ATE251945T1 - Hydrocarbylphosphinimin/cyclopentadienyl-komple e von metallen der gruppe 4 und deren verwendung zur olefinpolymerisation - Google Patents

Hydrocarbylphosphinimin/cyclopentadienyl-komple e von metallen der gruppe 4 und deren verwendung zur olefinpolymerisation

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Publication number
ATE251945T1
ATE251945T1 AT00954231T AT00954231T ATE251945T1 AT E251945 T1 ATE251945 T1 AT E251945T1 AT 00954231 T AT00954231 T AT 00954231T AT 00954231 T AT00954231 T AT 00954231T AT E251945 T1 ATE251945 T1 AT E251945T1
Authority
AT
Austria
Prior art keywords
complexes
cyclopentadienyl
hydrocarbylphosphiniminine
comple
metals
Prior art date
Application number
AT00954231T
Other languages
English (en)
Inventor
Rupert Edward Von Haken Spence
Stephen John Brown
Ryan Paul Wurz
Dusan Jeremic
Douglas W Stephan
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Application granted granted Critical
Publication of ATE251945T1 publication Critical patent/ATE251945T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT00954231T 1999-09-10 2000-08-24 Hydrocarbylphosphinimin/cyclopentadienyl-komple e von metallen der gruppe 4 und deren verwendung zur olefinpolymerisation ATE251945T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002282070A CA2282070C (en) 1999-09-10 1999-09-10 Hydrocarbyl phosphinimine/cyclopentadienyl complexes of group iv metals and preparation thereof
PCT/CA2000/000978 WO2001019512A1 (en) 1999-09-10 2000-08-24 Hydrocarbyl phosphinimine/cyclopentadienyl complexes of group 4 and their use in olefin polymerization

Publications (1)

Publication Number Publication Date
ATE251945T1 true ATE251945T1 (de) 2003-11-15

Family

ID=4164113

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00954231T ATE251945T1 (de) 1999-09-10 2000-08-24 Hydrocarbylphosphinimin/cyclopentadienyl-komple e von metallen der gruppe 4 und deren verwendung zur olefinpolymerisation

Country Status (11)

Country Link
US (1) US6440890B1 (de)
EP (1) EP1214146B1 (de)
JP (1) JP4619599B2 (de)
KR (1) KR100670424B1 (de)
AT (1) ATE251945T1 (de)
AU (1) AU6678300A (de)
BR (1) BR0013870B1 (de)
CA (1) CA2282070C (de)
DE (1) DE60005982T2 (de)
ES (1) ES2208398T3 (de)
WO (1) WO2001019512A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2347410C (en) * 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
US7309741B2 (en) * 2004-06-01 2007-12-18 Nova Chemicals (International) S.A. Polyolefin blends and pipe
EP1801113A1 (de) * 2005-12-22 2007-06-27 DSM IP Assets B.V. Zwitterionischer Phosphinimin-Katalysator
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
US9120984B2 (en) 2012-12-21 2015-09-01 Governors Of The University Of Alberta Transition metal catalysts for hydrodesulfurization
US9051229B2 (en) 2012-12-21 2015-06-09 Governors Of The University Of Alberta Transition metal catalysts for C—O hydrogenolysis and hydrodeoxygenation
US9120741B2 (en) 2012-12-21 2015-09-01 Governors Of The University Of Alberta Transition metal catalysts for hydrogenation and hydrosilylation
US8901334B2 (en) 2012-12-21 2014-12-02 Governors Of The University Of Alberta Transition metal-phosphoranimide catalysts
US9458395B2 (en) 2013-05-21 2016-10-04 Governors Of The University Of Alberta Catalysts for hydrodesulfurization
US9000198B2 (en) 2013-05-21 2015-04-07 Governors Of The University Of Alberta Mixed-valent transition metal-phosphoranimide catalysts
US9441063B2 (en) 2014-10-09 2016-09-13 Chevron Phillips Chemical Company Lp Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
KR101919435B1 (ko) * 2015-10-21 2018-11-16 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 폴리올레핀의 제조 방법
US10005865B1 (en) 2017-04-07 2018-06-26 Chevron Phillips Chemical Company Lp Methods for controlling molecular weight and molecular weight distribution
US10428091B2 (en) 2017-04-07 2019-10-01 Chevron Phillips Chemical Company Lp Catalyst systems containing low valent titanium-aluminum complexes and polymers produced therefrom
US10000595B1 (en) 2017-04-07 2018-06-19 Chevron Phillips Chemical Company Lp Catalyst systems containing low valent titanium compounds and polymers produced therefrom
JP7767014B2 (ja) * 2020-01-22 2025-11-11 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7839869B2 (ja) * 2022-03-31 2026-04-02 ポリプラスチックス株式会社 触媒組成物の保管方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
CA2206944C (en) * 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
US5986120A (en) * 1998-02-10 1999-11-16 The Research Foundation Of The State University Of New York Metal triflimide complexes

Also Published As

Publication number Publication date
JP4619599B2 (ja) 2011-01-26
ES2208398T3 (es) 2004-06-16
EP1214146B1 (de) 2003-10-15
KR20020034186A (ko) 2002-05-08
EP1214146A1 (de) 2002-06-19
WO2001019512A1 (en) 2001-03-22
DE60005982D1 (de) 2003-11-20
JP2003509388A (ja) 2003-03-11
US6440890B1 (en) 2002-08-27
BR0013870B1 (pt) 2011-07-12
KR100670424B1 (ko) 2007-01-18
BR0013870A (pt) 2002-07-23
CA2282070C (en) 2008-12-09
DE60005982T2 (de) 2004-09-09
AU6678300A (en) 2001-04-17
CA2282070A1 (en) 2001-03-10

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