ATE465974T1 - Mww-typ zeolith, entsprechendes vorläufermaterial,und verfahren zu deren herstellung - Google Patents
Mww-typ zeolith, entsprechendes vorläufermaterial,und verfahren zu deren herstellungInfo
- Publication number
- ATE465974T1 ATE465974T1 AT03707103T AT03707103T ATE465974T1 AT E465974 T1 ATE465974 T1 AT E465974T1 AT 03707103 T AT03707103 T AT 03707103T AT 03707103 T AT03707103 T AT 03707103T AT E465974 T1 ATE465974 T1 AT E465974T1
- Authority
- AT
- Austria
- Prior art keywords
- precursor
- mww
- production
- precursor material
- type zeolite
- Prior art date
Links
- 239000002243 precursor Substances 0.000 title abstract 6
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000010457 zeolite Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052795 boron group element Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000002210 silicon-based material Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/085—Group IVB- metallosilicates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002061542 | 2002-03-07 | ||
| JP2003026529A JP4241068B2 (ja) | 2002-03-07 | 2003-02-03 | Ｍｗｗ型ゼオライト物質の製造方法 |
| PCT/JP2003/002155 WO2003074422A1 (en) | 2002-03-07 | 2003-02-26 | Mww type zeolite substance, precursor substance therefor, and process for producing these substances |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE465974T1 true ATE465974T1 (de) | 2010-05-15 |
Family
ID=37777616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03707103T ATE465974T1 (de) | 2002-03-07 | 2003-02-26 | Mww-typ zeolith, entsprechendes vorläufermaterial,und verfahren zu deren herstellung |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7326401B2 (de) |
| EP (1) | EP1485321B1 (de) |
| JP (2) | JP4241068B2 (de) |
| KR (2) | KR20060092284A (de) |
| CN (2) | CN100584757C (de) |
| AT (1) | ATE465974T1 (de) |
| AU (1) | AU2003208616A1 (de) |
| CA (1) | CA2477491C (de) |
| SG (1) | SG141245A1 (de) |
| WO (1) | WO2003074422A1 (de) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368290C (zh) * | 2003-02-03 | 2008-02-13 | 昭和电工株式会社 | 改性层状金属硅酸盐材料及其制备方法 |
| ES2217962B1 (es) | 2003-02-14 | 2006-02-16 | Universidad Politecnica De Valencia | Material cristalino poroso (zeolita itq-24),su procedimiento de preparacion y su uso en la conversion catalitica de componentes organicos. |
| CN1299987C (zh) * | 2004-02-10 | 2007-02-14 | 中国科学院大连化学物理研究所 | 一种制备硅铝比可变的mww分子筛材料的方法 |
| JP4433843B2 (ja) | 2004-03-22 | 2010-03-17 | 住友化学株式会社 | プロピレンオキサイド製造用触媒及びプロピレンオキサイドの製造方法 |
| CN1328165C (zh) * | 2005-04-18 | 2007-07-25 | 华东师范大学 | 一种 mcm－22 分子筛的合成方法 |
| CN101346363B (zh) | 2005-12-26 | 2012-06-13 | 住友化学株式会社 | 生产氧化丙烯的方法 |
| JP2008162846A (ja) * | 2006-12-28 | 2008-07-17 | Japan Science & Technology Agency | ゼオライト層状前駆体からの大細孔ゼオライトの製造法 |
| WO2008153759A2 (en) | 2007-05-24 | 2008-12-18 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition |
| US9221723B2 (en) * | 2007-05-24 | 2015-12-29 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1 |
| US8993468B2 (en) * | 2007-05-24 | 2015-03-31 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites |
| US8969232B2 (en) | 2007-05-24 | 2015-03-03 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2 |
| US20100204494A1 (en) | 2007-07-11 | 2010-08-12 | Sumitomo Chemical Company, Limited | Method and apparatus for producing mixed gas, and apparatus and method for producing epoxy compound |
| ES2373189T3 (es) * | 2007-08-15 | 2012-02-01 | Exxonmobil Chemical Patents Inc. | Procedimiento para producir ciclohexilbenceno. |
| KR101175849B1 (ko) * | 2007-09-21 | 2012-08-24 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 사이클로헥실벤젠의 제조방법 |
| JP5192546B2 (ja) * | 2007-09-21 | 2013-05-08 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造プロセス |
| US8501068B2 (en) * | 2007-11-05 | 2013-08-06 | Regents Of The University Of Minnesota | Layered zeolite materials and methods related thereto |
| KR101123499B1 (ko) * | 2008-02-12 | 2012-06-12 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 사이클로헥실벤젠의 제조방법 |
| JP2009233656A (ja) * | 2008-03-05 | 2009-10-15 | Sumitomo Chemical Co Ltd | チタノシリケート触媒の再生方法 |
| WO2009128984A1 (en) | 2008-04-14 | 2009-10-22 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| US8106243B2 (en) * | 2008-05-01 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| CN102112397B (zh) * | 2008-07-28 | 2016-12-21 | 埃克森美孚化学专利公司 | 一种新型分子筛组合物emm‑12、其制备方法和使用方法 |
| CN102216215B (zh) * | 2008-07-28 | 2014-03-26 | 埃克森美孚化学专利公司 | 使用emm-12制备烷基芳族化合物的方法 |
| WO2010014404A1 (en) * | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Process of making alkylaromatics using emm-13 |
| JP5548686B2 (ja) * | 2008-07-28 | 2014-07-16 | エクソンモービル・ケミカル・パテンツ・インク | 新規なモレキュラーシーブ組成物ｅｍｍ−１３、その製造方法およびその使用プロセス |
| EP2334601B1 (de) | 2008-07-28 | 2019-01-30 | ExxonMobil Chemical Patents Inc. | Herstellungsverfahren von alkylaromatischen verbindungen unter verwendung von molekularsiebzusammensetzung emm-12 |
| US8212096B2 (en) | 2008-07-28 | 2012-07-03 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using EMM-13 |
| JP2012517469A (ja) | 2009-02-26 | 2012-08-02 | エクソンモービル・ケミカル・パテンツ・インク | シクロヘキシルベンゼンの製造方法 |
| JP2012081390A (ja) | 2010-10-08 | 2012-04-26 | Sumitomo Chemical Co Ltd | 触媒の調製方法及び当該調製方法により調製された触媒を用いたアルキレンオキサイドの製造方法 |
| CN103153461B (zh) | 2010-10-11 | 2015-11-25 | 埃克森美孚化学专利公司 | 加氢烷基化催化剂的活化和使用 |
| KR20140057473A (ko) | 2010-11-23 | 2014-05-13 | 릴라이언스 인더스트리즈 리미티드 | Ｍｗｗ형 제올라이트 제조 방법 |
| US9522390B2 (en) * | 2010-12-10 | 2016-12-20 | The Regents Of The University Of California | Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation |
| JP2012224608A (ja) | 2011-04-08 | 2012-11-15 | Sumitomo Chemical Co Ltd | プロピレンオキサイドの取得方法 |
| JP2012236177A (ja) | 2011-05-13 | 2012-12-06 | Sumitomo Chemical Co Ltd | チタノシリケート含有触媒の製造方法 |
| JP2013006806A (ja) | 2011-06-27 | 2013-01-10 | Sumitomo Chemical Co Ltd | アルキレンオキサイドの製造方法及びそれに用いられるパラジウム含有触媒 |
| US8697018B2 (en) * | 2011-08-05 | 2014-04-15 | Chevron U.S.A. Inc. | Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-25 |
| JP2013034948A (ja) | 2011-08-09 | 2013-02-21 | Sumitomo Chemical Co Ltd | 貴金属担持物およびその利用 |
| CN104066704B (zh) | 2011-10-17 | 2016-05-25 | 埃克森美孚化学专利公司 | 生产环己基苯的方法 |
| US9168513B2 (en) | 2012-02-07 | 2015-10-27 | Basf Se | Process for preparation of zeolitic material |
| HUE060651T2 (hu) | 2012-02-07 | 2023-04-28 | Basf Se | Bórmentesített MWW zeolit anyag |
| CN104105679B (zh) | 2012-02-08 | 2017-07-21 | 埃克森美孚化学专利公司 | 生产环己基苯的方法 |
| US8759597B2 (en) | 2012-04-18 | 2014-06-24 | Uop Llc | Methods for producing zeolite catalysts and methods for producing alkylated aromatic compounds using the zeolite catalysts |
| ES2435396B1 (es) * | 2012-05-18 | 2014-09-29 | Consejo Superior De Investigaciones Científicas (Csic) | Procedimiento de preparación de la forma titanosilicato de la zeolita mww utilizando mww pura sílice como precursor y su uso. |
| MY169039A (en) * | 2012-10-18 | 2019-02-07 | Basf Se | Post-treatment of deboronated mww zeolite |
| TW201420561A (zh) * | 2012-11-05 | 2014-06-01 | Basf Se | 有機羰基化合物之氧化方法 |
| US9371239B2 (en) | 2012-11-05 | 2016-06-21 | Basf Se | Tin-containing zeolitic material having an MWW-type framework structure |
| US8987497B2 (en) | 2012-11-05 | 2015-03-24 | Basf Se | Process for the oxidation of organic carbonyl compounds |
| JP6312154B2 (ja) * | 2012-11-05 | 2018-04-18 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Ｍｗｗ型骨格構造を有するスズ含有ゼオライト材料 |
| HUE055878T2 (hu) * | 2013-02-05 | 2021-12-28 | Basf Se | Eljárás bórt tartalmazó, MWW rácsszerkezetû zeolitos anyag elõállítására |
| CN110002463B (zh) | 2013-02-05 | 2022-10-11 | 巴斯夫欧洲公司 | 制备具有mww骨架结构的含钛沸石材料的方法 |
| TW201521868A (zh) * | 2013-11-05 | 2015-06-16 | Basf Se | 具有ｍｗｗ型骨架結構之含錫沸石材料 |
| WO2015067657A1 (en) * | 2013-11-05 | 2015-05-14 | Basf Se | Process for the oxidation of organic carbonyl compounds |
| CN105636693B (zh) | 2013-11-22 | 2019-12-13 | 沙特基础工业公司 | 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂 |
| SG11201603370VA (en) | 2014-01-27 | 2016-05-30 | Exxonmobil Chem Patents Inc | Synthesis of molecular sieves having mww framework structure |
| US20160376159A1 (en) * | 2014-03-10 | 2016-12-29 | Agency For Science, Technology And Research | Zeolites with mww framework formed of silicon and zinc or iron, and related methods |
| BR112017004074B1 (pt) * | 2014-09-09 | 2022-03-03 | Basf Se | Processo para a preparação de um material zeolítico, material zeolítico, moldagem e usos de um material zeolítico |
| CN104445255A (zh) * | 2014-12-04 | 2015-03-25 | 南京工业大学 | 一种杂原子mcm-49沸石分子筛的制备方法 |
| JP6544118B2 (ja) * | 2015-07-29 | 2019-07-17 | 住友化学株式会社 | ゼオライトの製造方法及びε−カプロラクタムの製造方法 |
| CN106745038B (zh) * | 2016-12-09 | 2018-11-13 | 卓悦环保新材料（上海）有限公司 | 一种Ti-MWW分子筛的合成方法 |
| US10780432B2 (en) * | 2017-01-18 | 2020-09-22 | Basf Se | Process for preparing a molding comprising zinc and a titanium-containing zeolite |
| ES2739646B2 (es) * | 2018-08-01 | 2021-01-18 | Univ Valencia Politecnica | Procedimiento de sintesis del material mww en su forma nanocristalina y su uso en aplicaciones cataliticas |
| BR112022018861A2 (pt) * | 2020-03-23 | 2022-11-22 | Basf Se | Material zeolítico, composto contendo ti, uso de um composto contendo ti, processos para preparar um material zeolítico e para oxidar um composto orgânico, moldagem, uso de uma moldagem, e, óxido de propileno |
| CN113683097B (zh) * | 2021-09-23 | 2023-04-04 | 深圳科冠华太新材料技术有限公司 | 一种富含骨架四配位钛的ts-1分子筛的制备方法 |
| CN119528174B (zh) * | 2023-08-30 | 2025-10-10 | 中国石油化工股份有限公司 | 改性mww分子筛及其制备方法、二甲苯异构化催化剂及其制备方法和应用 |
| CN117208926B (zh) * | 2023-09-12 | 2025-07-15 | 复旦大学 | 一种高结晶性的二维mww沸石分子筛及其制备方法 |
| GB202500291D0 (en) | 2025-01-10 | 2025-02-26 | Univ College Cardiff Consultants Ltd | Catalyst suitable for ammoximation of cyclohexanone |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4954325A (en) * | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
| US5284643A (en) * | 1992-12-10 | 1994-02-08 | Mobil Oil Corp. | Gallium-containing zeolite MCM-22 |
| ES2105982B1 (es) * | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | Zeolita itq-1 |
| ZA979264B (en) * | 1996-10-17 | 1998-12-29 | Exxon Chemical Patents Inc | Synthesis of large crystal zeolites |
| DE19649946A1 (de) * | 1996-12-03 | 1998-06-04 | Basf Ag | Verfahren zur Herstellung von Aminen aus Olefinen an Bor-MCM-22 oder ERB-1 Zeolithen |
| KR100565026B1 (ko) * | 1998-04-15 | 2006-03-30 | 다우 글로벌 테크놀로지스 인크. | 올레핀을 올레핀 옥사이드로 직접 산화시키는 방법 |
| DE19921783A1 (de) * | 1999-05-11 | 2000-11-16 | Basf Ag | Verfahren zur Herstellung von Phenolen und aromatischen Aminen |
| DE19939416A1 (de) * | 1999-08-20 | 2001-02-22 | Basf Ag | Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs |
| US6114551A (en) * | 1999-10-04 | 2000-09-05 | Mobil Oil Corporation | Olefin epoxidation catalysts |
| DE19955557A1 (de) * | 1999-11-18 | 2001-05-23 | Basf Ag | Oxidischer Katalysator mit Zeolithstruktur und Verfahren zu dessen Herstellung |
| US6475463B1 (en) * | 2000-03-07 | 2002-11-05 | Chevron U.S.A. Inc. | Zeolite SSZ-55 |
| JP2002102709A (ja) | 2000-09-29 | 2002-04-09 | Showa Denko Kk | 酸化化合物製造用結晶性ｍｗｗ型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法 |
| CN1111085C (zh) * | 2000-11-02 | 2003-06-11 | 中国石油化工股份有限公司 | 含杂原子的分子筛及其合成 |
| US6419894B1 (en) * | 2000-12-22 | 2002-07-16 | California Institute Of Technology | Process for preparing zeolites having MEL structure using 2,2-diethoxyethyltrimethylammonium structure directing agent |
-
2003
- 2003-02-03 JP JP2003026529A patent/JP4241068B2/ja not_active Expired - Lifetime
- 2003-02-26 CN CN200610153843A patent/CN100584757C/zh not_active Expired - Lifetime
- 2003-02-26 AT AT03707103T patent/ATE465974T1/de not_active IP Right Cessation
- 2003-02-26 KR KR1020067012905A patent/KR20060092284A/ko not_active Ceased
- 2003-02-26 KR KR1020047013787A patent/KR100699797B1/ko not_active Expired - Lifetime
- 2003-02-26 AU AU2003208616A patent/AU2003208616A1/en not_active Abandoned
- 2003-02-26 CA CA002477491A patent/CA2477491C/en not_active Expired - Lifetime
- 2003-02-26 WO PCT/JP2003/002155 patent/WO2003074422A1/en not_active Ceased
- 2003-02-26 US US10/506,532 patent/US7326401B2/en not_active Expired - Lifetime
- 2003-02-26 EP EP03707103A patent/EP1485321B1/de not_active Expired - Lifetime
- 2003-02-26 SG SG200606150-1A patent/SG141245A1/en unknown
- 2003-02-26 CN CNB038054310A patent/CN100522808C/zh not_active Expired - Lifetime
-
2008
- 2008-08-01 JP JP2008200163A patent/JP5047091B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2477491A1 (en) | 2003-09-12 |
| KR20040105746A (ko) | 2004-12-16 |
| EP1485321B1 (de) | 2010-04-28 |
| JP4241068B2 (ja) | 2009-03-18 |
| US7326401B2 (en) | 2008-02-05 |
| KR100699797B1 (ko) | 2007-03-27 |
| WO2003074422A1 (en) | 2003-09-12 |
| KR20060092284A (ko) | 2006-08-22 |
| JP2003327425A (ja) | 2003-11-19 |
| CN1919735A (zh) | 2007-02-28 |
| JP5047091B2 (ja) | 2012-10-10 |
| SG141245A1 (en) | 2008-04-28 |
| CN100522808C (zh) | 2009-08-05 |
| US20050158238A1 (en) | 2005-07-21 |
| CA2477491C (en) | 2009-04-28 |
| EP1485321A1 (de) | 2004-12-15 |
| CN1639065A (zh) | 2005-07-13 |
| AU2003208616A1 (en) | 2003-09-16 |
| CN100584757C (zh) | 2010-01-27 |
| JP2008290942A (ja) | 2008-12-04 |
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