ATE199562T1 - Verfahren zur herstellung eines styrolpolymeres und darin anwendbarer katalysator - Google Patents
Verfahren zur herstellung eines styrolpolymeres und darin anwendbarer katalysatorInfo
- Publication number
- ATE199562T1 ATE199562T1 AT92122164T AT92122164T ATE199562T1 AT E199562 T1 ATE199562 T1 AT E199562T1 AT 92122164 T AT92122164 T AT 92122164T AT 92122164 T AT92122164 T AT 92122164T AT E199562 T1 ATE199562 T1 AT E199562T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- producing
- styrene polymer
- electron
- styrenic polymer
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229940100198 alkylating agent Drugs 0.000 abstract 1
- 239000002168 alkylating agent Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910021480 group 4 element Inorganic materials 0.000 abstract 1
- 150000008040 ionic compounds Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- -1 tetra(pentafluorophenyl)borate Chemical compound 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP00123192A JP3194438B2 (ja) | 1992-01-08 | 1992-01-08 | スチレン系重合体の製造方法及びその触媒 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE199562T1 true ATE199562T1 (de) | 2001-03-15 |
Family
ID=11495702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT92122164T ATE199562T1 (de) | 1992-01-08 | 1992-12-31 | Verfahren zur herstellung eines styrolpolymeres und darin anwendbarer katalysator |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US5461128A (de) |
| EP (1) | EP0554574B1 (de) |
| JP (1) | JP3194438B2 (de) |
| AT (1) | ATE199562T1 (de) |
| DE (1) | DE69231722T2 (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5763549A (en) * | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| US5350723A (en) † | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| DE69325716T2 (de) * | 1992-10-05 | 2000-04-27 | Exxon Chemical Patents, Inc. | Polymerisationsverfahren mittels eines katalysatorsystems mit gesteigertem leistungsvermögen |
| JP3216662B2 (ja) * | 1992-10-08 | 2001-10-09 | 出光興産株式会社 | スチレン系重合体の製造方法 |
| EP1004604A3 (de) * | 1993-03-31 | 2001-01-17 | Idemitsu Kosan Co., Ltd. | Katalysator zur Herstellung von Vinylpolymeren und Verfahren zur Herstellung von aromatischen Vinylpolymeren |
| DE69426648D1 (de) * | 1993-06-15 | 2001-03-08 | Idemitsu Kosan Co | Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation |
| JPH0733812A (ja) * | 1993-07-02 | 1995-02-03 | Idemitsu Kosan Co Ltd | スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法 |
| JP3189175B2 (ja) * | 1993-07-02 | 2001-07-16 | 出光興産株式会社 | 芳香族ビニル化合物共重合体の製造方法 |
| JP3216748B2 (ja) * | 1993-07-23 | 2001-10-09 | 出光興産株式会社 | 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法 |
| JP3369294B2 (ja) * | 1994-03-11 | 2003-01-20 | 出光興産株式会社 | 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法 |
| US6008307A (en) * | 1994-04-28 | 1999-12-28 | Exxon Chemical Patents Inc | Process for producing olefin polymers using cationic catalysts |
| US6291389B1 (en) | 1994-04-28 | 2001-09-18 | Exxonmobil Chemical Patents Inc. | Cationic polymerization catalysts |
| US5625087A (en) * | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| JPH08134122A (ja) * | 1994-11-11 | 1996-05-28 | Idemitsu Kosan Co Ltd | 重合用触媒及びそれを用いたスチレン系重合体の製造方法 |
| DE19509785A1 (de) * | 1995-03-17 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von vinylaromatischen Verbindungen unter Druck in Gegenwart von leicht flüchtigen Kohlenwasserstoffen |
| IT1276801B1 (it) * | 1995-06-30 | 1997-11-03 | Enichem Spa | Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica |
| ES2152567T3 (es) * | 1995-11-27 | 2001-02-01 | Dow Chemical Co | Catalizador soportado que contiene un activador de formacion de cationes enlazados. |
| US5644009A (en) * | 1995-11-27 | 1997-07-01 | Industrial Technology Research Institute | Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same |
| JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
| US5895771A (en) * | 1997-06-05 | 1999-04-20 | Akzo Nobel Nv | Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations |
| CN1055096C (zh) * | 1997-09-03 | 2000-08-02 | 中国石油化工总公司 | 制备苯乙烯间规聚合物的催化剂 |
| CN1055097C (zh) * | 1997-09-03 | 2000-08-02 | 中国石油化工总公司 | 制备间规聚苯乙烯的催化剂 |
| DE19757540A1 (de) * | 1997-12-23 | 1999-06-24 | Hoechst Ag | Geträgertes Katalysatorsystem zur Polymerisation von Olefinen |
| EP1093476B1 (de) * | 1998-06-30 | 2004-04-28 | Dow Global Technologies, Inc. | Syndiotaktisches monovinylidenearomatisches polymerisationsverfahren |
| US20020002256A1 (en) * | 1998-09-16 | 2002-01-03 | Thomas Henry Peterson | Catalyst composition for the polymerization of olefins |
| US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| US6479424B1 (en) | 1998-12-14 | 2002-11-12 | Bp Corporation North America Inc. | Fluxional catalysts and related ligands containing bulky substituents |
| US6232414B1 (en) | 1999-03-31 | 2001-05-15 | Phillips Petroleum Company | Process to make a monovinylaromatic polymer and said monovinylaromatic polymer |
| JP2002179714A (ja) * | 2000-12-12 | 2002-06-26 | Idemitsu Petrochem Co Ltd | 重合体混合物の製造方法 |
| JP6704808B2 (ja) * | 2016-07-05 | 2020-06-03 | 株式会社Adeka | 薄膜形成用原料及び薄膜の製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5066741A (en) * | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
| EP0426637B2 (de) * | 1989-10-30 | 2001-09-26 | Fina Technology, Inc. | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation |
| JP2888648B2 (ja) * | 1990-12-28 | 1999-05-10 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
-
1992
- 1992-01-08 JP JP00123192A patent/JP3194438B2/ja not_active Expired - Fee Related
- 1992-12-31 AT AT92122164T patent/ATE199562T1/de not_active IP Right Cessation
- 1992-12-31 DE DE69231722T patent/DE69231722T2/de not_active Expired - Fee Related
- 1992-12-31 EP EP92122164A patent/EP0554574B1/de not_active Expired - Lifetime
-
1993
- 1993-01-04 US US08/000,213 patent/US5461128A/en not_active Expired - Fee Related
-
1995
- 1995-05-12 US US08/440,135 patent/US5543481A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5543481A (en) | 1996-08-06 |
| EP0554574A1 (de) | 1993-08-11 |
| JPH05186527A (ja) | 1993-07-27 |
| JP3194438B2 (ja) | 2001-07-30 |
| EP0554574B1 (de) | 2001-03-07 |
| DE69231722T2 (de) | 2001-06-21 |
| DE69231722D1 (de) | 2001-04-12 |
| US5461128A (en) | 1995-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |