ATE369350T1 - Verfahren zur epoxidierung unter verwendung eines mof(metal-organic framework)-katalysators - Google Patents

Verfahren zur epoxidierung unter verwendung eines mof(metal-organic framework)-katalysators

Info

Publication number
ATE369350T1
ATE369350T1 AT03730125T AT03730125T ATE369350T1 AT E369350 T1 ATE369350 T1 AT E369350T1 AT 03730125 T AT03730125 T AT 03730125T AT 03730125 T AT03730125 T AT 03730125T AT E369350 T1 ATE369350 T1 AT E369350T1
Authority
AT
Austria
Prior art keywords
metal
catalyst
mof
epoxidation
organic framework
Prior art date
Application number
AT03730125T
Other languages
English (en)
Inventor
Ulrich Mueller
Lisa Lobree
Michael Hesse
Omar Yaghi
Mohamed Eddaoudi
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of ATE369350T1 publication Critical patent/ATE369350T1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/27—Cadmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/44—Lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT03730125T 2002-05-30 2003-05-27 Verfahren zur epoxidierung unter verwendung eines mof(metal-organic framework)-katalysators ATE369350T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/157,494 US6624318B1 (en) 2002-05-30 2002-05-30 Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials

Publications (1)

Publication Number Publication Date
ATE369350T1 true ATE369350T1 (de) 2007-08-15

Family

ID=28041202

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03730125T ATE369350T1 (de) 2002-05-30 2003-05-27 Verfahren zur epoxidierung unter verwendung eines mof(metal-organic framework)-katalysators

Country Status (5)

Country Link
US (1) US6624318B1 (de)
EP (1) EP1513823B1 (de)
AT (1) ATE369350T1 (de)
DE (1) DE60315453T2 (de)
WO (1) WO2003101975A1 (de)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE334992T1 (de) * 2001-04-30 2006-08-15 Univ Michigan Isoretikuläre organometallische grundstrukturen, verfahren zu deren bildung und systematische entwicklung von deren porengrösse und funktionalität, mit anwendung für die gasspeicherung
US6929679B2 (en) * 2002-02-01 2005-08-16 Basf Aktiengesellschaft Method of storing, uptaking, releasing of gases by novel framework materials
EP1633760B1 (de) * 2003-05-09 2010-05-05 The Regents of The University of Michigan MOFs mit einer hohen Oberfläche und Methode zu deren Herstellung
US7309380B2 (en) * 2003-06-30 2007-12-18 Basf Aktiengesellschaft Gas storage system
US20050004404A1 (en) * 2003-07-03 2005-01-06 Basf Akiengesellschaft Process for the alkoxylation of monools in the presence of metallo-organic framework materials
DE10355087A1 (de) * 2003-11-24 2005-06-09 Basf Ag Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials
US7094915B2 (en) * 2003-11-26 2006-08-22 Vasant Ramchandra Choudhary Biphasic process for epoxidation of olefinic compound using chromate or dichromate catalyst
CN1914219A (zh) * 2003-12-05 2007-02-14 密歇根大学董事会 金属有机多面体
US7407816B2 (en) * 2004-05-07 2008-08-05 Gentius, Inc Isoelectric particles and uses thereof
KR101227824B1 (ko) 2004-10-22 2013-01-30 더 리젠츠 오브 더 유니버시티 오브 미시간 공유 결합 유기물의 골격구조들 및 폴리헤드라
US7524444B2 (en) * 2004-11-09 2009-04-28 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks
CN101151091B (zh) * 2005-04-07 2010-06-23 密歇根大学董事会 具有敞开的金属部位的微孔金属有机构架中的气体高吸附
DE102005017195B4 (de) 2005-04-13 2007-02-22 Gkss-Forschungszentrum Geesthacht Gmbh Kompositmaterial, insbesondere Kompositmembran und Verfahren zur Herstellung desselben
KR100620119B1 (ko) * 2005-06-16 2006-09-06 광주과학기술원 트랜스―아네톨을 신―아네톨―２,３―에폭사이드와안티―아네톨―２,３―에폭사이드로 생전환시키는슈도모나스 푸티다 ｊｙｒ―１
DE102005035762A1 (de) * 2005-07-29 2007-02-01 Süd-Chemie AG Hochporöse Schichten aus MOF-Materialien und Verfahren zur Herstellung derartiger Schichten
DE102005037893A1 (de) * 2005-08-10 2007-02-15 Süd-Chemie AG Verfahren zur Herstellung hochaktiver Metall/Metalloxid-Katalysatoren
DE602006002943D1 (de) * 2005-09-21 2008-11-13 Goodyear Tire & Rubber Luftreifen umfassend eine Kautschukkomponente enthaltend ein zinkorganisches Gerüstmaterial
US7799120B2 (en) * 2005-09-26 2010-09-21 The Regents Of The University Of Michigan Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
DE102005056564B4 (de) * 2005-11-25 2009-11-12 Gkss-Forschungszentrum Geesthacht Gmbh Polymerelektrolytmembran mit Koordinationspolymer, Verfahren zu seiner Herstellung sowie Verwendung in einer Brennstoffzelle
PL1988996T3 (pl) * 2006-02-28 2018-01-31 Univ Michigan Regents Otrzymywanie szkieletów zeolitu z grupami funkcyjnymi
CN101421183A (zh) 2006-04-18 2009-04-29 巴斯夫欧洲公司 由金属有机骨架材料制备的金属氧化物
GB0616350D0 (en) * 2006-08-17 2006-09-27 Univ St Andrews Adsorption and release of nitric oxide in metal organic frameworks
US9017584B2 (en) * 2006-10-30 2015-04-28 Alan M. Gilbert Flame-retardant materials and systems
US9719019B1 (en) 2006-10-30 2017-08-01 Alan M. Gilbert Flame-retardant materials and systems
US20080111114A1 (en) * 2006-10-30 2008-05-15 Gilbert Alan M Flame-retardant materials and systems
ES2383770T3 (es) 2006-10-30 2012-06-26 Basf Se Naftalindicarboxilato de aluminio como material estructural poroso organometálico
US7985868B1 (en) * 2006-11-01 2011-07-26 Sandia Corporation Hybrid metal organic scintillator materials system and particle detector
EP2114560A4 (de) * 2007-01-24 2012-02-15 Univ California Kristalline 3d- und 2d-kovalente organische rahmenwerke
EP2142297A1 (de) * 2007-04-24 2010-01-13 Basf Se Mit katalysator-metallkomponenten beladene poröse metallorganische gerüstmaterialien
US8372779B2 (en) 2007-04-24 2013-02-12 Basf Se Metal organic frameworks based on aluminum, iron and chromium
US8540802B2 (en) * 2007-05-11 2013-09-24 The Regents Of The University Of California Adsorptive gas separation of multi-component gases
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
WO2008144396A2 (en) * 2007-05-18 2008-11-27 Shell Oil Company A reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
US8569527B2 (en) 2007-05-18 2013-10-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
WO2009020745A2 (en) * 2007-07-17 2009-02-12 The Regents Of The University Of California Preparation of functionalized zeolitic frameworks
US9132411B2 (en) 2007-08-30 2015-09-15 The Regents Of The University Of Michigan Strategies, linkers and coordination polymers for high-performance sorbents
US8383545B2 (en) * 2007-08-30 2013-02-26 The Regents Of The University Of Michigan Strategies, linkers and coordination polymers for high-performance sorbents
US8222179B2 (en) * 2007-08-30 2012-07-17 The Regents Of The University Of Michigan Porous coordination copolymers and methods for their production
JP5730574B2 (ja) * 2007-09-25 2015-06-10 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 食用に適した生体適合性金属有機構造体
ES2345316B2 (es) 2007-09-28 2011-12-20 Ifp Metodo para la preparacion de esteres alcoholicos a partir de trigliceridos y alcoholes utilizando catalizadores heterogeneos basados en unsolido hibrido con una matriz mixta organica-inorganica.
US8034952B2 (en) * 2007-11-15 2011-10-11 University Of South Florida Supramolecular assemblies and building blocks
US8142746B2 (en) * 2008-02-21 2012-03-27 Exxonmobil Research And Engineering Company Separation of carbon dioxide from methane utilizing zeolitic imidazolate framework materials
US8192709B2 (en) * 2008-02-21 2012-06-05 Exxonmobil Research And Engineering Company Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials
US8142745B2 (en) * 2008-02-21 2012-03-27 Exxonmobil Research And Engineering Company Separation of carbon dioxide from nitrogen utilizing zeolitic imidazolate framework materials
EP2103604A1 (de) 2008-03-17 2009-09-23 Evonik Degussa GmbH Verfahren zur Herstellung von Epichlorhydrin
BRPI0912718B1 (pt) 2008-05-15 2017-12-26 Shell Internationale Research Maataschappij B.V Method for producing an alkylene carbonate and / or an alkylene glycol
CN102066352B (zh) 2008-05-15 2014-03-19 国际壳牌研究有限公司 制备亚烷基碳酸酯和亚烷基二醇的方法
WO2009149381A2 (en) * 2008-06-05 2009-12-10 The Regents Of University Of California Chemical framework compositions and methods of use
EP2149570A1 (de) * 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Verfahren zur Herstellung von Epichlorhydrin mit Wasserstoffperoxid und einem Mangankomplex
EP2149569A1 (de) 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Verfahren zur Herstellung eines 1,2-Epoxid
WO2010080618A2 (en) 2008-12-18 2010-07-15 The Regents Of The University Of California Porous reactive frameworks
EP2356072A1 (de) 2008-12-29 2011-08-17 The Regents of the University of California Gassensor mit poröser struktur
US8674128B2 (en) 2009-01-15 2014-03-18 The Regents Of The University Of California Conductive organometallic framework
EP2384237A1 (de) 2009-02-02 2011-11-09 The Regents of The University of California Reversibles einfangen von ethylenoxid in porösen gerüsten
FR2945966B1 (fr) * 2009-05-28 2014-06-20 Centre Nat Rech Scient Utilisation d'un solide hybride cristallin poreux comme catalyseur de reduction d'oxydes d'azote et dispositifs
WO2010148276A2 (en) 2009-06-19 2010-12-23 The Regents Of The University Of California Carbon dioxide capture and storage using open frameworks
CN102482294B (zh) 2009-06-19 2016-02-03 加利福尼亚大学董事会 复杂的混合配体开放骨架材料
CN102428057B (zh) 2009-07-27 2015-03-25 加利福尼亚大学董事会 使用多孔铜金属-有机骨架作为高效非均相催化剂的芳基硼酸的氧化均偶联反应
EP2467388A4 (de) 2009-09-25 2014-12-17 Univ California Offene metalloorganische rahmenwerke mit besonderem oberflächenbereich und hoher gasspeicherungskapazität
EP2343288A1 (de) * 2009-11-27 2011-07-13 Momentive Specialty Chemicals Research Belgium S.A. Verfahren zur Herstellung von Propylenoxid
DE102010062374A1 (de) 2009-12-04 2011-06-09 Basf Se Verfahren zur Herstellung von Homo- oder Copolymeren
JP2013533272A (ja) * 2010-07-20 2013-08-22 ザ レジェンツ オブ ザ ユニヴァースティ オブ カリフォルニア 触媒として金属有機構造体（ｍｏｆ）を使用する有機分子の官能基化
CA2812294A1 (en) 2010-09-27 2012-06-21 The Regents Of The University Of California Conductive open frameworks
AU2012207079A1 (en) 2011-01-21 2013-07-04 The Regents Of The University Of California Preparation of metal-triazolate frameworks
KR20140041445A (ko) 2011-02-04 2014-04-04 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 금속-카테콜레이트 골격체의 제조
CN104302387B (zh) 2011-10-13 2019-06-18 加利福尼亚大学董事会 具有格外大的孔口的金属有机骨架
US8809569B2 (en) 2012-02-28 2014-08-19 Saudi Basic Industries Corporation Process for preparing dialkyl carbonate and diol products
US8735608B2 (en) 2012-02-28 2014-05-27 Saudi Basic Industries Corporation Process for preparing carbonate and diol products
US9853270B2 (en) 2012-04-18 2017-12-26 King Abdullah University Of Science And Technology Nanostructured metal organic material electrode separators and methods therefor
WO2014009952A2 (en) 2012-07-09 2014-01-16 Yeda Research And Development Co. Ltd Logic circuits with plug and play solid-state molecular chips
CN103539762B (zh) * 2012-07-12 2016-01-13 中国石油化工股份有限公司 丙烯环氧化生产环氧丙烷的方法
US10035127B2 (en) 2013-11-04 2018-07-31 The Regents Of The University Of California Metal-organic frameworks with a high density of highly charged exposed metal cation sites
CN104707655A (zh) * 2013-12-11 2015-06-17 中国科学院大连化学物理研究所 一种金属卟啉催化剂及其催化氯丙烯环氧化的方法
JP6717749B2 (ja) 2014-02-19 2020-07-01 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 耐酸性、耐溶剤性、及び耐熱性金属−有機骨格
CN107148422A (zh) 2014-03-18 2017-09-08 加利福尼亚大学董事会 包含微孔金属有机骨架的有序超晶格的介观材料
ES2823823T3 (es) 2014-03-27 2021-05-10 Basf Se Películas porosas que comprenden materiales de estructura organometálica
US10087205B2 (en) 2014-03-28 2018-10-02 The Regents Of The University Of California Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups
CN104001547B (zh) * 2014-06-16 2016-03-30 上海师范大学 一种环境友好型核壳一维纳米铜线-有机金属骨架zif-8复合催化剂的制备方法及其应用
EP2985075A1 (de) 2014-08-15 2016-02-17 Basf Se Formkörper hergestellt aus einem porösen Material
US10118877B2 (en) 2014-12-03 2018-11-06 The Regents Of The University Of California Metal-organic frameworks for aromatic hydrocarbon separations
US10058855B2 (en) 2015-05-14 2018-08-28 The Regents Of The University Of California Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons
CN108290134A (zh) 2015-11-27 2018-07-17 巴斯夫欧洲公司 金属-有机骨架的超快高空时产率合成
JP2018538282A (ja) 2015-11-27 2018-12-27 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア ゼオライト様イミダゾレート構造体
US10597408B2 (en) 2015-11-27 2020-03-24 The Regents Of The University Of California Covalent organic frameworks with a woven structure
JP2019505637A (ja) 2016-01-15 2019-02-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 防水性通気性膜
CN107353412B (zh) * 2017-07-14 2020-06-16 昆明理工大学 一种金属有机骨架材料的制备方法及应用
WO2019036140A1 (en) 2017-07-17 2019-02-21 Zymergen Inc. METALLO-ORGANIC STRESS MATERIALS
WO2021220166A1 (en) 2020-04-28 2021-11-04 King Abdullah University Of Science And Technology Electrode separators
CN112958157B (zh) * 2021-02-08 2022-09-30 华侨大学 一种双金属有机骨架材料催化剂、制备方法及应用
CN114653403B (zh) * 2022-03-18 2023-02-03 大连理工大学 一种用于苯酚加氢制环己酮的双功能催化剂的制备方法及应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5601437A (en) 1994-10-17 1997-02-11 Methode Electronics, Inc. Clockspring with centering display device
US5648508A (en) 1995-11-22 1997-07-15 Nalco Chemical Company Crystalline metal-organic microporous materials
AU5777300A (en) * 1999-06-30 2001-01-31 Penn State Research Foundation, The Ligands based on chiral 2-amino-2'-hydroxy-1,1'-binaphthyl and related frameworks for asymmetric catalysis

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WO2003101975A1 (en) 2003-12-11
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DE60315453D1 (de) 2007-09-20
EP1513823B1 (de) 2007-08-08
EP1513823A1 (de) 2005-03-16

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