ATE547439T1 - Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere - Google Patents
Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymereInfo
- Publication number
- ATE547439T1 ATE547439T1 AT07861507T AT07861507T ATE547439T1 AT E547439 T1 ATE547439 T1 AT E547439T1 AT 07861507 T AT07861507 T AT 07861507T AT 07861507 T AT07861507 T AT 07861507T AT E547439 T1 ATE547439 T1 AT E547439T1
- Authority
- AT
- Austria
- Prior art keywords
- metallocene compounds
- catalysts
- ansa metallocene
- olefin
- copolymers
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 2
- FWEOQOXTVHGIFQ-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid Chemical compound C=12C(S(=O)(=O)O)=CC=CC2=CC=CC=1NC1=CC=CC=C1 FWEOQOXTVHGIFQ-UHFFFAOYSA-N 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 229920001577 copolymer Polymers 0.000 title 1
- 229920001519 homopolymer Polymers 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2007/022613 WO2009054831A1 (en) | 2007-10-25 | 2007-10-25 | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE547439T1 true ATE547439T1 (de) | 2012-03-15 |
Family
ID=39561857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07861507T ATE547439T1 (de) | 2007-10-25 | 2007-10-25 | Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8168556B2 (de) |
| EP (1) | EP2203486B9 (de) |
| JP (1) | JP5578473B2 (de) |
| KR (1) | KR101278336B1 (de) |
| CN (1) | CN101910216A (de) |
| AT (1) | ATE547439T1 (de) |
| BR (1) | BRPI0722163A2 (de) |
| MX (1) | MX2010004470A (de) |
| RU (1) | RU2476449C2 (de) |
| WO (1) | WO2009054831A1 (de) |
| ZA (1) | ZA201002873B (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101351103B1 (ko) * | 2008-12-31 | 2014-01-14 | 루머스 노보렌 테크놀로지 게엠베하 | 신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체 |
| EP2532687A3 (de) | 2011-06-10 | 2013-04-10 | Borealis AG | Verbrückte Metallocen-Katalysatoren |
| WO2013168928A1 (ko) | 2012-05-08 | 2013-11-14 | 주식회사 엘지화학 | 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법 |
| CN104918948B (zh) | 2012-12-21 | 2018-09-18 | 博里利斯股份公司 | 催化剂 |
| ES2645256T3 (es) | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| ES2674576T3 (es) | 2012-12-21 | 2018-07-02 | Borealis Ag | Catalizador |
| CN105358586A (zh) | 2013-07-17 | 2016-02-24 | 埃克森美孚化学专利公司 | 环丙基取代的茂金属催化剂 |
| EP3301119B1 (de) | 2013-07-17 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Isotaktische propylenpolymere |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| EP3022235B1 (de) | 2013-07-17 | 2020-04-08 | ExxonMobil Chemical Patents Inc. | Metallocene und katalysatorzusammensetzungen daraus |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| KR101599978B1 (ko) | 2013-09-30 | 2016-03-04 | 주식회사 엘지화학 | 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체 |
| JP6196581B2 (ja) * | 2014-05-21 | 2017-09-13 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＬｕｍｍｕｓ Ｎｏｖｏｌｅｎ Ｔｅｃｈｎｏｌｏｇｙ Ｇｍｂｈ | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
| KR101653356B1 (ko) | 2014-10-17 | 2016-09-01 | 주식회사 엘지화학 | 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법 |
| KR102124102B1 (ko) * | 2015-12-18 | 2020-06-17 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법 |
| KR101712318B1 (ko) * | 2016-04-29 | 2017-03-03 | 한화케미칼 주식회사 | 메탈로센 이성질체 촉매 및 이를 이용하여 제조된 폴리올레핀 수지 |
| US11352376B2 (en) | 2016-11-18 | 2022-06-07 | Borealis Ag | Catalysts |
| KR102618904B1 (ko) | 2016-12-29 | 2023-12-27 | 보레알리스 아게 | 촉매 |
| CN111406078B (zh) * | 2017-11-29 | 2023-03-10 | 埃克森美孚化学专利公司 | 制备具有宽的双峰分子量分布的聚乙烯的催化剂 |
| US10882925B2 (en) | 2017-11-29 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Catalysts that produce polyethylene with broad, bimodal molecular weight distribution |
| KR102343937B1 (ko) | 2017-12-26 | 2021-12-27 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| JP7297782B2 (ja) | 2018-03-19 | 2023-06-26 | ボレアリス エージー | オレフィン重合用触媒 |
| JP7440431B2 (ja) | 2018-06-28 | 2024-02-28 | ボレアリス エージー | 触媒 |
| US11101360B2 (en) * | 2018-11-29 | 2021-08-24 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| EP4036129B1 (de) * | 2021-02-02 | 2023-06-21 | Borealis AG | Folie aus c2c3c4-terpolymer - c3c4-copolymer-gemisch und c2c3c4-terpolymer - c3c4-copolymer-gemisch |
| CN117120489B (zh) | 2021-03-31 | 2026-02-06 | 三井化学株式会社 | 乙烯－α-烯烃共聚物、热塑性树脂组合物、膜和叠层体 |
| US20240191068A1 (en) | 2021-03-31 | 2024-06-13 | Mitsui Chemicals, Inc. | Ethylene resin composition and shaped article |
| JP7681098B2 (ja) | 2021-03-31 | 2025-05-21 | 三井化学株式会社 | エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム |
| WO2025016568A1 (en) * | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| CN120058994A (zh) * | 2023-11-30 | 2025-05-30 | 中石油(上海)新材料研究院有限公司 | 一种茂金属催化剂组合物及其制备方法与应用 |
| CN119350527B (zh) * | 2024-12-26 | 2025-05-06 | 中石油(上海)新材料研究院有限公司 | 一种茂金属催化剂组合物及其制备方法和应用 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3726067A1 (de) | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| JP3394997B2 (ja) | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法 |
| ES2113900T3 (es) * | 1992-06-13 | 1998-05-16 | Targor Gmbh | Proceso para la preparacion de catalizadores de metalocenos quirales, puenteados del tipo bisindenilo. |
| TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| US5449650A (en) | 1992-12-08 | 1995-09-12 | Mitsubishi Petrochemical Company Limited | Catalyst components for polymerization of olefins and use thereof |
| AU683899B2 (en) | 1993-05-25 | 1997-11-27 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
| DE69434709T2 (de) * | 1993-06-07 | 2006-10-19 | Mitsui Chemicals, Inc. | Propylenelastomere |
| US6465384B1 (en) * | 1994-08-02 | 2002-10-15 | The Dow Chemical Company | Biscyclopentadienyl diene complexes |
| IT1275777B1 (it) * | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| EP0859800B1 (de) | 1995-09-28 | 2003-07-23 | Basell Polyolefine GmbH | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| DE19606167A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Geträgerte Katalysatorsysteme |
| DE19622207A1 (de) | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
| US6265339B1 (en) | 1996-07-04 | 2001-07-24 | Basf Aktiengesellschaft | Process for preparing carrier-borne transition metal catalysts |
| EP0824112B1 (de) | 1996-08-13 | 2006-05-10 | Basell Polyolefine GmbH | Geträgerte chemische Verbindung |
| ATE202365T1 (de) | 1996-08-13 | 2001-07-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| DE19741876A1 (de) | 1997-09-23 | 1999-03-25 | Basf Ag | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
| TW476765B (en) | 1997-12-22 | 2002-02-21 | Mitsui Chemicals Inc | Catalyst component for ethylenically unsaturated monomer polymerization, catalyst for ethylenically unsaturated monomer polymerization, and process for ethylenically unsaturated monomer polymerization using said catalyst |
| DE19804970A1 (de) | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| CA2317485A1 (en) * | 1998-11-20 | 2000-06-02 | Montell Technology Company B.V. | Bridged metallocenes, preparation, use in catalytic systems |
| EP1548023B1 (de) | 1999-12-23 | 2013-08-14 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen |
| DE10030638A1 (de) | 2000-06-29 | 2002-01-10 | Basell Polyolefine Gmbh | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
| US6380334B1 (en) * | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| JP2004502699A (ja) * | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス（インデニル）メタロセン化合物 |
| JP2004507553A (ja) * | 2000-08-29 | 2004-03-11 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | アルキル架橋の配位子系及び遷移金属化合物の製造方法 |
| US7157591B2 (en) * | 2001-12-10 | 2007-01-02 | Exxonmobie Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| JP4390770B2 (ja) | 2002-10-25 | 2009-12-24 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | ｒａｃ−ジオルガノシリルビス（２−メチルベンゾ［ｅ］インデニル）ジルコニウム化合物のラセモ選択的合成法 |
| DE10358082A1 (de) * | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| JP2008504331A (ja) * | 2004-07-02 | 2008-02-14 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | アンサ−メタロセンをラセモ選択的に合成する方法 |
| DE102004032277A1 (de) * | 2004-07-02 | 2006-01-19 | Basell Polyolefine Gmbh | Verfahren zur racemoselektiven Synthese von ansa-Metallocenen |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| EP1866322B1 (de) * | 2004-12-16 | 2010-02-24 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung |
| US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
-
2007
- 2007-10-25 KR KR1020107011452A patent/KR101278336B1/ko not_active Expired - Fee Related
- 2007-10-25 JP JP2010530970A patent/JP5578473B2/ja not_active Expired - Fee Related
- 2007-10-25 WO PCT/US2007/022613 patent/WO2009054831A1/en not_active Ceased
- 2007-10-25 RU RU2010120915/04A patent/RU2476449C2/ru not_active IP Right Cessation
- 2007-10-25 BR BRPI0722163-0A patent/BRPI0722163A2/pt not_active IP Right Cessation
- 2007-10-25 MX MX2010004470A patent/MX2010004470A/es active IP Right Grant
- 2007-10-25 US US12/739,347 patent/US8168556B2/en not_active Expired - Fee Related
- 2007-10-25 EP EP07861507A patent/EP2203486B9/de not_active Not-in-force
- 2007-10-25 AT AT07861507T patent/ATE547439T1/de active
- 2007-10-25 CN CN2007801020496A patent/CN101910216A/zh active Pending
-
2010
- 2010-04-23 ZA ZA2010/02873A patent/ZA201002873B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009054831A1 (en) | 2009-04-30 |
| EP2203486A1 (de) | 2010-07-07 |
| CN101910216A (zh) | 2010-12-08 |
| BRPI0722163A2 (pt) | 2014-03-18 |
| EP2203486B9 (de) | 2012-08-01 |
| RU2476449C2 (ru) | 2013-02-27 |
| JP5578473B2 (ja) | 2014-08-27 |
| RU2010120915A (ru) | 2011-11-27 |
| KR20100101093A (ko) | 2010-09-16 |
| EP2203486B1 (de) | 2012-02-29 |
| KR101278336B1 (ko) | 2013-06-25 |
| JP2011502192A (ja) | 2011-01-20 |
| US20100261860A1 (en) | 2010-10-14 |
| ZA201002873B (en) | 2011-06-29 |
| MX2010004470A (es) | 2010-07-28 |
| US8168556B2 (en) | 2012-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE547439T1 (de) | Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere | |
| DE112008000408B8 (de) | Neuartige Verbindung eines Übergangsmetall der vierten Gruppe mit Cyclopentadienyl-Ligand, Verfahren zur Herstellung der Verbindung und Verfahren zur Herstellung von Olefin-Polymer unter Verwendung der Verbindung | |
| ATE501182T1 (de) | Verfahren zur herstellung eines olefinpolymerisationskatalysators | |
| DE102004015356A1 (de) | Phosphorhaltige Flammschutzmittelzusammensetzung für cellulosehaltige Materialien | |
| ATE532630T1 (de) | Harzzusammensetzung für lasergravur, reliefdruckplattenvorläufer für lasergravur, reliefdruckplatte und verfahren zur herstellung der reliefdruckplatte | |
| WO2006135732A3 (en) | System and method for karaoke style ringback tones and karaoke style ringtones | |
| CY1108703T1 (el) | Αλλοστερικοι ρυθμιστες μεταβολοτροπων υποδοχεων γλουταμικου | |
| TW200634035A (en) | Solid titanium catalyst component, catalyst for polymerization of olefin and process for producing olefin polymer | |
| DE602006006558D1 (de) | Verfahren zur verminderung von alpha, beta-ungesättigten ketonen in opioidzusammensetzungen | |
| EP1906239A3 (de) | Positive Resistzusammensetzung und Verfahren zur Strukturformung damit | |
| ATE539054T1 (de) | Verfahren zur herstellung von dihydropyrrolderivaten als zwischenprodukte | |
| DE602007001356D1 (de) | Positive Resistzusammensetzung und Verfahren zur Strukturformung damit | |
| ATE492572T1 (de) | Verfahren zur herstellung von kohlenstoffnanoröhrchen-polymer-mischungen mittels gasphasenpolymerisation | |
| ATE519787T1 (de) | Komponenten und katalysatoren für die polymerisation von olefinen | |
| ATE447588T1 (de) | Komponenten und katalysatoren zur olefinpolymerisation | |
| ATE513801T1 (de) | Verfahren zur synthese von propargylatierten aminoindanderivativen | |
| DE502007002353D1 (de) | Verfahren zur herstellung von cyclischen ketonen | |
| SG149776A1 (en) | Organic metal compound and process for preparing optically-active alcohols using the same | |
| TW200628433A (en) | N-substituted imides as polymerization initiators | |
| TW200643633A (en) | Positive-type photoresist composite for recording medium master disk, manufacturing method for recording medium master disk using the composite, and manufacturing method of stamper | |
| DE602004000069D1 (de) | Fluorinated Acrylic Verbindungen, ihre Herstellungsverfahren und diese enthaltende Photoresistzusammensetzungen | |
| DE502007006121D1 (de) | Elektrochemische herstellung sterisch gehinderter amine | |
| TW200634041A (en) | Composition comprising a hydrogenated bisglycidyl ether and a crosslinker | |
| DE602005024773D1 (de) | Isotaktisches 3,4-isopren-polymer | |
| ATE526312T1 (de) | Verfahren zur herstellung von reinen 4- pyrrolidinophenylbenzyletherderivaten als maob- inhibitoren |