BR9405252A - Composto de metaloceno; componente de catalisador; processo para preparação de um polímero de olefina; poliolefina; corpo de moldagem e aplicação do dito composto - Google Patents
Composto de metaloceno; componente de catalisador; processo para preparação de um polímero de olefina; poliolefina; corpo de moldagem e aplicação do dito compostoInfo
- Publication number
- BR9405252A BR9405252A BR9405252A BR9405252A BR9405252A BR 9405252 A BR9405252 A BR 9405252A BR 9405252 A BR9405252 A BR 9405252A BR 9405252 A BR9405252 A BR 9405252A BR 9405252 A BR9405252 A BR 9405252A
- Authority
- BR
- Brazil
- Prior art keywords
- compound
- catalyst component
- polyolefin
- preparing
- application
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000465 moulding Methods 0.000 title 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4344689A DE4344689A1 (de) | 1993-12-27 | 1993-12-27 | Metallocenverbindung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9405252A true BR9405252A (pt) | 1995-08-01 |
Family
ID=6506375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9405252A BR9405252A (pt) | 1993-12-27 | 1994-12-26 | Composto de metaloceno; componente de catalisador; processo para preparação de um polímero de olefina; poliolefina; corpo de moldagem e aplicação do dito composto |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US5532396A (pt) |
| EP (2) | EP0659757B1 (pt) |
| JP (1) | JP3789502B2 (pt) |
| KR (1) | KR950018027A (pt) |
| CN (1) | CN1068332C (pt) |
| AT (2) | ATE215091T1 (pt) |
| BR (1) | BR9405252A (pt) |
| DE (3) | DE4344689A1 (pt) |
| ES (2) | ES2238364T3 (pt) |
| RU (1) | RU2142466C1 (pt) |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW309523B (pt) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| ATE198207T1 (de) * | 1992-08-03 | 2001-01-15 | Targor Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene |
| NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| NL9400758A (nl) * | 1994-05-06 | 1995-12-01 | Dsm Nv | Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen. |
| US5563284A (en) * | 1994-09-09 | 1996-10-08 | Phillips Petroleum Company | Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use |
| DE4436113A1 (de) * | 1994-10-10 | 1996-04-11 | Hoechst Ag | Metallocenverbindung |
| TW383313B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers |
| IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| DE19516803A1 (de) * | 1995-05-08 | 1996-11-14 | Hoechst Ag | Organometallverbindung |
| JPH08325327A (ja) * | 1995-06-02 | 1996-12-10 | Chisso Corp | 高立体規則性ポリプロピレン |
| DE19527047A1 (de) * | 1995-07-25 | 1997-01-30 | Danubia Petrochem Deutschland | Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation |
| EP0858462B1 (en) * | 1995-10-27 | 2002-07-03 | The Dow Chemical Company | Supportable biscyclopentadienyl metal complexes |
| US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
| US5679814A (en) * | 1995-12-11 | 1997-10-21 | Albemarle Corporation | Purification of metallocenes |
| DE19548288A1 (de) * | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE69710838T2 (de) * | 1996-04-22 | 2002-10-31 | Japan Polyolefins Co. Ltd., Tokio/Tokyo | Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren |
| US5710299A (en) * | 1996-06-27 | 1998-01-20 | Albemarle Corporation | Production of bridged metallocene complexes and intermediates therefor |
| US5760262A (en) * | 1996-09-17 | 1998-06-02 | Albemarle Corporation | Enhanced production of bridged hafnocenes |
| US5936108A (en) * | 1996-10-17 | 1999-08-10 | Albemarle Corporation | Metallocene synthesis |
| WO1998022477A1 (en) * | 1996-11-22 | 1998-05-28 | Boulder Scientific Company | Preparation of chiral titanocenes |
| US5889128A (en) * | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US6037428A (en) * | 1997-04-25 | 2000-03-14 | Shin-Etsu Chemical Co., Ltd. | Polymerization of vinyl chloride with peroxide mixtures |
| US5905162A (en) * | 1997-08-12 | 1999-05-18 | Albemarle Corporation | Enhanced production of bridged hafnocenes |
| AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
| KR100274973B1 (ko) * | 1997-11-24 | 2000-12-15 | 성재갑 | 올레핀계 단량체의 중합 촉매 |
| JP2001527097A (ja) * | 1997-12-23 | 2001-12-25 | エクソンモービル・ケミカル・パテンツ・インク | 液体反応媒体中でのエチレン重合方法 |
| EP0980375B1 (en) * | 1998-01-30 | 2005-11-09 | Boulder Scientific Company | N-silylated compound synthesis |
| US6034192A (en) * | 1998-12-30 | 2000-03-07 | Univation Technologies, Llc | Germanium bridged metallocenes producing polymers with increased melt strength |
| US6818585B2 (en) * | 1998-12-30 | 2004-11-16 | Univation Technologies, Llc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
| EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| US6399722B1 (en) * | 1999-12-01 | 2002-06-04 | Univation Technologies, Llc | Solution feed of multiple catalysts |
| ES2210015T3 (es) | 1999-11-04 | 2004-07-01 | Exxonmobil Chemical Patents Inc. | Espumas de copolimero de propileno y su uso. |
| AU782786B2 (en) * | 1999-12-01 | 2005-08-25 | Exxonmobil Chemical Patents Inc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
| DE50006908D1 (de) * | 1999-12-13 | 2004-07-29 | Basf Ag | Pigmentkonzentrate und verfahren zu ihrer herstellung |
| JP4966463B2 (ja) | 1999-12-22 | 2012-07-04 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−ベース−接着剤組成物 |
| AU782996B2 (en) | 1999-12-23 | 2005-09-15 | Basell Polyolefine Gmbh | Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins |
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| WO2001058913A1 (en) * | 2000-02-08 | 2001-08-16 | Exxonmobil Chemical Patents Inc. | Method of preparing group 14 bridged biscyclopentadienyl ligands |
| JP4332029B2 (ja) * | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンの重合方法 |
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US6916892B2 (en) | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
| US20030236365A1 (en) * | 2002-06-24 | 2003-12-25 | Fina Technology, Inc. | Polyolefin production with a high performance support for a metallocene catalyst system |
| US6995279B2 (en) | 2002-08-02 | 2006-02-07 | Chisso Corporation | Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes |
| US6884748B2 (en) * | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
| US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7195806B2 (en) * | 2003-01-17 | 2007-03-27 | Fina Technology, Inc. | High gloss polyethylene articles |
| JP2005099712A (ja) * | 2003-08-28 | 2005-04-14 | Sharp Corp | 表示装置の駆動回路および表示装置 |
| JP4343231B2 (ja) * | 2003-10-15 | 2009-10-14 | ユニベーション・テクノロジーズ・エルエルシー | 重合方法及びポリマー組成物特性の調節 |
| DE10358082A1 (de) * | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| EP1694719A2 (en) | 2003-12-19 | 2006-08-30 | Basell Polyolefine GmbH | Monocyclopentadienyl complexes |
| US20050182210A1 (en) * | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
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| DZ520A1 (fr) * | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
| DE3726067A1 (de) * | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| DE3808268A1 (de) * | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
| DK0426637T4 (da) * | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| US5243001A (en) * | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| EP0485822B1 (de) * | 1990-11-12 | 1996-07-03 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| JP3117231B2 (ja) * | 1991-03-11 | 2000-12-11 | 三井化学株式会社 | 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法 |
| US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
| US5391789A (en) * | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
| TW300901B (pt) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| ATE286918T1 (de) * | 1991-10-15 | 2005-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
| DE69224463T2 (de) * | 1991-11-28 | 1998-07-09 | Showa Denko Kk | Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben |
| TW318184B (pt) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| EP0574597B2 (en) * | 1992-06-13 | 2002-06-26 | Basell Polyolefine GmbH | Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type |
| DE4431643C2 (de) * | 1994-07-22 | 2002-08-08 | Borealis Polymere Holding Ag | Verfahren zur Herstellung von Silizium-verbrückten unsymmetrischen Cyclopentadienyl-, Indenyl- und Fluorenyl-Ligandsystemen |
-
1993
- 1993-12-27 DE DE4344689A patent/DE4344689A1/de not_active Withdrawn
-
1994
- 1994-12-19 ES ES01114147T patent/ES2238364T3/es not_active Expired - Lifetime
- 1994-12-19 DE DE59410406T patent/DE59410406D1/de not_active Expired - Lifetime
- 1994-12-19 ES ES94120070T patent/ES2174860T3/es not_active Expired - Lifetime
- 1994-12-19 AT AT94120070T patent/ATE215091T1/de not_active IP Right Cessation
- 1994-12-19 EP EP94120070A patent/EP0659757B1/de not_active Expired - Lifetime
- 1994-12-19 DE DE59410090T patent/DE59410090D1/de not_active Expired - Lifetime
- 1994-12-19 EP EP01114147A patent/EP1188763B1/de not_active Expired - Lifetime
- 1994-12-19 AT AT01114147T patent/ATE290536T1/de not_active IP Right Cessation
- 1994-12-22 US US08/361,762 patent/US5532396A/en not_active Expired - Lifetime
- 1994-12-26 BR BR9405252A patent/BR9405252A/pt not_active IP Right Cessation
- 1994-12-26 RU RU94045142A patent/RU2142466C1/ru active
- 1994-12-27 KR KR1019940037116A patent/KR950018027A/ko not_active Abandoned
- 1994-12-27 CN CN94107627A patent/CN1068332C/zh not_active Expired - Lifetime
- 1994-12-27 JP JP32496894A patent/JP3789502B2/ja not_active Expired - Lifetime
-
1995
- 1995-06-07 US US08/477,853 patent/US5612428A/en not_active Expired - Lifetime
- 1995-06-07 US US08/475,938 patent/US5576260A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5576260A (en) | 1996-11-19 |
| ES2174860T3 (es) | 2002-11-16 |
| US5532396A (en) | 1996-07-02 |
| RU2142466C1 (ru) | 1999-12-10 |
| ES2238364T3 (es) | 2005-09-01 |
| ATE290536T1 (de) | 2005-03-15 |
| EP1188763A3 (de) | 2004-01-02 |
| JP3789502B2 (ja) | 2006-06-28 |
| EP1188763A2 (de) | 2002-03-20 |
| EP0659757B1 (de) | 2002-03-27 |
| DE4344689A1 (de) | 1995-06-29 |
| EP0659757A1 (de) | 1995-06-28 |
| EP1188763B1 (de) | 2005-03-09 |
| RU94045142A (ru) | 1996-11-20 |
| CN1107854A (zh) | 1995-09-06 |
| CN1068332C (zh) | 2001-07-11 |
| US5612428A (en) | 1997-03-18 |
| JPH0867689A (ja) | 1996-03-12 |
| ATE215091T1 (de) | 2002-04-15 |
| KR950018027A (ko) | 1995-07-22 |
| DE59410406D1 (de) | 2005-04-14 |
| DE59410090D1 (de) | 2002-05-02 |
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