ATE253087T1 - Olefinpolymerisation - Google Patents
OlefinpolymerisationInfo
- Publication number
- ATE253087T1 ATE253087T1 AT99916175T AT99916175T ATE253087T1 AT E253087 T1 ATE253087 T1 AT E253087T1 AT 99916175 T AT99916175 T AT 99916175T AT 99916175 T AT99916175 T AT 99916175T AT E253087 T1 ATE253087 T1 AT E253087T1
- Authority
- AT
- Austria
- Prior art keywords
- olefin polymerization
- olefin
- polymerization
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7039—Tridentate ligand
- C08F4/704—Neutral ligand
- C08F4/7042—NNN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8001898P | 1998-03-30 | 1998-03-30 | |
| US11747199P | 1999-01-27 | 1999-01-27 | |
| PCT/US1999/006769 WO1999050318A1 (en) | 1998-03-30 | 1999-03-29 | Polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE253087T1 true ATE253087T1 (de) | 2003-11-15 |
Family
ID=26762969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99916175T ATE253087T1 (de) | 1998-03-30 | 1999-03-29 | Olefinpolymerisation |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1068245B2 (de) |
| JP (2) | JP2002509954A (de) |
| KR (1) | KR100541311B1 (de) |
| CN (1) | CN1198855C (de) |
| AR (1) | AR018173A1 (de) |
| AT (1) | ATE253087T1 (de) |
| AU (1) | AU752734B2 (de) |
| BR (1) | BR9908406B1 (de) |
| CA (1) | CA2324310A1 (de) |
| DE (1) | DE69912411T3 (de) |
| EA (1) | EA200001002A1 (de) |
| IL (1) | IL138017A0 (de) |
| WO (1) | WO1999050318A1 (de) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002509954A (ja) † | 1998-03-30 | 2002-04-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | オレフィンの重合 |
| US6255414B1 (en) | 1998-09-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| US6620896B1 (en) * | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
| GB9906296D0 (en) | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
| US6620895B1 (en) | 1999-03-22 | 2003-09-16 | E. I. Du Pont De Nemours And Company | Processing polyethylenes |
| US6458979B1 (en) * | 1999-04-29 | 2002-10-01 | E. I. Du Pont De Nemours And Company | Polymerization of ethylene |
| GB9918189D0 (en) * | 1999-08-02 | 1999-10-06 | Bp Chem Int Ltd | Polymerisation process |
| KR20020037364A (ko) | 1999-09-29 | 2002-05-18 | 메리 이. 보울러 | 폴리에틸렌의 제조 |
| US6407188B1 (en) | 1999-09-29 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| JP4629939B2 (ja) * | 1999-09-29 | 2011-02-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 重合用二金属触媒系を用いたオレフィンの重合 |
| BR0014637B1 (pt) * | 1999-09-29 | 2011-02-22 | processo para a moldagem por sopro, extrusão ou produção de filme soprado extrusado de um polietileno. | |
| JP2003510428A (ja) † | 1999-09-29 | 2003-03-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 硬化性重合体の製造 |
| DE19960123A1 (de) * | 1999-12-13 | 2001-06-21 | Basf Ag | Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen |
| US6586541B2 (en) * | 2000-02-02 | 2003-07-01 | E. I. Du Pont De Nemours And Company | Process for production of polyolefins |
| EP1265935A1 (de) * | 2000-02-10 | 2002-12-18 | BP Chemicals Limited | Polymerisationskatalysator |
| GB0003363D0 (en) * | 2000-02-14 | 2000-04-05 | Bp Chem Int Ltd | Polymer blends |
| US6534691B2 (en) * | 2000-07-18 | 2003-03-18 | E. I. Du Pont De Nemours And Company | Manufacturing process for α-olefins |
| BE1014196A3 (fr) | 2001-05-23 | 2003-06-03 | Solvay | Complexes catalytiques et leur utilisation pour la polymerisation des alpha-olefines. |
| CN100528356C (zh) * | 2002-01-09 | 2009-08-19 | 纳幕尔杜邦公司 | 烯烃聚合催化剂 |
| AU2003261617A1 (en) * | 2002-08-29 | 2004-03-19 | Lg Chem, Ltd. | Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same |
| EP1403288A1 (de) * | 2002-09-27 | 2004-03-31 | ATOFINA Research | Hafnocenverbindungen enthaltendes Dual-site Katalysatorsystem zur Herstellung von bimodalen Polyolefinen |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| EP1650229A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Herstellung von Polyolefinen mittels zwei "single-site" Katalysatoren in einem Reaktor |
| EP1650231A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor |
| US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| DE102007017903A1 (de) * | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| CN101910205B (zh) * | 2007-12-24 | 2012-11-21 | 巴塞尔聚烯烃股份有限公司 | 用于烯烃聚合的多级方法 |
| JP5346088B2 (ja) * | 2008-09-25 | 2013-11-20 | バーゼル・ポリオレフィン・ゲーエムベーハー | 耐衝撃性lldpe組成物及びそれから製造されるフィルム |
| JP2012503686A (ja) * | 2008-09-25 | 2012-02-09 | バーゼル・ポリオレフィン・ゲーエムベーハー | 耐衝撃性lldpe組成物及びそれから製造されるフィルム |
| DE102009028353A1 (de) | 2009-08-07 | 2011-04-14 | Wacker Chemie Ag | Bindemittel auf der Basis von silangruppenhaltigen hochverzweigten Polyolefinen |
| CN102574944B (zh) * | 2009-08-17 | 2014-10-29 | 纳幕尔杜邦公司 | 改善的烯烃聚合方法 |
| US20130012659A1 (en) | 2010-03-29 | 2013-01-10 | E I Dupont De Nemours And Company | Lubricant component |
| JP6123165B2 (ja) * | 2011-03-30 | 2017-05-10 | 住友化学株式会社 | エチレン系重合体製造用触媒の製造方法、エチレン系重合体製造用触媒及びエチレン系重合体の製造方法 |
| JP2012224842A (ja) * | 2011-03-30 | 2012-11-15 | Sumitomo Chemical Co Ltd | エチレン系重合体製造用触媒およびエチレン系重合体の製造方法 |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| JP6848195B2 (ja) * | 2016-03-29 | 2021-03-24 | 日本ポリエチレン株式会社 | 特定の触媒と特定の工程によるエチレン共重合体の製造方法 |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| JP7164519B2 (ja) * | 2016-09-29 | 2022-11-01 | ダウ グローバル テクノロジーズ エルエルシー | オレフィンを重合する方法 |
| BR112019005532B1 (pt) | 2016-09-29 | 2023-04-11 | Dow Global Technologies Llc | Sistema e (pró)catalisador de ziegler-natta modificado |
| JP6850192B2 (ja) * | 2017-05-10 | 2021-03-31 | Eneos株式会社 | オリゴマーの製造方法 |
| US12473319B2 (en) * | 2020-05-01 | 2025-11-18 | Exxonmobil Chemical Patents Inc. | Transition metal-complex catalysts having appended group 13 Lewis acids and related polymerization methods |
| CN115246896B (zh) * | 2021-04-28 | 2023-08-15 | 中国石油化工股份有限公司 | 一种双/多金属催化剂及其制备方法与应用 |
| CN115463659B (zh) * | 2021-06-11 | 2025-11-25 | 上海大学 | 一种钴氧化物催化剂及其制备方法和应用 |
| US20250136728A1 (en) * | 2022-12-15 | 2025-05-01 | Lg Chem, Ltd. | Hybrid Metallocene Catalyst and Method for Preparing Polyethylene Using the Same |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5573712A (en) * | 1978-11-29 | 1980-06-03 | Nippon Oil Co Ltd | Preparation of copolymer |
| ZA844157B (en) † | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3621763A1 (de) * | 1986-06-28 | 1988-01-21 | Bayer Ag | Verfahren zur herstellung von verzweigtem niederdruckpolyethen, neue niederdruckpolyethene und praeformierte bifunktionelle katalysatoren |
| US5198401A (en) † | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US4966951A (en) * | 1988-09-26 | 1990-10-30 | Phillips Petroleum Company | High strength linear, low density polyethylene polymerization process |
| NZ235032A (en) † | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5562958A (en) * | 1991-10-15 | 1996-10-08 | The Dow Chemical Company | Packaging and wrapping film |
| EP0641362B1 (de) * | 1992-04-20 | 1998-11-11 | Exxon Chemical Patents Inc. | Copolymere des ethylens mit verzweigten olefinen |
| JP3172594B2 (ja) * | 1992-07-20 | 2001-06-04 | 出光興産株式会社 | オレフィン系重合体の製造方法 |
| EP0805826B1 (de) * | 1995-01-24 | 2003-04-23 | E.I. Du Pont De Nemours And Company | Polyolefine |
| WO1997048735A1 (en) † | 1996-06-17 | 1997-12-24 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
| IL129929A0 (en) * | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| DE19707236A1 (de) † | 1997-02-24 | 1998-08-27 | Targor Gmbh | Katalysatorzusammensetzung |
| US6103946A (en) † | 1997-07-15 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Manufacture of α-olefins |
| US6114483A (en) * | 1997-08-27 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| DZ2740A1 (fr) † | 1998-03-12 | 2003-09-08 | Bp Chem Int Ltd | Catalyseurs de polymésation. |
| JP2002509954A (ja) † | 1998-03-30 | 2002-04-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | オレフィンの重合 |
| GB9906296D0 (en) † | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
-
1999
- 1999-03-29 JP JP2000541216A patent/JP2002509954A/ja active Pending
- 1999-03-29 EP EP99916175A patent/EP1068245B2/de not_active Expired - Lifetime
- 1999-03-29 WO PCT/US1999/006769 patent/WO1999050318A1/en not_active Ceased
- 1999-03-29 EA EA200001002A patent/EA200001002A1/ru unknown
- 1999-03-29 BR BRPI9908406-6A patent/BR9908406B1/pt not_active IP Right Cessation
- 1999-03-29 KR KR1020007010852A patent/KR100541311B1/ko not_active Expired - Fee Related
- 1999-03-29 AT AT99916175T patent/ATE253087T1/de not_active IP Right Cessation
- 1999-03-29 CN CNB998048186A patent/CN1198855C/zh not_active Expired - Lifetime
- 1999-03-29 DE DE69912411T patent/DE69912411T3/de not_active Expired - Lifetime
- 1999-03-29 CA CA002324310A patent/CA2324310A1/en not_active Abandoned
- 1999-03-29 IL IL13801799A patent/IL138017A0/xx unknown
- 1999-03-29 AU AU34545/99A patent/AU752734B2/en not_active Ceased
- 1999-03-30 AR ARP990101450A patent/AR018173A1/es unknown
-
2010
- 2010-10-12 JP JP2010229908A patent/JP2011032482A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1296499A (zh) | 2001-05-23 |
| BR9908406B1 (pt) | 2009-01-13 |
| KR100541311B1 (ko) | 2006-01-10 |
| BR9908406A (pt) | 2000-10-17 |
| DE69912411T3 (de) | 2007-10-31 |
| EA200001002A1 (ru) | 2001-02-26 |
| EP1068245B2 (de) | 2007-05-23 |
| KR20010042304A (ko) | 2001-05-25 |
| CN1198855C (zh) | 2005-04-27 |
| WO1999050318A1 (en) | 1999-10-07 |
| JP2002509954A (ja) | 2002-04-02 |
| EP1068245B1 (de) | 2003-10-29 |
| CA2324310A1 (en) | 1999-10-07 |
| DE69912411T2 (de) | 2004-08-05 |
| EP1068245A1 (de) | 2001-01-17 |
| IL138017A0 (en) | 2001-10-31 |
| JP2011032482A (ja) | 2011-02-17 |
| AR018173A1 (es) | 2001-10-31 |
| AU752734B2 (en) | 2002-09-26 |
| DE69912411D1 (de) | 2003-12-04 |
| AU3454599A (en) | 1999-10-18 |
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