BR0010277A - Compostos metalocênicos heterocìclicos e seu uso em sistemas catalìticos para a produção de polìmeros olefìnicos - Google Patents

Compostos metalocênicos heterocìclicos e seu uso em sistemas catalìticos para a produção de polìmeros olefìnicos

Info

Publication number
BR0010277A
BR0010277A BR0010277-6A BR0010277A BR0010277A BR 0010277 A BR0010277 A BR 0010277A BR 0010277 A BR0010277 A BR 0010277A BR 0010277 A BR0010277 A BR 0010277A
Authority
BR
Brazil
Prior art keywords
chosen
production
hydrogen
catalytic systems
hydrocarbon groups
Prior art date
Application number
BR0010277-6A
Other languages
English (en)
Inventor
Ilya E Nifant Ev
Simona Guidotti
Luigi Resconi
Ilya P Laishevtsev
Original Assignee
Basell Technology Co Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co Bv filed Critical Basell Technology Co Bv
Publication of BR0010277A publication Critical patent/BR0010277A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"COMPOSTOS METALOCêNICOS HETEROCìCLICOS E SEU USO EM SISTEMAS CATALìTICOS PARA A PRODUçãO DE POLìMEROS OLEFìNICOS". 0 presente invento diz respeito a compostos metalocênicos de fórmula geral (I) LGZMX~ P~ em que L é um grupo divalente, Z é uma metade de fórmula (II): em que R^ 3^ e R^ 4^ são escolhidos dentre hidrogênio e grupos hidrocarboneto; A e B são escolhidos dentre S, O ou CR^ 5^, em que R^ 5^ é escolhido dentre hidrogênio e grupos hidrocarboneto, A ou B sendo diferentes de CR^ 5^; G é uma metade de fórmula (III): em que R^ 6^, R^ 7^, R^ 8^ e R^ 9^ são escolhidos dentre hidrogênio e grupos hidrocarboneto; M é um átomo de um metal de transição; X é escolhido dentre um átomo de halogênio, um grupo R^ 10^, OR^ 10^, OSO~ 2~CF~ 3~, OCOR^ 10^, SR^ 10^, NR^ 10^~ 2~, em que os substituintes R^ 10^ escolhidos dentre hidrogênio e grupos hidrocarboneto; p é um inteiro de 0 a 3.
BR0010277-6A 1999-12-28 2000-12-22 Compostos metalocênicos heterocìclicos e seu uso em sistemas catalìticos para a produção de polìmeros olefìnicos BR0010277A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99204567 1999-12-28
PCT/EP2000/013191 WO2001047939A1 (en) 1999-12-28 2000-12-22 Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers

Publications (1)

Publication Number Publication Date
BR0010277A true BR0010277A (pt) 2002-01-15

Family

ID=8241115

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0010277-6A BR0010277A (pt) 1999-12-28 2000-12-22 Compostos metalocênicos heterocìclicos e seu uso em sistemas catalìticos para a produção de polìmeros olefìnicos

Country Status (14)

Country Link
US (1) US7112638B2 (pt)
EP (2) EP1157027B1 (pt)
JP (1) JP4358470B2 (pt)
KR (1) KR100723853B1 (pt)
CN (1) CN1280300C (pt)
AR (1) AR027125A1 (pt)
AT (2) ATE508135T1 (pt)
AU (1) AU783097B2 (pt)
BR (1) BR0010277A (pt)
CA (1) CA2363265A1 (pt)
DE (2) DE60036459D1 (pt)
RU (1) RU2243229C2 (pt)
WO (1) WO2001047939A1 (pt)
ZA (1) ZA200106825B (pt)

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RU2243229C2 (ru) 2004-12-27
WO2001047939A1 (en) 2001-07-05
ATE508135T1 (de) 2011-05-15
AU783097B2 (en) 2005-09-22
JP4358470B2 (ja) 2009-11-04
DE60036459D1 (de) 2007-10-31
EP1157027B1 (en) 2007-09-19
AU2843301A (en) 2001-07-09
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US7112638B2 (en) 2006-09-26
ZA200106825B (en) 2002-11-18
EP1854804B1 (en) 2011-05-04
ATE373669T1 (de) 2007-10-15
KR100723853B1 (ko) 2007-05-31
JP2003519156A (ja) 2003-06-17
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EP1854804A1 (en) 2007-11-14
US20030036612A1 (en) 2003-02-20
KR20010108278A (ko) 2001-12-07
CN1348459A (zh) 2002-05-08
CA2363265A1 (en) 2001-07-05
AR027125A1 (es) 2003-03-12

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