ES2208388T3 - Poliaminas zwitterionicas y un procedimiento para su produccion. - Google Patents

Poliaminas zwitterionicas y un procedimiento para su produccion.

Info

Publication number: ES2208388T3
Authority: ES; Spain
Prior art keywords: polyamine; group; formula; carbon atoms; zwitterionic
Prior art date: 1999-07-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES00951335T

Other languages

English (en)

Spanish (es)

Inventor

Dieter Boeckh

Oliver Borzyk

Michael Ehle

Ralf Norenberg

Eugene P. Gosselink

Jeffrey S. Dupont

Robert H. Rohrbaugh

Kenneth N. Price

Randall S. Deinhammer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-07-16

Filing date

2000-07-05

Publication date

2004-06-16

2000-07-05 Application filed by BASF SE filed Critical BASF SE

2004-06-16 Application granted granted Critical

2004-06-16 Publication of ES2208388T3 publication Critical patent/ES2208388T3/es

2020-07-05 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 18
238000004519 manufacturing process Methods 0.000 title claims abstract description 11
229920000768 polyamine Polymers 0.000 claims abstract description 107
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 27
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 21
125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 19
125000006850 spacer group Chemical group 0.000 claims abstract description 17
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 13
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
239000001257 hydrogen Substances 0.000 claims abstract description 10
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 8
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 8
230000002209 hydrophobic effect Effects 0.000 claims abstract description 6
150000001340 alkali metals Chemical group 0.000 claims abstract description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 52
229910052757 nitrogen Inorganic materials 0.000 claims description 35
125000002947 alkylene group Chemical group 0.000 claims description 32
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 31
-1 hydroxypropyl Chemical group 0.000 claims description 18
239000002253 acid Substances 0.000 claims description 17
125000004429 atom Chemical group 0.000 claims description 13
239000000047 product Substances 0.000 claims description 13
238000005956 quaternization reaction Methods 0.000 claims description 13
125000002993 cycloalkylene group Chemical group 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 11
MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
239000000203 mixture Substances 0.000 claims description 9
125000001424 substituent group Chemical group 0.000 claims description 9
150000003512 tertiary amines Chemical class 0.000 claims description 9
125000003710 aryl alkyl group Chemical group 0.000 claims description 8
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 8
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 7
239000007795 chemical reaction product Substances 0.000 claims description 7
XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 7
XUSNPFGLKGCWGN-UHFFFAOYSA-N 3-[4-(3-aminopropyl)piperazin-1-yl]propan-1-amine Chemical compound NCCCN1CCN(CCCN)CC1 XUSNPFGLKGCWGN-UHFFFAOYSA-N 0.000 claims description 6
150000001875 compounds Chemical class 0.000 claims description 6
150000003254 radicals Chemical class 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 5
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims description 4
FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 claims description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
PAOXFRSJRCGJLV-UHFFFAOYSA-N 2-[4-(2-aminoethyl)piperazin-1-yl]ethanamine Chemical compound NCCN1CCN(CCN)CC1 PAOXFRSJRCGJLV-UHFFFAOYSA-N 0.000 claims description 3
150000007513 acids Chemical class 0.000 claims description 3
125000003277 amino group Chemical group 0.000 claims description 3
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 claims description 3
229940073608 benzyl chloride Drugs 0.000 claims description 3
125000004122 cyclic group Chemical group 0.000 claims description 3
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 3
SMOXLGSFWOUPHC-UHFFFAOYSA-N C(=C)P(O)(O)O Chemical compound C(=C)P(O)(O)O SMOXLGSFWOUPHC-UHFFFAOYSA-N 0.000 claims description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
239000004721 Polyphenylene oxide Substances 0.000 claims description 2
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
125000005395 methacrylic acid group Chemical group 0.000 claims description 2
229940050176 methyl chloride Drugs 0.000 claims description 2
229920000570 polyether Polymers 0.000 claims description 2
150000003141 primary amines Chemical class 0.000 claims description 2
150000003335 secondary amines Chemical class 0.000 claims 1
125000000129 anionic group Chemical group 0.000 abstract description 14
239000003599 detergent Substances 0.000 abstract description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
150000002431 hydrogen Chemical group 0.000 abstract 1
125000001302 tertiary amino group Chemical group 0.000 abstract 1
150000001412 amines Chemical class 0.000 description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 7
102100025991 Betaine-homocysteine S-methyltransferase 1 Human genes 0.000 description 6
101000933413 Homo sapiens Betaine-homocysteine S-methyltransferase 1 Proteins 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000004927 clay Substances 0.000 description 6
CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 5
229910052786 argon Inorganic materials 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
238000005160 1H NMR spectroscopy Methods 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
238000007046 ethoxylation reaction Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
MPPPKRYCTPRNTB-UHFFFAOYSA-N 1-bromobutane Chemical compound CCCCBr MPPPKRYCTPRNTB-UHFFFAOYSA-N 0.000 description 1
CQWCZJWYHPCXRK-UHFFFAOYSA-N 1-n,2-n-bis(2-aminoethyl)propane-1,2-diamine Chemical compound NCCNC(C)CNCCN CQWCZJWYHPCXRK-UHFFFAOYSA-N 0.000 description 1
QQGSUBFMZJESQO-UHFFFAOYSA-N 1-n,2-n-bis(3-aminopropyl)propane-1,2-diamine Chemical compound NCCCNC(C)CNCCCN QQGSUBFMZJESQO-UHFFFAOYSA-N 0.000 description 1
JQGSGESIGLISGL-UHFFFAOYSA-N 1-n-[3-(dimethylamino)propyl]propane-1,2-diamine Chemical compound CC(N)CNCCCN(C)C JQGSGESIGLISGL-UHFFFAOYSA-N 0.000 description 1
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
ZJINVUVGTWOUJI-UHFFFAOYSA-N 2-n-(2-aminoethyl)propane-1,2-diamine Chemical compound NCC(C)NCCN ZJINVUVGTWOUJI-UHFFFAOYSA-N 0.000 description 1
ZAXCZCOUDLENMH-UHFFFAOYSA-N 3,3,3-tetramine Chemical compound NCCCNCCCNCCCN ZAXCZCOUDLENMH-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VRPPEXGZBZBARW-UHFFFAOYSA-N N-(2-aminoethyl)butane-1,4-diamine Chemical compound NCCCCNCCN VRPPEXGZBZBARW-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229920002873 Polyethylenimine Polymers 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
PZDZPPFYJBZKJD-UHFFFAOYSA-N [4-(aminomethylidene)cyclohexa-2,5-dien-1-ylidene]methanamine Chemical compound NC=C1C=CC(=CN)C=C1 PZDZPPFYJBZKJD-UHFFFAOYSA-N 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
150000008052 alkyl sulfonates Chemical class 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
AGEZXYOZHKGVCM-UHFFFAOYSA-N benzyl bromide Chemical compound BrCC1=CC=CC=C1 AGEZXYOZHKGVCM-UHFFFAOYSA-N 0.000 description 1
RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
229940106681 chloroacetic acid Drugs 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
239000003245 coal Substances 0.000 description 1
WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical group C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
150000008050 dialkyl sulfates Chemical class 0.000 description 1
DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
229940008406 diethyl sulfate Drugs 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
DRNBLNIUGKCELA-UHFFFAOYSA-N ethenol hydrochloride Chemical compound C=CO.Cl DRNBLNIUGKCELA-UHFFFAOYSA-N 0.000 description 1
229960003750 ethyl chloride Drugs 0.000 description 1
239000004744 fabric Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000010354 integration Effects 0.000 description 1
150000008040 ionic compounds Chemical class 0.000 description 1
GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229940102396 methyl bromide Drugs 0.000 description 1
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
ZKKMLXOYLORBLV-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-ethylpropane-1,3-diamine Chemical compound NCCCN(CC)CCCN ZKKMLXOYLORBLV-UHFFFAOYSA-N 0.000 description 1
INAQHJUDGSEXDR-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-octylpropane-1,3-diamine Chemical compound CCCCCCCCN(CCCN)CCCN INAQHJUDGSEXDR-UHFFFAOYSA-N 0.000 description 1
QHJABUZHRJTCAR-UHFFFAOYSA-N n'-methylpropane-1,3-diamine Chemical compound CNCCCN QHJABUZHRJTCAR-UHFFFAOYSA-N 0.000 description 1
ODBJKENDOPPIFT-UHFFFAOYSA-N n,n'-bis(2-aminoethyl)butane-1,4-diamine Chemical compound NCCNCCCCNCCN ODBJKENDOPPIFT-UHFFFAOYSA-N 0.000 description 1
WOVJRSMTQMZAJS-UHFFFAOYSA-N n,n'-bis(3-aminopropyl)hexane-1,6-diamine Chemical compound NCCCNCCCCCCNCCCN WOVJRSMTQMZAJS-UHFFFAOYSA-N 0.000 description 1
UQUPIHHYKUEXQD-UHFFFAOYSA-N n,n′-dimethyl-1,3-propanediamine Chemical compound CNCCCNC UQUPIHHYKUEXQD-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000012457 nonaqueous media Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
PFNFFQXMRSDOHW-UHFFFAOYSA-N spermine Chemical compound NCCCNCCCCNCCCN PFNFFQXMRSDOHW-UHFFFAOYSA-N 0.000 description 1
239000012258 stirred mixture Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
238000006277 sulfonation reaction Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
229960001124 trientine Drugs 0.000 description 1
ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Detergent Compositions (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polyethers (AREA)

ES00951335T 1999-07-16 2000-07-05 Poliaminas zwitterionicas y un procedimiento para su produccion. Expired - Lifetime ES2208388T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US14416599P	1999-07-16	1999-07-16
US144165P		1999-07-16

Publications (1)

Publication Number	Publication Date
ES2208388T3 true ES2208388T3 (es)	2004-06-16

Family

ID=22507378

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES00951335T Expired - Lifetime ES2208388T3 (es)	1999-07-16	2000-07-05	Poliaminas zwitterionicas y un procedimiento para su produccion.

Country Status (13)

Country	Link
EP (1)	EP1198492B1 (de)
JP (1)	JP5174305B2 (de)
KR (1)	KR100675579B1 (de)
CN (1)	CN1158335C (de)
AT (1)	ATE251652T1 (de)
AU (1)	AU771572B2 (de)
BR (1)	BR0012490B1 (de)
CA (1)	CA2379036A1 (de)
DE (1)	DE60005839T2 (de)
ES (1)	ES2208388T3 (de)
MX (1)	MXPA02000446A (de)
WO (1)	WO2001005874A1 (de)
ZA (1)	ZA200201296B (de)

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2000
- 2000-07-05 ES ES00951335T patent/ES2208388T3/es not_active Expired - Lifetime
- 2000-07-05 BR BRPI0012490-7A patent/BR0012490B1/pt not_active IP Right Cessation
- 2000-07-05 AT AT00951335T patent/ATE251652T1/de not_active IP Right Cessation
- 2000-07-05 CA CA002379036A patent/CA2379036A1/en not_active Abandoned
- 2000-07-05 KR KR1020027000997A patent/KR100675579B1/ko not_active Expired - Fee Related
- 2000-07-05 AU AU64315/00A patent/AU771572B2/en not_active Ceased
- 2000-07-05 DE DE60005839T patent/DE60005839T2/de not_active Expired - Lifetime
- 2000-07-05 EP EP00951335A patent/EP1198492B1/de not_active Expired - Lifetime
- 2000-07-05 WO PCT/EP2000/006296 patent/WO2001005874A1/en not_active Ceased
- 2000-07-05 MX MXPA02000446A patent/MXPA02000446A/es active IP Right Grant
- 2000-07-05 JP JP2001511525A patent/JP5174305B2/ja not_active Expired - Fee Related
- 2000-07-05 CN CNB008104107A patent/CN1158335C/zh not_active Expired - Fee Related
2002
- 2002-02-15 ZA ZA200201296A patent/ZA200201296B/en unknown

Also Published As

Publication number	Publication date
DE60005839T2 (de)	2004-05-06
WO2001005874A1 (en)	2001-01-25
ZA200201296B (en)	2003-04-30
ATE251652T1 (de)	2003-10-15
EP1198492B1 (de)	2003-10-08
EP1198492A1 (de)	2002-04-24
KR100675579B1 (ko)	2007-02-01
KR20020016912A (ko)	2002-03-06
CN1361805A (zh)	2002-07-31
JP2003505551A (ja)	2003-02-12
DE60005839D1 (de)	2003-11-13
JP5174305B2 (ja)	2013-04-03
BR0012490A (pt)	2002-04-02
MXPA02000446A (es)	2002-07-02
AU6431500A (en)	2001-02-05
CN1158335C (zh)	2004-07-21
CA2379036A1 (en)	2001-01-25
BR0012490B1 (pt)	2010-06-15
AU771572B2 (en)	2004-03-25

Publication	Publication Date	Title
ES2208388T3 (es)	2004-06-16	Poliaminas zwitterionicas y un procedimiento para su produccion.
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KR101233548B1 (ko)	2013-02-15	변성 폴리아민계 중합체의 세제용 첨가제로서의 용도
CN101448925A (zh)	2009-06-03	用于改善油脂清洁的液体洗涤剂组合物
ES2278607T3 (es)	2007-08-16	Metodo para usar promotores de las jabonaduras polimericos de ion hibrido.
JP5660905B2 (ja)	2015-01-28	ポリアルキレンアミンアルキレンオキシド共重合体
US5073286A (en)	1991-12-17	Stable alkyl and/or aryl silyl ether capped polyether surfactants for liquid cleaning agents containing hypohalite bleaches
CN101460542A (zh)	2009-06-17	洗涤剂组合物
ES2211571T3 (es)	2004-07-16	Polieterpoliaminas zwitterionicas y procedimiento para su obtencion.
US6703523B1 (en)	2004-03-09	Zwitterionic polyetherpolyamines and process for their production
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WO2001009223A1 (en)	2001-02-08	Zwitterionic polyamines and a process for their production
JP5385773B2 (ja)	2014-01-08	衣料洗剤用高分子ビルダー
ES2321313T3 (es)	2009-06-04	Copolimeros con grupos n-heterociclicos y su uso como aditivo en detergentes.
AU2012226552A1 (en)	2013-08-22	Carpet cleaning composition
ES2710014T3 (es)	2019-04-22	Polieteraminas con bajo punto de fusión
JP2007529612A (ja)	2007-10-25	選択ポリマー類の硫酸化方法
ES2200498T3 (es)	2004-03-01	Composiciones detergentes blanqueantes que contienen polimeros de poliamina modificados.
ES2394549T3 (es)	2013-02-01	Proceso para la alcoxilación de polímeros que contienen el grupo amino
JP3910530B2 (ja)	2007-04-25	汚れ放出剤