ATE395368T1 - Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren - Google Patents

Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren

Info

Publication number
ATE395368T1
ATE395368T1 AT00986633T AT00986633T ATE395368T1 AT E395368 T1 ATE395368 T1 AT E395368T1 AT 00986633 T AT00986633 T AT 00986633T AT 00986633 T AT00986633 T AT 00986633T AT E395368 T1 ATE395368 T1 AT E395368T1
Authority
AT
Austria
Prior art keywords
olefin polymers
prepared
ionic catalysts
supported ionic
producing polyolefins
Prior art date
Application number
AT00986633T
Other languages
English (en)
Inventor
Patrick Brant
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE395368T1 publication Critical patent/ATE395368T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1386—Natural or synthetic rubber or rubber-like compound containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT00986633T 1999-12-20 2000-12-20 Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren ATE395368T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17273799P 1999-12-20 1999-12-20

Publications (1)

Publication Number Publication Date
ATE395368T1 true ATE395368T1 (de) 2008-05-15

Family

ID=22629002

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00986633T ATE395368T1 (de) 1999-12-20 2000-12-20 Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren

Country Status (11)

Country Link
US (3) US6562920B2 (de)
EP (1) EP1250362B1 (de)
JP (1) JP2003518169A (de)
KR (1) KR20020063242A (de)
CN (2) CN1227272C (de)
AT (1) ATE395368T1 (de)
BR (1) BR0016495A (de)
CA (1) CA2393327A1 (de)
DE (1) DE60038900D1 (de)
MX (1) MXPA02006197A (de)
WO (1) WO2001046273A1 (de)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60038900D1 (de) 1999-12-20 2008-06-26 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
US6818013B2 (en) * 2001-06-14 2004-11-16 Cordis Corporation Intravascular stent device
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
WO2004026923A2 (en) 2002-09-20 2004-04-01 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7807769B2 (en) 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US7144934B2 (en) * 2002-10-24 2006-12-05 Dow Global Technologies Inc. Charge dissipation modifiers for olefinic interpolymer compositions
US7439312B2 (en) 2002-10-24 2008-10-21 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
AU2003287683A1 (en) * 2002-12-05 2004-06-30 Exxonmobil Chemical Patents Inc. High temperature bulk polymerization of branched crystalline polypropylene
US7339018B2 (en) 2002-12-05 2008-03-04 Exxonmobil Chemical Patents Inc. Diene-modified propylene copolymers
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
BRPI0513057A (pt) 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US7741420B2 (en) 2004-07-14 2010-06-22 Exxonmobil Chemical Patents Inc. Polymer production at supercritical conditions
US7662895B2 (en) * 2005-11-22 2010-02-16 Exxonmobil Chemical Patents Inc. Syndiotactic propylene elastomers
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
JP2010529253A (ja) * 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
EP2201042B1 (de) * 2007-09-13 2012-06-27 ExxonMobil Research and Engineering Company In-line-mischen von weichmachern mit einem basispolymer
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN101945942B (zh) 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7939610B2 (en) 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US8399586B2 (en) 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US20100113692A1 (en) * 2008-11-04 2010-05-06 Mcguire Jr James E Apparatus for Continuous Production of Partially Polymerized Compositions
US8765217B2 (en) * 2008-11-04 2014-07-01 Entrotech, Inc. Method for continuous production of (meth)acrylate syrup and adhesives therefrom
US8329079B2 (en) * 2009-04-20 2012-12-11 Entrochem, Inc. Method and apparatus for continuous production of partially polymerized compositions and polymers therefrom
WO2011087731A1 (en) * 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
US8562915B2 (en) 2010-01-14 2013-10-22 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US20230002514A1 (en) * 2019-10-28 2023-01-05 Exxonmobil Chemical Patents Inc. Supported Non-Coordinating Anion Activators, Use Thereof, and Production Thereof
KR102692427B1 (ko) * 2020-11-24 2024-08-06 주식회사 엘지화학 유무기 하이브리드 폴리올레핀 복합체 및 그의 제조 방법
WO2022114710A1 (ko) * 2020-11-24 2022-06-02 주식회사 엘지화학 유무기 하이브리드 폴리올레핀 복합체 및 그의 제조 방법

Family Cites Families (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4414369A (en) 1977-08-17 1983-11-08 Nippon Oil Company, Limited Continuous process for the preparation of polyolefins having widely distributed molecular weights
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153282A (en) 1987-06-08 1992-10-06 Exxon Chemical Patents Inc. Preparation of polyolefin incorporating functional groups from masked functional group-containing monomers
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
CN1038284A (zh) * 1988-04-29 1989-12-27 联合碳化公司 高纯度α-烯烃聚合物的制备方法
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE3831355A1 (de) 1988-09-15 1990-03-29 Hoechst Ag Hochleistungsdielektrikumsfolie mit verbesserter thermostabilitaet
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5087809A (en) 1990-11-26 1992-02-11 Eastman Kodak Company Spectrally selective dithering and color filter mask for increased image sensor blue sensitivity
DE69033368T3 (de) 1990-01-02 2008-07-03 Exxon Chemical Patents, Inc. Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation
EP0551277B2 (de) 1990-06-22 2005-03-09 ExxonMobil Chemical Patents Inc. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
ES2085000T3 (es) 1990-12-27 1996-05-16 Exxon Chemical Patents Inc Un compuesto de amido-metal de transicion y un sistema catalitico para la produccion de polipropileno isotactico.
EP0516458B2 (de) 1991-05-31 2007-12-19 Mitsui Chemicals, Inc. Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
TW300901B (de) 1991-08-26 1997-03-21 Hoechst Ag
EP0537686B1 (de) 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
ES2108861T3 (es) 1991-11-25 1998-01-01 Exxon Chemical Patents Inc Composiciones cataliticas polionicas de metales de transicion.
CA2105555C (en) 1992-01-06 2003-12-30 Brian W. S. Kolthammer Improved catalyst composition
EP0631589A1 (de) 1992-03-16 1995-01-04 Exxon Chemical Patents Inc. Ionischer kalaysator zur herstellung von polyalphaolefinen mit kontrolliertem taktizitaetsgrad
EP0578838A1 (de) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
WO1994001471A1 (en) 1992-07-01 1994-01-20 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
EP1110974B1 (de) 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten
JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
US5461127A (en) 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US5837787A (en) 1993-01-19 1998-11-17 Exxon Chemical Patents, Inc. Process for producing elastic thermoplastic α-olefin/cyclic olefin copolymers
DE4304310A1 (de) 1993-02-12 1994-08-18 Hoechst Ag Teilkristalline Cycloolefin-Copolymer-Folie
DE9302594U1 (de) 1993-02-23 1993-04-15 Alten, Kurt, 3015 Wennigsen Fahrbare Schrägrampe
FR2701938B1 (fr) 1993-02-23 1995-05-24 Cuir Jean Pierre Dispositif de distribution de feuilles semi-rigides, notamment de carton, à partir d'un empilement.
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
EP0638593A1 (de) 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzungen
GB9319340D0 (en) 1993-09-17 1993-11-03 Exxon Chemical Patents Inc Olefin polymersisation process
WO1995016716A1 (en) 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US6403307B1 (en) 1997-03-21 2002-06-11 University Of Iowa Research Foundation Glaucoma therapeutics and diagnostics
CA2195879C (en) 1994-08-03 2001-01-09 John Flexer Walzer Jr. Supported ionic catalyst composition
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
DE69511352T2 (de) 1994-10-03 2000-03-30 Sumitomo Chemical Co., Ltd. Verfahren zur Herstellung eines Copolymerkautschuks
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
EP0728773B1 (de) 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
US6143682A (en) 1995-06-07 2000-11-07 Exxon Chemical Patents Inc. Bimetallocyclic transition metal catalyst systems
US5900466A (en) 1995-09-08 1999-05-04 Shell Oil Company Polyolefin-substituted dicarboxylic derivatives
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
BR9611772A (pt) * 1995-11-27 1999-02-23 Dow Chemical Co Suporte para uso na preparação de catalisadores para polimerizações por adição catalisador suportado e processo de polimerização por adição
WO1997022639A1 (en) 1995-12-19 1997-06-26 Exxon Chemical Patents Inc. High temperature solution polymerization process
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
JPH103277A (ja) 1996-04-15 1998-01-06 Matsushita Electric Works Ltd 表示装置
US5763556A (en) 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
HU223533B1 (hu) 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
HU223376B1 (hu) 1996-07-23 2004-06-28 Dow Global Technologies Inc. A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátor készítmények
EP0885918B1 (de) 1996-08-09 2002-07-17 Toray Industries, Inc. Polypropylenfolie und kondensator hergestellt durch verwendung derselben als dielektrikum
US5763533A (en) * 1996-12-10 1998-06-09 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US5851945A (en) 1997-02-07 1998-12-22 Exxon Chemical Patents Inc. Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
US6100354A (en) 1997-02-24 2000-08-08 Exxon Chemical Patents Inc. Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
US5770022A (en) 1997-06-05 1998-06-23 Dow Corning Corporation Method of making silica nanoparticles
US6100214A (en) * 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
FR2764895B1 (fr) 1997-06-19 2000-02-11 Toray Plastics Europ Sa Films barriere composites metallises
JP2003517362A (ja) 1997-08-20 2003-05-27 イムプリコ ベスローテン フェンノートシャップ 接触コンバーター
WO1999030822A1 (en) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Group 11 transition metal amine catalysts for olefin polymerization
WO1999045042A1 (en) 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Noncoordinating anions for olefin polymerization
KR100586118B1 (ko) * 1998-05-01 2006-06-02 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합반응을 위한 삼좌 리간드-함유 금속 촉매 착체
US6403773B1 (en) * 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
DE60038900D1 (de) 1999-12-20 2008-06-26 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren

Also Published As

Publication number Publication date
CN1227272C (zh) 2005-11-16
US6590055B2 (en) 2003-07-08
DE60038900D1 (de) 2008-06-26
BR0016495A (pt) 2002-09-17
US7163993B2 (en) 2007-01-16
JP2003518169A (ja) 2003-06-03
US6562920B2 (en) 2003-05-13
WO2001046273A1 (en) 2001-06-28
CN1411473A (zh) 2003-04-16
US20020004567A1 (en) 2002-01-10
KR20020063242A (ko) 2002-08-01
EP1250362A1 (de) 2002-10-23
US20030208023A1 (en) 2003-11-06
MXPA02006197A (es) 2002-12-09
EP1250362B1 (de) 2008-05-14
US20020007030A1 (en) 2002-01-17
CN1631910A (zh) 2005-06-29
CA2393327A1 (en) 2001-06-28

Similar Documents

Publication Publication Date Title
DE60038900D1 (de) Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
EA200001002A1 (ru) Способ полимеризации олефинов
PL338979A1 (en) Polymerisation of olefins
ATE492552T1 (de) Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
DE69501971D1 (de) Ternäres Katalysatorsystem und Verfahren zur Herstellung von Polymeren von Diolefinen
DE69730838D1 (de) Polymerisationsverfahren für olefinen
DE3671749D1 (de) Verfahren zur polymerisierung von olefinen mit einem ziegler-natta-katalysator und zwei organometallverbindungen.
ATE132507T1 (de) Trägerkatalysator für olefinpolymerisation mit monozyklopentadienylkomplexen von übergangsmetallen
ES521093A0 (es) Procedimiento para producir un catalizador para la polimerizacion de 1-olefinas.
DE50210711D1 (de) Verfahren zur herstellung von homo- und copolymeren des isobutens
ES8304159A1 (es) Procedimiento para la obtencion de un catalizador para la polimerizacion de olefinas.
GB2114463B (en) Silica-supported chromium oxide-containing olefin polymerization catalysts
DE69029917D1 (de) Verfahren zur Polymerisation von Olefinen
ATE268785T1 (de) Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators
EP1026176A4 (de) Katalysator für die olefinpolymerproduktion, verfahren zu dessen herstellung und verfahren zur herstellung des olefinpolymers
ATE420119T1 (de) Additiv zur inertisierung von aciden oder halogenhaltigen verbindungen, die in olefinpolymeren enthalten sind
ATE299153T1 (de) Verfahren zur polymerisierung von olefine
DE58906136D1 (de) Katalysator für die Polymerisation von Ethylen, Verfahren zu dessen Herstellung und Verwendung der erhaltenen Ethylenpolymerisate zur Herstellung von Folien mit geringen Blockeigenschaften.
IN2012DN01974A (de)
FI903953A0 (fi) Menetelmä olefiinien polymeroimiseksi
BR0014798A (pt) Complexos catiÈnicos carbênio adequados para catalisadores de polimerização
DE60042683D1 (de) Verfahren zur herstellung von oxycarbonylpolymeren, funktionalisierung, hergestellte polymere und funktionalisierungsagens
DE69703883D1 (de) Yttrium enthaltend metallkomplexe und verfahren zur polymerisation von olefinen
DE69914303D1 (de) Verfahren zur polymerisation von olefinen mit geträgerten ziegler-natta katalysatorsystemen
CA2314898A1 (en) Solid catalyst for olefin polymerization and method for producing olefinic polymer using the same

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties