AU621977B2 - Improved method of lubricating iron and steel before cold working - Google Patents

Improved method of lubricating iron and steel before cold working Download PDF

Info

Publication number: AU621977B2
Authority: AU; Australia
Prior art keywords: ions; sulfonic acid; process according; phosphating; phosphate
Prior art date: 1989-01-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU48736/90A

Other languages

English (en)

Other versions

AU4873690A (en

Inventor

Yoshio Nagae

Yasuo Okumura

Yoshihiko Sawasaki

Yasuo Tanizawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel Corp

Original Assignee

Henkel Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-01-26

Filing date

1990-01-25

Publication date

1992-03-26

1990-01-25 Application filed by Henkel Corp filed Critical Henkel Corp

1990-08-02 Publication of AU4873690A publication Critical patent/AU4873690A/en

1992-03-26 Application granted granted Critical

1992-03-26 Publication of AU621977B2 publication Critical patent/AU621977B2/en

2010-01-25 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 38
238000000034 method Methods 0.000 title claims description 25
229910052742 iron Inorganic materials 0.000 title claims description 18
229910000831 Steel Inorganic materials 0.000 title claims description 11
239000010959 steel Substances 0.000 title claims description 11
230000001050 lubricating effect Effects 0.000 title claims description 10
238000005482 strain hardening Methods 0.000 title description 14
239000000243 solution Substances 0.000 claims description 43
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 30
229910019142 PO4 Inorganic materials 0.000 claims description 27
239000010452 phosphate Substances 0.000 claims description 26
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 24
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 21
-1 nitrate ions Chemical class 0.000 claims description 21
229910001448 ferrous ion Inorganic materials 0.000 claims description 19
230000008569 process Effects 0.000 claims description 12
229910001424 calcium ion Inorganic materials 0.000 claims description 10
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 6
LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 5
JIAMRSLGASIQPE-UHFFFAOYSA-N 1,6-dimethyl-5-nitrocyclohexa-2,4-diene-1-sulfonic acid Chemical compound [N+](=O)([O-])C=1C(C(C=CC1)(C)S(=O)(=O)O)C JIAMRSLGASIQPE-UHFFFAOYSA-N 0.000 claims description 3
HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 claims description 3
229910002651 NO3 Inorganic materials 0.000 claims description 3
IZJVVXCHJIQVOL-UHFFFAOYSA-N nitro(phenyl)methanesulfonic acid Chemical compound OS(=O)(=O)C([N+]([O-])=O)C1=CC=CC=C1 IZJVVXCHJIQVOL-UHFFFAOYSA-N 0.000 claims description 3
CUYDQRGVPLSZQI-UHFFFAOYSA-N nitro(phenyl)sulfamic acid Chemical compound OS(=O)(=O)N([N+]([O-])=O)C1=CC=CC=C1 CUYDQRGVPLSZQI-UHFFFAOYSA-N 0.000 claims description 3
229920006395 saturated elastomer Polymers 0.000 claims description 3
235000010288 sodium nitrite Nutrition 0.000 claims description 3
239000002253 acid Substances 0.000 claims description 2
150000007513 acids Chemical class 0.000 claims description 2
229910021538 borax Inorganic materials 0.000 claims description 2
230000006872 improvement Effects 0.000 claims description 2
239000000463 material Substances 0.000 claims description 2
235000010339 sodium tetraborate Nutrition 0.000 claims description 2
150000008054 sulfonate salts Chemical class 0.000 claims description 2
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
125000003118 aryl group Chemical group 0.000 claims 2
239000007864 aqueous solution Substances 0.000 claims 1
125000004432 carbon atom Chemical group C* 0.000 claims 1
235000003441 saturated fatty acids Nutrition 0.000 claims 1
150000004671 saturated fatty acids Chemical class 0.000 claims 1
125000000542 sulfonic acid group Chemical group 0.000 claims 1
235000021122 unsaturated fatty acids Nutrition 0.000 claims 1
150000004670 unsaturated fatty acids Chemical class 0.000 claims 1
238000011282 treatment Methods 0.000 description 43
239000011701 zinc Substances 0.000 description 18
239000000314 lubricant Substances 0.000 description 15
230000015572 biosynthetic process Effects 0.000 description 14
238000000576 coating method Methods 0.000 description 14
239000011248 coating agent Substances 0.000 description 13
150000002500 ions Chemical class 0.000 description 13
238000012360 testing method Methods 0.000 description 11
239000002585 base Substances 0.000 description 9
239000013078 crystal Substances 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 9
239000002184 metal Substances 0.000 description 9
239000000344 soap Substances 0.000 description 8
239000011575 calcium Substances 0.000 description 7
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
238000005461 lubrication Methods 0.000 description 6
239000010802 sludge Substances 0.000 description 6
229910000165 zinc phosphate Inorganic materials 0.000 description 6
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
229910052791 calcium Inorganic materials 0.000 description 5
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 5
229910052725 zinc Inorganic materials 0.000 description 5
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
150000001491 aromatic compounds Chemical class 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
238000007654 immersion Methods 0.000 description 4
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
239000002738 chelating agent Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000470 constituent Substances 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229940085991 phosphate ion Drugs 0.000 description 3
229910052827 phosphophyllite Inorganic materials 0.000 description 3
230000009467 reduction Effects 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
239000005069 Extreme pressure additive Substances 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000007598 dipping method Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
239000008149 soap solution Substances 0.000 description 2
SPDJAIKMJHJYAV-UHFFFAOYSA-H trizinc;diphosphate;tetrahydrate Chemical compound O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SPDJAIKMJHJYAV-UHFFFAOYSA-H 0.000 description 2
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
FVHAWXWFPBPFOS-UHFFFAOYSA-N 1,2-dimethyl-3-nitrobenzene Chemical group CC1=CC=CC([N+]([O-])=O)=C1C FVHAWXWFPBPFOS-UHFFFAOYSA-N 0.000 description 1
102100033646 40-kDa huntingtin-associated protein Human genes 0.000 description 1
229910000851 Alloy steel Inorganic materials 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229910000975 Carbon steel Inorganic materials 0.000 description 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
101000871817 Homo sapiens 40-kDa huntingtin-associated protein Proteins 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
229910001315 Tool steel Inorganic materials 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
AWUCVROLDVIAJX-UHFFFAOYSA-N alpha-glycerophosphate Natural products OCC(O)COP(O)(O)=O AWUCVROLDVIAJX-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
238000010273 cold forging Methods 0.000 description 1
238000007739 conversion coating Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
229910001447 ferric ion Inorganic materials 0.000 description 1
238000005242 forging Methods 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011796 hollow space material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229940005654 nitrite ion Drugs 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
102220062469 rs786203185 Human genes 0.000 description 1
AWUCVROLDVIAJX-GSVOUGTGSA-N sn-glycerol 3-phosphate Chemical compound OC[C@@H](O)COP(O)(O)=O AWUCVROLDVIAJX-GSVOUGTGSA-N 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
239000002436 steel type Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
238000010998 test method Methods 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Treatment Of Metals (AREA)
Lubricants (AREA)

AU48736/90A 1989-01-26 1990-01-25 Improved method of lubricating iron and steel before cold working Ceased AU621977B2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP1-15128		1989-01-26
JP1015128A JP2636919B2 (ja)	1989-01-26	1989-01-26	鉄鋼の冷間塑性加工用潤滑処理方法

Publications (2)

Publication Number	Publication Date
AU4873690A AU4873690A (en)	1990-08-02
AU621977B2 true AU621977B2 (en)	1992-03-26

Family

ID=11880186

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU48736/90A Ceased AU621977B2 (en)	1989-01-26	1990-01-25	Improved method of lubricating iron and steel before cold working

Country Status (11)

Country	Link
EP (1)	EP0380067B1 (de)
JP (1)	JP2636919B2 (de)
AR (1)	AR244117A1 (de)
AT (1)	ATE89875T1 (de)
AU (1)	AU621977B2 (de)
BR (1)	BR9000328A (de)
CA (1)	CA2008551A1 (de)
DE (1)	DE69001680T2 (de)
DK (1)	DK0380067T3 (de)
ES (1)	ES2042082T3 (de)
ZA (1)	ZA90305B (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1995007370A1 (de) *	1993-09-06	1995-03-16	Henkel Kommanditgesellschaft Auf Aktien	Nickelfreies phosphatierverfahren
CN115980111A (zh) *	2022-12-23	2023-04-18	首钢集团有限公司	一种磷化膜膜重的检测方法
CN121629379A (zh) *	2026-02-04	2026-03-10	长春设备工艺研究所	一种火炮身管的无槽式外壁喷淋发黑连续处理方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU575380B2 (en) *	1984-03-09	1988-07-28	Metallgesellschaft Aktiengesellschaft	Zinc accelerated acidic phosphating spray process
GB2204067A (en) *	1987-04-11	1988-11-02	Ardrox Pyrene Ltd	A process for phosphating steel or galvanized steel prior to electro-immersion painting
AU592671B2 (en) *	1986-09-26	1990-01-18	Ppg Industries Ohio, Inc.	Phosphate coating composition and method of applying a zinc-nickel phosphate coating

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6020463B2 (ja) *	1982-06-04	1985-05-22	日本パ−カライジング株式会社	鉄鋼材の冷間加工潤滑処理方法
DE3407513A1 (de) *	1984-03-01	1985-09-05	Gerhard Collardin GmbH, 5000 Köln	Verfahren zur zink-calcium-phosphatierung von metalloberflaechen bei niedriger behandlungstemperatur

1989
- 1989-01-26 JP JP1015128A patent/JP2636919B2/ja not_active Expired - Lifetime
1990
- 1990-01-16 ZA ZA90305A patent/ZA90305B/xx unknown
- 1990-01-24 DK DK90101350.8T patent/DK0380067T3/da active
- 1990-01-24 EP EP90101350A patent/EP0380067B1/de not_active Expired - Lifetime
- 1990-01-24 DE DE90101350T patent/DE69001680T2/de not_active Expired - Fee Related
- 1990-01-24 AT AT90101350T patent/ATE89875T1/de active
- 1990-01-24 ES ES199090101350T patent/ES2042082T3/es not_active Expired - Lifetime
- 1990-01-25 AR AR90316014A patent/AR244117A1/es active
- 1990-01-25 BR BR909000328A patent/BR9000328A/pt not_active Application Discontinuation
- 1990-01-25 AU AU48736/90A patent/AU621977B2/en not_active Ceased
- 1990-01-25 CA CA002008551A patent/CA2008551A1/en not_active Abandoned

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU575380B2 (en) *	1984-03-09	1988-07-28	Metallgesellschaft Aktiengesellschaft	Zinc accelerated acidic phosphating spray process
AU592671B2 (en) *	1986-09-26	1990-01-18	Ppg Industries Ohio, Inc.	Phosphate coating composition and method of applying a zinc-nickel phosphate coating
GB2204067A (en) *	1987-04-11	1988-11-02	Ardrox Pyrene Ltd	A process for phosphating steel or galvanized steel prior to electro-immersion painting

Also Published As

Publication number	Publication date
EP0380067B1 (de)	1993-05-26
DE69001680D1 (de)	1993-07-01
JPH02197581A (ja)	1990-08-06
AR244117A1 (es)	1993-10-29
DE69001680T2 (de)	1993-09-30
ZA90305B (en)	1991-03-27
ES2042082T3 (es)	1993-12-01
BR9000328A (pt)	1990-11-27
AU4873690A (en)	1990-08-02
EP0380067A1 (de)	1990-08-01
DK0380067T3 (da)	1993-06-21
CA2008551A1 (en)	1990-07-26
JP2636919B2 (ja)	1997-08-06
ATE89875T1 (de)	1993-06-15

Publication	Publication Date	Title
CA1198655A (en)	1985-12-31	Process for the cold forming of iron and steel
AU604395B2 (en)	1990-12-13	Process for phosphating metal surfaces
EP1988189B1 (de)	2014-03-12	Verfahren zur herstellung feuerverzinkter stahlbleche mit zinkphosphatüberzug
EP0412788A1 (de)	1991-02-13	Schmierverfahren zur plastischen Bearbeitung metallischer Materialien
JPH0355204B2 (de)	1991-08-22
JPH0465151B2 (de)	1992-10-19
AU621977B2 (en)	1992-03-26	Improved method of lubricating iron and steel before cold working
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