ATE217318T1 - Ansa bis(.mu.-aluminium)-substituierte gruppe-4- metallkomplexe - Google Patents

Ansa bis(.mu.-aluminium)-substituierte gruppe-4- metallkomplexe

Info

Publication number
ATE217318T1
ATE217318T1 AT99927519T AT99927519T ATE217318T1 AT E217318 T1 ATE217318 T1 AT E217318T1 AT 99927519 T AT99927519 T AT 99927519T AT 99927519 T AT99927519 T AT 99927519T AT E217318 T1 ATE217318 T1 AT E217318T1
Authority
AT
Austria
Prior art keywords
group
aluminum
metal
groups
ansa
Prior art date
Application number
AT99927519T
Other languages
English (en)
Inventor
Eugene Y Chen
William J Kruper Jr
Peter N Nickias
David R Wilson
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE217318T1 publication Critical patent/ATE217318T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Dental Preparations (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
AT99927519T 1998-08-11 1999-06-11 Ansa bis(.mu.-aluminium)-substituierte gruppe-4- metallkomplexe ATE217318T1 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US9608898P 1998-08-11 1998-08-11
US9680098P 1998-08-17 1998-08-17
US10049098P 1998-09-16 1998-09-16
US10422998P 1998-10-14 1998-10-14
US12261599P 1999-03-03 1999-03-03
PCT/US1999/013344 WO2000009523A1 (en) 1998-08-11 1999-06-11 Ansa-group-4-metal bis (.mu.-substituted) aluminum complexes

Publications (1)

Publication Number Publication Date
ATE217318T1 true ATE217318T1 (de) 2002-05-15

Family

ID=27536779

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99927519T ATE217318T1 (de) 1998-08-11 1999-06-11 Ansa bis(.mu.-aluminium)-substituierte gruppe-4- metallkomplexe

Country Status (9)

Country Link
US (1) US6140521A (de)
EP (1) EP1104429B1 (de)
JP (1) JP2002522551A (de)
AT (1) ATE217318T1 (de)
AU (1) AU4440499A (de)
CA (1) CA2337024A1 (de)
DE (1) DE69901451T2 (de)
MY (1) MY133950A (de)
WO (1) WO2000009523A1 (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US6214760B1 (en) * 1998-08-11 2001-04-10 The Dow Chemical Company Catalyst activator composition
WO2005090425A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
EP2792690B1 (de) 2004-03-17 2019-05-15 Dow Global Technologies LLC Katalysatorzusammensetzung mit Kettenübertragungsreagenz (chain shuttling) zur Herstellung von Ethylen-Multiblock-Copolymeren
NZ549262A (en) 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
CN102321201B (zh) 2004-06-16 2013-06-26 陶氏环球技术有限责任公司 选择聚合改性剂的方法
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
EP2894176B1 (de) * 2005-03-17 2022-06-01 Dow Global Technologies LLC Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
CA2600140A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
KR20080055838A (ko) 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. 다중심 셔틀링제를 통한 중합체 구성 및 분자량 분포의제어
AR058449A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Copolimeros de bloque de olefina cataliticos via un agente de transferencia polimerizable
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
BRPI0711029A2 (pt) * 2006-05-17 2011-05-31 Dow Global Technologies Inc processo para polimerização de etileno e uma ou mais a-olefinas ou diolefinas de c3-30
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ES2435568T3 (es) * 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
US8592615B2 (en) 2009-03-06 2013-11-26 Dow Global Technologies, Llc Catalysts, processes for making catalysts, processes for making polyolefin compositions, and polyolefin compositions
WO2011016992A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Polymeric chain transfer/shuttling agents
BR112012001948B1 (pt) 2009-07-29 2019-08-20 Dow Global Technologies Llc Agente de translado de cadeia, processo para a polimerização de pelo menos um monômero polimerizável por adição, copolímero em multi-bloco e composição de catalisador
CN108026115B (zh) 2015-09-30 2021-11-09 陶氏环球技术有限责任公司 可用于链穿梭的多头或双头组合物及其制备方法
WO2018064553A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3519474B1 (de) 2016-09-30 2024-09-25 Dow Global Technologies LLC Verfahren zur herstellung von mehrfach- oder doppelkopfzusammensetzungen zur kettenübertragung
JP7029448B2 (ja) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用な封鎖されたマルチまたはデュアルヘッド組成物、およびそれを調製するプロセス
ES3040148T3 (en) 2018-12-28 2025-10-28 Dow Global Technologies Llc Organometallic chain transfer agents
US20220073540A1 (en) 2018-12-28 2022-03-10 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
US12590174B2 (en) 2018-12-28 2026-03-31 Dow Global Technologies Llc Curable compositions comprising telechelic polyolefins
CN113454091A (zh) 2018-12-28 2021-09-28 陶氏环球技术有限责任公司 包括不饱和聚烯烃的可固化组合物
SG11202107051UA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
JPH05230134A (ja) * 1992-02-24 1993-09-07 Mitsui Toatsu Chem Inc 分子量分布の広いポリオレフィンの製造方法
KR100292158B1 (ko) * 1992-08-04 2001-06-01 가지와라 야스시 올레핀중합용 촉매 및 올레핀의 중합방법

Also Published As

Publication number Publication date
JP2002522551A (ja) 2002-07-23
MY133950A (en) 2007-11-30
DE69901451T2 (de) 2002-12-12
WO2000009523A1 (en) 2000-02-24
AU4440499A (en) 2000-03-06
CA2337024A1 (en) 2000-02-24
EP1104429A1 (de) 2001-06-06
DE69901451D1 (de) 2002-06-13
EP1104429B1 (de) 2002-05-08
US6140521A (en) 2000-10-31

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