ATE547439T1 - Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere - Google Patents
Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymereInfo
- Publication number
- ATE547439T1 ATE547439T1 AT07861507T AT07861507T ATE547439T1 AT E547439 T1 ATE547439 T1 AT E547439T1 AT 07861507 T AT07861507 T AT 07861507T AT 07861507 T AT07861507 T AT 07861507T AT E547439 T1 ATE547439 T1 AT E547439T1
- Authority
- AT
- Austria
- Prior art keywords
- metallocene compounds
- catalysts
- ansa metallocene
- olefin
- copolymers
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 2
- FWEOQOXTVHGIFQ-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid Chemical compound C=12C(S(=O)(=O)O)=CC=CC2=CC=CC=1NC1=CC=CC=C1 FWEOQOXTVHGIFQ-UHFFFAOYSA-N 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 229920001577 copolymer Polymers 0.000 title 1
- 229920001519 homopolymer Polymers 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2007/022613 WO2009054831A1 (en) | 2007-10-25 | 2007-10-25 | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE547439T1 true ATE547439T1 (de) | 2012-03-15 |
Family
ID=39561857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07861507T ATE547439T1 (de) | 2007-10-25 | 2007-10-25 | Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8168556B2 (de) |
| EP (1) | EP2203486B9 (de) |
| JP (1) | JP5578473B2 (de) |
| KR (1) | KR101278336B1 (de) |
| CN (1) | CN101910216A (de) |
| AT (1) | ATE547439T1 (de) |
| BR (1) | BRPI0722163A2 (de) |
| MX (1) | MX2010004470A (de) |
| RU (1) | RU2476449C2 (de) |
| WO (1) | WO2009054831A1 (de) |
| ZA (1) | ZA201002873B (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0823407A2 (pt) * | 2008-12-31 | 2015-06-16 | Lummus Novolen Technology Gmbh | Novos compostos de metaloceno, catalisadores que os compreendem, processo para produção de um polímero de olefina por uso dos catalisadores e homo- e copolímeros de olefina |
| EP2532687A3 (de) | 2011-06-10 | 2013-04-10 | Borealis AG | Verbrückte Metallocen-Katalysatoren |
| US9284386B2 (en) | 2012-05-08 | 2016-03-15 | Lg Chem, Ltd. | Ansa-metallocene compound and method for preparing supported catalyst using the same |
| ES2674576T3 (es) | 2012-12-21 | 2018-07-02 | Borealis Ag | Catalizador |
| ES2645256T3 (es) | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| EP3301098B1 (de) | 2012-12-21 | 2020-02-19 | Borealis AG | Verfahren zur herstellung eines liganden für ein katalysator |
| EP3022236B1 (de) | 2013-07-17 | 2017-11-15 | ExxonMobil Chemical Patents Inc. | Verfahren mit substituierten metallocenkatalysatoren und produkte daraus |
| US9249239B2 (en) | 2013-07-17 | 2016-02-02 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| SG10201802959WA (en) | 2013-07-17 | 2018-05-30 | Exxonmobil Chemical Patents Inc | Cyclopropyl substituted metallocene catalysts |
| EP3034523B1 (de) | 2013-09-30 | 2021-07-07 | LG Chem, Ltd. | Verfahren zur herstellung von propylen-1-buten-copolymer |
| JP6196581B2 (ja) * | 2014-05-21 | 2017-09-13 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＬｕｍｍｕｓ Ｎｏｖｏｌｅｎ Ｔｅｃｈｎｏｌｏｇｙ Ｇｍｂｈ | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
| KR101653356B1 (ko) | 2014-10-17 | 2016-09-01 | 주식회사 엘지화학 | 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법 |
| KR102124102B1 (ko) * | 2015-12-18 | 2020-06-17 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법 |
| KR101712318B1 (ko) * | 2016-04-29 | 2017-03-03 | 한화케미칼 주식회사 | 메탈로센 이성질체 촉매 및 이를 이용하여 제조된 폴리올레핀 수지 |
| CN110177798B (zh) | 2016-11-18 | 2022-08-30 | 博里利斯股份公司 | 催化剂 |
| US11807655B2 (en) | 2016-12-29 | 2023-11-07 | Borealis Ag | Catalysts |
| US10882925B2 (en) | 2017-11-29 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Catalysts that produce polyethylene with broad, bimodal molecular weight distribution |
| WO2019108408A1 (en) * | 2017-11-29 | 2019-06-06 | Exxonmobil Chemical Patents Inc. | Catalysts that produce polyethylene with broad, bimodal molecular weight distribution |
| KR102343937B1 (ko) | 2017-12-26 | 2021-12-27 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| JP7297782B2 (ja) | 2018-03-19 | 2023-06-26 | ボレアリス エージー | オレフィン重合用触媒 |
| CN112424241B (zh) | 2018-06-28 | 2023-06-06 | 博里利斯股份公司 | 催化剂 |
| US11101360B2 (en) * | 2018-11-29 | 2021-08-24 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| PT4036129T (pt) * | 2021-02-02 | 2023-09-11 | Borealis Ag | Película feita a partir de mistura de terpolímero c2c3c4 - copolímero c3c4 e mistura de terpolímero c2c3c4 - copolímero c3c4 |
| US20240191011A1 (en) | 2021-03-31 | 2024-06-13 | Mitsui Chemicals, Inc. | ETHYLENE-alpha-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, AND FILM |
| CN117083336B (zh) | 2021-03-31 | 2026-02-06 | 三井化学株式会社 | 乙烯系树脂组合物和成型体 |
| JP7681097B2 (ja) | 2021-03-31 | 2025-05-21 | 三井化学株式会社 | エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、フィルムおよび積層体 |
| EP4743472A1 (de) * | 2023-07-14 | 2026-05-20 | Borealis GmbH | Metallocene zur herstellung von polypropylen |
| CN120058994A (zh) * | 2023-11-30 | 2025-05-30 | 中石油(上海)新材料研究院有限公司 | 一种茂金属催化剂组合物及其制备方法与应用 |
| CN119350527B (zh) * | 2024-12-26 | 2025-05-06 | 中石油(上海)新材料研究院有限公司 | 一种茂金属催化剂组合物及其制备方法和应用 |
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| DE3726067A1 (de) | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| DE59210001D1 (de) | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| DE69224184T2 (de) * | 1992-06-13 | 1999-06-02 | Targor GmbH, 55116 Mainz | Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl |
| TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| US5449650A (en) | 1992-12-08 | 1995-09-12 | Mitsubishi Petrochemical Company Limited | Catalyst components for polymerization of olefins and use thereof |
| DE69408989T2 (de) | 1993-05-25 | 1998-11-05 | Exxon Chemical Patents Inc | Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung |
| DE69431222T2 (de) * | 1993-06-07 | 2003-04-17 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator |
| US6465384B1 (en) * | 1994-08-02 | 2002-10-15 | The Dow Chemical Company | Biscyclopentadienyl diene complexes |
| IT1275777B1 (it) * | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| CA2241812A1 (en) | 1995-09-28 | 1997-04-03 | Cornelia Fritze | Supported catalyst system, process for its production and its use in polymerising olefines |
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| DE19622207A1 (de) | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
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| ATE202365T1 (de) | 1996-08-13 | 2001-07-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| ATE325821T1 (de) | 1996-08-13 | 2006-06-15 | Basell Polyolefine Gmbh | Geträgerte chemische verbindung |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| DE19741876A1 (de) | 1997-09-23 | 1999-03-25 | Basf Ag | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
| EP0924223B1 (de) | 1997-12-22 | 2004-05-19 | Mitsui Chemicals, Inc. | Katalysatorbestandteil, Katalysator und Verfahren zur Polymerisation von äthylenisch ungesättigten Monomeren |
| DE19804970A1 (de) | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| EP1049704B1 (de) * | 1998-11-20 | 2005-07-27 | Basell Polyolefine GmbH | Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator |
| CN1590422A (zh) | 1999-12-23 | 2005-03-09 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物，配体体系，催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
| DE10030638A1 (de) | 2000-06-29 | 2002-01-10 | Basell Polyolefine Gmbh | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
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| DE50105968D1 (de) | 2000-08-29 | 2005-05-25 | Basell Polyolefine Gmbh | VERFAHREN ZUR HERSTELLUNG VON AlKYLVERBRÜCKTEN LIGANDSYSTEMEN UND ÜBERGANGSMETALLVERBINDUNGEN |
| US7157591B2 (en) * | 2001-12-10 | 2007-01-02 | Exxonmobie Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US7098354B2 (en) | 2002-10-25 | 2006-08-29 | Basell Polyolefine Gmbh | Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl)zirconium compounds |
| DE10358082A1 (de) * | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| DE102004032277A1 (de) * | 2004-07-02 | 2006-01-19 | Basell Polyolefine Gmbh | Verfahren zur racemoselektiven Synthese von ansa-Metallocenen |
| JP2008504331A (ja) * | 2004-07-02 | 2008-02-14 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | アンサ−メタロセンをラセモ選択的に合成する方法 |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| WO2006065809A2 (en) * | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Heteroatom bridged metallocene compounds for olefin polymerization |
| US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
-
2007
- 2007-10-25 JP JP2010530970A patent/JP5578473B2/ja not_active Expired - Fee Related
- 2007-10-25 US US12/739,347 patent/US8168556B2/en not_active Expired - Fee Related
- 2007-10-25 RU RU2010120915/04A patent/RU2476449C2/ru not_active IP Right Cessation
- 2007-10-25 CN CN2007801020496A patent/CN101910216A/zh active Pending
- 2007-10-25 EP EP07861507A patent/EP2203486B9/de not_active Not-in-force
- 2007-10-25 KR KR1020107011452A patent/KR101278336B1/ko not_active Expired - Fee Related
- 2007-10-25 AT AT07861507T patent/ATE547439T1/de active
- 2007-10-25 WO PCT/US2007/022613 patent/WO2009054831A1/en not_active Ceased
- 2007-10-25 MX MX2010004470A patent/MX2010004470A/es active IP Right Grant
- 2007-10-25 BR BRPI0722163-0A patent/BRPI0722163A2/pt not_active IP Right Cessation
-
2010
- 2010-04-23 ZA ZA2010/02873A patent/ZA201002873B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2203486B9 (de) | 2012-08-01 |
| KR20100101093A (ko) | 2010-09-16 |
| RU2010120915A (ru) | 2011-11-27 |
| JP5578473B2 (ja) | 2014-08-27 |
| BRPI0722163A2 (pt) | 2014-03-18 |
| CN101910216A (zh) | 2010-12-08 |
| WO2009054831A1 (en) | 2009-04-30 |
| MX2010004470A (es) | 2010-07-28 |
| JP2011502192A (ja) | 2011-01-20 |
| RU2476449C2 (ru) | 2013-02-27 |
| EP2203486A1 (de) | 2010-07-07 |
| US20100261860A1 (en) | 2010-10-14 |
| KR101278336B1 (ko) | 2013-06-25 |
| US8168556B2 (en) | 2012-05-01 |
| EP2203486B1 (de) | 2012-02-29 |
| ZA201002873B (en) | 2011-06-29 |
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