ATE373669T1 - Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren - Google Patents

Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren

Info

Publication number
ATE373669T1
ATE373669T1 AT00993614T AT00993614T ATE373669T1 AT E373669 T1 ATE373669 T1 AT E373669T1 AT 00993614 T AT00993614 T AT 00993614T AT 00993614 T AT00993614 T AT 00993614T AT E373669 T1 ATE373669 T1 AT E373669T1
Authority
AT
Austria
Prior art keywords
catalyst systems
olefin polymers
producing olefin
heterocyclic metallocenes
metallocenes
Prior art date
Application number
AT00993614T
Other languages
English (en)
Inventor
Ev Ilya E Nifant
Simona Guidotti
Luigi Resconi
Ilya P Laishevtsev
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE373669T1 publication Critical patent/ATE373669T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT00993614T 1999-12-28 2000-12-22 Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren ATE373669T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP99204567 1999-12-28

Publications (1)

Publication Number Publication Date
ATE373669T1 true ATE373669T1 (de) 2007-10-15

Family

ID=8241115

Family Applications (2)

Application Number Title Priority Date Filing Date
AT07115467T ATE508135T1 (de) 1999-12-28 2000-12-22 Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren
AT00993614T ATE373669T1 (de) 1999-12-28 2000-12-22 Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren

Family Applications Before (1)

Application Number Title Priority Date Filing Date
AT07115467T ATE508135T1 (de) 1999-12-28 2000-12-22 Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren

Country Status (14)

Country Link
US (1) US7112638B2 (de)
EP (2) EP1854804B1 (de)
JP (1) JP4358470B2 (de)
KR (1) KR100723853B1 (de)
CN (1) CN1280300C (de)
AR (1) AR027125A1 (de)
AT (2) ATE508135T1 (de)
AU (1) AU783097B2 (de)
BR (1) BR0010277A (de)
CA (1) CA2363265A1 (de)
DE (2) DE60045930D1 (de)
RU (1) RU2243229C2 (de)
WO (1) WO2001047939A1 (de)
ZA (1) ZA200106825B (de)

Families Citing this family (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3538601A (en) * 1999-12-28 2001-07-09 Basell Technology Company B.V. Process for the preparation of ethylene polymers
WO2001048039A2 (en) * 1999-12-28 2001-07-05 Basell Technology Company B.V. Process for the preparation of ethylene polymers
ATE430753T1 (de) 2000-01-18 2009-05-15 Basell Polyolefine Gmbh Ligand für einen metallocenkatalysator für die polymerisation von propylen und dessen herstellungsverfahren
ES2223832T3 (es) 2000-03-22 2005-03-01 Basell Polyolefine Gmbh Procedimiento para la preparacion de composiciones termoplasticas de propileno isotactico y polipropileno flexible de isotacticidad inferior.
WO2002092564A2 (en) 2001-05-15 2002-11-21 Basell Polyolefine Gmbh Synthesis of cyclopentadiene derivatives
EP1397371B1 (de) 2001-06-22 2006-03-22 Basell Polyolefine GmbH Metallocene, verwendung in katalysatoren für olefinpolymerisation
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
EP1446430B1 (de) 2001-11-12 2007-02-07 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-buten und 1-buten polymeren
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
WO2003070778A1 (en) * 2002-02-25 2003-08-28 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
KR100921365B1 (ko) 2002-06-26 2009-10-15 바셀 폴리올레핀 이탈리아 에스.알.엘 내충격성 폴리올레핀 조성물
MXPA04012699A (es) * 2002-06-26 2005-03-23 Basell Poliolefine Spa Composiciones de poliolefina resistentes a impactos.
JP2006509064A (ja) * 2002-12-04 2006-03-16 バセル ポリオレフィン ジーエムビーエイチ 1−ブテンコポリマー類およびそれらの製造方法
DE10260095A1 (de) * 2002-12-19 2004-07-01 Basell Polyolefine Gmbh Verfahren zur Herstellung von heterocyclischen Ketonen
DE10303225A1 (de) * 2003-01-28 2004-08-05 Inventis Technologies Gmbh Katalysatorkombination, isotaktische Polymere sowie ein Verfahren zur Herstellung von linearen isotaktischen Polymeren und dessen Verwendung
JP4771938B2 (ja) * 2003-05-12 2011-09-14 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US7122606B2 (en) 2003-07-04 2006-10-17 Basell Polyolefine Gmbh Olefin polymerization process
WO2005063828A1 (en) * 2003-12-22 2005-07-14 Basell Polyolefine Gmbh Metallocene compounds
EP1564226A1 (de) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Katalysatorsystem auf Basis von Titanocene
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ 1−ヘキセンまたは高級α−オレフィンの重合方法
CN101001892A (zh) 2004-03-12 2007-07-18 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的催化剂体系
EP1723184A1 (de) * 2004-03-12 2006-11-22 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
JP2008501659A (ja) * 2004-06-04 2008-01-24 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 遷移金属化合物、リガンド、触媒組成物及びポリオレフィンを製造する方法
WO2006005648A1 (en) * 2004-07-13 2006-01-19 Basell Polyolefine Gmbh Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom
CN101039967B (zh) * 2004-10-18 2010-06-09 巴塞尔聚烯烃意大利有限责任公司 低全同立构规整度丁烯-1均聚物或共聚物
DE602005026837D1 (de) * 2004-10-21 2011-04-21 Basell Polyolefine Gmbh 1-buten-polymer und herstellungsverfahren dafür
EP1655314A1 (de) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Polymerisationsverfahren von 1-buten mit propen
DE602005015479D1 (de) * 2004-11-09 2009-08-27 Basell Polyolefine Gmbh Verfahren zur herstellung von 1-buten/propylen-copolymeren
CN101061142B (zh) * 2004-11-22 2012-04-18 巴塞尔聚烯烃股份有限公司 基于丙烯的三元共聚物
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
PL1858907T3 (pl) * 2005-03-18 2009-04-30 Basell Polyolefine Gmbh Metalocenowe związki
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
WO2006100258A1 (en) 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerization of olefins
AU2006226366A1 (en) 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerizatio of olefins
EP1877453A1 (de) 2005-05-03 2008-01-16 Basell Polyolefine GmbH Verfahren zur polymerisation von alpha-olefinen
WO2006120177A2 (en) 2005-05-11 2006-11-16 Basell Poliolefine Itatia S.R.L. Polymerization process for preparing polyolefin blends
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
JP5004954B2 (ja) * 2005-06-30 2012-08-22 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
US20070181179A1 (en) 2005-12-21 2007-08-09 Konarka Technologies, Inc. Tandem photovoltaic cells
US20070131270A1 (en) * 2005-07-14 2007-06-14 Russell Gaudiana Window with photovoltaic cell
US8158881B2 (en) 2005-07-14 2012-04-17 Konarka Technologies, Inc. Tandem photovoltaic cells
US7772485B2 (en) * 2005-07-14 2010-08-10 Konarka Technologies, Inc. Polymers with low band gaps and high charge mobility
US20080006324A1 (en) * 2005-07-14 2008-01-10 Konarka Technologies, Inc. Tandem Photovoltaic Cells
US20070267055A1 (en) * 2005-07-14 2007-11-22 Konarka Technologies, Inc. Tandem Photovoltaic Cells
US7781673B2 (en) * 2005-07-14 2010-08-24 Konarka Technologies, Inc. Polymers with low band gaps and high charge mobility
JP2009508910A (ja) * 2005-09-19 2009-03-05 バーゼル・ポリオレフィン・ゲーエムベーハー シクロペンタジエンジチオフェン誘導体の合成
DE602006011643D1 (de) * 2005-11-21 2010-02-25 Shell Int Research Katalytische oligomerisierung von olefinischen monomeren
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
CN101511931B (zh) * 2006-08-30 2013-02-06 巴塞尔聚烯烃股份有限公司 1-丁烯丙烯共聚物组合物
US8008421B2 (en) 2006-10-11 2011-08-30 Konarka Technologies, Inc. Photovoltaic cell with silole-containing polymer
US8008424B2 (en) * 2006-10-11 2011-08-30 Konarka Technologies, Inc. Photovoltaic cell with thiazole-containing polymer
EP2197871A1 (de) * 2007-10-19 2010-06-23 Basell Polyolefine GmbH Auf ethandiyl-verbrückten inden- und cyclopentadithiophenliganden basierende metallocenverbindungen
EP2220101B1 (de) * 2007-12-18 2018-09-19 Basell Polyolefine GmbH Übergangsmetallverbindungen
JP2011513951A (ja) * 2008-02-21 2011-04-28 コナルカ テクノロジーズ インコーポレイテッド タンデム型光電池
JP5263845B2 (ja) * 2008-02-29 2013-08-14 サンアロマー株式会社 ポリオレフィン組成物
WO2009115402A1 (en) * 2008-03-20 2009-09-24 Basell Poliolefine Italia S.R.L. 1-butene terpolymers
US20100324244A1 (en) * 2008-03-20 2010-12-23 Basell Poliolefine Italia S.R.L. 1-butene copolymers
EP2254919A1 (de) * 2008-03-20 2010-12-01 Basell Poliolefine Italia S.R.L. 1-buten-copolymere
WO2009115400A1 (en) * 2008-03-20 2009-09-24 Basell Polyolefine Italia S.R.L Compositions of 1-butene based polymers
US8455606B2 (en) * 2008-08-07 2013-06-04 Merck Patent Gmbh Photoactive polymers
DE102011106849A1 (de) * 2010-12-15 2012-06-21 Merck Patent Gmbh Verfahren zur Synthese N-N verknüpfter und um die N-N Bindung rotationsgehinderter bis-N-heterocyclische Carbene und deren Einsatz als Liganden für Metallkomplexe
RU2529020C2 (ru) * 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
US9862698B2 (en) 2014-12-16 2018-01-09 Adt Pharmaceuticals, Inc. Indenyl compounds, pharmaceutical compositions, and medical uses thereof
US20160168108A1 (en) 2014-12-16 2016-06-16 Adt Pharmaceuticals, Inc. Method of treating or preventing ras-mediated diseases
WO2017150731A1 (ja) * 2016-03-04 2017-09-08 日本ポリエチレン株式会社 メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法
PL3266825T3 (pl) 2016-07-07 2022-05-09 Basell Poliolefine Italia S.R.L. Kompozycja polimerowa butenu-1 o wysokim wskaźniku szybkości płynięcia
PT3266824T (pt) 2016-07-07 2022-04-06 Basell Poliolefine Italia Srl Composição polimérica de buteno-1 tendo um índice de fluidez elevado
CN108250252B (zh) * 2016-12-28 2020-09-04 中国石油天然气股份有限公司 含杂环结构的桥联茂金属化合物及其制备方法和应用
CN110891984A (zh) 2017-08-04 2020-03-17 巴塞尔聚烯烃意大利有限公司 具有高熔体流动速率的丁烯-1聚合物
EP3661971B1 (de) 2017-08-04 2024-04-10 Basell Poliolefine Italia S.r.l. Buten-1-polymer-zusammensetzung mit hoher schmelzflussrate
WO2019025582A1 (en) 2017-08-04 2019-02-07 Basell Poliolefine Italia S.R.L. BUTENE-1 POLYMER WITH HIGH FLUIDITY INDEX
CN110891978A (zh) 2017-08-04 2020-03-17 巴塞尔聚烯烃意大利有限公司 具有高熔体流动速率的丁烯-1聚合物组合物
CN107540949B (zh) * 2017-09-30 2021-12-31 青岛科技大学 一种高等规聚丙烯合金及其制备方法
WO2019072695A1 (en) 2017-10-11 2019-04-18 Basell Polyolefine Gmbh CATALYST SUPPORTED SYSTEM
CN112020354A (zh) 2018-04-26 2020-12-01 Adt制药有限责任公司 抗癌茚类、茚满类、氮杂茚类、氮杂茚满类、药物组合物和用途
CN110922516B (zh) * 2018-09-20 2022-12-30 中国石油化工股份有限公司 一种乙烯共聚物及其制备方法
JP7700224B2 (ja) 2020-10-22 2025-06-30 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 射出成形用ポリマー組成物
EP4263637A1 (de) 2020-12-15 2023-10-25 Basell Poliolefine Italia S.r.l. Polyolefinzusammensetzung mit hoher transparenz
CN114890987B (zh) * 2022-04-13 2023-12-19 万华化学集团股份有限公司 一种硫酚-噻吩配体及其制备方法、烯烃聚合催化剂及其制备方法、应用
WO2025051517A1 (en) 2023-09-07 2025-03-13 Basell Poliolefine Italia S.R.L. Polyolefin-based hot melt adhesive composition
WO2025114148A1 (en) 2023-11-28 2025-06-05 Basell Poliolefine Italia S.R.L. Ethylene copolymer and use thereof in polyolefin compositions
WO2025149457A1 (en) 2024-01-11 2025-07-17 Basell Poliolefine Italia S.R.L. Ethylene copolymer and use thereof in polyolefin compositions
WO2025157894A1 (en) 2024-01-24 2025-07-31 Basell Poliolefine Italia S.R.L. Polyolefin-based hot melt adhesive composition
WO2025229047A1 (en) 2024-05-02 2025-11-06 Basell Poliolefine Italia S.R.L. Polyolefin plastomer

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4335225A (en) * 1978-06-20 1982-06-15 E. I. Du Pont De Nemours And Company Elastomeric polypropylene
EP0551277B2 (de) 1990-06-22 2005-03-09 ExxonMobil Chemical Patents Inc. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
IT1269931B (it) 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1269837B (it) 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
AU733813B2 (en) * 1996-11-15 2001-05-24 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts
ES2203965T3 (es) * 1997-03-29 2004-04-16 Basell Polyolefine Gmbh Metalocenos y catalizadores para la polimerizacion de olefinas.
US6017615A (en) * 1997-08-25 2000-01-25 Huntsman Polymers Corporation Film product comprising novel polyolefins
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
DE19804970A1 (de) 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
EP1230280A1 (de) 1999-09-17 2002-08-14 BP Chemicals Limited Katalysator für polyethylen mit verbesserter verteilung der kurzen ketten
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins

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AU783097B2 (en) 2005-09-22
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CN1348459A (zh) 2002-05-08
JP4358470B2 (ja) 2009-11-04
EP1157027B1 (de) 2007-09-19
US20030036612A1 (en) 2003-02-20
CA2363265A1 (en) 2001-07-05
CN1280300C (zh) 2006-10-18
ATE508135T1 (de) 2011-05-15
WO2001047939A1 (en) 2001-07-05
AR027125A1 (es) 2003-03-12
AU2843301A (en) 2001-07-09
EP1854804A1 (de) 2007-11-14
KR100723853B1 (ko) 2007-05-31
US7112638B2 (en) 2006-09-26
EP1854804B1 (de) 2011-05-04
JP2003519156A (ja) 2003-06-17
DE60045930D1 (de) 2011-06-16
ZA200106825B (en) 2002-11-18
RU2243229C2 (ru) 2004-12-27
DE60036459D1 (de) 2007-10-31
BR0010277A (pt) 2002-01-15

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