ATE268785T1 - Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators - Google Patents
Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysatorsInfo
- Publication number
- ATE268785T1 ATE268785T1 AT00960647T AT00960647T ATE268785T1 AT E268785 T1 ATE268785 T1 AT E268785T1 AT 00960647 T AT00960647 T AT 00960647T AT 00960647 T AT00960647 T AT 00960647T AT E268785 T1 ATE268785 T1 AT E268785T1
- Authority
- AT
- Austria
- Prior art keywords
- compound
- catalyst
- transition metal
- polymerization
- catalyst component
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000009826 distribution Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- 239000011949 solid catalyst Substances 0.000 abstract 3
- -1 cyclopentadienyl transition metal compound Chemical class 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 150000002681 magnesium compounds Chemical class 0.000 abstract 2
- 229920000098 polyolefin Polymers 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 229920000092 linear low density polyethylene Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920001179 medium density polyethylene Polymers 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/399,305 US6403520B1 (en) | 1999-09-17 | 1999-09-17 | Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst |
| PCT/EP2000/008888 WO2001021673A1 (en) | 1999-09-17 | 2000-09-11 | Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE268785T1 true ATE268785T1 (de) | 2004-06-15 |
Family
ID=23579024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00960647T ATE268785T1 (de) | 1999-09-17 | 2000-09-11 | Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6403520B1 (de) |
| EP (1) | EP1216261B1 (de) |
| JP (1) | JP2003523415A (de) |
| AT (1) | ATE268785T1 (de) |
| DE (1) | DE60011453T2 (de) |
| WO (1) | WO2001021673A1 (de) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6143854A (en) * | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
| US6653254B1 (en) * | 1999-02-22 | 2003-11-25 | Fina Technology, Inc | Ziegler-Natta catalyst with metallocene for olefin polymerization |
| US6992152B2 (en) * | 1999-10-19 | 2006-01-31 | Texas Petrochemicals Lp | Apparatus and method for controlling olefin polymerization process |
| GB0023662D0 (en) | 2000-09-27 | 2000-11-08 | Borealis Tech Oy | Supported catalyst |
| GC0000293A (en) * | 2000-10-10 | 2006-11-01 | Saudi Basic Ind Corp | Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems |
| EP1231223B1 (de) * | 2001-02-07 | 2004-04-28 | Saudi Basic Industries Corporation | Verfahren zur Olefinpolymerisation |
| DE60104809T2 (de) * | 2001-02-07 | 2005-01-05 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung |
| EP1238990B1 (de) * | 2001-02-15 | 2005-06-08 | Saudi Basic Industries Corporation | Geträgerte katalysatorzusammensetzung für die olefinpolymerisation : verfahren zu deren herstellung und polymerisationsverfahren unter deren verwendung |
| EP1302480B1 (de) * | 2001-10-15 | 2004-08-11 | Saudi Basic Industries Corporation (Sabic) | Geträter Polymerisationskatalysator enthaltend Magnesium und einen Metallocen |
| AU2002332129A1 (en) * | 2001-11-30 | 2003-06-17 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
| AU2002365867A1 (en) * | 2001-11-30 | 2003-06-17 | Exxonmobil Chemical Patents Inc. | Method of making mixed ziegler-natta/metallocene catalysts |
| ATE296319T1 (de) * | 2002-07-12 | 2005-06-15 | Saudi Basic Ind Corp | Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen |
| US6861487B2 (en) * | 2003-04-15 | 2005-03-01 | Saudi Basic Industries Corporation | Catalyst precursor for the polymerization of olefins and polymerization process using the same |
| US7662894B2 (en) * | 2006-12-19 | 2010-02-16 | Saudi Bosic Industries Corporation | Polymer supported metallocene catalyst composition for polymerizing olefins |
| CN101274968B (zh) * | 2007-03-28 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于生产宽分子量分布的聚乙烯的复合催化剂 |
| KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| CN104736579A (zh) | 2013-06-28 | 2015-06-24 | 株式会社Lg化学 | 弹性二烯三元共聚物及其制备方法 |
| WO2014209085A1 (ko) | 2013-06-28 | 2014-12-31 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| CN117624414A (zh) * | 2022-08-12 | 2024-03-01 | 中国石油天然气股份有限公司 | 用于熔喷聚乙烯的茂金属催化剂 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107415A (en) | 1972-09-26 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereospecific polymerization of alpha-olefins |
| US4414369A (en) | 1977-08-17 | 1983-11-08 | Nippon Oil Company, Limited | Continuous process for the preparation of polyolefins having widely distributed molecular weights |
| JPS6045645B2 (ja) | 1980-10-09 | 1985-10-11 | 三井化学株式会社 | オレフイン類の気相重合方法 |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US4522982A (en) | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| KR900008459B1 (ko) | 1984-12-14 | 1990-11-22 | 엑손 리서치 앤드 엔지니어링 컴패니 | 튜브 반응기내에서의 분자량 분포 조절 다중 모드 |
| FR2577558B1 (fr) | 1985-02-19 | 1987-03-06 | Bp Chimie Sa | Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| JPH0742327B2 (ja) * | 1987-08-04 | 1995-05-10 | 住友化学工業株式会社 | エチレン共重合体の製造法 |
| JPH0714975B2 (ja) * | 1987-05-20 | 1995-02-22 | 住友化学工業株式会社 | α−オレフィン重合体の製造法 |
| JP2953523B2 (ja) * | 1989-12-29 | 1999-09-27 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| JP2953525B2 (ja) * | 1989-12-29 | 1999-09-27 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| US5070055A (en) | 1990-06-29 | 1991-12-03 | Union Carbide Chemicals And Plastics Technology Corporation | Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution |
| JP3095800B2 (ja) * | 1991-03-22 | 2000-10-10 | 三菱化学株式会社 | オレフィン重合体の製造 |
| DE69224600T2 (de) | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
| BE1007040A3 (fr) | 1993-05-25 | 1995-02-28 | Solvay | Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur. |
| US5840808A (en) | 1995-02-07 | 1998-11-24 | Mitsui Petrochemical Industries, Ltd. | Process for preparing olefin polymer |
| US5885924A (en) | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
| US5882750A (en) | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
| JPH10152516A (ja) * | 1996-11-22 | 1998-06-09 | Chisso Corp | αーオレフィン重合用触媒を含む液組成物、αーオレフィン重合用触媒、及びオレフィン重合体の製造方法 |
-
1999
- 1999-09-17 US US09/399,305 patent/US6403520B1/en not_active Expired - Lifetime
-
2000
- 2000-09-11 DE DE60011453T patent/DE60011453T2/de not_active Expired - Lifetime
- 2000-09-11 WO PCT/EP2000/008888 patent/WO2001021673A1/en not_active Ceased
- 2000-09-11 JP JP2001525245A patent/JP2003523415A/ja active Pending
- 2000-09-11 AT AT00960647T patent/ATE268785T1/de not_active IP Right Cessation
- 2000-09-11 EP EP00960647A patent/EP1216261B1/de not_active Expired - Lifetime
-
2002
- 2002-01-18 US US10/052,326 patent/US6784263B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20020165085A1 (en) | 2002-11-07 |
| US6784263B2 (en) | 2004-08-31 |
| JP2003523415A (ja) | 2003-08-05 |
| EP1216261B1 (de) | 2004-06-09 |
| DE60011453T2 (de) | 2005-06-30 |
| WO2001021673A1 (en) | 2001-03-29 |
| US6403520B1 (en) | 2002-06-11 |
| DE60011453D1 (de) | 2004-07-15 |
| EP1216261A1 (de) | 2002-06-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |