205871A (es) Sistema catalizador y proceso para la preparacion de un polimero que utiliza dicho sistema catalizador.
ATE136560T1 (de) Verfahren zur herstellung von farblosen kohlenwasserstoffharzen und nach diesem verfahren hergestellte produkte
ATE53017T1 (de) Verfahren zur herstellung von sekundaeren merkaptanen aus linearen olefinen.
ATE96771T1 (de) Verfahren zur herstellung von paralkylbiphenylen.

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee