DK0638363T3 - Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner - Google Patents

Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner

Info

Publication number
DK0638363T3
DK0638363T3 DK94202241T DK94202241T DK0638363T3 DK 0638363 T3 DK0638363 T3 DK 0638363T3 DK 94202241 T DK94202241 T DK 94202241T DK 94202241 T DK94202241 T DK 94202241T DK 0638363 T3 DK0638363 T3 DK 0638363T3
Authority
DK
Denmark
Prior art keywords
silica
olefins
oleides
inoculated
aliphatic carbon
Prior art date
Application number
DK94202241T
Other languages
English (en)
Inventor
Carlo Perego
Angelis Alberto De
Luciano Montanari
Mario Gabriele Clerici
Original Assignee
Enitecnologie Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enitecnologie Spa filed Critical Enitecnologie Spa
Application granted granted Critical
Publication of DK0638363T3 publication Critical patent/DK0638363T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicon Polymers (AREA)
DK94202241T 1993-08-06 1994-08-01 Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner DK0638363T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Publications (1)

Publication Number Publication Date
DK0638363T3 true DK0638363T3 (da) 2000-07-24

Family

ID=11366796

Family Applications (1)

Application Number Title Priority Date Filing Date
DK94202241T DK0638363T3 (da) 1993-08-06 1994-08-01 Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner

Country Status (19)

Country Link
US (2) US5571762A (da)
EP (1) EP0638363B1 (da)
JP (1) JPH07165414A (da)
KR (1) KR100194230B1 (da)
CN (1) CN1054152C (da)
AT (1) ATE190521T1 (da)
AU (1) AU683661B2 (da)
BR (1) BR9403189A (da)
CA (1) CA2129389A1 (da)
DE (1) DE69423398T2 (da)
DK (1) DK0638363T3 (da)
ES (1) ES2142907T3 (da)
GR (1) GR3032968T3 (da)
HU (1) HU214083B (da)
IT (1) IT1265051B1 (da)
MX (1) MXPA99005011A (da)
PL (2) PL179479B1 (da)
PT (1) PT638363E (da)
RU (1) RU2126295C1 (da)

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CN1045305C (zh) * 1995-12-20 1999-09-29 中国石油化工总公司石油化工科学研究院 重整生成油烯烃饱和加氢工艺
DK172907B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til rensning af en carbonhydridstrøm
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
DK123796A (da) * 1996-11-05 1998-05-06 Haldor Topsoe As Fremgangsmåde til fremstilling af carbonhydrid produkt med et højt indhold af middeldistilleret produktfraktionering
EP1140357A4 (en) * 1997-05-07 2002-05-08 George A Olah SOLID SUPER ACID CATALYST ON THE NANO SCALE WITH SIDE STANDARD GROUPS OF FLUOR-ALKYL-SULFONIC, FLUORIC OR PERFLUOR-ALKYLSULFONIC ACID
WO1999008960A1 (fr) * 1997-08-20 1999-02-25 Asahi Kasei Kogyo Kabushiki Kaisha Corps spherique poreux
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6277342B1 (en) * 1999-08-23 2001-08-21 Air Products And Chemicals, Inc. Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers
KR100642775B1 (ko) * 2000-06-17 2006-11-13 주식회사 엘지이아이 김치냉장고의 숙성제어방법 및 장치
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030018970A1 (en) * 2001-07-19 2003-01-23 Digeo, Inc. Object representation of television programs within an interactive television system
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
MXPA06000470A (es) 2003-07-15 2006-08-23 Grt Inc Sintesis de hidrocarburos.
US8329603B2 (en) * 2003-09-16 2012-12-11 Uop Llc Isoparaffin-olefin alkylation
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20070098619A1 (en) * 2005-10-27 2007-05-03 Harmer Mark A Porous microcomposite of fluorinated sulfonic acid and a network of silica
CN101817720A (zh) 2006-02-03 2010-09-01 Grt公司 天然气转化为液体烃的连续方法
EP1993951B1 (en) 2006-02-03 2014-07-30 GRT, Inc. Separation of light gases from bromine
AU2008256606A1 (en) 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
NZ591207A (en) 2008-07-18 2013-03-28 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN117943003B (zh) * 2024-01-29 2026-07-17 西北工业大学 一种超疏水强酸磁性催化剂及其制备方法和应用

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CA1020590A (en) * 1973-05-21 1977-11-08 Gulf Research And Development Company Hydrogen fluoride alkylation of iso-paraffins in the presence of trifluoromethanesulfonic acid
US3970721A (en) * 1975-03-24 1976-07-20 Texaco Inc. Alkylation process for production of motor fuels utilizing sulfuric acid catalyst with trifluoromethane sulfonic acid
IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
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Also Published As

Publication number Publication date
US5571762A (en) 1996-11-05
JPH07165414A (ja) 1995-06-27
PL304574A1 (en) 1995-02-20
DE69423398T2 (de) 2000-11-02
GR3032968T3 (en) 2000-07-31
HUT71951A (en) 1996-02-28
RU2126295C1 (ru) 1999-02-20
CA2129389A1 (en) 1995-02-07
EP0638363A1 (en) 1995-02-15
ATE190521T1 (de) 2000-04-15
US5659105A (en) 1997-08-19
HU9402296D0 (en) 1994-09-28
DE69423398D1 (de) 2000-04-20
PL179947B1 (pl) 2000-11-30
KR100194230B1 (ko) 1999-06-15
PT638363E (pt) 2000-06-30
ITMI931796A1 (it) 1995-02-06
HU214083B (en) 1997-12-29
RU94028658A (ru) 1996-06-20
BR9403189A (pt) 1995-04-11
ITMI931796A0 (it) 1993-08-06
MXPA99005011A (es) 2004-08-31
AU6885394A (en) 1995-02-16
CN1054152C (zh) 2000-07-05
PL179479B1 (pl) 2000-09-29
KR950005781A (ko) 1995-03-20
CN1108293A (zh) 1995-09-13
AU683661B2 (en) 1997-11-20
ES2142907T3 (es) 2000-05-01
EP0638363B1 (en) 2000-03-15
IT1265051B1 (it) 1996-10-28

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