ATE309259T1 - Überbrückte bisindenylmetallocenverbindungen - Google Patents

Überbrückte bisindenylmetallocenverbindungen

Info

Publication number
ATE309259T1
ATE309259T1 AT03027480T AT03027480T ATE309259T1 AT E309259 T1 ATE309259 T1 AT E309259T1 AT 03027480 T AT03027480 T AT 03027480T AT 03027480 T AT03027480 T AT 03027480T AT E309259 T1 ATE309259 T1 AT E309259T1
Authority
AT
Austria
Prior art keywords
alkenyl
aryl
alkyl
metallocene compound
arylalkenyl
Prior art date
Application number
AT03027480T
Other languages
English (en)
Inventor
Matthew C Kuchta
Udo M Stehling
Robert T Li
William T Haygood
Terry J Burkhardt
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE309259T1 publication Critical patent/ATE309259T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
AT03027480T 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen ATE309259T1 (de)

Applications Claiming Priority (14)

Application Number Priority Date Filing Date Title
US21559700P 2000-06-30 2000-06-30
US21545900P 2000-06-30 2000-06-30
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions

Publications (1)

Publication Number Publication Date
ATE309259T1 true ATE309259T1 (de) 2005-11-15

Family

ID=27585093

Family Applications (2)

Application Number Title Priority Date Filing Date
AT01937633T ATE260289T1 (de) 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen
AT03027480T ATE309259T1 (de) 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
AT01937633T ATE260289T1 (de) 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen

Country Status (6)

Country Link
EP (2) EP1411058B1 (de)
JP (1) JP2004502698A (de)
AT (2) ATE260289T1 (de)
DE (2) DE60114896T8 (de)
ES (2) ES2247473T3 (de)
WO (1) WO2002002575A1 (de)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
JP2005522406A (ja) * 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE60306147T2 (de) * 2002-04-23 2007-04-19 Dow Global Technologies, Inc., Midland Alkarylsubstituierte komplexe von gruppe-4-metallen, katalysatoren und verfahren zur polymerisierung von olefinen
WO2004033510A2 (de) * 2002-10-10 2004-04-22 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
JP4590037B2 (ja) * 2003-09-30 2010-12-01 日本ポリプロ株式会社 オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
AU2007211498A1 (en) * 2006-02-02 2007-08-09 Basell Polyolefine Gmbh Propylene melt blown resins, propylene melt blown resin fibers and non-woven fabric made from the same, and methods of making the same
TW200932770A (en) 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes
US8603933B2 (en) 2009-11-13 2013-12-10 Borealis Ag Process for recovering a transition metal compound
CN102666601B (zh) 2009-11-13 2014-04-23 博瑞立斯有限公司 烯烃聚合方法
EP2322568B1 (de) 2009-11-13 2013-05-15 Borealis AG Verfahren zur Herstellung eines Olefin-Polymerisationskatalysatoren
EP2499168B1 (de) 2009-11-13 2017-05-10 Borealis AG Verfahren zur Wiederherstellung einer Übergangsmetallverbindung
EP2330136B1 (de) 2009-12-07 2013-08-28 Borealis AG Verfahren zur Herstellung eines nicht geträgerten, festen Metallocenkatalysatorsystems und dessen Verwendung bei der Polymerisation von Olefinen
PT2495038T (pt) 2011-03-02 2020-11-06 Borealis Ag Conjunto de reator flexível para polimerização de olefinas
ES2813282T3 (es) 2011-03-02 2021-03-23 Borealis Ag Conjunto de reactor de alto rendimiento para la polimerización de olefinas
EP2532687A3 (de) 2011-06-10 2013-04-10 Borealis AG Verbrückte Metallocen-Katalysatoren
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
CN104582829B (zh) 2012-08-29 2016-12-28 博里利斯股份公司 用于烯烃聚合的反应器装置和方法
US9321914B2 (en) * 2012-10-31 2016-04-26 Exxonmobil Chemical Patents Inc. Propylene copolymer compositions and processes to produce them
EP2745926A1 (de) 2012-12-21 2014-06-25 Borealis AG Gasphasenpolymerisation und Reaktoranordnung mit einem Fließbettreaktor und einem externen Wanderbettreaktor
EP3301098B1 (de) 2012-12-21 2020-02-19 Borealis AG Verfahren zur herstellung eines liganden für ein katalysator
EP2745927A1 (de) 2012-12-21 2014-06-25 Borealis AG Fließbettreaktor mit interner Wanderbettreaktionseinheit
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
ES2674576T3 (es) 2012-12-21 2018-07-02 Borealis Ag Catalizador
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
US9249239B2 (en) 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
EP3022236B1 (de) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Verfahren mit substituierten metallocenkatalysatoren und produkte daraus
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用
CN110483670B (zh) * 2014-03-20 2021-11-30 日本聚丙烯株式会社 茂金属配合物和生产烯烃聚合物的方法
JP6201853B2 (ja) * 2014-03-25 2017-09-27 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
EP3023450B1 (de) 2014-11-21 2017-07-19 Borealis AG Verfahren zur Herstellung von Pellets aus weichen Copolymeren
US11292156B2 (en) 2014-12-08 2022-04-05 Borealis Ag Process for producing pellets of copolymers of propylene
EP3303423A1 (de) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Einzelreaktor-herstellung von polymeren in der gas- oder suspensionsphase
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
EP3303422B1 (de) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Herstellung von heterophasischen polymeren in gas- oder schlämmephase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
EP3124567A1 (de) 2015-07-30 2017-02-01 Borealis AG Polypropylenbasierte heissschmelzklebstoffzusammensetzung
EP3178853B1 (de) 2015-12-07 2018-07-25 Borealis AG Verfahren zur polymerisierung von alpha-olefin-monomeren
JP6613987B2 (ja) * 2016-03-28 2019-12-04 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法
EP3243622B1 (de) 2016-05-13 2020-09-09 Borealis AG Verfahren zum hydraulischen transportieren von polyolefinpellets
EP3464390A1 (de) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocenkatalysatorzusammensetzungen und und polymerisationsverfahren damit
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
EP3608364A1 (de) 2018-08-06 2020-02-12 Borealis AG Multimodale propylen-random-copolymer-basierte zusammensetzung zur verwendung als schmelzklebstoffzusammensetzung
ES2986685T3 (es) 2018-11-30 2024-11-12 Borealis Ag Proceso de lavado
CN114929761A (zh) 2019-08-22 2022-08-19 埃克森美孚化学专利公司 用c1对称的茂金属催化剂生产的全同立构的丙烯均聚物和共聚物
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US20230416418A1 (en) 2020-11-23 2023-12-28 Exxonmobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
EP4144435A1 (de) 2021-09-01 2023-03-08 Borealis AG Gasphasenpolymerisationsverfahren mit verbesserter gasrückführung
US20250002617A1 (en) 2021-09-02 2025-01-02 ExxonMobil Technology and Engineering Company C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
EP4568980A1 (de) 2022-08-09 2025-06-18 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von diphenylsilanverbrückten c1-symmetrischen katalysatoren und daraus hergestellte polymere
EP4389776A1 (de) 2022-12-20 2024-06-26 Borealis AG Verfahren
EP4389783A1 (de) 2022-12-20 2024-06-26 Borealis AG Katalysatorübergangsverfahren
TW202438539A (zh) 2022-12-23 2024-10-01 奧地利商柏列利斯股份公司 高流動性聚丙烯均聚物的製造方法
CN120380039A (zh) 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯共聚物的生产方法
KR20250126808A (ko) 2022-12-23 2025-08-25 보레알리스 아게 폴리프로필렌 단독중합체 또는 공중합체의 제조방법
CN121175162A (zh) 2023-05-23 2025-12-19 博里利斯有限责任公司 用于生产聚烯烃的粒料的方法和由此生产的粒料
EP4735486A1 (de) 2023-06-30 2026-05-06 Borealis GmbH Verfahren
WO2025219537A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for propylene polymerization with optimized prepolymerization conditions
WO2025219533A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for the preparation of a propylene homopolymer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW294669B (de) * 1992-06-27 1997-01-01 Hoechst Ag

Also Published As

Publication number Publication date
DE60114896D1 (de) 2005-12-15
DE60102156D1 (de) 2004-04-01
ATE260289T1 (de) 2004-03-15
JP2004502698A (ja) 2004-01-29
EP1411058B1 (de) 2005-11-09
ES2247473T3 (es) 2006-03-01
DE60114896T2 (de) 2006-07-27
DE60102156T2 (de) 2004-12-09
DE60102156T8 (de) 2005-06-23
EP1411058A1 (de) 2004-04-21
EP1294733B1 (de) 2004-02-25
WO2002002575A1 (en) 2002-01-10
ES2211808T3 (es) 2004-07-16
DE60114896T8 (de) 2007-04-26
EP1294733A1 (de) 2003-03-26

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