ATE368021T1 - Verfahren zur alkylierung in der gasphase - zur transalkylierung in der flüssigen phase - Google Patents
Verfahren zur alkylierung in der gasphase - zur transalkylierung in der flüssigen phaseInfo
- Publication number
- ATE368021T1 ATE368021T1 AT00201106T AT00201106T ATE368021T1 AT E368021 T1 ATE368021 T1 AT E368021T1 AT 00201106 T AT00201106 T AT 00201106T AT 00201106 T AT00201106 T AT 00201106T AT E368021 T1 ATE368021 T1 AT E368021T1
- Authority
- AT
- Austria
- Prior art keywords
- alkylation
- ethylbenzene
- catalyst
- diethylbenzene
- benzene
- Prior art date
Links
- 238000005804 alkylation reaction Methods 0.000 title abstract 11
- 230000029936 alkylation Effects 0.000 title abstract 8
- 238000010555 transalkylation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 239000007791 liquid phase Substances 0.000 title 1
- 239000012071 phase Substances 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 12
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 10
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 3
- 238000011084 recovery Methods 0.000 abstract 3
- 239000008096 xylene Substances 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Polymers 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 238000007323 disproportionation reaction Methods 0.000 abstract 1
- 230000006203 ethylation Effects 0.000 abstract 1
- 238000006200 ethylation reaction Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/073—Ethylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/289,488 US6222084B1 (en) | 1999-04-09 | 1999-04-09 | Gas phase alkylation-liquid phase transalkylation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE368021T1 true ATE368021T1 (de) | 2007-08-15 |
Family
ID=23111755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00201106T ATE368021T1 (de) | 1999-04-09 | 2000-03-27 | Verfahren zur alkylierung in der gasphase - zur transalkylierung in der flüssigen phase |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6222084B1 (de) |
| EP (1) | EP1043296B1 (de) |
| KR (1) | KR100729576B1 (de) |
| AT (1) | ATE368021T1 (de) |
| DE (1) | DE60035634T2 (de) |
| ES (1) | ES2289995T3 (de) |
| TW (1) | TW524790B (de) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040138511A1 (en) * | 2003-01-10 | 2004-07-15 | James Butler | Aromatic alkylation process with direct recycle |
| US7084318B2 (en) * | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) * | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| US6987078B2 (en) * | 2003-10-03 | 2006-01-17 | Fina Technology, Inc. | Alkylation and catalyst regenerative process |
| US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| US7399727B2 (en) * | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| US7285511B2 (en) * | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| FR2876098B1 (fr) * | 2004-10-06 | 2007-03-09 | Inst Francais Du Petrole | Procede de production de phenylalcanes mettant en oeuvre au moins deux reacteurs d'alkylation en parallele |
| FR2876099B1 (fr) * | 2004-10-06 | 2007-03-09 | Inst Francais Du Petrole | Procede de production de phenylalcanes mettant en oeuvre au moins deux reacteurs d'alkylation en parallele |
| US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| US20070161838A1 (en) * | 2006-01-07 | 2007-07-12 | Fina Technology, Inc. | Dilute liquid phase alkylation |
| US8742190B2 (en) * | 2006-01-07 | 2014-06-03 | Fina Technology, Inc. | Dilute ethylene alkylation of benzene |
| EP2110368A1 (de) | 2008-04-18 | 2009-10-21 | Total Petrochemicals France | Alkylierung aromatischer Substrate und Transalkylierungsverfahren |
| US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4520220A (en) | 1982-02-22 | 1985-05-28 | Cosden Technology, Inc. | Alkylation of aromatics employing silicalite catalysts |
| US4489214A (en) | 1982-03-01 | 1984-12-18 | Cosden Technology, Inc. | Production of ortho-suppressed dialkyl benzenes |
| US4599473A (en) | 1983-12-19 | 1986-07-08 | Cosden Technology, Inc. | Process for para selective alkylation of aromatic hydrocarbons |
| US4781906A (en) | 1983-12-19 | 1988-11-01 | Labofina, S.A. | Crystalline silicas |
| US4772456A (en) | 1983-12-19 | 1988-09-20 | Labofina, S.A. | Process for preparing crystalline silicas |
| US4774377A (en) | 1987-09-11 | 1988-09-27 | Uop Inc. | Alkylation/transalkylation process |
| US5202516A (en) * | 1987-11-23 | 1993-04-13 | The Dow Chemical Company | Process of recovering monoalkylbenzene and pure 1,3,5-trialkylbenzene from a mixture of dialkyl- and trialkylbenzenes |
| US5243116A (en) * | 1987-11-23 | 1993-09-07 | The Dow Chemical Company | Alkylation of aromatic compounds |
| US4922053A (en) | 1989-05-24 | 1990-05-01 | Fina Technology, Inc. | Process for ethylbenzene production |
| JPH036457A (ja) | 1989-06-02 | 1991-01-11 | Koyo Seiko Co Ltd | 車輪回転速度検出器を備えた車軸用軸受装置 |
| DE69033689T2 (de) * | 1990-11-13 | 2001-05-17 | Fina Technology, Inc. | Herstellung alkylierter Aromaten |
| JPH08176026A (ja) * | 1994-12-22 | 1996-07-09 | Sumitomo Chem Co Ltd | パラジアルキルベンゼンの製造方法 |
| US5955642A (en) * | 1996-10-30 | 1999-09-21 | Fina Technology, Inc. | Gas phase alkylation-liquid transalkylation process |
| US5847255A (en) * | 1997-05-21 | 1998-12-08 | Fina Technology, Inc. | Gas phase alkylation-liquid phase transalkylation process |
-
1999
- 1999-04-09 US US09/289,488 patent/US6222084B1/en not_active Expired - Fee Related
-
2000
- 2000-03-14 TW TW089104631A patent/TW524790B/zh not_active IP Right Cessation
- 2000-03-27 ES ES00201106T patent/ES2289995T3/es not_active Expired - Lifetime
- 2000-03-27 EP EP00201106A patent/EP1043296B1/de not_active Expired - Lifetime
- 2000-03-27 AT AT00201106T patent/ATE368021T1/de not_active IP Right Cessation
- 2000-03-27 DE DE60035634T patent/DE60035634T2/de not_active Expired - Lifetime
- 2000-04-10 KR KR1020000018747A patent/KR100729576B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR100729576B1 (ko) | 2007-06-18 |
| EP1043296A3 (de) | 2001-04-18 |
| ES2289995T3 (es) | 2008-02-16 |
| TW524790B (en) | 2003-03-21 |
| DE60035634T2 (de) | 2008-05-21 |
| EP1043296B1 (de) | 2007-07-25 |
| US6222084B1 (en) | 2001-04-24 |
| KR20000071628A (ko) | 2000-11-25 |
| DE60035634D1 (de) | 2007-09-06 |
| EP1043296A2 (de) | 2000-10-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |