ATE284422T1 - Verbrückte metallocene zur olefincopolymerisation - Google Patents
Verbrückte metallocene zur olefincopolymerisationInfo
- Publication number
- ATE284422T1 ATE284422T1 AT99974265T AT99974265T ATE284422T1 AT E284422 T1 ATE284422 T1 AT E284422T1 AT 99974265 T AT99974265 T AT 99974265T AT 99974265 T AT99974265 T AT 99974265T AT E284422 T1 ATE284422 T1 AT E284422T1
- Authority
- AT
- Austria
- Prior art keywords
- polymerization
- atom
- bridged metallocene
- metallocene catalyst
- olefin
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 2
- 239000012968 metallocene catalyst Substances 0.000 abstract 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 238000003780 insertion Methods 0.000 abstract 1
- 230000037431 insertion Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10532998P | 1998-10-23 | 1998-10-23 | |
| US13106799P | 1999-04-26 | 1999-04-26 | |
| PCT/US1999/024944 WO2000024793A1 (en) | 1998-10-23 | 1999-10-22 | Bridged metallocenes for olefin copolymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE284422T1 true ATE284422T1 (de) | 2004-12-15 |
Family
ID=26802468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99974265T ATE284422T1 (de) | 1998-10-23 | 1999-10-22 | Verbrückte metallocene zur olefincopolymerisation |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6528670B1 (de) |
| EP (1) | EP1196464B9 (de) |
| JP (1) | JP4689829B2 (de) |
| KR (1) | KR100568839B1 (de) |
| CN (1) | CN1138796C (de) |
| AT (1) | ATE284422T1 (de) |
| AU (1) | AU757241B2 (de) |
| BR (1) | BR9914717A (de) |
| CA (1) | CA2345628C (de) |
| DE (1) | DE69922548T2 (de) |
| ES (1) | ES2233109T3 (de) |
| HK (1) | HK1041705A1 (de) |
| MX (1) | MXPA01003978A (de) |
| RU (1) | RU2232766C2 (de) |
| WO (1) | WO2000024793A1 (de) |
Families Citing this family (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
| DE60028242T2 (de) * | 1999-10-22 | 2007-03-29 | Exxonmobil Chemical Patents Inc., Baytown | Für polymerisationskatalysatoren geeignete carbenium-kationische komplexe |
| US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
| EP2465879B1 (de) * | 2002-09-27 | 2019-04-24 | Mitsui Chemicals, Inc. | Verbrückte Metallocenverbindung zur Olefinpolymerisierung und Verfahren zur Polymerisierung von Olefin unter Verwendung davon |
| JP4610859B2 (ja) * | 2002-09-27 | 2011-01-12 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| EP1589043A3 (de) | 2003-08-11 | 2006-02-15 | ExxonMobil Chemical Patents Inc. | Polymere, bestehend aus Ethylen und gegebenenfalls copolymerisierbaren Estern, Filme aus diesen Polymeren und dieses Filme verwendendes Stretchfolienhaubenverpackungsverfahren |
| US8263722B2 (en) * | 2004-03-24 | 2012-09-11 | Exxonmobil Chemical Patents Inc. | Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers |
| WO2005100410A1 (ja) * | 2004-03-31 | 2005-10-27 | Mitsui Chemicals, Inc. | オレフィン重合体の製造方法 |
| EP1802699B1 (de) * | 2004-10-13 | 2011-07-27 | ExxonMobil Chemical Patents Inc. | Elastomere reaktorblendzusammensetzungen |
| PL1858907T3 (pl) * | 2005-03-18 | 2009-04-30 | Basell Polyolefine Gmbh | Metalocenowe związki |
| EP1734059A1 (de) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Kohlenstoffverbrückte Cyclopentadienyl-Fluorenyl-Liganden |
| US8222358B2 (en) * | 2006-03-02 | 2012-07-17 | Exxonmobil Chemical Patents Inc. | Process for producing propylene copolymers |
| EP2024402B2 (de) | 2006-05-17 | 2023-01-25 | Dow Global Technologies LLC | Hochtemperatur-polymerisierungsverfahren mit einer lösung |
| EP1903061A1 (de) * | 2006-09-25 | 2008-03-26 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung eines Biphenyl verbrückten Cyclopentadienyl-Fluorenyl Liganden |
| EP2083046A1 (de) | 2008-01-25 | 2009-07-29 | ExxonMobil Chemical Patents Inc. | Thermoplastische Elastomerzusammensetzungen |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| FR2934599B1 (fr) * | 2008-07-29 | 2012-12-21 | Arkema France | Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations |
| US8378042B2 (en) * | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
| CN102762785A (zh) | 2009-12-23 | 2012-10-31 | 英威达技术有限公司 | 聚烯烃弹性纤维 |
| EP2516709A4 (de) | 2009-12-23 | 2013-11-06 | Invista Tech Sarl | Stoff mit elastischer polyolefinfaser |
| CN104894666A (zh) | 2009-12-23 | 2015-09-09 | 英威达技术有限公司 | 包含抗粘添加剂的弹性纤维 |
| BR112012015382A2 (pt) | 2009-12-23 | 2016-03-15 | Invista Tech Sarl | artigo de estiramento e método para a produção |
| WO2011087731A1 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
| CN102190749B (zh) * | 2010-03-05 | 2013-02-20 | 中国石油天然气股份有限公司 | 一种乙烯/α-烯烃共聚合的方法 |
| US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
| US10336845B2 (en) | 2014-09-30 | 2019-07-02 | Exxonmobil Chemical Patents Inc. | Low ethylene amorphous propylene-ethylene-diene terpolymer compositions |
| CN107207807B (zh) | 2015-01-14 | 2020-06-16 | 埃克森美孚化学专利公司 | 生产聚合物组合物的方法 |
| WO2016171807A1 (en) | 2015-04-20 | 2016-10-27 | Exxonmobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
| EP3274381B1 (de) * | 2015-04-20 | 2019-05-15 | ExxonMobil Chemical Patents Inc. | Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon |
| JP2018522099A (ja) | 2015-06-15 | 2018-08-09 | エクソンモービル・ケミカル・パテンツ・インク | 連続溶液重合プロセス |
| KR102034973B1 (ko) | 2015-09-29 | 2019-10-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 스파이럴 열교환기를 사용하는 중합 |
| EP3414272A1 (de) | 2016-02-12 | 2018-12-19 | ExxonMobil Chemical Patents Inc. | Cyclische olefincopolymere und verfahren zur herstellung davon |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| EP3484931A1 (de) | 2016-07-14 | 2019-05-22 | ExxonMobil Chemical Patents Inc. | Doppelmetallocenkatalysierte bimodale copolymerzusammensetzungen |
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| US11352376B2 (en) | 2016-11-18 | 2022-06-07 | Borealis Ag | Catalysts |
| ES2943392T3 (es) | 2016-12-15 | 2023-06-13 | Borealis Ag | Sistema catalizador para la producción de copolímeros de polietileno en un proceso de polimerización en solución a alta temperatura |
| WO2018108917A1 (en) * | 2016-12-15 | 2018-06-21 | Borealis Ag | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| JP7130649B2 (ja) | 2016-12-29 | 2022-09-05 | ボレアリス エージー | 触媒 |
| CN110520471B (zh) | 2017-02-28 | 2022-05-24 | 埃克森美孚化学专利公司 | 用油增量的双峰茂金属合成的epdm制备的热塑性硫化橡胶 |
| US10730978B2 (en) | 2017-04-10 | 2020-08-04 | Exxonmobil Chemical Patents Inc. | Linear ethylene cyclic olefin polymers |
| WO2018231224A1 (en) | 2017-06-14 | 2018-12-20 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| KR102455607B1 (ko) * | 2017-11-10 | 2022-10-14 | 한화솔루션 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
| US11008449B2 (en) | 2017-11-14 | 2021-05-18 | Exxonmobil Chemical Patents Inc. | Bimodal ethylene, alpha-olefin, and diene polymers using dual organometallic catalysts |
| US11142593B2 (en) | 2018-02-22 | 2021-10-12 | Exxonmobil Chemical Patents Inc. | Lecithin quenching agent |
| US10654949B2 (en) | 2018-02-22 | 2020-05-19 | Exxonmobil Chemical Patents Inc. | High molecular weight functionalized olefin copolymer quenching agent |
| US11046793B2 (en) | 2018-02-22 | 2021-06-29 | Exxonmobil Chemical Patents Inc. | Silica quenching agents for use in polymerization process |
| EP3768735B1 (de) | 2018-03-19 | 2021-12-29 | Borealis AG | Katalysatoren zur olefinpolymerisation |
| US11643427B2 (en) | 2018-06-28 | 2023-05-09 | Borealis Ag | Catalysts |
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| US20200172715A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Blends of Cyclic Olefin Copolymers and Films Prepared Therefrom |
| WO2020167399A1 (en) | 2019-02-11 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Biphasic polymerization processes and ethylene-based polyolefins therefrom |
| EP3763745A1 (de) * | 2019-07-10 | 2021-01-13 | Borealis AG | Hochtemperaturlösungsverfahren zur copolymerisierung von alpha-olefinen |
| US20230002525A1 (en) | 2019-12-17 | 2023-01-05 | Exxonmobil Chemical Patents Inc. | Solution Polymerization Process for Making High-Density Polyethylene with Long-Chain Branching |
| WO2022005634A1 (en) | 2020-07-02 | 2022-01-06 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same |
| BR112023006045A2 (pt) * | 2020-09-30 | 2023-05-09 | Borealis Ag | Copolímero de etileno e uma alfa-olefina |
| US12540206B2 (en) | 2020-09-30 | 2026-02-03 | Borealis Gmbh | Ethylene copolymers with improved melting and glass transition temperature |
| WO2022114635A1 (ko) * | 2020-11-25 | 2022-06-02 | 한화솔루션 주식회사 | 전이금속 화합물, 이를 포함하는 촉매 및 이들의 제조방법 |
| WO2022260891A1 (en) | 2021-06-11 | 2022-12-15 | Exxonmobil Chemical Patents Inc. | Processes for making polypropylene random copolymers and products made therefrom |
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| KR102831436B1 (ko) * | 2022-01-13 | 2025-07-09 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| KR102888044B1 (ko) * | 2022-01-13 | 2025-11-18 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| JP2025526711A (ja) | 2022-08-09 | 2025-08-15 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ジフェニルシラン架橋ｃ１対称触媒及びそれから製造するポリマー |
| CN120303312A (zh) | 2022-09-28 | 2025-07-11 | 埃克森美孚化学专利公司 | 用于光伏电池的乙烯共聚物 |
| CN115572341B (zh) * | 2022-11-04 | 2024-04-23 | 大连万慷工业科技有限公司 | 一类功能化聚烯烃弹性体及其制备方法 |
| CN121666411A (zh) | 2023-08-07 | 2026-03-13 | 埃克森美孚技术与工程公司 | 乙烯共聚物组合物和由其制成的制品 |
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Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
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-
1999
- 1999-10-22 CA CA2345628A patent/CA2345628C/en not_active Expired - Fee Related
- 1999-10-22 WO PCT/US1999/024944 patent/WO2000024793A1/en not_active Ceased
- 1999-10-22 ES ES99974265T patent/ES2233109T3/es not_active Expired - Lifetime
- 1999-10-22 BR BR9914717-3A patent/BR9914717A/pt not_active IP Right Cessation
- 1999-10-22 CN CNB998123811A patent/CN1138796C/zh not_active Expired - Lifetime
- 1999-10-22 HK HK02103341.8A patent/HK1041705A1/zh unknown
- 1999-10-22 AU AU13212/00A patent/AU757241B2/en not_active Ceased
- 1999-10-22 RU RU2001113445/04A patent/RU2232766C2/ru not_active IP Right Cessation
- 1999-10-22 KR KR1020017004930A patent/KR100568839B1/ko not_active Expired - Fee Related
- 1999-10-22 JP JP2000578362A patent/JP4689829B2/ja not_active Expired - Lifetime
- 1999-10-22 MX MXPA01003978A patent/MXPA01003978A/es not_active IP Right Cessation
- 1999-10-22 EP EP99974265A patent/EP1196464B9/de not_active Expired - Lifetime
- 1999-10-22 DE DE69922548T patent/DE69922548T2/de not_active Expired - Lifetime
- 1999-10-22 US US09/426,099 patent/US6528670B1/en not_active Expired - Lifetime
- 1999-10-22 AT AT99974265T patent/ATE284422T1/de not_active IP Right Cessation
-
2002
- 2002-03-07 US US10/092,660 patent/US6506857B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010099705A (ko) | 2001-11-09 |
| US6506857B2 (en) | 2003-01-14 |
| AU1321200A (en) | 2000-05-15 |
| BR9914717A (pt) | 2001-07-10 |
| US20020137959A1 (en) | 2002-09-26 |
| WO2000024793A8 (en) | 2001-10-11 |
| AU757241B2 (en) | 2003-02-06 |
| DE69922548T2 (de) | 2006-01-05 |
| JP2002528463A (ja) | 2002-09-03 |
| EP1196464B1 (de) | 2004-12-08 |
| RU2232766C2 (ru) | 2004-07-20 |
| CA2345628A1 (en) | 2000-05-04 |
| CN1138796C (zh) | 2004-02-18 |
| DE69922548D1 (de) | 2005-01-13 |
| CA2345628C (en) | 2010-02-16 |
| EP1196464A1 (de) | 2002-04-17 |
| MXPA01003978A (es) | 2003-06-06 |
| EP1196464B9 (de) | 2005-03-23 |
| WO2000024793A1 (en) | 2000-05-04 |
| ES2233109T3 (es) | 2005-06-01 |
| US6528670B1 (en) | 2003-03-04 |
| CN1328580A (zh) | 2001-12-26 |
| KR100568839B1 (ko) | 2006-04-10 |
| JP4689829B2 (ja) | 2011-05-25 |
| HK1041705A1 (zh) | 2002-07-19 |
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