ATE486044T1 - Anorganische oxiden mit mesoporosität oder kombinierte meso-und mikroporosität und verfahren zu ihrer herstellung - Google Patents

Anorganische oxiden mit mesoporosität oder kombinierte meso-und mikroporosität und verfahren zu ihrer herstellung

Info

Publication number
ATE486044T1
ATE486044T1 AT00918065T AT00918065T ATE486044T1 AT E486044 T1 ATE486044 T1 AT E486044T1 AT 00918065 T AT00918065 T AT 00918065T AT 00918065 T AT00918065 T AT 00918065T AT E486044 T1 ATE486044 T1 AT E486044T1
Authority
AT
Austria
Prior art keywords
mesoporosity
microporosity
production
inorganic oxides
combined meso
Prior art date
Application number
AT00918065T
Other languages
English (en)
Inventor
Zhiping Shan
Thomas Maschmeyer
Jacobus Jansen
Original Assignee
Univ Delft Tech
Lummus Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23541821&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE486044(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US09/390,276 external-priority patent/US6358486B1/en
Application filed by Univ Delft Tech, Lummus Technology Inc filed Critical Univ Delft Tech
Application granted granted Critical
Publication of ATE486044T1 publication Critical patent/ATE486044T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/005Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084Y-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/69Pore distribution bimodal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14Methods for preparing oxides or hydroxides in general
    • C01B13/36Methods for preparing oxides or hydroxides in general by precipitation reactions in aqueous solutions
    • C01B13/366Methods for preparing oxides or hydroxides in general by precipitation reactions in aqueous solutions by hydrothermal processing
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/126Preparation of silica of undetermined type
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60Synthesis on support
    • B01J2229/62Synthesis on support in or on other molecular sieves
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Silicon Compounds (AREA)
  • Catalysts (AREA)
AT00918065T 1999-09-07 2000-03-16 Anorganische oxiden mit mesoporosität oder kombinierte meso-und mikroporosität und verfahren zu ihrer herstellung ATE486044T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/390,276 US6358486B1 (en) 1988-09-17 1999-09-07 Inorganic oxides with mesoporosity or combined meso-and microporosity and process for the preparation thereof
PCT/US2000/007094 WO2001017901A1 (en) 1999-09-07 2000-03-16 Inorganic oxides with mesoporosity or combined meso-and microporosity and process for the preparation thereof

Publications (1)

Publication Number Publication Date
ATE486044T1 true ATE486044T1 (de) 2010-11-15

Family

ID=23541821

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00918065T ATE486044T1 (de) 1999-09-07 2000-03-16 Anorganische oxiden mit mesoporosität oder kombinierte meso-und mikroporosität und verfahren zu ihrer herstellung

Country Status (11)

Country Link
EP (1) EP1214272B1 (de)
JP (1) JP2003508333A (de)
CN (2) CN100509623C (de)
AT (1) ATE486044T1 (de)
AU (1) AU770364B2 (de)
BR (1) BR0013787B1 (de)
CA (1) CA2384090C (de)
DE (1) DE60045157D1 (de)
ES (1) ES2355468T3 (de)
RU (1) RU2248934C2 (de)
WO (1) WO2001017901A1 (de)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6762143B2 (en) 1999-09-07 2004-07-13 Abb Lummus Global Inc. Catalyst containing microporous zeolite in mesoporous support
US7084087B2 (en) * 1999-09-07 2006-08-01 Abb Lummus Global Inc. Zeolite composite, method for making and catalytic application thereof
JP4151884B2 (ja) 2001-08-08 2008-09-17 独立行政法人理化学研究所 固体表面に複合金属酸化物のナノ材料が形成された材料の製造方法
DE60309707T2 (de) 2002-06-28 2007-09-20 Haldor Topsoe A/S Verwendung eines zeolith beta enthaltender katalysators in kohlenwasserstoffumwandlungsverfahren
JP2005053744A (ja) * 2003-08-05 2005-03-03 Dsl Japan Co Ltd 高吸油性非晶質シリカ粒子
US8439047B2 (en) 2003-12-22 2013-05-14 Philip Morris Usa Inc. Composite mesoporous/microporous materials and their use in smoking articles for removing certain gas phase constituents from tobacco smoke
US7985400B2 (en) * 2004-01-26 2011-07-26 Lummus Technology Inc. Method for making mesoporous or combined mesoporous and microporous inorganic oxides
US7589041B2 (en) 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
CN101035618A (zh) * 2004-09-07 2007-09-12 Abb路慕斯全球股份有限公司 具有沸石和高度中孔性的加氢处理催化剂
CN100429148C (zh) * 2004-10-21 2008-10-29 中国石油天然气股份有限公司 一种微孔分子筛表面附晶生长介孔分子筛的方法
US7601326B2 (en) 2004-11-23 2009-10-13 E. I. Du Pont De Nemours And Company Mesoporous oxide of zirconium
US20060263291A1 (en) 2004-11-23 2006-11-23 Carmine Torardi Mesoporous amorphous oxide of titanium
US7988947B2 (en) 2004-11-23 2011-08-02 E. I. Du Pont De Nemours And Company Mesoporous oxide of titanium
US7601327B2 (en) 2004-11-23 2009-10-13 E.I. Du Pont De Nemours And Company Mesoporous oxide of hafnium
RU2282587C1 (ru) * 2005-04-08 2006-08-27 Ирина Игоревна Иванова Способ получения материала с микромезопористой структурой
FR2886637B1 (fr) * 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau mesostructure a forte teneur en aluminium
FR2886636B1 (fr) * 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
US20080227628A1 (en) * 2005-10-12 2008-09-18 Raymond Le Van Mao Silica Nanoboxes, Method of Making and Use thereof
US7678955B2 (en) 2005-10-13 2010-03-16 Exxonmobil Chemical Patents Inc Porous composite materials having micro and meso/macroporosity
RU2288034C1 (ru) * 2005-10-14 2006-11-27 Ирина Игоревна Иванова Способ конверсии углеводородов, катализатор для его осуществления с микро-мезопористой структурой и способ приготовления катализатора
RU2312096C1 (ru) * 2006-10-04 2007-12-10 Ирина Игоревна Иванова Способ получения линейных алкилбензолов с использованием катализатора с микромезопористой структурой
CN101631614B (zh) * 2006-10-17 2013-12-11 路慕斯技术有限公司 双金属烷基化催化剂
FR2909012B1 (fr) * 2006-11-23 2009-05-08 Inst Francais Du Petrole Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/ hydroconversion et d'hydrotraitement de charges hydrocarbonees.
US7858066B2 (en) 2007-05-08 2010-12-28 E.I. Du Pont De Nemours And Company Method of making titanium dioxide particles
EP2095866B1 (de) * 2008-02-25 2014-10-29 JGC Catalysts and Chemicals Ltd. Vorrichtung zur Abgasnachbehandlung
WO2010083488A2 (en) 2009-01-19 2010-07-22 Rive Technologies, Inc. Introduction of mesoporosity in low si/ai zeolites
RU2393992C1 (ru) * 2009-03-17 2010-07-10 Общество с ограниченной ответственностью "УНИСИТ" Микромезопористый кристаллический материал и способ его получения
WO2011002417A1 (en) 2009-07-03 2011-01-06 Nanyang Technological University Method of forming single-walled carbon nanotubes
US8685875B2 (en) 2009-10-20 2014-04-01 Rive Technology, Inc. Methods for enhancing the mesoporosity of zeolite-containing materials
MX2010005333A (es) * 2010-05-14 2011-11-23 Mexicano Inst Petrol Proceso para modificar las propiedades fisicoquimicas de zeolitas del tipo faujasita y.
CN102476975B (zh) * 2010-11-25 2014-04-30 中国石油化工股份有限公司 一种镁和铝改性的钛硅分子筛催化氧化环酮的方法
WO2012138910A2 (en) 2011-04-08 2012-10-11 Rive Technology, Inc. Mesoporous framework-modified zeolites
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
WO2013106816A1 (en) 2012-01-13 2013-07-18 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids
US9662640B2 (en) 2013-12-27 2017-05-30 Rive Technology, Inc. Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
EP3129138B1 (de) * 2014-04-10 2020-07-01 Danmarks Tekniske Universitet Allgemeines verfahren zur einbringung von metallnanopartikeln in zeolithe und zeotype
US9604194B2 (en) * 2014-10-14 2017-03-28 Saudi Arabian Oil Company Synthesis of ordered microporous carbons by chemical vapor deposition
US9963349B2 (en) 2014-12-11 2018-05-08 Rive Technology, Inc. Preparation of mesoporous zeolites with reduced processing
US10626019B2 (en) 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content
KR20180127306A (ko) 2015-10-21 2018-11-28 사우디 아라비안 오일 컴퍼니 양이온성 폴리머 및 다공성 물질
JP6733501B2 (ja) * 2016-01-18 2020-08-05 東ソー株式会社 芳香族化合物製造触媒及び芳香族化合物の製造方法
CN109216548A (zh) * 2018-10-22 2019-01-15 东莞理工学院 一种钙钛矿太阳能电池的刮涂制备方法
CN109368653B (zh) * 2018-10-24 2021-07-20 深圳大学 一种双介孔Co-TUD-1分子筛及其制备方法
US12606447B2 (en) 2021-06-14 2026-04-21 Saudi Arabian Oil Company Mesoporous silica manufactured in the presence of water-soluble ODSO
CN116328784B (zh) * 2023-05-24 2023-08-11 山东公泉化工股份有限公司 一种炼油催化剂及其制备方法
CN117509654B (zh) * 2023-10-23 2025-08-19 确成硅化学股份有限公司 一种隔热沉淀二氧化硅的制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1139733A (en) * 1979-01-15 1983-01-18 Francis G. Dwyer Form of zeolite zsm-11, preparation thereof and catalytic conversion therewith
US4377502A (en) * 1979-12-26 1983-03-22 Standard Oil Company (Indiana) Synthesis of crystalline aluminosilicate molecular sieves
AU579656B2 (en) * 1984-09-04 1988-12-01 W.R. Grace & Co.-Conn. Process to make small crystallites of zsm-5
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione
EP0987220A1 (de) * 1998-09-17 2000-03-22 Technische Universiteit Delft Mesoporöse amorphe Silikatmaterialien und Verfahren zu deren Herstellung
US5076815A (en) * 1989-07-07 1991-12-31 Lonza Ltd. Process for producing sintered material based on aluminum oxide and titanium oxide
JPH0825921B2 (ja) * 1990-08-10 1996-03-13 株式会社ジャパンエナジー 芳香族炭化水素の製造方法および触媒並びにその触媒の製造方法
AU642817B2 (en) * 1991-06-14 1993-10-28 Mobil Oil Corporation A method of synthesizing zeolite beta
GB2287459B (en) * 1992-06-02 1996-02-14 British Gas Plc Porous amorphous silica-alumina refractory oxides,their preparation and use as separation membranes
NO300012B1 (no) * 1993-08-17 1997-03-17 Polymers Holding As Mikroporost krystallinsk silikoaluminofosfat, fremgangsmate for fremstilling av dette, samt anvendelse derav
US5601798A (en) * 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
IT1270230B (it) * 1994-06-16 1997-04-29 Enichem Sintesi Composizione catalitica e processo per l'alchilazione di composti aromatici
US5672556A (en) * 1994-08-22 1997-09-30 Board Of Trustees Operating Michigan State University Crystalline silicate compositions and method of preparation
US5795555A (en) * 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
US5538710A (en) * 1994-12-14 1996-07-23 Energy Mines And Resources-Canada Synthesis of mesoporous catalytic materials
JPH09208219A (ja) * 1995-12-01 1997-08-12 Toray Ind Inc モルデナイト構造を有するゼオライトおよびその製造方法
JP3684265B2 (ja) * 1996-03-26 2005-08-17 触媒化成工業株式会社 均一なミクロポアと均一なメソポアの2種類の細孔を有するフォージャサイト型ゼオライトおよびその製造方法
JPH09295811A (ja) * 1996-04-30 1997-11-18 Lion Corp 無定形多孔体及びその製造方法
US5849258A (en) * 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same
US5919430A (en) * 1996-06-19 1999-07-06 Degussa Aktiengesellschaft Preparation of crystalline microporous and mesoporous metal silicates, products produced thereby and use thereof
JPH11226391A (ja) * 1998-02-19 1999-08-24 Toyota Motor Corp 排ガス浄化用ゼオライト及びその製造方法

Also Published As

Publication number Publication date
CN1827525A (zh) 2006-09-06
JP2003508333A (ja) 2003-03-04
CN100509623C (zh) 2009-07-08
EP1214272B1 (de) 2010-10-27
RU2248934C2 (ru) 2005-03-27
WO2001017901A1 (en) 2001-03-15
ES2355468T3 (es) 2011-03-28
CN1387496A (zh) 2002-12-25
EP1214272A1 (de) 2002-06-19
CN1234456C (zh) 2006-01-04
BR0013787B1 (pt) 2010-11-16
DE60045157D1 (de) 2010-12-09
AU770364B2 (en) 2004-02-19
BR0013787A (pt) 2002-08-27
CA2384090C (en) 2009-02-03
CA2384090A1 (en) 2001-03-15
AU3893900A (en) 2001-04-10

Similar Documents

Publication Publication Date Title
ATE486044T1 (de) Anorganische oxiden mit mesoporosität oder kombinierte meso-und mikroporosität und verfahren zu ihrer herstellung
EA200100319A1 (ru) Неорганические оксиды с мезопористостью или сочетанием мезо и микропористости и способ их получения
CR6938A (es) Monohidrato cristalino metodo para su fabricacion y su empleo en la fabricacion de un medicamento.
AU2002230782A1 (en) Process for air enrichment in producing hydrogen for use with fuel cells
WO2009102815A3 (en) Alpha alumina (corundum) whiskers and fibrous-porous ceramics and method of preparing thereof
WO2011005530A3 (en) Non-crystalline materials having complete photonic, electronic, or phononic band gaps
MXPA03001181A (es) Productos de perlita expandida con distribucion controlada de tamano de particula.
WO2009108362A3 (en) Honeycomb manufacturing method using ground nut shells and honeycomb body produced thereby
CN203795761U (zh) 复合无醛装饰板
CN102951925A (zh) 一种具有调湿功能的硅藻土基多孔材料及其制备方法
CN102061620B (zh) 一种自发热抗菌材料的制备方法
CN104892017B (zh) 一种吸附室内甲醛气体的内墙砖制备方法
CN108495969A (zh) 功能性印花砖及其制造方法
ATE356083T1 (de) Poröse anorganische makrostrukturen und verfahren zur herstellung derselben
CN104257176A (zh) 一种蚕丝被的制作方法及蚕丝被
WO2006052917A3 (en) Silica mesoporous materials
WO2017216135A3 (en) Porous carbonaceous structure prepared by using porous geopolymer, method of preparing the same, and use of the same
WO2008096708A1 (ja) 金属素材の穿孔圧延に用いられるプラグの製造方法、金属管の製造方法及び金属素材の穿孔圧延に用いられるプラグ
Manap et al. Influence of concentration of pore forming agent on porosity of SiO2 ceramic from rice husk ash
CN205201880U (zh) 用于制备凝胶枕芯的模具
CN203391426U (zh) 一种运用印刷技术的功能性面料
CN201422680Y (zh) 高低差枕头
CN107355057A (zh) 一种抗菌防滑瓷砖
ATE451339T1 (de) Verfahren zur herstellung porösen calciumphospat körpern zur knochenregeneration und wie zellenträger, und die erhaltene poröse körper
CN203160519U (zh) 一种复合型环保墙板

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties