ATE251652T1 - Zwitterionische polyamine und verfahren zu ihrer herstellung - Google Patents
Zwitterionische polyamine und verfahren zu ihrer herstellungInfo
- Publication number
- ATE251652T1 ATE251652T1 AT00951335T AT00951335T ATE251652T1 AT E251652 T1 ATE251652 T1 AT E251652T1 AT 00951335 T AT00951335 T AT 00951335T AT 00951335 T AT00951335 T AT 00951335T AT E251652 T1 ATE251652 T1 AT E251652T1
- Authority
- AT
- Austria
- Prior art keywords
- formula
- zwitterionic
- polyamines
- group
- nitrogen atoms
- Prior art date
Links
- 229920000768 polyamine Polymers 0.000 title abstract 8
- 125000000129 anionic group Chemical group 0.000 abstract 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000006850 spacer group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Detergent Compositions (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14416599P | 1999-07-16 | 1999-07-16 | |
| PCT/EP2000/006296 WO2001005874A1 (en) | 1999-07-16 | 2000-07-05 | Zwitterionic polyamines and a process for their production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE251652T1 true ATE251652T1 (de) | 2003-10-15 |
Family
ID=22507378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00951335T ATE251652T1 (de) | 1999-07-16 | 2000-07-05 | Zwitterionische polyamine und verfahren zu ihrer herstellung |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1198492B1 (de) |
| JP (1) | JP5174305B2 (de) |
| KR (1) | KR100675579B1 (de) |
| CN (1) | CN1158335C (de) |
| AT (1) | ATE251652T1 (de) |
| AU (1) | AU771572B2 (de) |
| BR (1) | BR0012490B1 (de) |
| CA (1) | CA2379036A1 (de) |
| DE (1) | DE60005839T2 (de) |
| ES (1) | ES2208388T3 (de) |
| MX (1) | MXPA02000446A (de) |
| WO (1) | WO2001005874A1 (de) |
| ZA (1) | ZA200201296B (de) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1237162C (zh) * | 2000-02-23 | 2006-01-18 | 宝洁公司 | 具有增强泥土清除益处的液体衣用洗涤剂组合物 |
| HUP0204287A3 (en) * | 2000-02-23 | 2005-05-30 | Procter & Gamble | Hydrophilic soil dispersant and laundry detergent composition comprising the same |
| AU2003268193A1 (en) * | 2002-08-30 | 2004-03-19 | The Procter And Gamble Company | Detergent compositions comprising hydrophobically modified polyamines |
| DE10356341A1 (de) * | 2003-11-28 | 2005-06-23 | Bayer Chemicals Ag | Alkoxylierte Polyalkylenimine mit anionischen Gruppen und ihre Verwendung |
| WO2005092952A1 (en) | 2004-03-19 | 2005-10-06 | The Procter & Gamble Company | Process of sulfating select polymers |
| ES2326818T5 (es) * | 2004-11-22 | 2013-04-08 | The Procter & Gamble Company | Bolsa que contiene líquidos, soluble en agua |
| MX2007007318A (es) | 2004-12-17 | 2007-07-09 | Procter & Gamble | Polioles modificados hidrofilamente para una mejor limpieza de la suciedad hidrofoba. |
| CA2590434A1 (en) | 2004-12-17 | 2006-06-22 | The Procter & Gamble Company | Hydrophobically modified polyols for improved hydrophobic soil cleaning |
| AR059157A1 (es) | 2006-01-23 | 2008-03-12 | Procter & Gamble | Composiciones detergentes |
| ES2960774T3 (es) | 2006-01-23 | 2024-03-06 | Procter & Gamble | Composiciones que contienen enzima y agente de matizado de tejidos |
| CA2642970C (en) | 2006-03-22 | 2013-09-24 | The Procter & Gamble Company | Liquid treatment compositions comprising pearlescent agents |
| US7629158B2 (en) | 2006-06-16 | 2009-12-08 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
| US8021436B2 (en) | 2007-09-27 | 2011-09-20 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a xyloglucan conjugate |
| US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
| EP2522688A4 (de) | 2010-01-04 | 2014-05-14 | Rhodia Operations | Polyamin und verfahren zu seiner herstellung |
| US20110243874A1 (en) | 2010-04-01 | 2011-10-06 | Rajan Keshav Panandiker | Care polymers |
| EP2569408A1 (de) | 2010-05-12 | 2013-03-20 | The Procter and Gamble Company | Pflegepolymere |
| EP2585573A1 (de) | 2010-06-23 | 2013-05-01 | The Procter and Gamble Company | Produkt zur vorbehandlung und reinigung von verschmutzten stoffen |
| US8846596B2 (en) | 2011-02-16 | 2014-09-30 | The Procter & Gamble Company | Liquid cleaning compositions |
| US20120324655A1 (en) | 2011-06-23 | 2012-12-27 | Nalini Chawla | Product for pre-treatment and laundering of stained fabric |
| CN104487561B (zh) | 2012-07-19 | 2018-04-10 | 宝洁公司 | 清洁组合物 |
| JP6122114B2 (ja) | 2012-07-27 | 2017-04-26 | ザ プロクター アンド ギャンブル カンパニー | ポリシロキサンコポリマー |
| US9095787B2 (en) | 2012-10-24 | 2015-08-04 | The Procter & Gamble Company | Compositions comprising anti-foams |
| US9133421B2 (en) | 2012-10-24 | 2015-09-15 | The Procter & Gamble Company | Compositions comprising anti-foams |
| US9267095B2 (en) | 2013-05-24 | 2016-02-23 | The Procter & Gamble Company | Low pH detergent composition comprising nonionic surfactants |
| JP6271717B2 (ja) | 2013-05-24 | 2018-01-31 | ザ プロクター アンド ギャンブル カンパニー | 濃縮界面活性剤組成物 |
| CN105431515A (zh) | 2013-05-24 | 2016-03-23 | 宝洁公司 | 低ph洗涤剂组合物 |
| JP6367976B2 (ja) | 2014-02-26 | 2018-08-01 | 信越化学工業株式会社 | 消泡剤組成物 |
| CN106232794B (zh) | 2014-04-29 | 2023-04-21 | 宝洁公司 | 包含聚氨酯、聚脲和/或聚氨酯脲聚合物的织物护理组合物 |
| EP3152288A1 (de) | 2014-06-06 | 2017-04-12 | The Procter & Gamble Company | Waschmittelzusammensetzung mit polyalkyleniminpolymeren |
| CA2956095C (en) | 2014-08-27 | 2019-10-08 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
| JP6728132B2 (ja) | 2014-08-27 | 2020-07-22 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | カチオン性ポリマーを含む洗剤組成物 |
| US9809782B2 (en) | 2014-08-27 | 2017-11-07 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer and anionic/nonionic surfactant mixture |
| WO2016032995A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Method of treating a fabric |
| CA2958305A1 (en) | 2014-09-08 | 2016-03-17 | The Procter & Gamble Company | Detergent compositions containing a branched surfactant |
| US9493726B2 (en) | 2014-09-08 | 2016-11-15 | The Procter & Gamble Company | Detergent compositions containing a predominantly C15 branched alkyl alkoxylated surfactant |
| US10280237B2 (en) * | 2014-09-15 | 2019-05-07 | Basf Se | Salts of etheramines and polymeric acid |
| EP3197992B1 (de) | 2014-09-25 | 2023-06-28 | The Procter & Gamble Company | Gewebepflegezusammensetzungen mit einem polyetheramine |
| US9506019B2 (en) | 2015-01-28 | 2016-11-29 | The Procter & Gamble Company | Silicone nanoemulsion comprising alkylene glycol alkyl ether |
| US9994800B2 (en) | 2015-03-26 | 2018-06-12 | The Procter & Gamble Company | Fabric care compositions comprising organosiloxane polymers with an amine-containing end cap |
| WO2016191237A1 (en) | 2015-05-22 | 2016-12-01 | The Procter & Gamble Company | Surfactant and detergent compositions containing ethoxylated glycerine |
| JP6633101B2 (ja) | 2015-05-22 | 2020-01-22 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 溶媒としてアルコキシル化グリセリンを含む界面活性剤組成物及び洗剤組成物の作製方法 |
| WO2016200440A1 (en) | 2015-06-11 | 2016-12-15 | The Procter & Gamble Company | Device and methods for applying compositions to surfaces |
| EP3109306A1 (de) * | 2015-06-22 | 2016-12-28 | The Procter and Gamble Company | Lösungsmittelarme flüssige reinigungsmittelzusammensetzungen |
| JP6665307B2 (ja) | 2016-02-02 | 2020-03-13 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 組成物 |
| US9840684B2 (en) | 2016-03-02 | 2017-12-12 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| US9856440B2 (en) | 2016-03-02 | 2018-01-02 | The Procter & Gamble Company | Compositions containing anionic surfactant and a solvent comprising butanediol |
| US9790454B2 (en) | 2016-03-02 | 2017-10-17 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| US9896648B2 (en) | 2016-03-02 | 2018-02-20 | The Procter & Gamble Company | Ethoxylated diols and compositions containing ethoxylated diols |
| WO2017174468A1 (en) | 2016-04-08 | 2017-10-12 | Basf Se | Copolymers comprising polyalkylene oxide groups and quaternary nitrogen atoms |
| CA3045698A1 (en) | 2017-01-13 | 2018-07-19 | The Procter & Gamble Company | Compositions comprising branched sulfonated surfactants |
| US20180216031A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US20180216029A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US20180216030A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Concentrated surfactant composition |
| US10731107B2 (en) | 2017-06-30 | 2020-08-04 | The Procter & Gamble Company | Detergent compositions comprising AES surfactant having alkyl chain lengths of fourteen total carbons |
| US10836981B2 (en) | 2017-11-10 | 2020-11-17 | The Procter & Gamble Company | Anti-foam compositions comprising an organopolysiloxane with adjacent hydrolysable groups |
| WO2019166277A1 (en) | 2018-03-02 | 2019-09-06 | Unilever Plc | Laundry composition |
| US11130451B2 (en) | 2019-03-13 | 2021-09-28 | Guillermo Viniegra | Tailgate integrated toolbox |
| WO2020264077A1 (en) | 2019-06-28 | 2020-12-30 | The Procter & Gamble Company | Cleaning composition |
| JP2022547846A (ja) | 2019-09-30 | 2022-11-16 | ザ プロクター アンド ギャンブル カンパニー | コポリマーを含む布地ケア組成物及び関連する方法 |
| CA3154794C (en) * | 2019-12-20 | 2025-06-17 | The Procter & Gamble Company | SPECIAL FABRIC CARE COMPOSITION |
| US11186805B2 (en) | 2019-12-20 | 2021-11-30 | The Procter & Gamble Company | Particulate fabric care composition |
| EP3910050B1 (de) | 2020-05-14 | 2024-03-20 | The Procter & Gamble Company | Zusammensetzung für die gewebepflege |
| AU2021280970B2 (en) | 2020-05-29 | 2023-10-05 | Unilever Global Ip Limited | A liquid laundry composition |
| ES2983533T3 (es) | 2020-05-29 | 2024-10-23 | Basf Se | Etoxilatos de oligopropilenimina modificados anfotéricamente para mejorar la eliminación de manchas de los detergentes para ropa |
| US20230374415A1 (en) * | 2020-09-28 | 2023-11-23 | Basf Se | Anti-greying composition for laundry |
| CN118318027A (zh) | 2021-11-29 | 2024-07-09 | 巴斯夫欧洲公司 | 用于改善衣物洗涤剂污渍去除的两性改性三亚烷基四胺乙氧基化物 |
| CA3260784A1 (en) | 2022-07-11 | 2024-01-18 | The Procter & Gamble Company | LAUNDRY DETERGENT COMPOSITION CONTAINING A GRAFTED COPOLYMER AND A BENEFICIAL AGENT |
| CN115232277B (zh) * | 2022-08-11 | 2023-09-22 | 山东一诺威新材料有限公司 | 仿乳胶聚氨酯软质泡沫用特种聚醚多元醇及其制备方法 |
| WO2024036125A1 (en) | 2022-08-12 | 2024-02-15 | The Procter & Gamble Company | Low-water compositions |
| EP4569073A1 (de) | 2022-08-12 | 2025-06-18 | The Procter & Gamble Company | Feste lösliche zusammensetzungen |
| EP4630525A1 (de) | 2022-12-05 | 2025-10-15 | The Procter & Gamble Company | Wäschebehandlungszusammensetzung mit einer polyalkylencarbonatverbindung |
| WO2025194486A1 (en) | 2024-03-22 | 2025-09-25 | The Procter & Gamble Company | Packaged composition with mixed particles |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5869874A (ja) * | 1981-10-23 | 1983-04-26 | Takeo Saegusa | 双性イオン化化合物 |
| ATE51890T1 (de) * | 1982-12-23 | 1990-04-15 | Procter & Gamble | Zwitterionische verbindungen mit fleckenentfernungs- und antiwiederabsetzeigenschaften, verwendbar in detergenszusammensetzungen. |
| DE3446921A1 (de) * | 1984-12-21 | 1986-07-03 | Bayer Ag, 5090 Leverkusen | Neue alkoxylierte aminopolyether, verfahren zu ihrer herstellung und sie enthaltende kohle-wasser-aufschlaemmungen |
| US5049680A (en) * | 1990-05-03 | 1991-09-17 | Lce Partnership | Novel cationic lactam polymers and 1-(3-alkyl amino propyl)pyrrolidone-2 intermediates therefor |
| US5747440A (en) * | 1996-01-30 | 1998-05-05 | Procter & Gamble Company | Laundry detergents comprising heavy metal ion chelants |
| DE69733653T2 (de) * | 1996-05-03 | 2006-04-27 | The Procter & Gamble Company, Cincinnati | Schmutzabweisende polymere für baumwollmaterialien |
| DE19647060A1 (de) * | 1996-11-14 | 1998-05-20 | Huels Chemische Werke Ag | Verwendung von anionischen Geminitensiden in Formulierungen für Wasch-, Reinigungs- und Körperpflegemittel |
| TR199901340T2 (xx) * | 1996-12-20 | 1999-08-23 | The Procter & Gamble Company | Organik diaminler i�eren bula��k deterjan� bile�imleri. |
-
2000
- 2000-07-05 ES ES00951335T patent/ES2208388T3/es not_active Expired - Lifetime
- 2000-07-05 BR BRPI0012490-7A patent/BR0012490B1/pt not_active IP Right Cessation
- 2000-07-05 AT AT00951335T patent/ATE251652T1/de not_active IP Right Cessation
- 2000-07-05 CA CA002379036A patent/CA2379036A1/en not_active Abandoned
- 2000-07-05 KR KR1020027000997A patent/KR100675579B1/ko not_active Expired - Fee Related
- 2000-07-05 AU AU64315/00A patent/AU771572B2/en not_active Ceased
- 2000-07-05 DE DE60005839T patent/DE60005839T2/de not_active Expired - Lifetime
- 2000-07-05 EP EP00951335A patent/EP1198492B1/de not_active Expired - Lifetime
- 2000-07-05 WO PCT/EP2000/006296 patent/WO2001005874A1/en not_active Ceased
- 2000-07-05 MX MXPA02000446A patent/MXPA02000446A/es active IP Right Grant
- 2000-07-05 JP JP2001511525A patent/JP5174305B2/ja not_active Expired - Fee Related
- 2000-07-05 CN CNB008104107A patent/CN1158335C/zh not_active Expired - Fee Related
-
2002
- 2002-02-15 ZA ZA200201296A patent/ZA200201296B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2208388T3 (es) | 2004-06-16 |
| DE60005839T2 (de) | 2004-05-06 |
| WO2001005874A1 (en) | 2001-01-25 |
| ZA200201296B (en) | 2003-04-30 |
| EP1198492B1 (de) | 2003-10-08 |
| EP1198492A1 (de) | 2002-04-24 |
| KR100675579B1 (ko) | 2007-02-01 |
| KR20020016912A (ko) | 2002-03-06 |
| CN1361805A (zh) | 2002-07-31 |
| JP2003505551A (ja) | 2003-02-12 |
| DE60005839D1 (de) | 2003-11-13 |
| JP5174305B2 (ja) | 2013-04-03 |
| BR0012490A (pt) | 2002-04-02 |
| MXPA02000446A (es) | 2002-07-02 |
| AU6431500A (en) | 2001-02-05 |
| CN1158335C (zh) | 2004-07-21 |
| CA2379036A1 (en) | 2001-01-25 |
| BR0012490B1 (pt) | 2010-06-15 |
| AU771572B2 (en) | 2004-03-25 |
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