ATE417817T1 - Verfahren zur herstellung eines optisch aktiven amids ausgehend von einem alpha, beta- ungesättigtem amid derivat in anwesenheit eines optisch aktiven übergangsmetallkomplexes, der eine phosphin-phosphoran verbindung und rhodium enthält - Google Patents

Verfahren zur herstellung eines optisch aktiven amids ausgehend von einem alpha, beta- ungesättigtem amid derivat in anwesenheit eines optisch aktiven übergangsmetallkomplexes, der eine phosphin-phosphoran verbindung und rhodium enthält

Info

Publication number
ATE417817T1
ATE417817T1 AT02291876T AT02291876T ATE417817T1 AT E417817 T1 ATE417817 T1 AT E417817T1 AT 02291876 T AT02291876 T AT 02291876T AT 02291876 T AT02291876 T AT 02291876T AT E417817 T1 ATE417817 T1 AT E417817T1
Authority
AT
Austria
Prior art keywords
optically active
beta
alpha
amide
producing
Prior art date
Application number
AT02291876T
Other languages
English (en)
Inventor
Kazuhiko Matsumura
Takao Saito
Original Assignee
Takasago Perfumery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago Perfumery Co Ltd filed Critical Takasago Perfumery Co Ltd
Application granted granted Critical
Publication of ATE417817T1 publication Critical patent/ATE417817T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT02291876T 2001-07-24 2002-07-24 Verfahren zur herstellung eines optisch aktiven amids ausgehend von einem alpha, beta- ungesättigtem amid derivat in anwesenheit eines optisch aktiven übergangsmetallkomplexes, der eine phosphin-phosphoran verbindung und rhodium enthält ATE417817T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001222421 2001-07-24
JP2002168014A JP4226847B2 (ja) 2001-07-24 2002-06-10 ホスフィン−ホスホラン化合物と遷移金属とを含有する遷移金属錯体の存在下、α，β−不飽和アミド誘導体から光学活性アミド類を製造する方法。

Publications (1)

Publication Number Publication Date
ATE417817T1 true ATE417817T1 (de) 2009-01-15

Family

ID=26619144

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02291876T ATE417817T1 (de) 2001-07-24 2002-07-24 Verfahren zur herstellung eines optisch aktiven amids ausgehend von einem alpha, beta- ungesättigtem amid derivat in anwesenheit eines optisch aktiven übergangsmetallkomplexes, der eine phosphin-phosphoran verbindung und rhodium enthält

Country Status (5)

Country Link
US (1) US6855847B2 (de)
EP (1) EP1279660B1 (de)
JP (1) JP4226847B2 (de)
AT (1) ATE417817T1 (de)
DE (1) DE60230366D1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4005801B2 (ja) 2001-12-10 2007-11-14 高砂香料工業株式会社 新規なホスフィン配位子
JP4005800B2 (ja) * 2001-12-10 2007-11-14 高砂香料工業株式会社 新規不斉ホスフィン配位子
EP1622918B1 (de) * 2003-05-09 2010-03-24 Solvias AG Phospholansalze und deren verwendung in der enantioselektive hydrierung
DE102005014055A1 (de) * 2005-03-23 2006-09-28 Degussa Ag Unsymmetrisch substituierte Phospholankatalysatoren
WO2020194337A2 (en) * 2019-03-28 2020-10-01 Council Of Scientific And Industrial Research A process for the asymmetric synthesis of sitagliptin intermediate

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5008457A (en) 1990-05-17 1991-04-16 E. I. Du Pont De Nemours And Company Chiral phospholane transition metal catalysts
US5171892A (en) 1991-07-02 1992-12-15 E. I. Du Pont De Nemours And Company Chiral phospholanes via chiral 1,4-diol cyclic sulfates
WO1999059721A1 (en) 1998-05-18 1999-11-25 The Penn State Research Foundation Catalytic asymmetric hydrogenation, hydroformylation, and hydrovinylation via transition metal catalysts with phosphines and phosphites
WO2000011008A1 (en) 1998-08-21 2000-03-02 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes
GB9823716D0 (en) 1998-10-29 1998-12-23 Isis Innovation Diphosphines
DE19956414A1 (de) 1999-11-24 2001-06-13 Aventis Res & Tech Gmbh & Co Verfahren zur Herstellung von chiralen Aminen durch homogen katalysierte asymmetrische Hydrierung von Enaminen
DE10100971A1 (de) * 2001-01-11 2002-07-18 Degussa Verfahren zur Herstellung enantiomerenangereicherter beta-Aminosäure
JP4005801B2 (ja) * 2001-12-10 2007-11-14 高砂香料工業株式会社 新規なホスフィン配位子
JP4005800B2 (ja) * 2001-12-10 2007-11-14 高砂香料工業株式会社 新規不斉ホスフィン配位子

Also Published As

Publication number Publication date
JP4226847B2 (ja) 2009-02-18
EP1279660B1 (de) 2008-12-17
US6855847B2 (en) 2005-02-15
JP2003104946A (ja) 2003-04-09
US20030120067A1 (en) 2003-06-26
EP1279660A1 (de) 2003-01-29
DE60230366D1 (de) 2009-01-29

Similar Documents

Publication Publication Date Title
De Luca et al. A very mild and chemoselective oxidation of alcohols to carbonyl compounds
Malkov et al. Organocatalysis with a fluorous tag: asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides
DE60200346D1 (de) Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators
ATE314144T1 (de) Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren
ATE136878T1 (de) Neue methoden zur katalytischen reduktion organischer substrate
DE60014542D1 (de) Ein verfahren zur herstellung von carbonsäure-derivaten und ein kondensationshilfsmittel mit einem quarternären ammonium-salz
ATE417817T1 (de) Verfahren zur herstellung eines optisch aktiven amids ausgehend von einem alpha, beta- ungesättigtem amid derivat in anwesenheit eines optisch aktiven übergangsmetallkomplexes, der eine phosphin-phosphoran verbindung und rhodium enthält
ATE381561T1 (de) Verfahren zur herstellung von chiralen propionsäurederivaten
BRPI0210981B8 (pt) processo de preparação de complexos metálicos e processo de hidrossililação de compostos etilenicamente e/ou acetilenicamente insaturados
Kukula et al. Effects of reaction variables on enantioselectivity of modified Raney nickel catalyst
Bolm et al. A novel asymmetric synthesis of highly enantiomerically enriched norbornane-type diamine derivatives
Xu et al. TMSCl-Promoted transition metal-catalyzed aza-Michael reactions of chalcones with carbamates
EP2078709A4 (de) Verfahren zur herstellung von olefin
Szöllösi et al. Heterogeneous asymmetric reactions. Part 24. Heterogeneous catalytic enantioselective hydrogenation of the C= N group over cinchona alkaloid modified palladium catalyst
DE50211719D1 (de) Verfahren zur Herstellung von Aldehyden
DE602004032359D1 (de) Verfahren zur herstellung von cumen und verfahren es produktionsverfahrens
Anthes et al. An improved synthesis of a selective serotonin reuptake inhibitor
DE60039533D1 (de) Verbessertes verfahren zur herstellung von 2s,3s-n-isobutyl-n-(2-hydroxy-3-amino-4-phenylbutyl)-p-nitrobenzenesulfonylamid hydrochlorid und anderen derivaten von 2-hydroxy-1,3-diamin
ATE411257T1 (de) Verfahren zur herstellung von wasserstoffperoxid
ATE299130T1 (de) Verfahren zur herstellung von tetrahydrogeraniol
DE602005001340D1 (de) Verfahren zur Herstellung von Tolterodine und deren Zwischenprodukten.
Konno et al. A novel synthesis of fluorine-containing quaternary amino acid derivatives via palladium-catalyzed allylation reaction
EP1270582A4 (de) Triphenylphosphin-derivate, verfahren zu deren herstellung, diese enthaltender palladium-komplex und verfahren zur herstellung von biaryl-derivaten
DE50211314D1 (de) Verfahren zur katalytischen Hydrierung
Takasu et al. Chiral amine–silyl triflate complex mediated asymmetric intramolecular Michael–aldol reaction via a novel enantioselective enol silylation process

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties