ATE535560T1 - Verfahren zur herstellung von organischen verbindungen in gegenwart eines framework- materials - Google Patents
Verfahren zur herstellung von organischen verbindungen in gegenwart eines framework- materialsInfo
- Publication number
- ATE535560T1 ATE535560T1 AT02781271T AT02781271T ATE535560T1 AT E535560 T1 ATE535560 T1 AT E535560T1 AT 02781271 T AT02781271 T AT 02781271T AT 02781271 T AT02781271 T AT 02781271T AT E535560 T1 ATE535560 T1 AT E535560T1
- Authority
- AT
- Austria
- Prior art keywords
- organic compounds
- framework material
- producing organic
- metal ion
- catalyst system
- Prior art date
Links
- 150000002894 organic compounds Chemical class 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910021645 metal ion Inorganic materials 0.000 abstract 2
- 229920000570 polyether Polymers 0.000 abstract 2
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000013384 organic framework Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/039,733 US20030078311A1 (en) | 2001-10-19 | 2001-10-19 | Process for the alkoxylation of organic compounds in the presence of novel framework materials |
| PCT/EP2002/011700 WO2003035717A1 (en) | 2001-10-19 | 2002-10-18 | Process for the alkoxylation of organic compounds in the presence of novel framework materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE535560T1 true ATE535560T1 (de) | 2011-12-15 |
Family
ID=21907076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02781271T ATE535560T1 (de) | 2001-10-19 | 2002-10-18 | Verfahren zur herstellung von organischen verbindungen in gegenwart eines framework- materials |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20030078311A1 (de) |
| EP (1) | EP1440106B1 (de) |
| JP (1) | JP4173101B2 (de) |
| KR (1) | KR100940290B1 (de) |
| CN (1) | CN100424115C (de) |
| AT (1) | ATE535560T1 (de) |
| CA (1) | CA2464352A1 (de) |
| ES (1) | ES2376050T3 (de) |
| MX (1) | MXPA04003467A (de) |
| PL (1) | PL370429A1 (de) |
| RU (1) | RU2308465C2 (de) |
| TW (1) | TWI300072B (de) |
| WO (1) | WO2003035717A1 (de) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1383775B1 (de) * | 2001-04-30 | 2006-08-02 | The Regents of The University of Michigan | Isoretikuläre organometallische grundstrukturen, verfahren zu deren bildung und systematische entwicklung von deren porengrösse und funktionalität, mit anwendung für die gasspeicherung |
| US6893564B2 (en) * | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| US7008607B2 (en) * | 2002-10-25 | 2006-03-07 | Basf Aktiengesellschaft | Process for preparing hydrogen peroxide from the elements |
| ATE466865T1 (de) * | 2003-05-09 | 2010-05-15 | Univ Michigan | Mofs mit einer hohen oberfläche und methode zu deren herstellung |
| US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
| US20050004404A1 (en) * | 2003-07-03 | 2005-01-06 | Basf Akiengesellschaft | Process for the alkoxylation of monools in the presence of metallo-organic framework materials |
| DE10355087A1 (de) * | 2003-11-24 | 2005-06-09 | Basf Ag | Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials |
| CN1914219A (zh) * | 2003-12-05 | 2007-02-14 | 密歇根大学董事会 | 金属有机多面体 |
| JP4659356B2 (ja) * | 2003-12-26 | 2011-03-30 | 株式会社イノアックコーポレーション | 再生ポリウレタンフォームの製造方法 |
| CN101189244A (zh) | 2004-10-22 | 2008-05-28 | 密歇根大学董事会 | 共价连接的有机骨架和多面体 |
| US7524444B2 (en) * | 2004-11-09 | 2009-04-28 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| US7343747B2 (en) * | 2005-02-23 | 2008-03-18 | Basf Aktiengesellschaft | Metal-organic framework materials for gaseous hydrocarbon storage |
| CN101151091B (zh) | 2005-04-07 | 2010-06-23 | 密歇根大学董事会 | 具有敞开的金属部位的微孔金属有机构架中的气体高吸附 |
| US8628055B2 (en) * | 2005-07-27 | 2014-01-14 | The Board Of Trustees Of The University Of Illinois | Bi-direction rapid action electrostatically actuated microvalve |
| US7799120B2 (en) * | 2005-09-26 | 2010-09-21 | The Regents Of The University Of Michigan | Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature |
| US8123834B2 (en) * | 2005-10-06 | 2012-02-28 | The Board Of Trustees Of The University Of Illinois | High gain selective metal organic framework preconcentrators |
| DE102005054523A1 (de) | 2005-11-14 | 2007-05-16 | Basf Ag | Poröses metallorganisches Gerüstmaterial enthaltend ein weiteres Polymer |
| US8314245B2 (en) | 2006-02-28 | 2012-11-20 | The Regents Of The University Of Michigan | Preparation of functionalized zeolitic frameworks |
| US7880026B2 (en) * | 2006-04-14 | 2011-02-01 | The Board Of Trustees Of The University Of Illinois | MOF synthesis method |
| KR20080112349A (ko) | 2006-04-18 | 2008-12-24 | 바스프 에스이 | 금속-유기 골격재로 제조된 금속 산화물 |
| US7441574B2 (en) | 2006-08-17 | 2008-10-28 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| US9017584B2 (en) * | 2006-10-30 | 2015-04-28 | Alan M. Gilbert | Flame-retardant materials and systems |
| US20080111114A1 (en) * | 2006-10-30 | 2008-05-15 | Gilbert Alan M | Flame-retardant materials and systems |
| US9719019B1 (en) | 2006-10-30 | 2017-08-01 | Alan M. Gilbert | Flame-retardant materials and systems |
| ATE555851T1 (de) | 2006-10-30 | 2012-05-15 | Basf Se | Aluminium-naphthalindicarboxylat als poröses metallorganisches gerüstmaterial |
| JP5559545B2 (ja) * | 2007-01-24 | 2014-07-23 | ザ レジェンツ オブ ザ ユニヴァースティ オブ カリフォルニア | 結晶性3d−および2d−共有結合性有機骨格 |
| ES2397231T3 (es) | 2007-04-24 | 2013-03-05 | Basf Se | Materiales estructurales organometálicos, con una estructura hexagonal y trigonal, basados en aluminio, hierro o cromo, así como un ácido dicarboxílico |
| EP2155608A4 (de) * | 2007-05-11 | 2011-01-12 | Univ California | Adsorptive gastrennung von mehrkomponentigen gasen |
| US8480792B2 (en) * | 2007-07-17 | 2013-07-09 | The Regents Of The University Of California | Preparation of functionalized zeolitic frameworks |
| US8222179B2 (en) * | 2007-08-30 | 2012-07-17 | The Regents Of The University Of Michigan | Porous coordination copolymers and methods for their production |
| US9132411B2 (en) | 2007-08-30 | 2015-09-15 | The Regents Of The University Of Michigan | Strategies, linkers and coordination polymers for high-performance sorbents |
| US8383545B2 (en) * | 2007-08-30 | 2013-02-26 | The Regents Of The University Of Michigan | Strategies, linkers and coordination polymers for high-performance sorbents |
| WO2009042802A1 (en) * | 2007-09-25 | 2009-04-02 | The Regents Of The University Of California | Edible and biocompatible metal-organic frameworks |
| BRPI0817443A2 (pt) * | 2007-09-28 | 2015-06-16 | Inst Francais Du Petrole | Processo de produção de ésteres alcoólicos, a partir de triglicerídeos e de álcoois, por meio de catalisadores heterogêneos à base de sólido híbrido de matriz mista orgânica - inorgânica |
| FR2921660B1 (fr) | 2007-10-01 | 2015-09-25 | Centre Nat Rech Scient | Nanoparticules hybrides organiques inorganiques a base de carboxylates de fer. |
| FR2921661B1 (fr) * | 2007-10-01 | 2013-05-31 | Centre Nat Rech Scient | Solide hybride organique inorganique a surface modifiee. |
| US8034952B2 (en) * | 2007-11-15 | 2011-10-11 | University Of South Florida | Supramolecular assemblies and building blocks |
| US8152908B2 (en) * | 2008-01-16 | 2012-04-10 | The Board Of Trustees Of The University Of Illinois | Micromachined gas chromatography columns for fast separation of Organophosphonate and Organosulfur compounds and methods for deactivating same |
| US8142746B2 (en) * | 2008-02-21 | 2012-03-27 | Exxonmobil Research And Engineering Company | Separation of carbon dioxide from methane utilizing zeolitic imidazolate framework materials |
| US8192709B2 (en) * | 2008-02-21 | 2012-06-05 | Exxonmobil Research And Engineering Company | Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials |
| US8142745B2 (en) * | 2008-02-21 | 2012-03-27 | Exxonmobil Research And Engineering Company | Separation of carbon dioxide from nitrogen utilizing zeolitic imidazolate framework materials |
| FR2929278A1 (fr) * | 2008-04-01 | 2009-10-02 | Centre Nat Rech Scient | Solide hybride cristallin poreux pour l'adsorption et la liberation de gaz a interet biologique. |
| US8269029B2 (en) * | 2008-04-08 | 2012-09-18 | The Board Of Trustees Of The University Of Illinois | Water repellent metal-organic frameworks, process for making and uses regarding same |
| US8946454B2 (en) * | 2008-06-05 | 2015-02-03 | The Regents Of The University Of California | Chemical framework compositions and methods of use |
| EP2358726B1 (de) | 2008-12-18 | 2017-08-02 | The Regents of the University of California | Poröse reaktive rahmenwerke |
| WO2010078337A1 (en) | 2008-12-29 | 2010-07-08 | The Regents Of The University Of California | A gas sensor incorporating a porous framework |
| WO2010083418A1 (en) | 2009-01-15 | 2010-07-22 | The Regents Of The University Of California | Conductive organometallic framework |
| US8709134B2 (en) | 2009-02-02 | 2014-04-29 | The Regents Of The University Of California | Reversible ethylene oxide capture in porous frameworks |
| FR2942229B1 (fr) | 2009-02-18 | 2011-02-25 | Univ Paris Curie | Materiau solide hybride inorganique-organique polycarboxylate a base de titane, son procede de preparation et utilisations |
| KR20120099204A (ko) | 2009-06-19 | 2012-09-07 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | 복잡한 혼합된 리간드 개방 골격체 물질 |
| EP2437867A4 (de) | 2009-06-19 | 2012-12-05 | Univ California | Kohlendioxiderfassung und -lagerung mithilfe offener rahmenwerke |
| KR20120084662A (ko) | 2009-07-27 | 2012-07-30 | 바스프 에스이 | 고효율 불균일 촉매로서 다공성 구리 금속-유기 구조체를 이용한 아릴 보론산의 산화 호모-커플링 반응 |
| EP2467388A4 (de) | 2009-09-25 | 2014-12-17 | Univ California | Offene metalloorganische rahmenwerke mit besonderem oberflächenbereich und hoher gasspeicherungskapazität |
| ES2547729T3 (es) | 2009-11-30 | 2015-10-08 | Basf Se | Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico |
| US8716359B2 (en) * | 2010-03-18 | 2014-05-06 | Vanderbilt Chemicals, Llc | Polyurethane foam scorch inhibitor |
| WO2011123795A1 (en) | 2010-04-02 | 2011-10-06 | Battelle Memorial Institute | Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies |
| EP2585472A4 (de) * | 2010-07-20 | 2014-02-12 | Univ California | Funktionalisierung organischer moleküle mit metallorganischen rahmen (mofs) als katalysatoren |
| CN103228663A (zh) | 2010-09-27 | 2013-07-31 | 加利福尼亚大学董事会 | 传导性开放骨架 |
| US8852320B2 (en) | 2011-01-21 | 2014-10-07 | The Regents Of The University Of California | Preparation of metal-triazolate frameworks |
| EP2670761A4 (de) | 2011-02-04 | 2016-05-25 | Univ California | Herstellung von metall-catecholat-rahmen |
| ES2645260T3 (es) | 2011-10-13 | 2017-12-04 | The Regents Of The University Of California | Estructura organometálica con apertura de poro excepcionalmente grande |
| WO2013158484A1 (en) | 2012-04-18 | 2013-10-24 | King Abdullah University Of Science And Technology | Electrode separator |
| CN103333182A (zh) * | 2013-06-04 | 2013-10-02 | 中南大学 | 一种制备mof-5的方法 |
| WO2015066693A1 (en) | 2013-11-04 | 2015-05-07 | The Regents Of Thd University Of California | Metal-organic frameworks with a high density of highly charged exposed metal cation sites |
| WO2015127033A1 (en) | 2014-02-19 | 2015-08-27 | The Regents Of The University Of California | Acid, solvent, and thermal resistant metal-organic frameworks |
| EP3074405A2 (de) | 2014-03-18 | 2016-10-05 | The Regents of the University of California | Mesoskopische materialien aus geordneten supergittern aus mikroporösen metallorganische gerüsten |
| EP3122451B1 (de) | 2014-03-27 | 2018-02-28 | Basf Se | Poröse folien mit metallorganischen gerüstmaterialien |
| US10087205B2 (en) | 2014-03-28 | 2018-10-02 | The Regents Of The University Of California | Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups |
| EP2985075A1 (de) | 2014-08-15 | 2016-02-17 | Basf Se | Formkörper hergestellt aus einem porösen Material |
| US10118877B2 (en) | 2014-12-03 | 2018-11-06 | The Regents Of The University Of California | Metal-organic frameworks for aromatic hydrocarbon separations |
| US10058855B2 (en) | 2015-05-14 | 2018-08-28 | The Regents Of The University Of California | Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons |
| CN108290134A (zh) | 2015-11-27 | 2018-07-17 | 巴斯夫欧洲公司 | 金属-有机骨架的超快高空时产率合成 |
| JP2019503407A (ja) | 2015-11-27 | 2019-02-07 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 織状構造を有する共有結合性有機構造体 |
| US10821417B2 (en) | 2015-11-27 | 2020-11-03 | The Regents Of The University Of California | Zeolitic imidazolate frameworks |
| WO2019036140A1 (en) | 2017-07-17 | 2019-02-21 | Zymergen Inc. | METALLO-ORGANIC STRESS MATERIALS |
| WO2021220166A1 (en) | 2020-04-28 | 2021-11-04 | King Abdullah University Of Science And Technology | Electrode separators |
| CN113828281B (zh) * | 2021-09-18 | 2023-07-14 | 集美大学 | 一种聚氨酯复合材料的制备方法、产品及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3144418A (en) * | 1959-08-17 | 1964-08-11 | Union Carbide Corp | Polymerization of epoxides |
| DE4408772B4 (de) * | 1993-03-16 | 2006-09-07 | Mitsubishi Chemical Corp. | Verfahren zur Herstellung eines Polyoxyalkylenglykols und neues Metallaluminosilikat |
| US5601437A (en) | 1994-10-17 | 1997-02-11 | Methode Electronics, Inc. | Clockspring with centering display device |
| US5648508A (en) | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
| US5767323A (en) * | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| DE19928156A1 (de) | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| CN1597202A (zh) | 1999-07-21 | 2005-03-23 | 布莱克-德克尔公司 | 动力驱动夹头 |
| DE19941242A1 (de) | 1999-08-31 | 2001-03-08 | Basf Ag | Polyetheralkohole |
| DE19949092A1 (de) | 1999-10-12 | 2001-04-19 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| DE10111230A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung |
| DE10143195A1 (de) | 2001-09-04 | 2003-03-20 | Basf Ag | Integriertes Verfahren zur Herstellung von Polyurethan-Schäumen |
-
2001
- 2001-10-19 US US10/039,733 patent/US20030078311A1/en not_active Abandoned
-
2002
- 2002-10-18 EP EP02781271A patent/EP1440106B1/de not_active Expired - Lifetime
- 2002-10-18 CA CA002464352A patent/CA2464352A1/en not_active Abandoned
- 2002-10-18 RU RU2004115338/04A patent/RU2308465C2/ru not_active IP Right Cessation
- 2002-10-18 WO PCT/EP2002/011700 patent/WO2003035717A1/en not_active Ceased
- 2002-10-18 PL PL02370429A patent/PL370429A1/xx not_active Application Discontinuation
- 2002-10-18 CN CNB028207831A patent/CN100424115C/zh not_active Expired - Fee Related
- 2002-10-18 ES ES02781271T patent/ES2376050T3/es not_active Expired - Lifetime
- 2002-10-18 TW TW091124078A patent/TWI300072B/zh active
- 2002-10-18 US US10/492,192 patent/US7279517B2/en not_active Expired - Fee Related
- 2002-10-18 AT AT02781271T patent/ATE535560T1/de active
- 2002-10-18 MX MXPA04003467A patent/MXPA04003467A/es active IP Right Grant
- 2002-10-18 KR KR1020047005723A patent/KR100940290B1/ko not_active Expired - Fee Related
- 2002-10-18 JP JP2003538229A patent/JP4173101B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20030078311A1 (en) | 2003-04-24 |
| JP4173101B2 (ja) | 2008-10-29 |
| KR20040083413A (ko) | 2004-10-01 |
| TWI300072B (en) | 2008-08-21 |
| EP1440106B1 (de) | 2011-11-30 |
| US20040249189A1 (en) | 2004-12-09 |
| CN100424115C (zh) | 2008-10-08 |
| ES2376050T3 (es) | 2012-03-08 |
| PL370429A1 (en) | 2005-05-30 |
| EP1440106A1 (de) | 2004-07-28 |
| KR100940290B1 (ko) | 2010-02-05 |
| CA2464352A1 (en) | 2003-05-01 |
| US7279517B2 (en) | 2007-10-09 |
| RU2004115338A (ru) | 2005-10-27 |
| CN1571803A (zh) | 2005-01-26 |
| JP2005506421A (ja) | 2005-03-03 |
| WO2003035717A9 (en) | 2004-12-29 |
| WO2003035717A1 (en) | 2003-05-01 |
| MXPA04003467A (es) | 2004-07-30 |
| RU2308465C2 (ru) | 2007-10-20 |
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