BR0111239A - Processo para produzir propileno a partir do metanol - Google Patents
Processo para produzir propileno a partir do metanolInfo
- Publication number
- BR0111239A BR0111239A BR0111239-2A BR0111239A BR0111239A BR 0111239 A BR0111239 A BR 0111239A BR 0111239 A BR0111239 A BR 0111239A BR 0111239 A BR0111239 A BR 0111239A
- Authority
- BR
- Brazil
- Prior art keywords
- mixture
- reactor
- vapor
- dme
- methanol
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 239000013067 intermediate product Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
"PROCESSO PARA PRODUZIR PROPILENO A PARTIR DO METANOL". Vapor de metanol é reagido em um primeiro catalisador para formar uma primeira mistura de vapor contendo éter dimetílico (DME) e da primeira mistura de vapor produz-se em um catalisador de zeólita seletivo quanto a forma uma mistura de produto contendo propileno. O catalisador de zeólita seletivo quanto a forma está disposto como carga em pelo menos dois reatores de cuba ligados em série. Uma primeira corrente parcial da primeira mistura de vapor contendo DME é conduzido junto com vapor de água para o primeiro reator de cuba, do primeiro reator de cuba remove-se uma primeira mistura de produto intermediário e aduz-se ao segundo reator de cuba, sendo que se aduz ao segundo reator de cuba também uma segunda corrente parcial da primeira mistura de vapor contendo DME. Do último reator de cuba ligado em série remove-se uma mistura de produto e separa-se uma fração rica em propileno, sendo que se obtêm substâncias restantes, que são parcialmente gasosas. Pelo menos uma parte das substâncias restantes é reconduzida a pelo menos um dos reatores de cuba.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10027159A DE10027159A1 (de) | 2000-05-31 | 2000-05-31 | Verfahren zum Erzeugen von Propylen aus Methanol |
| DE10117248A DE10117248A1 (de) | 2000-05-31 | 2001-04-06 | Verfahren zum Erzeugen von Propylen aus Methanol |
| PCT/EP2001/005855 WO2001092190A1 (de) | 2000-05-31 | 2001-05-22 | Verfahren zum erzeugen von propylen aus methanol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0111239A true BR0111239A (pt) | 2003-06-10 |
| BR0111239B1 BR0111239B1 (pt) | 2012-07-24 |
Family
ID=26005922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0111239-2A BR0111239B1 (pt) | 2000-05-31 | 2001-05-22 | processo para produzir propileno a partir do metanol. |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US7015369B2 (pt) |
| EP (1) | EP1289912B1 (pt) |
| JP (1) | JP3844734B2 (pt) |
| CN (1) | CN1203033C (pt) |
| AR (1) | AR028640A1 (pt) |
| AT (1) | ATE338015T1 (pt) |
| AU (2) | AU2001266008B2 (pt) |
| BR (1) | BR0111239B1 (pt) |
| CA (1) | CA2408590C (pt) |
| CZ (1) | CZ303969B6 (pt) |
| DE (2) | DE10117248A1 (pt) |
| DK (1) | DK1289912T3 (pt) |
| DZ (1) | DZ3071A1 (pt) |
| EG (1) | EG22799A (pt) |
| HU (1) | HU228854B1 (pt) |
| MX (1) | MXPA02011865A (pt) |
| PL (1) | PL202517B1 (pt) |
| RU (1) | RU2266885C2 (pt) |
| SA (1) | SA01220443B1 (pt) |
| SK (1) | SK287532B6 (pt) |
| UA (1) | UA73577C2 (pt) |
| WO (1) | WO2001092190A1 (pt) |
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4604509B2 (ja) * | 2004-02-23 | 2011-01-05 | 三菱化学株式会社 | プロピレンの製造方法 |
| JP4608926B2 (ja) * | 2004-03-30 | 2011-01-12 | 三菱化学株式会社 | プロピレンの製造方法 |
| KR101159087B1 (ko) | 2003-12-12 | 2012-06-25 | 미쓰비시 가가꾸 가부시키가이샤 | 프로필렌의 제조 방법 |
| JP4604508B2 (ja) * | 2004-02-23 | 2011-01-05 | 三菱化学株式会社 | プロピレンの製造方法 |
| JP4826707B2 (ja) * | 2003-12-12 | 2011-11-30 | 三菱化学株式会社 | プロピレンの製造方法 |
| JP4599851B2 (ja) * | 2004-02-23 | 2010-12-15 | 三菱化学株式会社 | プロピレンの製造方法 |
| PL1706428T3 (pl) * | 2004-01-22 | 2010-02-26 | Merck Patent Gmbh | Przeciwciała przeciwnowotworowe o zredukowanym wiązaniu dopełniacza |
| US7663012B2 (en) * | 2004-06-25 | 2010-02-16 | Uop Llc | Conversion of dimethylether to propylene using moving bed technology |
| US7371915B1 (en) | 2004-06-25 | 2008-05-13 | Uop Llc | Conversion of oxygenate to propylene using moving bed technology |
| US20060020155A1 (en) * | 2004-07-21 | 2006-01-26 | Beech James H Jr | Processes for converting oxygenates to olefins at reduced volumetric flow rates |
| US7371916B1 (en) * | 2004-09-16 | 2008-05-13 | Uop Llc | Conversion of an alcoholic oxygenate to propylene using moving bed technology and an etherification step |
| US7405337B2 (en) * | 2004-09-21 | 2008-07-29 | Uop Llc | Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream |
| DE102004052828B3 (de) * | 2004-11-02 | 2005-12-15 | Lurgi Ag | Verfahren und Vorrichtung zur Herstellung von niederen Olefinen aus Oxigenaten |
| US7408092B2 (en) * | 2004-11-12 | 2008-08-05 | Uop Llc | Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst |
| US20060149109A1 (en) * | 2004-12-30 | 2006-07-06 | Ruziska Philip A | Converting methanol and ethanol to light olefins |
| US7414167B2 (en) * | 2005-01-14 | 2008-08-19 | Uop Llc | Conversion of oxygenate to propylene using moving bed technology and a separate heavy olefin interconversion step |
| DE102005003109B4 (de) * | 2005-01-22 | 2015-02-12 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten |
| JP4774813B2 (ja) * | 2005-06-03 | 2011-09-14 | 三菱化学株式会社 | プロピレンの製造方法 |
| CN100430349C (zh) | 2005-08-15 | 2008-11-05 | 中国石油化工股份有限公司 | 由甲醇或二甲醚生产丙烯的方法 |
| US20100022815A1 (en) * | 2005-08-24 | 2010-01-28 | Jgc Corporation | Process for production of lower hydrocarbons and apparatus for the production |
| DE102005048931B8 (de) * | 2005-10-13 | 2015-06-18 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von C2-C4-Olefinen aus Methanol und/oder Dimethylether |
| EP1955989B1 (en) * | 2005-11-14 | 2017-01-25 | JGC Corporation | Method for production of lower olefin |
| US7687671B2 (en) * | 2005-12-05 | 2010-03-30 | Uop Llc | Integrated oxygenate conversion and product cracking |
| US7582268B1 (en) | 2006-07-12 | 2009-09-01 | Uop Llc | Reactor system with interstage product removal |
| US7722825B1 (en) | 2006-07-31 | 2010-05-25 | Uop Llc | Preparing a light-olefin containing product stream from an oxygenate-containing feed stream using reactors directing a flow of a fluidized dual-function catalyst system |
| WO2008029631A1 (en) * | 2006-08-30 | 2008-03-13 | Jgc Corporation | Propylene production process and propylene production apparatus |
| JP5050466B2 (ja) * | 2006-09-21 | 2012-10-17 | 三菱化学株式会社 | プロピレンの製造方法 |
| JP5023638B2 (ja) * | 2006-09-27 | 2012-09-12 | 三菱化学株式会社 | プロピレンの製造方法 |
| JP5020587B2 (ja) * | 2006-09-28 | 2012-09-05 | 日揮株式会社 | プロピレンの製造方法およびプロピレンの製造装置 |
| US20080081936A1 (en) * | 2006-09-29 | 2008-04-03 | Bozzano Andrea G | Integrated processing of methanol to olefins |
| WO2008080363A1 (en) * | 2006-12-29 | 2008-07-10 | Accelergy Shanghai R & D Center Co., Ltd. | High throughput propylene from methanol catalytic process development method |
| CN101157593B (zh) * | 2007-03-07 | 2010-09-22 | 中国科学院大连化学物理研究所 | 由甲醇或/和二甲醚生产低碳烯烃的方法 |
| US7989669B2 (en) * | 2007-03-28 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Recycle of DME in an oxygenate-to-olefin reaction system |
| JP5388436B2 (ja) * | 2007-10-23 | 2014-01-15 | 出光興産株式会社 | 軽質オレフィン類の製造方法 |
| US20100305377A1 (en) | 2007-11-19 | 2010-12-02 | Van Westrenen Jeroen | Process for the preparation of an olefin |
| WO2009065875A1 (en) * | 2007-11-19 | 2009-05-28 | Shell Internationale Research Maatschappij B.V. | Process for converting an oxygenate into an olefin-containing product, and reactor system |
| US7919660B2 (en) * | 2007-12-21 | 2011-04-05 | Uop Llc | Methods of converting methanol feedstock to olefins |
| EP2123736A1 (de) | 2008-05-19 | 2009-11-25 | C.E.-Technology Limited | Verfahren zur Herstellung von Dieselkraftstoffen und Flugzeugtreibstoffen aus C1-C5-Alkoholen |
| US8003841B2 (en) * | 2008-06-30 | 2011-08-23 | Uop Llc | Integration of OTO process with direct DME synthesis |
| CN101381270B (zh) * | 2008-10-15 | 2012-10-31 | 惠生工程(中国)有限公司 | 一种mto/mtp反应混合物的分离方法 |
| EA019862B1 (ru) | 2009-07-30 | 2014-06-30 | Мицубиси Кемикал Корпорейшн | Способ получения пропилена и катализатор получения пропилена |
| DE102010005704A1 (de) | 2010-01-26 | 2011-07-28 | Süd-Chemie AG, 80333 | Verbesserter Katalysator auf Zeolithbasis zur Herstellung von Olefinen und zur Oligomerisierung von Olefinen |
| DE102010022138A1 (de) | 2010-05-20 | 2011-11-24 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung oxygenatarmer Olefinströme |
| CN101880212B (zh) * | 2010-06-18 | 2015-09-23 | 王伟跃 | 一种由含氧化合物制备丙烯的工艺 |
| JPWO2012015060A1 (ja) * | 2010-07-30 | 2013-09-12 | 日本ガス合成株式会社 | プロピレンの製造方法 |
| DE102010042216A1 (de) | 2010-10-08 | 2011-06-09 | Basf Se | Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure |
| DE102011013908A1 (de) | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen |
| CN102320912B (zh) * | 2011-06-03 | 2014-04-16 | 神华集团有限责任公司 | 最大化含氧化合物转化制备低碳烯烃工艺中的乙烯和丙烯总收率的方法 |
| CN102875290B (zh) * | 2011-07-12 | 2014-08-13 | 中国石油化工股份有限公司 | 由甲醇和石脑油制备低碳烯烃的反应装置 |
| US8981165B2 (en) * | 2011-09-14 | 2015-03-17 | Enerkem, Inc. | Production of alcohols having three carbon atoms from carbonaceous materials |
| US8987530B2 (en) * | 2011-09-14 | 2015-03-24 | Enerkem, Inc. | Production of alcohols having at least four carbon atoms from carbonaceous materials |
| DE102011114367A1 (de) * | 2011-09-27 | 2013-03-28 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung von Olefinen aus Dimethylether |
| EP2796197B1 (en) | 2011-12-19 | 2020-04-08 | Dalian Institute Of Chemical Physics, Chinese Academy of Sciences | Method for preparing ethylene and propylene by using methyl alcohol and/or dimethyl ether, |
| DE102012104128A1 (de) | 2012-05-11 | 2013-11-14 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Herstellung kurzkettiger Olefine mit verlängerter Zykluszeit |
| DE102012215757A1 (de) * | 2012-09-05 | 2014-03-06 | Evonik Industries Ag | Verfahren zur Herstellung von linearen Butenen aus Methanol |
| DE102013101575B4 (de) * | 2012-12-21 | 2019-06-06 | L’AIR LIQUIDE Société Anonyme pour l’Etude et l’Exploitation des Procédés Georges Claude | Verfahren und Anlage zur Herstellung von Olefinen aus Oxygenaten |
| CN104056654B (zh) * | 2013-03-22 | 2016-07-06 | 中国石油化工股份有限公司 | 一种zsm-5分子筛组合物、制备方法及其应用 |
| DE102013102980A1 (de) | 2013-03-22 | 2014-09-25 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Herstellung kurzkettiger Olefine aus Oxygenaten |
| CN103553863B (zh) * | 2013-10-30 | 2015-04-29 | 神华集团有限责任公司 | 一种由甲醇制备丙烯的方法和系统 |
| WO2015084576A2 (en) | 2013-12-06 | 2015-06-11 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion |
| US10131588B2 (en) | 2013-12-06 | 2018-11-20 | Exxonmobil Chemical Patents Inc. | Production of C2+ olefins |
| WO2015084575A2 (en) | 2013-12-06 | 2015-06-11 | Exxonmobil Chemical Patents Inc. | Production of c2+ olefins |
| US9682899B2 (en) | 2013-12-06 | 2017-06-20 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion |
| US10293333B2 (en) | 2013-12-20 | 2019-05-21 | Clariant Produkte (Deutschland) Gmbh | Catalyst containing phosphorus for converting oxygenates into olefins |
| WO2015147919A1 (en) | 2014-03-25 | 2015-10-01 | Exxonmobil Chemical Patents Inc. | Production of aromatics and c2+ olefins |
| EP3103858A1 (de) | 2015-06-08 | 2016-12-14 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur wäsche organischer flüssigkeiten mit einer aus fluorkohlenstoff bestehende flüssigkeit |
| US9815749B2 (en) | 2015-09-25 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon dehydrocyclization |
| CN107032944B (zh) * | 2016-02-03 | 2019-12-17 | 中石化广州工程有限公司 | 一种甲醇转化为丙烯的方法 |
| CN106928036B (zh) * | 2017-04-19 | 2021-01-15 | 四川达兴能源股份有限公司 | 利用丁缩醛制备聚甲氧基丁基醚的方法 |
| KR102893876B1 (ko) | 2018-07-26 | 2025-12-03 | 바스프 에스이 | 액상 p 중 존재하는 아크릴산의 원치않는 라디칼 중합의 억제 방법 |
| CN115335354A (zh) | 2020-03-26 | 2022-11-11 | 巴斯夫欧洲公司 | 抑制存在于液相p中的丙烯酸的不期望的自由基聚合的方法 |
| CN119365434A (zh) | 2022-06-30 | 2025-01-24 | 住友化学株式会社 | 碳原子数2~8的不饱和烃的制造方法、碳原子数2~8的不饱和烃混合物的制造方法、烯烃类聚合物的制造方法、化合物的制造方法、聚合物的制造方法、烯烃类聚合物和聚合物 |
| EP4438586A1 (de) | 2023-03-30 | 2024-10-02 | Covestro Deutschland AG | Nachhaltige herstellung von bisphenol-a für die produktion von polycarbonat |
| EP4442859A1 (de) | 2023-04-06 | 2024-10-09 | Covestro Deutschland AG | Nachhaltige herstellung von hexamethylendiisocyanat für die produktion von polyurethan |
| WO2025247906A1 (en) * | 2024-05-27 | 2025-12-04 | Basf Se | A process for producing olefins |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4404414A (en) * | 1982-09-28 | 1983-09-13 | Mobil Oil Corporation | Conversion of methanol to gasoline |
| SU1133252A1 (ru) * | 1983-06-06 | 1985-01-07 | Институт органической химии им.Н.Д.Зелинского | Способ получени этилена и пропилена |
| SU1574584A1 (ru) * | 1987-12-08 | 1990-06-30 | Предприятие П/Я А-7372 | Способ получени пропилена |
| DE4009459A1 (de) | 1990-03-23 | 1991-09-26 | Metallgesellschaft Ag | Verfahren zur erzeugung von niederen olefinen |
| US5744680A (en) * | 1995-08-10 | 1998-04-28 | Uop | Process for producing light olefins |
| US5817906A (en) * | 1995-08-10 | 1998-10-06 | Uop Llc | Process for producing light olefins using reaction with distillation as an intermediate step |
| DE19723363A1 (de) | 1997-06-04 | 1998-12-10 | Metallgesellschaft Ag | Verfahren zum Erzeugen von Ethylen, Propylen und wahlweise auch Butenisomeren aus Methanol- und/oder Dimethylether |
| JP2001517643A (ja) * | 1997-09-24 | 2001-10-09 | ダイク,クリスチャン ピー. ヴァン | シリコアルミナリン酸塩分子ふるい触媒でメタノールを変換するための固定床プロセス |
-
2001
- 2001-04-06 DE DE10117248A patent/DE10117248A1/de not_active Ceased
- 2001-05-21 DZ DZ010033A patent/DZ3071A1/xx active
- 2001-05-22 AT AT01943427T patent/ATE338015T1/de not_active IP Right Cessation
- 2001-05-22 BR BRPI0111239-2A patent/BR0111239B1/pt not_active IP Right Cessation
- 2001-05-22 PL PL358969A patent/PL202517B1/pl unknown
- 2001-05-22 DE DE50110883T patent/DE50110883D1/de not_active Expired - Lifetime
- 2001-05-22 WO PCT/EP2001/005855 patent/WO2001092190A1/de not_active Ceased
- 2001-05-22 US US10/296,356 patent/US7015369B2/en not_active Expired - Lifetime
- 2001-05-22 HU HU0301930A patent/HU228854B1/hu not_active IP Right Cessation
- 2001-05-22 UA UA20021210700A patent/UA73577C2/uk unknown
- 2001-05-22 RU RU2002135910/04A patent/RU2266885C2/ru active
- 2001-05-22 SK SK1817-2002A patent/SK287532B6/sk not_active IP Right Cessation
- 2001-05-22 MX MXPA02011865A patent/MXPA02011865A/es active IP Right Grant
- 2001-05-22 CA CA002408590A patent/CA2408590C/en not_active Expired - Fee Related
- 2001-05-22 JP JP2002500807A patent/JP3844734B2/ja not_active Expired - Fee Related
- 2001-05-22 AU AU2001266008A patent/AU2001266008B2/en not_active Ceased
- 2001-05-22 DK DK01943427T patent/DK1289912T3/da active
- 2001-05-22 AU AU6600801A patent/AU6600801A/xx active Pending
- 2001-05-22 EP EP01943427A patent/EP1289912B1/de not_active Expired - Lifetime
- 2001-05-22 CZ CZ20024174A patent/CZ303969B6/cs not_active IP Right Cessation
- 2001-05-22 CN CNB01810472XA patent/CN1203033C/zh not_active Expired - Fee Related
- 2001-05-28 AR ARP010102545A patent/AR028640A1/es active IP Right Grant
- 2001-05-30 EG EG20010581A patent/EG22799A/xx active
- 2001-10-10 SA SA01220443A patent/SA01220443B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SA01220443B1 (ar) | 2006-07-03 |
| HUP0301930A2 (hu) | 2003-09-29 |
| EG22799A (en) | 2003-08-31 |
| AU2001266008B2 (en) | 2005-11-24 |
| PL358969A1 (en) | 2004-08-23 |
| MXPA02011865A (es) | 2004-05-17 |
| BR0111239B1 (pt) | 2012-07-24 |
| PL202517B1 (pl) | 2009-07-31 |
| DE50110883D1 (de) | 2006-10-12 |
| SK287532B6 (sk) | 2011-01-04 |
| DK1289912T3 (da) | 2007-01-08 |
| DZ3071A1 (fr) | 2004-09-14 |
| CZ303969B6 (cs) | 2013-07-24 |
| EP1289912A1 (de) | 2003-03-12 |
| HU228854B1 (en) | 2013-06-28 |
| SK18172002A3 (sk) | 2003-08-05 |
| JP2003535069A (ja) | 2003-11-25 |
| WO2001092190A1 (de) | 2001-12-06 |
| EP1289912B1 (de) | 2006-08-30 |
| CN1431982A (zh) | 2003-07-23 |
| CA2408590A1 (en) | 2002-11-12 |
| CA2408590C (en) | 2007-10-02 |
| HUP0301930A3 (en) | 2007-09-28 |
| AR028640A1 (es) | 2003-05-21 |
| AU6600801A (en) | 2001-12-11 |
| US20030139635A1 (en) | 2003-07-24 |
| JP3844734B2 (ja) | 2006-11-15 |
| CN1203033C (zh) | 2005-05-25 |
| UA73577C2 (uk) | 2005-08-15 |
| US7015369B2 (en) | 2006-03-21 |
| ATE338015T1 (de) | 2006-09-15 |
| DE10117248A1 (de) | 2002-10-10 |
| RU2266885C2 (ru) | 2005-12-27 |
| CZ20024174A3 (cs) | 2003-06-18 |
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