ATE251652T1 - Zwitterionische polyamine und verfahren zu ihrer herstellung - Google Patents
Zwitterionische polyamine und verfahren zu ihrer herstellungInfo
- Publication number
- ATE251652T1 ATE251652T1 AT00951335T AT00951335T ATE251652T1 AT E251652 T1 ATE251652 T1 AT E251652T1 AT 00951335 T AT00951335 T AT 00951335T AT 00951335 T AT00951335 T AT 00951335T AT E251652 T1 ATE251652 T1 AT E251652T1
- Authority
- AT
- Austria
- Prior art keywords
- formula
- zwitterionic
- polyamines
- group
- nitrogen atoms
- Prior art date
Links
- 229920000768 polyamine Polymers 0.000 title abstract 8
- 125000000129 anionic group Chemical group 0.000 abstract 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000006850 spacer group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14416599P | 1999-07-16 | 1999-07-16 | |
| PCT/EP2000/006296 WO2001005874A1 (en) | 1999-07-16 | 2000-07-05 | Zwitterionic polyamines and a process for their production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE251652T1 true ATE251652T1 (de) | 2003-10-15 |
Family
ID=22507378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00951335T ATE251652T1 (de) | 1999-07-16 | 2000-07-05 | Zwitterionische polyamine und verfahren zu ihrer herstellung |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1198492B1 (de) |
| JP (1) | JP5174305B2 (de) |
| KR (1) | KR100675579B1 (de) |
| CN (1) | CN1158335C (de) |
| AT (1) | ATE251652T1 (de) |
| AU (1) | AU771572B2 (de) |
| BR (1) | BR0012490B1 (de) |
| CA (1) | CA2379036A1 (de) |
| DE (1) | DE60005839T2 (de) |
| ES (1) | ES2208388T3 (de) |
| MX (1) | MXPA02000446A (de) |
| WO (1) | WO2001005874A1 (de) |
| ZA (1) | ZA200201296B (de) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2396974C (en) * | 2000-02-23 | 2006-06-27 | The Procter & Gamble Company | Liquid laundry detergent compositions having enhanced clay removal benefits |
| HUP0204287A3 (en) * | 2000-02-23 | 2005-05-30 | Procter & Gamble | Hydrophilic soil dispersant and laundry detergent composition comprising the same |
| WO2004020563A1 (en) * | 2002-08-30 | 2004-03-11 | The Procter & Gamble Company | Detergent compositions comprising hydrophobically modified polyamines |
| DE10356341A1 (de) * | 2003-11-28 | 2005-06-23 | Bayer Chemicals Ag | Alkoxylierte Polyalkylenimine mit anionischen Gruppen und ihre Verwendung |
| JP2007529612A (ja) | 2004-03-19 | 2007-10-25 | ザ プロクター アンド ギャンブル カンパニー | 選択ポリマー類の硫酸化方法 |
| EP1666579B2 (de) * | 2004-11-22 | 2012-11-28 | The Procter & Gamble Company | Wasserlöslicher Beutel gefüllt mit einer Flüssigkeit |
| CN101084297A (zh) | 2004-12-17 | 2007-12-05 | 宝洁公司 | 用于改善疏水性污垢清洁效果的疏水改性的多羟基化合物 |
| WO2006066060A1 (en) | 2004-12-17 | 2006-06-22 | The Procter & Gamble Company | Hydrophilically modified polyols for improved hydrophobic soil cleaning |
| RU2479627C2 (ru) | 2006-01-23 | 2013-04-20 | Дзе Проктер Энд Гэмбл Компани | Композиции моющих средств |
| HUE063025T2 (hu) | 2006-01-23 | 2023-12-28 | Procter & Gamble | Enzimeket és szövetszínezõ anyagokat tartalmazó készítmények |
| ES2376365T3 (es) | 2006-03-22 | 2012-03-13 | The Procter & Gamble Company | Composición para lavado de ropa. |
| US7629158B2 (en) | 2006-06-16 | 2009-12-08 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
| US8021436B2 (en) | 2007-09-27 | 2011-09-20 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a xyloglucan conjugate |
| US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
| CA2785949A1 (en) | 2010-01-04 | 2011-07-07 | Rhodia Operations | Polyamine and method for producing thereof |
| US8940284B2 (en) | 2010-04-01 | 2015-01-27 | The Procter & Gamble Company | Organosilicones |
| WO2011143321A1 (en) | 2010-05-12 | 2011-11-17 | The Procter & Gamble Company | Care polymers |
| JP5710756B2 (ja) | 2010-06-23 | 2015-04-30 | ザ プロクター アンド ギャンブルカンパニー | 汚れた布地の前処理及び洗濯方法並びに洗濯用製品 |
| EP2675880B1 (de) | 2011-02-16 | 2016-12-14 | The Procter and Gamble Company | Flüssige reinigungszusammensetzungen |
| US20120324655A1 (en) | 2011-06-23 | 2012-12-27 | Nalini Chawla | Product for pre-treatment and laundering of stained fabric |
| BR112015001130A2 (pt) | 2012-07-19 | 2017-06-27 | Procter & Gamble | composições de limpeza |
| JP6122114B2 (ja) | 2012-07-27 | 2017-04-26 | ザ プロクター アンド ギャンブル カンパニー | ポリシロキサンコポリマー |
| WO2014066309A1 (en) | 2012-10-24 | 2014-05-01 | The Procter & Gamble Company | Anti foam compositions comprising partly phenyl bearing polyorganosilicons |
| WO2014066308A1 (en) | 2012-10-24 | 2014-05-01 | The Procter & Gamble Company | Anti foam compositions comprising aryl bearing polyorganosilicons |
| BR112015028853A2 (pt) | 2013-05-24 | 2017-08-29 | Procter & Gamble | Composição detergente com ph baixo |
| US9840681B2 (en) | 2013-05-24 | 2017-12-12 | The Procter & Gamble Company | Concentrated surfactant composition |
| JP6138355B2 (ja) | 2013-05-24 | 2017-05-31 | ザ プロクター アンド ギャンブル カンパニー | 非イオン性界面活性剤を含む低pH洗剤組成物 |
| EP3110933B1 (de) | 2014-02-26 | 2019-07-31 | The Procter and Gamble Company | Reinigungszusammensetzungen mit alkoxyliertem polyalkylenimin, organomodifiziertem silikon und siloxanbasiertem verdünnungsmittel |
| JP6453361B2 (ja) | 2014-04-29 | 2019-01-16 | ザ プロクター アンド ギャンブル カンパニー | ポリウレタン、ポリ尿素及び/又はポリウレタン尿素ポリマーを含む、布地ケア組成物 |
| WO2015187757A1 (en) | 2014-06-06 | 2015-12-10 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
| CA2956121A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Method of treating a fabric |
| JP6728132B2 (ja) | 2014-08-27 | 2020-07-22 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | カチオン性ポリマーを含む洗剤組成物 |
| JP6479959B2 (ja) | 2014-08-27 | 2019-03-06 | ザ プロクター アンド ギャンブル カンパニー | カチオン性ポリマーを含む洗剤組成物 |
| CA2956088C (en) | 2014-08-27 | 2019-07-30 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
| WO2016040241A1 (en) | 2014-09-08 | 2016-03-17 | The Procter & Gamble Company | Detergent compositions containing a branched surfactant |
| EP3191570B1 (de) | 2014-09-08 | 2019-05-15 | The Procter and Gamble Company | Reinigungsmittelzusammensetzungen mit einem verzweigten tensid |
| WO2016041697A1 (en) * | 2014-09-15 | 2016-03-24 | Basf Se | Salts of etheramines and polymeric acid |
| EP3197992B1 (de) | 2014-09-25 | 2023-06-28 | The Procter & Gamble Company | Gewebepflegezusammensetzungen mit einem polyetheramine |
| US9506019B2 (en) | 2015-01-28 | 2016-11-29 | The Procter & Gamble Company | Silicone nanoemulsion comprising alkylene glycol alkyl ether |
| US9994800B2 (en) | 2015-03-26 | 2018-06-12 | The Procter & Gamble Company | Fabric care compositions comprising organosiloxane polymers with an amine-containing end cap |
| JP6623234B2 (ja) | 2015-05-22 | 2019-12-18 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 界面活性剤及びエトキシル化グリセリンを含有する洗剤組成物 |
| WO2016191103A1 (en) | 2015-05-22 | 2016-12-01 | The Procter & Gamble Company | Method of making surfactant compositions and detergent compositions comprising alkoxylatep glycerine as a solvent |
| CN107743421B (zh) | 2015-06-11 | 2021-02-09 | 宝洁公司 | 用于将组合物施涂至表面的装置和方法 |
| EP3109306A1 (de) * | 2015-06-22 | 2016-12-28 | The Procter and Gamble Company | Lösungsmittelarme flüssige reinigungsmittelzusammensetzungen |
| JP6665307B2 (ja) | 2016-02-02 | 2020-03-13 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 組成物 |
| US9856440B2 (en) | 2016-03-02 | 2018-01-02 | The Procter & Gamble Company | Compositions containing anionic surfactant and a solvent comprising butanediol |
| US9896648B2 (en) | 2016-03-02 | 2018-02-20 | The Procter & Gamble Company | Ethoxylated diols and compositions containing ethoxylated diols |
| US9790454B2 (en) | 2016-03-02 | 2017-10-17 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| US9840684B2 (en) | 2016-03-02 | 2017-12-12 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| US10815327B2 (en) | 2016-04-08 | 2020-10-27 | Basf Se | Copolymers comprising polyalkylene oxide groups and quaternary nitrogen atoms |
| US20180201875A1 (en) | 2017-01-13 | 2018-07-19 | The Procter & Gamble Company | Compositions comprising branched sulfonated surfactants |
| US20180216031A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US20180216029A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US20180216030A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US10731107B2 (en) | 2017-06-30 | 2020-08-04 | The Procter & Gamble Company | Detergent compositions comprising AES surfactant having alkyl chain lengths of fourteen total carbons |
| US10836981B2 (en) | 2017-11-10 | 2020-11-17 | The Procter & Gamble Company | Anti-foam compositions comprising an organopolysiloxane with adjacent hydrolysable groups |
| CN111868222A (zh) | 2018-03-02 | 2020-10-30 | 荷兰联合利华有限公司 | 洗衣组合物 |
| US11130451B2 (en) | 2019-03-13 | 2021-09-28 | Guillermo Viniegra | Tailgate integrated toolbox |
| JP7747525B2 (ja) | 2019-06-28 | 2025-10-01 | ザ プロクター アンド ギャンブル カンパニー | 洗浄組成物 |
| CN114302946A (zh) | 2019-09-30 | 2022-04-08 | 宝洁公司 | 包含共聚物的织物护理组合物及相关方法 |
| US11186805B2 (en) | 2019-12-20 | 2021-11-30 | The Procter & Gamble Company | Particulate fabric care composition |
| WO2021127696A1 (en) | 2019-12-20 | 2021-06-24 | The Procter & Gamble Company | Particulate fabric care composition |
| EP3910050B1 (de) | 2020-05-14 | 2024-03-20 | The Procter & Gamble Company | Zusammensetzung für die gewebepflege |
| WO2021239547A1 (en) | 2020-05-29 | 2021-12-02 | Basf Se | Amphoterically-modified oligopropyleneimine ethoxylates for improved stain removal of laundry detergents |
| CN115698244B (zh) | 2020-05-29 | 2024-12-17 | 联合利华知识产权控股有限公司 | 液体洗衣组合物 |
| CN116057159A (zh) * | 2020-09-28 | 2023-05-02 | 巴斯夫欧洲公司 | 洗衣用抗泛灰组合物 |
| WO2023094275A1 (en) | 2021-11-29 | 2023-06-01 | Basf Se | Amphoterically-modified trialkylene tetramine ethoxylates for improved stain removal of laundry detergents |
| WO2024011345A1 (en) | 2022-07-11 | 2024-01-18 | The Procter & Gamble Company | Laundry detergent composition containing graft copolymer and benefit agent |
| CN115232277B (zh) * | 2022-08-11 | 2023-09-22 | 山东一诺威新材料有限公司 | 仿乳胶聚氨酯软质泡沫用特种聚醚多元醇及其制备方法 |
| CN119630773A (zh) | 2022-08-12 | 2025-03-14 | 宝洁公司 | 固体可溶性组合物 |
| EP4569074A1 (de) | 2022-08-12 | 2025-06-18 | The Procter & Gamble Company | Zusammensetzungen mit geringem wasseranteil |
| WO2024119295A1 (en) | 2022-12-05 | 2024-06-13 | The Procter & Gamble Company | Laundry treatment composition including a polyalkylenecarbonate compound |
| WO2025194486A1 (en) | 2024-03-22 | 2025-09-25 | The Procter & Gamble Company | Packaged composition with mixed particles |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5869874A (ja) * | 1981-10-23 | 1983-04-26 | Takeo Saegusa | 双性イオン化化合物 |
| ATE51890T1 (de) * | 1982-12-23 | 1990-04-15 | Procter & Gamble | Zwitterionische verbindungen mit fleckenentfernungs- und antiwiederabsetzeigenschaften, verwendbar in detergenszusammensetzungen. |
| DE3446921A1 (de) * | 1984-12-21 | 1986-07-03 | Bayer Ag, 5090 Leverkusen | Neue alkoxylierte aminopolyether, verfahren zu ihrer herstellung und sie enthaltende kohle-wasser-aufschlaemmungen |
| US5049680A (en) * | 1990-05-03 | 1991-09-17 | Lce Partnership | Novel cationic lactam polymers and 1-(3-alkyl amino propyl)pyrrolidone-2 intermediates therefor |
| US5747440A (en) * | 1996-01-30 | 1998-05-05 | Procter & Gamble Company | Laundry detergents comprising heavy metal ion chelants |
| ES2244997T3 (es) * | 1996-05-03 | 2005-12-16 | THE PROCTER & GAMBLE COMPANY | Polimeros para liberar la suciedad en tejidos de algodon. |
| DE19647060A1 (de) * | 1996-11-14 | 1998-05-20 | Huels Chemische Werke Ag | Verwendung von anionischen Geminitensiden in Formulierungen für Wasch-, Reinigungs- und Körperpflegemittel |
| CN1247560A (zh) * | 1996-12-20 | 2000-03-15 | 普罗格特-甘布尔公司 | 含有有机二胺的餐具洗涤组合物 |
-
2000
- 2000-07-05 AT AT00951335T patent/ATE251652T1/de not_active IP Right Cessation
- 2000-07-05 MX MXPA02000446A patent/MXPA02000446A/es active IP Right Grant
- 2000-07-05 BR BRPI0012490-7A patent/BR0012490B1/pt not_active IP Right Cessation
- 2000-07-05 DE DE60005839T patent/DE60005839T2/de not_active Expired - Lifetime
- 2000-07-05 KR KR1020027000997A patent/KR100675579B1/ko not_active Expired - Fee Related
- 2000-07-05 JP JP2001511525A patent/JP5174305B2/ja not_active Expired - Fee Related
- 2000-07-05 CA CA002379036A patent/CA2379036A1/en not_active Abandoned
- 2000-07-05 WO PCT/EP2000/006296 patent/WO2001005874A1/en not_active Ceased
- 2000-07-05 EP EP00951335A patent/EP1198492B1/de not_active Expired - Lifetime
- 2000-07-05 ES ES00951335T patent/ES2208388T3/es not_active Expired - Lifetime
- 2000-07-05 AU AU64315/00A patent/AU771572B2/en not_active Ceased
- 2000-07-05 CN CNB008104107A patent/CN1158335C/zh not_active Expired - Fee Related
-
2002
- 2002-02-15 ZA ZA200201296A patent/ZA200201296B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1198492A1 (de) | 2002-04-24 |
| AU6431500A (en) | 2001-02-05 |
| KR100675579B1 (ko) | 2007-02-01 |
| EP1198492B1 (de) | 2003-10-08 |
| CA2379036A1 (en) | 2001-01-25 |
| ES2208388T3 (es) | 2004-06-16 |
| JP2003505551A (ja) | 2003-02-12 |
| WO2001005874A1 (en) | 2001-01-25 |
| MXPA02000446A (es) | 2002-07-02 |
| BR0012490A (pt) | 2002-04-02 |
| KR20020016912A (ko) | 2002-03-06 |
| DE60005839D1 (de) | 2003-11-13 |
| AU771572B2 (en) | 2004-03-25 |
| BR0012490B1 (pt) | 2010-06-15 |
| JP5174305B2 (ja) | 2013-04-03 |
| DE60005839T2 (de) | 2004-05-06 |
| CN1158335C (zh) | 2004-07-21 |
| ZA200201296B (en) | 2003-04-30 |
| CN1361805A (zh) | 2002-07-31 |
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