ATE268785T1 - Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators - Google Patents

Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators

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Publication number
ATE268785T1
ATE268785T1 AT00960647T AT00960647T ATE268785T1 AT E268785 T1 ATE268785 T1 AT E268785T1 AT 00960647 T AT00960647 T AT 00960647T AT 00960647 T AT00960647 T AT 00960647T AT E268785 T1 ATE268785 T1 AT E268785T1
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AT
Austria
Prior art keywords
compound
catalyst
transition metal
polymerization
catalyst component
Prior art date
Application number
AT00960647T
Other languages
English (en)
Inventor
Orass Hamed
Akhlaq Moman
Atieh Abu-Raqabah
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Application granted granted Critical
Publication of ATE268785T1 publication Critical patent/ATE268785T1/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT00960647T 1999-09-17 2000-09-11 Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators ATE268785T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/399,305 US6403520B1 (en) 1999-09-17 1999-09-17 Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
PCT/EP2000/008888 WO2001021673A1 (en) 1999-09-17 2000-09-11 Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst

Publications (1)

Publication Number Publication Date
ATE268785T1 true ATE268785T1 (de) 2004-06-15

Family

ID=23579024

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00960647T ATE268785T1 (de) 1999-09-17 2000-09-11 Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators

Country Status (6)

Country Link
US (2) US6403520B1 (de)
EP (1) EP1216261B1 (de)
JP (1) JP2003523415A (de)
AT (1) ATE268785T1 (de)
DE (1) DE60011453T2 (de)
WO (1) WO2001021673A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6653254B1 (en) * 1999-02-22 2003-11-25 Fina Technology, Inc Ziegler-Natta catalyst with metallocene for olefin polymerization
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
GC0000293A (en) * 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
EP1231223B1 (de) * 2001-02-07 2004-04-28 Saudi Basic Industries Corporation Verfahren zur Olefinpolymerisation
DE60104809T2 (de) * 2001-02-07 2005-01-05 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung
EP1238990B1 (de) * 2001-02-15 2005-06-08 Saudi Basic Industries Corporation Geträgerte katalysatorzusammensetzung für die olefinpolymerisation : verfahren zu deren herstellung und polymerisationsverfahren unter deren verwendung
EP1302480B1 (de) * 2001-10-15 2004-08-11 Saudi Basic Industries Corporation (Sabic) Geträter Polymerisationskatalysator enthaltend Magnesium und einen Metallocen
AU2002332129A1 (en) * 2001-11-30 2003-06-17 Exxonmobil Chemical Patents, Inc. Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use
AU2002365867A1 (en) * 2001-11-30 2003-06-17 Exxonmobil Chemical Patents Inc. Method of making mixed ziegler-natta/metallocene catalysts
ATE296319T1 (de) * 2002-07-12 2005-06-15 Saudi Basic Ind Corp Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen
US6861487B2 (en) * 2003-04-15 2005-03-01 Saudi Basic Industries Corporation Catalyst precursor for the polymerization of olefins and polymerization process using the same
US7662894B2 (en) * 2006-12-19 2010-02-16 Saudi Bosic Industries Corporation Polymer supported metallocene catalyst composition for polymerizing olefins
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
CN104736579A (zh) 2013-06-28 2015-06-24 株式会社Lg化学 弹性二烯三元共聚物及其制备方法
WO2014209085A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
CN117624414A (zh) * 2022-08-12 2024-03-01 中国石油天然气股份有限公司 用于熔喷聚乙烯的茂金属催化剂

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4107415A (en) 1972-09-26 1978-08-15 Montecatini Edison S.P.A. Process for the stereospecific polymerization of alpha-olefins
US4414369A (en) 1977-08-17 1983-11-08 Nippon Oil Company, Limited Continuous process for the preparation of polyolefins having widely distributed molecular weights
JPS6045645B2 (ja) 1980-10-09 1985-10-11 三井化学株式会社 オレフイン類の気相重合方法
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4522982A (en) 1983-06-06 1985-06-11 Exxon Research & Engineering Co. Isotactic-stereoblock polymers of alpha-olefins and process for producing the same
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
KR900008459B1 (ko) 1984-12-14 1990-11-22 엑손 리서치 앤드 엔지니어링 컴패니 튜브 반응기내에서의 분자량 분포 조절 다중 모드
FR2577558B1 (fr) 1985-02-19 1987-03-06 Bp Chimie Sa Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
JPH0742327B2 (ja) * 1987-08-04 1995-05-10 住友化学工業株式会社 エチレン共重合体の製造法
JPH0714975B2 (ja) * 1987-05-20 1995-02-22 住友化学工業株式会社 α−オレフィン重合体の製造法
JP2953523B2 (ja) * 1989-12-29 1999-09-27 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP2953525B2 (ja) * 1989-12-29 1999-09-27 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
US5070055A (en) 1990-06-29 1991-12-03 Union Carbide Chemicals And Plastics Technology Corporation Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution
JP3095800B2 (ja) * 1991-03-22 2000-10-10 三菱化学株式会社 オレフィン重合体の製造
DE69224600T2 (de) 1991-11-12 1998-08-27 Nippon Oil Co Ltd Katalysatorbestandteile für Olefinpolymerisation
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
US5840808A (en) 1995-02-07 1998-11-24 Mitsui Petrochemical Industries, Ltd. Process for preparing olefin polymer
US5885924A (en) 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
US5882750A (en) 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
JPH10152516A (ja) * 1996-11-22 1998-06-09 Chisso Corp αーオレフィン重合用触媒を含む液組成物、αーオレフィン重合用触媒、及びオレフィン重合体の製造方法

Also Published As

Publication number Publication date
US20020165085A1 (en) 2002-11-07
US6784263B2 (en) 2004-08-31
JP2003523415A (ja) 2003-08-05
EP1216261B1 (de) 2004-06-09
DE60011453T2 (de) 2005-06-30
WO2001021673A1 (en) 2001-03-29
US6403520B1 (en) 2002-06-11
DE60011453D1 (de) 2004-07-15
EP1216261A1 (de) 2002-06-26

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