ATE328057T1 - Verwendung von metallkomplexverbindungen als oxidationskatalysatoren - Google Patents

Verwendung von metallkomplexverbindungen als oxidationskatalysatoren

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Publication number
ATE328057T1
ATE328057T1 AT02740514T AT02740514T ATE328057T1 AT E328057 T1 ATE328057 T1 AT E328057T1 AT 02740514 T AT02740514 T AT 02740514T AT 02740514 T AT02740514 T AT 02740514T AT E328057 T1 ATE328057 T1 AT E328057T1
Authority
AT
Austria
Prior art keywords
metal complex
complex compounds
oxidation catalysts
relates
present
Prior art date
Application number
AT02740514T
Other languages
English (en)
Inventor
Gunther Schlingloff
Torsten Wieprecht
Frank Bachmann
Joseph Dannacher
Marie-Josee Dubs
Menno Hazenkamp
Grit Haensler
Brigitte Schmidt
Albert Schneider
Peter Weingartner
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Application granted granted Critical
Publication of ATE328057T1 publication Critical patent/ATE328057T1/de

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61Halogen atoms or nitro radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62Oxygen or sulfur atoms
    • C07D213/63One oxygen atom
    • C07D213/68One oxygen atom attached in position 4
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72Nitrogen atoms
    • C07D213/74Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005Compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3932Inorganic compounds or complexes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15Locally discharging the dyes
    • D06P5/153Locally discharging the dyes with oxidants
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • D21C9/1026Other features in bleaching processes
    • D21C9/1036Use of compounds accelerating or improving the efficiency of the processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72Epoxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/34Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • D21C9/16Bleaching ; Apparatus therefor with per compounds
    • D21C9/163Bleaching ; Apparatus therefor with per compounds with peroxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
AT02740514T 2001-04-30 2002-04-25 Verwendung von metallkomplexverbindungen als oxidationskatalysatoren ATE328057T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01810425 2001-04-30
CH22782001 2001-12-13

Publications (1)

Publication Number Publication Date
ATE328057T1 true ATE328057T1 (de) 2006-06-15

Family

ID=25739052

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02740514T ATE328057T1 (de) 2001-04-30 2002-04-25 Verwendung von metallkomplexverbindungen als oxidationskatalysatoren

Country Status (11)

Country Link
US (4) US7161005B2 (de)
EP (1) EP1383857B1 (de)
JP (1) JP4414653B2 (de)
KR (1) KR100889467B1 (de)
CN (1) CN100567471C (de)
AT (1) ATE328057T1 (de)
BR (1) BR0209292B1 (de)
DE (1) DE60211884T2 (de)
ES (1) ES2265041T3 (de)
MX (1) MXPA03009905A (de)
WO (1) WO2002088289A2 (de)

Families Citing this family (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1383857B1 (de) * 2001-04-30 2006-05-31 Ciba SC Holding AG Verwendung von metallkomplexverbindungen als oxidationskatalysatoren
BRPI0306187B1 (pt) 2002-02-25 2021-01-12 Ciba Specialty Chemicals Holding Inc. composições detergentes e mistura de compostos para o tratamento de materiais de fibras têxteis
JP4643259B2 (ja) * 2002-07-11 2011-03-02 チバ ホールディング インコーポレーテッド 金属錯体化合物及びその酸化触媒としての使用
US20060019853A1 (en) * 2002-10-29 2006-01-26 Torsten Wieprecht Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air
US7138363B2 (en) 2002-10-30 2006-11-21 Ciba Specialty Chemicals Corporation Use of metal complex compounds as oxidation catalysts
GB2394720A (en) * 2002-10-30 2004-05-05 Reckitt Benckiser Nv Metal complex compounds in dishwasher formulations
EP1585721A2 (de) * 2003-01-24 2005-10-19 Ciba SC Holding AG Kristallmodifikation eines mangankomplexes
AU2004241037B2 (en) * 2003-05-21 2010-07-08 Basf Se Stable particulate composition comprising bleach catalysts
JP5057633B2 (ja) * 2003-08-25 2012-10-24 三菱化学株式会社 芳香族6員環がm−連結している有機化合物
GB2409207B (en) * 2003-12-20 2006-08-09 Reckitt Benckiser Nv Use of metal complex compounds as oxidation catalysts
EP1703977A1 (de) * 2004-01-12 2006-09-27 Ciba SC Holding AG Verwendung einer metallkomplexverbindungen und polyphosphonate enthaltenden zusammensetzung als katalysatoren für oxidationen
EP1703976A2 (de) * 2004-01-12 2006-09-27 Ciba Specialty Chemicals Holding Inc. Verwendung von metallkomplexverbindungen mit von pyridin, pyrimidin oder s-triazin abgeleiteten liganden als katalysatoren für oxidationen mit organischen peroxysäuren und/oder vorläufern von organischen peroxysäuren und h2o2
EP1740306A1 (de) * 2004-04-29 2007-01-10 CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement Verwendung von metallkomplexen mit bispyridylpyrimidin- oder bispyridyltriazin-liganden als katalysatoren für reaktionen mit peroxyverbindungen zum bleichen von farbigen flecken auf harten oberflächen
US20080167321A1 (en) 2004-09-20 2008-07-10 Xenon Pharmaceuticals Inc. Pyridine Derivatives For Inhibiting Human Stearoyl-Coa-Desaturase
BRPI0621307A2 (pt) * 2006-02-06 2011-12-06 Ciba Holding Inc. uso de compostos de complexo metálico como catalisadores de oxidação
JP4915609B2 (ja) * 2006-02-22 2012-04-11 有機合成薬品工業株式会社 4−クロロピリジン−2−カルボン酸クロリドの製造方法
US7967948B2 (en) * 2006-06-02 2011-06-28 International Paper Company Process for non-chlorine oxidative bleaching of mechanical pulp in the presence of optical brightening agents
CN100448857C (zh) * 2006-06-12 2009-01-07 北京科技大学 一种选择性催化烯烃环氧化制备环氧化物的方法
JP5352099B2 (ja) * 2007-03-09 2013-11-27 住友化学株式会社 変性金属錯体を用いたレッドックス触媒
WO2009000685A1 (en) * 2007-06-25 2008-12-31 Basf Se Use of metal complex oxidation catalysts together with zinc compounds in laundry compositions
DE102007042615A1 (de) * 2007-09-07 2009-03-12 Bk Giulini Gmbh Erhöhung der bioziden Wirkung von Wasserstoffperoxid in Abwässern durch Übergangsmetallkatalysatoren
US20090325841A1 (en) 2008-02-11 2009-12-31 Ecolab Inc. Use of activator complexes to enhance lower temperature cleaning in alkaline peroxide cleaning systems
CA2711118C (en) * 2008-02-11 2017-01-03 Ecolab Inc. Use of activator complexes to enhance lower temperature cleaning in alkaline peroxide cleaning systems
WO2009109533A1 (en) * 2008-03-07 2009-09-11 Basf Se Bleach catalysts and their use as teeth whitening agents
EP2103604A1 (de) 2008-03-17 2009-09-23 Evonik Degussa GmbH Verfahren zur Herstellung von Epichlorhydrin
EP2103735A1 (de) 2008-03-18 2009-09-23 Unilever PLC Katalytische Substratbleichung
BRPI0909022B1 (pt) 2008-04-09 2020-11-10 Basf Se uso de pelo menos um composto, composição detergente, limpadora, desinfetante ou alvejante, e, grânulo
EP2304014A1 (de) * 2008-05-23 2011-04-06 Henkel AG & Co. KGaA Textilschonendes waschmittel
EP2149569A1 (de) 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Verfahren zur Herstellung eines 1,2-Epoxid
EP2149570A1 (de) * 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Verfahren zur Herstellung von Epichlorhydrin mit Wasserstoffperoxid und einem Mangankomplex
WO2010020583A1 (en) * 2008-08-20 2010-02-25 Basf Se Improved bleach process
EP2228429A1 (de) 2009-03-13 2010-09-15 Unilever PLC Abschattungsfärbung und Katalysatorkombination
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
MX382645B (es) 2009-05-28 2025-03-13 Gp Cellulose Gmbh Celulosa modificada a partir de fibra kraft química y métodos para elaborarla y su uso.
AU2010259935B2 (en) 2009-06-13 2016-05-26 Archer-Daniels-Midland Company Production of glutaric acid and derivatives from carbohydrate-containing materials
AU2010259937B2 (en) 2009-06-13 2016-07-14 Archer-Daniels-Midland Company Production of adipic acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8236915B2 (en) * 2009-07-10 2012-08-07 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8415443B2 (en) 2009-07-10 2013-04-09 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
WO2012000846A1 (en) 2010-06-28 2012-01-05 Basf Se Metal free bleaching composition
PL2651907T3 (pl) 2010-12-13 2015-03-31 Basf Se Katalizatory wybielania
WO2012170183A1 (en) 2011-05-23 2012-12-13 Gp Cellulose Gmbh Softwood kraft fiber having improved whiteness and brightness and methods of making and using the same
US20140298591A1 (en) 2011-10-25 2014-10-09 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
CN104145012A (zh) 2011-10-25 2014-11-12 巴斯夫欧洲公司 丙烯酸酯共聚物作为抗污垢再沉积剂和去污剂在洗衣过程中的用途
CN103174007B (zh) * 2011-11-24 2015-05-13 东华大学 三吡啶基四氮金属配合物在纺织品低温练漂助剂中的应用
CN103174006A (zh) * 2011-11-24 2013-06-26 东华大学 双吡啶嘧啶金属配合物在纺织品低温练漂助剂中的应用
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
TWI628331B (zh) 2012-01-12 2018-07-01 Gp纖維股份有限公司 具有降低黃化性質之低黏度牛皮紙纖維及其製造與使用方法
JP6242859B2 (ja) 2012-04-18 2017-12-06 ゲーペー ツェルローゼ ゲーエムベーハー ビスコースおよび他の二次的繊維製品の製造のための、パルプを処理して、クラフトパルプの繊維への取り込みを改良するための界面活性剤の使用
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
CA2898417C (en) 2013-02-08 2021-07-27 Arthur J. Nonni Softwood kraft fiber having an improved .alpha.-cellulose content and its use in the production of chemical cellulose products
MX364379B (es) 2013-03-14 2019-04-24 Gp Cellulose Gmbh Un metodo para preparar una fibra kraft altamente funcional y de baja viscosidad, usando una secuencia de blanqueamiento acido, y una fibra hecha por el proceso.
CN105143547B (zh) 2013-03-15 2018-05-01 Gp 纤维素股份有限公司 具有增高羧基含量的低粘度牛皮纸纤维及其制造和使用方法
KR20150135489A (ko) 2013-03-27 2015-12-02 바스프 에스이 세탁 과정에서 오염물 방출제로서 블록 공중합체
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
TWI623544B (zh) 2013-05-15 2018-05-11 摩曼帝夫特性材料公司 使用矽氫之金屬鹽的活化及其在矽氫化反應之用途
AU2014307707B2 (en) 2013-08-16 2018-08-02 Chemsenti Limited Composition
US9581612B2 (en) 2013-08-26 2017-02-28 EveryFit, Inc. Systems and methods for a power efficient method for detecting wear and non-wear of a sensor
US9947198B2 (en) 2013-08-26 2018-04-17 EveryFit, Inc. Systems and methods for context-aware transmission of longitudinal safety and wellness data wearable sensors
US9554747B2 (en) 2013-08-26 2017-01-31 EveryFit, Inc. Power efficient system and method for measuring physical activity in resource constrained devices
JP6486924B2 (ja) 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
JP6486925B2 (ja) 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
WO2015077344A1 (en) 2013-11-19 2015-05-28 The Trustees Of Princeton University Hydroboration and borylation with cobalt catalysts
HUE035705T2 (en) 2013-11-27 2018-05-28 Basf Se Random copolymers in the washing process as a dirt remover
WO2017076771A1 (en) 2015-11-03 2017-05-11 Basf Se Bleach catalysts
EP3176157A1 (de) 2015-12-01 2017-06-07 Basf Se Bleichkatalysatoren
WO2017182295A1 (en) 2016-04-18 2017-10-26 Basf Se Liquid cleaning compositions
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition
WO2018093697A1 (en) 2016-11-16 2018-05-24 Gp Cellulose Gmbh Modified cellulose from chemical fiber and methods of making and using the same
EP3372663A1 (de) 2017-03-10 2018-09-12 Basf Se Bleichkatalysatoren
CN107537574B (zh) * 2017-09-18 2020-05-12 温州大学 可催化2-碘联苯与取代基碘苯的c-c偶联反应的钯三联吡啶配合物的制备及其应用方法
EP3724310A4 (de) 2017-12-15 2021-07-21 Rhodia Operations Zusammensetzung mit lanthanidmetallkomplex
EP3967742A1 (de) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Bleichkatalysatorhaltige zusammensetzungen, verfahren zu ihrer herstellung und bleich- und reinigungsmittel damit
CN120769877A (zh) 2023-02-21 2025-10-10 巴斯夫欧洲公司 改性的烷氧基化聚亚烷基亚胺或改性的烷氧基化多胺
WO2024175409A1 (en) 2023-02-21 2024-08-29 Basf Se Modified hyperbranched alkoxylated polyalkylene imines
EP4669690A1 (de) 2023-02-21 2025-12-31 Basf Se Modifizierte alkoxylierte polyalkylenimine oder modifizierte alkoxylierte polyamine
CN120882779A (zh) 2023-03-13 2025-10-31 巴斯夫欧洲公司 烷氧基化含氮聚合物及其用途
CN116554371B (zh) * 2023-03-27 2025-05-09 浙江大学 一种用于烯烃聚合反应的球形催化剂
CN120981505A (zh) 2023-05-05 2025-11-18 巴斯夫欧洲公司 可生物降解的多元醇丙氧基化物、其制备、用途以及包含它们的组合物
EP4728032A1 (de) 2023-06-13 2026-04-22 Basf Se Stabilisierte reinigungszusammensetzungen mit edds und enzymen und deren verwendung
WO2025125117A1 (en) 2023-12-15 2025-06-19 Basf Se Biodegradable propoxylated ethylenediamines, their preparation, uses, and compositions comprising them
WO2025131888A1 (en) 2023-12-19 2025-06-26 Basf Se Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines
WO2025180874A1 (en) 2024-02-27 2025-09-04 Basf Se Substituted 1,3-dioxolane sulfates and their use
WO2025195856A1 (en) 2024-03-19 2025-09-25 Basf Se Compositions of guerbet alkyl sulfates and their use
WO2025195357A1 (en) 2024-03-19 2025-09-25 Basf Se Bleaching catalyst and use thereof in hydrogen peroxide bleaching
WO2025202032A1 (en) 2024-03-26 2025-10-02 Basf Se Biodegradable alkoxylated polyols, their preparation, uses, and compositions comprising them

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH082878B2 (ja) * 1988-02-12 1996-01-17 富士写真フイルム株式会社 4’−アルコキシ−2,2’:6’,2〃−デルピリジン誘導体及びその金属錯体
AU643542B2 (en) * 1990-06-14 1993-11-18 Monsanto Company RNA hydrolysis/cleavage
FR2677766B1 (fr) * 1991-06-14 1994-11-10 Asulab Sa Capteur de mesure de la quantite d'un composant en solution.
DE4316180A1 (de) * 1992-09-16 1994-11-17 Basf Ag Verfahren zur Herstellung von Aldehyden
US5453450A (en) * 1993-06-16 1995-09-26 Minnesota Mining And Manufacturing Company Stabilized curable adhesives
US5916481A (en) * 1995-07-25 1999-06-29 The Procter & Gamble Company Low hue photobleaches
US5908952A (en) * 1997-03-24 1999-06-01 General Electric Company Method for preparing diaryl carbonates employing β-diketone salts
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
US6197991B1 (en) * 1999-04-29 2001-03-06 General Electric Company Method and catalyst system for producing
GB9930248D0 (en) * 1999-12-22 2000-02-09 Johnson Matthey Plc Surface cleaner
EP1383857B1 (de) * 2001-04-30 2006-05-31 Ciba SC Holding AG Verwendung von metallkomplexverbindungen als oxidationskatalysatoren
JP4643259B2 (ja) * 2002-07-11 2011-03-02 チバ ホールディング インコーポレーテッド 金属錯体化合物及びその酸化触媒としての使用

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US7161005B2 (en) 2007-01-09
US7692004B2 (en) 2010-04-06
WO2002088289A2 (en) 2002-11-07
ES2265041T3 (es) 2007-02-01
JP4414653B2 (ja) 2010-02-10
KR100889467B1 (ko) 2009-03-20
JP2004533918A (ja) 2004-11-11
US7456285B2 (en) 2008-11-25
EP1383857B1 (de) 2006-05-31
US20060264633A1 (en) 2006-11-23
DE60211884T2 (de) 2006-11-23
BR0209292B1 (pt) 2014-04-29
MXPA03009905A (es) 2004-01-29
KR20040015213A (ko) 2004-02-18
BR0209292A (pt) 2004-07-13
US20080262225A1 (en) 2008-10-23
EP1383857A2 (de) 2004-01-28
CN100567471C (zh) 2009-12-09
WO2002088289A3 (en) 2003-02-27
US8044013B2 (en) 2011-10-25
US20040142843A1 (en) 2004-07-22
CN1646672A (zh) 2005-07-27
US20090068282A1 (en) 2009-03-12

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