ATE314144T1 - Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren - Google Patents

Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren

Info

Publication number
ATE314144T1
ATE314144T1 AT01932385T AT01932385T ATE314144T1 AT E314144 T1 ATE314144 T1 AT E314144T1 AT 01932385 T AT01932385 T AT 01932385T AT 01932385 T AT01932385 T AT 01932385T AT E314144 T1 ATE314144 T1 AT E314144T1
Authority
AT
Austria
Prior art keywords
chiral
catalysts
epoxides
compounds
producing
Prior art date
Application number
AT01932385T
Other languages
English (en)
Inventor
Geon-Joong Kim
Dae-Woon Park
Ho Seong Lee
Jin Won Yun
Seong Jin Kim
Original Assignee
Rstech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rstech Co Ltd filed Critical Rstech Co Ltd
Application granted granted Critical
Publication of ATE314144T1 publication Critical patent/ATE314144T1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
    • B01J2231/485—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates
    • B01J2231/487—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates by hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
AT01932385T 2000-05-24 2001-05-23 Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren ATE314144T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20000028099 2000-05-24
PCT/KR2001/000854 WO2001089690A1 (en) 2000-05-24 2001-05-23 Novel chiral salen catalysts, and a process for preparing chiral compounds from racemic epoxides for using them

Publications (1)

Publication Number Publication Date
ATE314144T1 true ATE314144T1 (de) 2006-01-15

Family

ID=19670066

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01932385T ATE314144T1 (de) 2000-05-24 2001-05-23 Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren

Country Status (9)

Country Link
US (1) US6720434B2 (de)
EP (1) EP1289655B1 (de)
JP (1) JP3962587B2 (de)
CN (1) CN1174804C (de)
AT (1) ATE314144T1 (de)
AU (1) AU5891201A (de)
DE (1) DE60116295D1 (de)
IN (1) IN2002DE01011A (de)
WO (1) WO2001089690A1 (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3968076B2 (ja) * 2001-06-27 2007-08-29 アールエス テック コーポレイション 新しいキラルサレン化合物、キラルサレン触媒及びこれを利用したラセミックエポキシ化合物からキラル化合物を製造する方法
WO2003018520A1 (en) 2001-08-22 2003-03-06 Rhodia Pharma Solutions Inc. Improved hydrolytic kinetic resolution of epoxides
US6639087B2 (en) * 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
DE10164348A1 (de) 2001-12-28 2003-07-17 Basf Ag Verfahren zur Herstellung von 1-Methoypropanol-2
DE10208252A1 (de) * 2002-02-26 2003-09-04 Celanese Ventures Gmbh Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
JPWO2004076391A1 (ja) * 2003-02-28 2006-06-01 独立行政法人科学技術振興機構 光学活性化合物の製造方法
US20070092541A1 (en) * 2004-03-01 2007-04-26 Walling David W Direct contact quench crystallization process and cosmetic products produced thereby
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
US7399822B2 (en) * 2005-06-21 2008-07-15 Cornell Research Foundation, Inc. Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide)
KR100894680B1 (ko) * 2007-06-13 2009-04-24 주식회사 카이로켐 신규 키랄 살렌 촉매와 이를 이용한 라세믹 에폭시화합물로부터 키랄 화합물의 제조방법
US20090286968A1 (en) 2008-04-25 2009-11-19 Auburn University 2-Quinoxalinol Salen Compounds and Uses Thereof
CN101967165B (zh) * 2010-09-21 2012-09-05 中国科学院上海有机化学研究所 桥链双希夫碱-钴络合物及其合成方法和用途
TR201202779A2 (tr) 2012-03-12 2013-10-21 Petkim Petrokimya Holding Anonim Sirketi Polietilen karbonat üretim yöntemi.
EP2664641B1 (de) 2012-05-18 2018-04-25 Petkim Petrokimya Holding Anonim Sirekti Verfahren zur herstellung von polyethylencarbonat mit metallsalzen
CA3107987C (en) * 2018-07-31 2024-10-08 Shanghai Research Institute Of Petrochemical Technology Sinopec NANOCAGED CATALYST, PREPARATION AND USE PROCESS
CN111097529B (zh) * 2018-10-25 2023-05-02 中国石油化工股份有限公司 高性能纳米笼限域催化剂、制备方法及应用
CN113943206A (zh) * 2021-10-25 2022-01-18 华今(山东)新材料科技有限公司 一种高品质（r）-3-氯-1,2-丙二醇的制备方法
CN117658953B (zh) * 2023-12-04 2026-01-30 上海中化科技有限公司 手性环氧化合物、手性β-内酯及聚羟基脂肪酸酯的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2077541C (en) * 1990-03-21 1998-08-18 Eric N. Jacobsen Chiral catalysts and epoxidation reactions catalyzed thereby
US5637739A (en) * 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US6262278B1 (en) * 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions

Also Published As

Publication number Publication date
EP1289655A4 (de) 2004-03-31
JP3962587B2 (ja) 2007-08-22
CN1436098A (zh) 2003-08-13
WO2001089690A1 (en) 2001-11-29
US6720434B2 (en) 2004-04-13
DE60116295D1 (de) 2006-02-02
CN1174804C (zh) 2004-11-10
AU5891201A (en) 2001-12-03
JP2003534117A (ja) 2003-11-18
EP1289655B1 (de) 2005-12-28
EP1289655A1 (de) 2003-03-12
US20030032821A1 (en) 2003-02-13
IN2002DE01011A (de) 2005-01-28

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