BE879012A - Procede de preparation de dibenzylidene-sorbitol et composition en contenant - Google Patents

Procede de preparation de dibenzylidene-sorbitol et composition en contenant Download PDF

Info

Publication number: BE879012A
Authority: BE; Belgium
Prior art keywords: emi; reaction; sorbitol; stage; weight
Prior art date: 1978-11-29

Application number

BE197326A

Other languages

English (en)

French (fr)

Original Assignee

Ec Chemical Ind Co Ltd

Itoh C & Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-29

Filing date

1979-09-26

Publication date

1980-01-16

1979-09-26 Application filed by Ec Chemical Ind Co Ltd, Itoh C & Co Ltd filed Critical Ec Chemical Ind Co Ltd

1980-01-16 Publication of BE879012A publication Critical patent/BE879012A/fr

Links

239000000203 mixture Substances 0.000 title claims description 26
FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 title claims description 9
229940087101 dibenzylidene sorbitol Drugs 0.000 title claims description 9
238000004519 manufacturing process Methods 0.000 title description 3
238000006243 chemical reaction Methods 0.000 claims description 83
238000000034 method Methods 0.000 claims description 25
239000000600 sorbitol Substances 0.000 claims description 25
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 22
HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 18
230000008569 process Effects 0.000 claims description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
239000003377 acid catalyst Substances 0.000 claims description 12
230000008602 contraction Effects 0.000 claims description 10
239000000725 suspension Substances 0.000 claims description 10
239000006227 byproduct Substances 0.000 claims description 9
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 9
-1 polyethylene Polymers 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 7
229920000642 polymer Polymers 0.000 claims description 7
239000000047 product Substances 0.000 claims description 7
239000012431 aqueous reaction media Substances 0.000 claims description 6
238000010438 heat treatment Methods 0.000 claims description 5
238000001746 injection moulding Methods 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
230000005070 ripening Effects 0.000 claims description 4
230000007704 transition Effects 0.000 claims description 4
239000004698 Polyethylene Substances 0.000 claims description 3
229920000573 polyethylene Polymers 0.000 claims description 3
239000000470 constituent Substances 0.000 claims description 2
238000002347 injection Methods 0.000 claims description 2
239000007924 injection Substances 0.000 claims description 2
239000008188 pellet Substances 0.000 claims description 2
JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 claims 1
239000000376 reactant Substances 0.000 claims 1
229960002920 sorbitol Drugs 0.000 description 21
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 19
239000007864 aqueous solution Substances 0.000 description 12
229920000098 polyolefin Polymers 0.000 description 11
238000000465 moulding Methods 0.000 description 7
239000007795 chemical reaction product Substances 0.000 description 6
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000000654 additive Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
230000006872 improvement Effects 0.000 description 2
230000000977 initiatory effect Effects 0.000 description 2
239000002609 medium Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
229920005672 polyolefin resin Polymers 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000011342 resin composition Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
HZVFRKSYUGFFEJ-YVECIDJPSA-N (2r,3r,4s,5r)-7-phenylhept-6-ene-1,2,3,4,5,6-hexol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=CC1=CC=CC=C1 HZVFRKSYUGFFEJ-YVECIDJPSA-N 0.000 description 1
MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
229920003355 Novatec® Polymers 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
210000001124 body fluid Anatomy 0.000 description 1
239000010839 body fluid Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000008395 clarifying agent Substances 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
AOVGTXWIQWMZGB-UHFFFAOYSA-N cyclohexane-1,2-dicarbaldehyde Chemical compound O=CC1CCCCC1C=O AOVGTXWIQWMZGB-UHFFFAOYSA-N 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000003349 gelling agent Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
RLAWWYSOJDYHDC-BZSNNMDCSA-N lisinopril Chemical compound C([C@H](N[C@@H](CCCCN)C(=O)N1[C@@H](CCC1)C(O)=O)C(O)=O)CC1=CC=CC=C1 RLAWWYSOJDYHDC-BZSNNMDCSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000306 polymethylpentene Polymers 0.000 description 1
239000011116 polymethylpentene Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

BE197326A 1978-11-29 1979-09-26 Procede de preparation de dibenzylidene-sorbitol et composition en contenant BE879012A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP14658778A JPS5573683A (en)	1978-11-29	1978-11-29	Preparation of dibenzylidenesorbitol

Publications (1)

Publication Number	Publication Date
BE879012A true BE879012A (fr)	1980-01-16

Family

ID=15411076

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BE197326A BE879012A (fr)	1978-11-29	1979-09-26	Procede de preparation de dibenzylidene-sorbitol et composition en contenant

Country Status (2)

Country	Link
JP (1)	JPS5573683A (de)
BE (1)	BE879012A (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5718682A (en) *	1980-07-08	1982-01-30	Mitsui Toatsu Chem Inc	Preparation of bis p-ethylbenzylidene sorbitol
JPS57147532A (en) *	1981-03-09	1982-09-11	New Japan Chem Co Ltd	Modifying method of molded polyethylene and polypropylene
JPS57185288A (en) *	1981-05-11	1982-11-15	Mitsui Toatsu Chem Inc	Preparation of bis(alkylbenzylidene)sorbitol
JP5426120B2 (ja) *	2008-08-06	2014-02-26	南海化学株式会社	ジベンジリデンアルジトール類の製造方法

1978
- 1978-11-29 JP JP14658778A patent/JPS5573683A/ja active Granted
1979
- 1979-09-26 BE BE197326A patent/BE879012A/fr unknown

Also Published As

Publication number	Publication date
JPS5573683A (en)	1980-06-03
JPS6117833B2 (de)	1986-05-09

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