BR0014603A - Poliuretanos e polìmeros mistos de enxerto na base de poliuretano, bem como seu uso para produção de materiais de revestimento, adesivos e massas de vedação - Google Patents

Poliuretanos e polìmeros mistos de enxerto na base de poliuretano, bem como seu uso para produção de materiais de revestimento, adesivos e massas de vedação

Info

Publication number
BR0014603A
BR0014603A BR0014603-0A BR0014603A BR0014603A BR 0014603 A BR0014603 A BR 0014603A BR 0014603 A BR0014603 A BR 0014603A BR 0014603 A BR0014603 A BR 0014603A
Authority
BR
Brazil
Prior art keywords
polyurethane
monomer
polyurethanes
adhesives
production
Prior art date
Application number
BR0014603-0A
Other languages
English (en)
Inventor
Stephan Schwarte
Egon Wegner
Harald Angermueller
Original Assignee
Basf Coatings Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Coatings Ag filed Critical Basf Coatings Ag
Publication of BR0014603A publication Critical patent/BR0014603A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/067—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C08G18/4233—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups derived from polymerised higher fatty acids or alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4291—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing monoepoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Sealing Material Composition (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Patente de Invenção: "POLIURETANOS E POLìMEROS MISTOS DE ENXERTO NA BASE DE POLIURETANO, BEM COMO SEU USO PARA PRODUçãO DE MATERIAIS DE REVESTIMENTO, ADESIVOS E MASSAS DE VEDAçãO". A invenção refere-se a um poliuretano (B), com grupos etenilarileno de posição lateral e/ou de posição terminal, que pode ser preparado reagindo-se um pré-polímero de poliuretano, que contém grupos isocianato livres, com um produto de adição, que é obtenível reagindo-se um monoisocianato de etenilarileno com um poliol, poliamina e/ou um composto, que contém grupos hidroxila e grupos amino, na razão molar de 1:1. A invenção também se refere a um polímero misto de enxerto, que contém um núcleo hidrófobo, de pelo menos um monómero e um invólucro hidrófilo, que contém um poliuretano ou consiste no mesmo, ou um núcleo hidrófobo, que contém um poliuretano ou consiste no mesmo, e um invólucro hidrófilo, de pelo menos um monómero, que pode ser preparado sob uso do poliuretano (B); bem como a um polímero misto de enxerto, que contém um núcleo hidrófobo, de pelo menos um monómero, e um invólucro hidrófilo, que contém um poliuretano ou consiste no mesmo, que pode ser preparado dispersando-se pelo menos um poliuretano olefinicamente insaturado, hidrófilo, com grupos etenilarileno de posição lateral e de posição terminal, em um meio aquoso, após o que (co)polimeriza-se radicalmente, em emulsão, pelo menos um monómero hidrófobo, na presença do poliuretano.
BR0014603-0A 1999-10-06 2000-10-05 Poliuretanos e polìmeros mistos de enxerto na base de poliuretano, bem como seu uso para produção de materiais de revestimento, adesivos e massas de vedação BR0014603A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19948004A DE19948004B4 (de) 1999-10-06 1999-10-06 Polyurethane und Pfropfmischpolymerisate auf Polyurethanbasis sowie ihre Verwendung zur Herstellung von Beschichtungsstoffen, Klebstoffen und Dichtungsmassen
PCT/EP2000/009757 WO2001025307A1 (de) 1999-10-06 2000-10-05 Polyurethane und pfropfmischpolymerisate auf polyurethanbasis sowie ihre verwendung zur herstellung von beschichtungsstoffen, klebstoffen und dichtungsmassen

Publications (1)

Publication Number Publication Date
BR0014603A true BR0014603A (pt) 2002-06-11

Family

ID=7924606

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0014603-0A BR0014603A (pt) 1999-10-06 2000-10-05 Poliuretanos e polìmeros mistos de enxerto na base de poliuretano, bem como seu uso para produção de materiais de revestimento, adesivos e massas de vedação

Country Status (11)

Country Link
US (1) US6632915B1 (pt)
EP (1) EP1218434B1 (pt)
JP (1) JP5294524B2 (pt)
AT (1) ATE321800T1 (pt)
AU (1) AU7914900A (pt)
BR (1) BR0014603A (pt)
CA (1) CA2388518A1 (pt)
DE (2) DE19948004B4 (pt)
ES (1) ES2261246T3 (pt)
MX (1) MXPA02003475A (pt)
WO (1) WO2001025307A1 (pt)

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DE102006030059A1 (de) * 2006-06-29 2008-01-17 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen
GB2453473B (en) * 2006-08-31 2011-04-20 Kansai Paint Co Ltd Aqueous coating resin composition and aqueous coating composition
DE102006053776A1 (de) 2006-11-15 2008-05-21 Basf Coatings Ag Lösemittelhaltige, pigmentierte Beschichtungsmittel und ihre Verwendung zur Herstellung von Mehrschichtlackierungen sowie Verfahren zur Verbesserung des Flops von effektgebenden Lackierungen
DE102007014720A1 (de) 2007-03-23 2008-09-25 Basf Coatings Japan Ltd., Yokohama Phosphonat-haltiges Zweikomponenten-Lacksystem, dessen Herstellung und Verwendung
DE102007023539A1 (de) 2007-05-18 2008-11-20 Basf Coatings Ag Wässrige, pigmentierte Beschichtungsmittel, Verfahren zu deren Herstellung und deren Verwendung zur Herstellung von Mehrschichtlackierungen
DE102007038487A1 (de) 2007-08-14 2009-02-19 Basf Coatings Ag Wässriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung
DE102008002989A1 (de) 2007-08-16 2009-02-19 Basf Se Elektrisch leitfähiges, magnetisches Kompositmaterial, Verfahren zu seiner Herstellung und seine Verwendung
DE102008008779A1 (de) 2008-02-12 2009-08-13 Basf Coatings Ag Wässriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung
DE102008009481A1 (de) 2008-02-15 2009-08-20 Basf Coatings Ag Wässrige Beschichtungszusammensetzung, Verfahren zur Herstellung und ihre Verwendung
US8128744B2 (en) 2008-02-15 2012-03-06 BASF Coating GmbH Aqueous coating composition, method for production of the same, and use thereof
DE102008064254A1 (de) 2008-12-20 2010-06-24 Basf Coatings Ag Wässriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung
DE102009007629A1 (de) 2009-02-05 2010-08-12 Basf Coatings Ag Beschichtungsmittel für korrosionsstabile Lackierungen
DE102009007633B4 (de) 2009-02-05 2013-09-26 Basf Coatings Ag Mehrstufiges Verfahren zur Lackierung metallischer Substrate
DE102009007624A1 (de) 2009-02-05 2010-08-12 Basf Coatings Ag Beschichtungsmittel für korrosionsstabile Lackierungen
DE102009007632A1 (de) 2009-02-05 2010-08-12 Basf Coatings Ag Beschichtungsmittel für korrosionsstabile Lackierungen
DE102009007630A1 (de) 2009-02-05 2010-08-12 Basf Coatings Ag Beschichtungsmittel für korrosionsstabile Lackierungen
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DE19948004B4 (de) 2006-05-11
ATE321800T1 (de) 2006-04-15
JP2003511498A (ja) 2003-03-25
US6632915B1 (en) 2003-10-14
DE19948004A1 (de) 2001-07-12
WO2001025307A1 (de) 2001-04-12
EP1218434A1 (de) 2002-07-03
JP5294524B2 (ja) 2013-09-18
AU7914900A (en) 2001-05-10
ES2261246T3 (es) 2006-11-16
CA2388518A1 (en) 2001-04-12
MXPA02003475A (es) 2002-08-20
EP1218434B1 (de) 2006-03-29

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