ATE240976T1 - Verbesserte polymerausbeute durch geträgerte metallocenkatalysatoren - Google Patents

Verbesserte polymerausbeute durch geträgerte metallocenkatalysatoren

Info

Publication number
ATE240976T1
ATE240976T1 AT97122162T AT97122162T ATE240976T1 AT E240976 T1 ATE240976 T1 AT E240976T1 AT 97122162 T AT97122162 T AT 97122162T AT 97122162 T AT97122162 T AT 97122162T AT E240976 T1 ATE240976 T1 AT E240976T1
Authority
AT
Austria
Prior art keywords
catalyst
polymer yield
supported metallocene
metalloce
catalysts
Prior art date
Application number
AT97122162T
Other languages
English (en)
Inventor
Edwar S Shamshoum
Christopher G Bauch
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology filed Critical Fina Technology
Application granted granted Critical
Publication of ATE240976T1 publication Critical patent/ATE240976T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT97122162T 1996-12-20 1997-12-16 Verbesserte polymerausbeute durch geträgerte metallocenkatalysatoren ATE240976T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/770,886 US5847059A (en) 1996-12-20 1996-12-20 Catalyst yield from supported metallocene catalysts

Publications (1)

Publication Number Publication Date
ATE240976T1 true ATE240976T1 (de) 2003-06-15

Family

ID=25090008

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97122162T ATE240976T1 (de) 1996-12-20 1997-12-16 Verbesserte polymerausbeute durch geträgerte metallocenkatalysatoren

Country Status (9)

Country Link
US (1) US5847059A (de)
EP (1) EP0849286B1 (de)
JP (1) JPH10182718A (de)
KR (1) KR100483364B1 (de)
CN (2) CN1097061C (de)
AT (1) ATE240976T1 (de)
DE (1) DE69722152T2 (de)
ES (1) ES2198525T3 (de)
TW (1) TW474952B (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6207606B1 (en) * 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
ES2270899T3 (es) * 1999-12-16 2007-04-16 Basell Polyolefine Gmbh Procedimiento y aparato para obtener sistemas cataliticos soportados para polimerizacion de olefinas.
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
GB0111443D0 (en) 2001-05-10 2001-07-04 Borealis Tech Oy Olefin polymerisation process
FR2830868B1 (fr) 2001-10-11 2004-12-03 Atofina Composition a base de polypropylene isotactique obtenu par catalyse metallocene et de polypropylene isotactique obtenu par catalyse ziegler natta, greffe
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
US6864210B2 (en) * 2003-02-06 2005-03-08 Equistar Chemicals, Lp Bimetallic olefin polymerization catalysts containing indigoid ligands
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
EP1574525B1 (de) * 2004-03-12 2007-05-02 Saudi Basic Industries Corporation Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung
EP1762577A1 (de) * 2005-09-02 2007-03-14 Total Petrochemicals Research Feluy Schlagfeste propylen-copolymere vorbereitet in einem reactor
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US20080287619A1 (en) * 2007-05-18 2008-11-20 William Gauthier Supported metallocene catalysts
BRPI0705994A2 (pt) * 2007-10-19 2009-10-06 Braskem Sa processo de preparação de suporte catalìtico e catalisadores bimetálicos suportados para a produção de homopolìmeros e copolìmeros de etileno com alfa-olefinas de alto e ultra alto peso molecular e com ampla distribuição de peso molecular em processos em lama, massa e fase gás e os produtos assim obtidos
JP5182224B2 (ja) * 2009-05-29 2013-04-17 住友化学株式会社 カレンダー成形用エチレン−α−オレフィン共重合体およびカレンダー成形体
ES2547867T3 (es) * 2009-06-29 2015-10-09 Chevron Phillips Chemical Company Lp El uso de catalizadores de eliminación de hidrógeno para controlar el peso molecular del polímero y los niveles de hidrógeno en un reactor de polimerización
KR101741855B1 (ko) 2009-06-29 2017-05-30 셰브론 필립스 케미컬 컴퍼니 엘피 용융지수 감소 및 중합체 생성률 증가를 위한 이중 메탈로센 촉매시스템
KR101339550B1 (ko) * 2011-11-24 2013-12-10 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법
BR112015011215B1 (pt) 2012-11-26 2018-11-21 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY107639A (en) * 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
ES2155492T3 (es) * 1991-05-27 2001-05-16 Basell Polyolefine Gmbh Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares.
DK0619325T3 (da) * 1993-04-07 2001-12-03 Atofina Res Katalysator og fremgangsmåde til fremstilling af polyalkener
US5422325A (en) * 1993-09-17 1995-06-06 Exxon Chemical Patents Inc. Supported polymerization catalysts, their production and use
ATE207085T1 (de) * 1994-06-24 2001-11-15 Exxonmobil Chem Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und verwendung
DE69514661T2 (de) * 1994-06-24 2000-08-03 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsystem, ihre herstellung und gebrauch
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use

Also Published As

Publication number Publication date
CN1185445A (zh) 1998-06-24
EP0849286A1 (de) 1998-06-24
DE69722152T2 (de) 2004-04-08
KR19980064401A (ko) 1998-10-07
TW474952B (en) 2002-02-01
CN1194019C (zh) 2005-03-23
EP0849286B1 (de) 2003-05-21
US5847059A (en) 1998-12-08
CN1097061C (zh) 2002-12-25
KR100483364B1 (ko) 2005-07-07
JPH10182718A (ja) 1998-07-07
CN1434061A (zh) 2003-08-06
DE69722152D1 (de) 2003-06-26
ES2198525T3 (es) 2004-02-01

Similar Documents

Publication Publication Date Title
DE69722152D1 (de) Verbesserte Polymerausbeute durch geträgerte Metallocenkatalysatoren
NO952217L (no) Etylenselektive metallocener med höy aktivitet
CA2163789A1 (en) Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
ATE114323T1 (de) Katalysatorsystem für polyolefinproduktion mit breiter molekulargewichtsverteilung.
ATE265473T1 (de) Verbesserte ziegler-natta katalysatoren für olefinpolymerisation
BG100904A (bg) Металоцени, метод за тяхното получаване, приложението им в катализатори за полимеризация на олефини
MY120272A (en) Protecting catalytic activity of a sapo molecular sieve.
ATE279450T1 (de) Olefinenpolymerisation
HUT72277A (en) Catalyst systems and process for producing broad molecular weight polyolefin
MY132781A (en) Olefin polymerization
WO1992000333A3 (en) Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
BR9301145A (pt) Processo continuo para polimerizacao da fase gasosa de etileno e suas misturas com-olefinas ch2-chr,polimeros e copolimeros,e polimeros e copolimeros de etileno
RU93004614A (ru) Способ газофазной полимеризации этилена и его смесей с олефинами и полимеры
PL359783A1 (en) Catalytic solid supported on calcined hydrotalcite for olefinic polymerisation
ES2117065T3 (es) Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo.
BR0105177A (pt) Processo para produzir homopolìmeros ou copolìmeros substancialmente amorfos de propileno
PT99615A (pt) Processo para a preparacao de um cocatalisador de polimerizacao de propileno a base de silano e de monoeter
ATE286919T1 (de) Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene
ATE400591T1 (de) Polymerisationsverfahren
BR9707179A (pt) Processo para a polimerização de etileno sistema de catalisador e composição de polímero
ATE291041T1 (de) Geträgerter und modifizierter katalysator für die polymerisation von olefine
IT1275812B1 (it) Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine
EP1860127A3 (de) Verfahren zur Olefinpolymerisation, neue Polyethylene und daraus hergestellte Folien und Artikel
BR9914828B1 (pt) processo para a polimerizaÇço de pelo menos uma ou mais olefinas.

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 0849286

Country of ref document: EP

REN Ceased due to non-payment of the annual fee