BRPI0408243A - método para fabricação de partìculas de polìmeros superabsorvente de cor estável, partìculas superabsorventes de cor estável, artigo absorvente, e, fralda - Google Patents
método para fabricação de partìculas de polìmeros superabsorvente de cor estável, partìculas superabsorventes de cor estável, artigo absorvente, e, fraldaInfo
- Publication number
- BRPI0408243A BRPI0408243A BRPI0408243-5A BRPI0408243A BRPI0408243A BR PI0408243 A BRPI0408243 A BR PI0408243A BR PI0408243 A BRPI0408243 A BR PI0408243A BR PI0408243 A BRPI0408243 A BR PI0408243A
- Authority
- BR
- Brazil
- Prior art keywords
- superabsorbent
- stable color
- particles
- color
- manufacturing
- Prior art date
Links
- 229920000247 superabsorbent polymer Polymers 0.000 title abstract 5
- 239000002245 particle Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000002250 absorbent Substances 0.000 title abstract 2
- 230000002745 absorbent Effects 0.000 title abstract 2
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000003860 storage Methods 0.000 abstract 1
- 150000003452 sulfinic acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/915—Redox catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Hematology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
"MéTODO PARA FABRICAçãO DE PARTìCULAS DE POLìMERO SUPERABSORVENTE DE COR ESTáVEL, PARTìCULAS SUPERABSORVENTES DE COR ESTáVEL, ARTIGO ABSORVENTE, E, FRALDA". São divulgados polímeros superabsorventes de cor estável possuindo estabilidade de cor a longo prazo e métodos para fabricação dos polímeros. Os polímeros superabsorventes são preparados usando um derivado de ácido sulfínico, tal como o ácido 2-hidroxi-2-sulfinatoacético, um sal do mesmo, ou uma mistura do mesmo, como o agente redutor em um sistema iniciador de polimerização para a preparação de um polímero superabsorvente a partir de monómeros. O polímero superabsorvente resultante resiste à degradação da cor durante períodos de armazenagem prolongados, mesmo em temperaturas e umidades elevadas.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45784103P | 2003-03-26 | 2003-03-26 | |
| US60/457,841 | 2003-03-26 | ||
| PCT/EP2004/002874 WO2004084962A1 (en) | 2003-03-26 | 2004-03-19 | Color-stable superabsorbent polymer composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0408243A true BRPI0408243A (pt) | 2006-03-01 |
| BRPI0408243B1 BRPI0408243B1 (pt) | 2015-03-17 |
| BRPI0408243B8 BRPI0408243B8 (pt) | 2021-06-22 |
Family
ID=33098249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0408243A BRPI0408243B8 (pt) | 2003-03-26 | 2004-03-19 | método para fabricação de partículas de polímeros superabsorvente de cor estável, partículas superabsorventes de cor estável, artigo absorvente, e, fralda |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7504551B2 (pt) |
| EP (1) | EP1610831B1 (pt) |
| JP (1) | JP4903038B2 (pt) |
| CN (1) | CN100525842C (pt) |
| AT (1) | ATE337801T1 (pt) |
| BR (1) | BRPI0408243B8 (pt) |
| DE (1) | DE602004002202T2 (pt) |
| MX (1) | MXPA05009238A (pt) |
| TW (1) | TW200500046A (pt) |
| WO (1) | WO2004084962A1 (pt) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1504772A1 (en) * | 2003-08-06 | 2005-02-09 | The Procter & Gamble Company | Superabsorbent polymers having radiation activable surface cross-linkers and method of making them |
| US8080705B2 (en) * | 2004-07-28 | 2011-12-20 | The Procter & Gamble Company | Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them |
| EP1669394A1 (en) * | 2004-12-10 | 2006-06-14 | The Procter & Gamble Company | Superabsorbent polymer particles with improved surface cross-linking and hydrophilicity and method of making them |
| US20060128827A1 (en) * | 2004-12-10 | 2006-06-15 | The Procter & Gamble Company | Absorbent members comprising modified water absorbent resin for use in diapers |
| DE602006012640D1 (de) | 2005-04-12 | 2010-04-15 | Nippon Catalytic Chem Ind | Altend wasserabsorbierendes harz auf basis von polyacrylsäure (polyacrylat) als hauptkomponente, herstellungsverfahren dafür, wasserabsorbierender kerige wasserabsorbierende mittel verwendet wird |
| EP1757642A1 (en) * | 2005-08-23 | 2007-02-28 | The Procter and Gamble Company | Method of surface cross-linking superabsorbent polymer particles using vacuum ultraviolet radiation |
| JP2007077366A (ja) * | 2005-09-16 | 2007-03-29 | Procter & Gamble Co | 吸水剤の製法 |
| EP1776966A1 (en) * | 2005-10-21 | 2007-04-25 | The Procter and Gamble Company | Absorbent article having improved absorption and retention capacity for proteinaceous or serous body fluids |
| EP1776967B2 (en) * | 2005-10-21 | 2013-03-13 | The Procter & Gamble Company | Absorbent articles having increased absorption and retention capacity for proteinaceous or serous body fluids |
| ES2344572T5 (es) * | 2005-10-21 | 2013-07-18 | The Procter & Gamble Company | Artículos absorbentes que tienen capacidad de absorción y retención incrementada para fluidos corporales proteináceos o serosos |
| EP1829563B1 (en) * | 2006-03-03 | 2013-05-01 | The Procter and Gamble Company | Thermoplastic absorbent material having increased absorption and retention capacity for proteinaceous or serous body fluid |
| US7745507B2 (en) * | 2006-04-10 | 2010-06-29 | The Procter & Gamble Company | Absorbent member comprising a modified water absorbent resin |
| EP2046871B1 (en) | 2006-07-31 | 2020-07-08 | Nippon Shokubai Co., Ltd. | Production method of water absorbent resin powder and package of water absorbent resin powder |
| US7960490B2 (en) | 2006-09-19 | 2011-06-14 | Basf Se | Process for preparing color-stable water-absorbing polymer particles with a low degree of neutralization |
| US7718713B2 (en) * | 2006-10-02 | 2010-05-18 | Formosa Plastics Corporation | Method of manufacturing the super-absorbent polymer (SAP) which is powdery, insoluble in water, and able to absorb water, blood and urine and has slight soluble things |
| WO2008102322A2 (en) | 2007-02-22 | 2008-08-28 | The Procter & Gamble Company | Method of surface treating particulate material using electromagnetic radiation |
| US9657257B2 (en) * | 2007-05-10 | 2017-05-23 | Kimberly-Clark Worldwide, Inc. | Colorant neutralizer |
| US7816426B2 (en) | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| WO2009055128A2 (en) * | 2007-08-17 | 2009-04-30 | Massachusetts Institute Of Technology | Compositions for chemical and biological defense |
| US20090062764A1 (en) * | 2007-08-30 | 2009-03-05 | Kimberly-Clark Worldwide, Inc. | Zoned application of decolorizing composition for use in absorbent articles |
| DE102007053619A1 (de) * | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| US8613834B2 (en) | 2008-04-03 | 2013-12-24 | Basf Se | Paper coating or binding formulations and methods of making and using same |
| US20110118114A1 (en) * | 2008-07-31 | 2011-05-19 | Basf Se | Color stable superabsorbent |
| CN102405063B (zh) * | 2009-02-18 | 2015-12-09 | 奎克-麦德技术公司 | 含有过氧化物的超吸收材料 |
| DE102009029194A1 (de) | 2009-09-04 | 2011-04-07 | Kimberly-Clark Worldwide, Inc., Neenah | Abtrennung gefärbter Stoffe aus wasserhaltigen Flüssigkeiten |
| EP2477664A1 (de) | 2009-09-17 | 2012-07-25 | Basf Se | Farbstabiler superabsorber |
| CN102549028B (zh) | 2009-09-30 | 2016-03-02 | 株式会社日本触媒 | 聚丙烯酸(盐)系吸水树脂及其制造方法 |
| KR101887706B1 (ko) | 2009-09-30 | 2018-08-10 | 가부시키가이샤 닛폰 쇼쿠바이 | 입자상 흡수제 및 그 제조방법 |
| JP2013511608A (ja) * | 2009-11-23 | 2013-04-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 色安定性が改善された吸水性ポリマー粒子の製造方法 |
| US8703876B2 (en) * | 2010-03-15 | 2014-04-22 | Basf Se | Process for producing water absorbing polymer particles with improved color stability |
| EP2371869A1 (en) | 2010-03-30 | 2011-10-05 | Evonik Stockhausen GmbH | A process for the production of a superabsorbent polymer |
| US8791230B2 (en) | 2010-06-08 | 2014-07-29 | Nippon Shokubai Co., Ltd. | Method for producing particulate water absorbent resin |
| KR20130096218A (ko) | 2010-06-14 | 2013-08-29 | 바스프 에스이 | 개선된 색 안정성을 갖는 수분-흡수 중합체 입자 |
| KR101448225B1 (ko) * | 2010-11-03 | 2014-10-07 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| RU2013125088A (ru) * | 2010-11-23 | 2014-12-27 | Дзе Проктер Энд Гэмбл Компани | Термопластические композиции, содержащие крахмал |
| WO2012081355A1 (ja) * | 2010-12-16 | 2012-06-21 | 住友精化株式会社 | 吸水性樹脂の製造方法 |
| JP2012210947A (ja) * | 2011-03-30 | 2012-11-01 | Brother Industries Ltd | 抜染処理剤収容容器 |
| US20120296297A1 (en) * | 2011-05-18 | 2012-11-22 | Achille Di Cintio | Feminine hygiene absorbent articles comprising water-absorbing polymeric foams |
| ES2607441T3 (es) | 2012-03-15 | 2017-03-31 | Xtract Gmbh | Procedimiento para la granulación de material en partículas obtenido de procesos industriales, el granulado así producido |
| WO2013139959A1 (de) | 2012-03-22 | 2013-09-26 | Xtract Gmbh | Verfahren zur behandlung von klärschlamm durch zusatz von organischem polymer sowie aus dem verfahren erhaltene granulate |
| DE102012102473A1 (de) | 2012-03-22 | 2013-09-26 | Xtract Gmbh | Verfahren zur Behandlung von Klärschlamm |
| WO2013144027A1 (de) | 2012-03-30 | 2013-10-03 | Basf Se | Farbstabiler superabsorber |
| US9220646B2 (en) | 2012-03-30 | 2015-12-29 | Kimberly-Clark Worldwide, Inc. | Absorbent articles with improved stain decolorization |
| WO2013144026A1 (de) | 2012-03-30 | 2013-10-03 | Basf Se | Farbstabiler superabsorber |
| JP2016503449A (ja) | 2012-11-21 | 2016-02-04 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴を重合することによる吸水性ポリマー粒子の製造方法 |
| DE102013203781A1 (de) | 2013-03-06 | 2014-09-11 | Evonik Industries Ag | Superabsorbierende Polymere mit verbesserten Eigenschaften, insbesondere Geruchskontrolle und Farbbeständigkeit, sowie Verfahren zu dessen Herstellung |
| US9237975B2 (en) | 2013-09-27 | 2016-01-19 | Kimberly-Clark Worldwide, Inc. | Absorbent article with side barriers and decolorizing agents |
| KR101680829B1 (ko) * | 2013-09-30 | 2016-11-29 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| WO2015133440A1 (ja) | 2014-03-03 | 2015-09-11 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂の製造方法 |
| KR101725950B1 (ko) * | 2014-06-23 | 2017-04-12 | 주식회사 엘지화학 | 수용성 염을 포함하는 고흡수성 수지 및 그 제조 방법 |
| JP5719079B1 (ja) | 2014-07-11 | 2015-05-13 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| JP5766344B1 (ja) | 2014-07-11 | 2015-08-19 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| KR101782501B1 (ko) * | 2014-12-10 | 2017-09-27 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| JP6957637B2 (ja) * | 2016-12-13 | 2021-11-02 | エル. ブリュッゲマン ゲーエムベーハー ウント ツェーオー. カーゲー | スルホン酸塩組成物および色安定化のためのその使用 |
| KR102075733B1 (ko) * | 2016-12-13 | 2020-02-10 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
| CN110809587B (zh) * | 2017-06-30 | 2022-12-23 | 索尔维特殊聚合物意大利有限公司 | 用于制造部分氟化的聚合物的方法 |
| US20200123284A1 (en) * | 2017-07-05 | 2020-04-23 | Nitto Boseki Co., Ltd. | High purity allylamine (co)polymer and method for producing same |
| CN111278551B (zh) | 2017-11-10 | 2023-09-29 | 巴斯夫欧洲公司 | 超吸收剂 |
| EP3781108B1 (en) * | 2018-04-20 | 2023-11-29 | Basf Se | Process for producing superabsorbents |
| JP2024504945A (ja) * | 2021-01-14 | 2024-02-02 | ソーン マテリアルズ エルエルシー | 吸収性繊維複合物および得られる高性能生成物 |
| JP7614924B2 (ja) * | 2021-04-20 | 2025-01-16 | 東京応化工業株式会社 | ナノインプリント用組成物及びパターン形成方法 |
| JP2024517003A (ja) | 2021-05-05 | 2024-04-18 | エボニック オペレーションズ ゲーエムベーハー | 少なくとも1種のバイオ界面活性剤と少なくとも1種のスルホン酸誘導体またはスルフィン酸誘導体とを含有する組成物 |
| WO2026082482A1 (en) | 2024-10-17 | 2026-04-23 | Basf Se | Odor-control superabsorbent comprising pelargonic acid |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0764896B2 (ja) | 1987-04-17 | 1995-07-12 | 三菱化学株式会社 | 吸水性複合材料の製造法 |
| US5408019A (en) * | 1990-05-11 | 1995-04-18 | Chemische Fabrik Stockhausen Gmbh | Cross-linked, water-absorbing polymer and its use in the production of hygiene items |
| JPH04120112A (ja) | 1990-09-07 | 1992-04-21 | Sanyo Chem Ind Ltd | 吸水性樹脂組成物及びその製造法 |
| US5599335A (en) | 1994-03-29 | 1997-02-04 | The Procter & Gamble Company | Absorbent members for body fluids having good wet integrity and relatively high concentrations of hydrogel-forming absorbent polymer |
| JP3569322B2 (ja) * | 1994-09-12 | 2004-09-22 | 松原産業株式会社 | 吸水性樹脂の製造方法 |
| DE19743759A1 (de) * | 1997-10-02 | 1999-04-08 | Brueggemann L Kg | Sulfinsäurederivate und deren Herstellung und Verwendung |
| DE19806482A1 (de) * | 1998-02-17 | 1999-08-19 | Sueddeutsche Kalkstickstoff | Wasserlösliche oder wasserquellbare sulfogruppenhaltige Copolymere, Verfahren zu deren Herstellung und ihre Verwendung |
| US6444744B1 (en) * | 1998-03-11 | 2002-09-03 | Nippon Shokubai Co., Ltd. | Hydrophilic resin, absorbent article, and acrylic acid for polymerization |
| AU3870700A (en) * | 1999-03-12 | 2000-10-04 | Basf Aktiengesellschaft | Color-stable superabsorbent polymer composition |
| US6262141B1 (en) | 1999-10-06 | 2001-07-17 | Cytec Technology Corporation | Process for the preparation of polymers having low residual monomer content |
| GB0001883D0 (en) * | 2000-01-28 | 2000-03-22 | Ciba Spec Chem Water Treat Ltd | Polymerisation process |
| US6696519B2 (en) * | 2000-10-17 | 2004-02-24 | Rohm And Haas Company | Redox process for preparing emulsion polymer having low residual monomer content |
| MXPA05009236A (es) * | 2003-03-26 | 2005-10-19 | Basf Ag | Composicion de polimeros super absorbentes con estabilidad de color. |
-
2004
- 2004-02-24 TW TW093104677A patent/TW200500046A/zh unknown
- 2004-03-19 MX MXPA05009238A patent/MXPA05009238A/es active IP Right Grant
- 2004-03-19 US US10/547,353 patent/US7504551B2/en not_active Expired - Lifetime
- 2004-03-19 JP JP2006504740A patent/JP4903038B2/ja not_active Expired - Lifetime
- 2004-03-19 DE DE602004002202T patent/DE602004002202T2/de not_active Expired - Lifetime
- 2004-03-19 BR BRPI0408243A patent/BRPI0408243B8/pt not_active IP Right Cessation
- 2004-03-19 EP EP04721850A patent/EP1610831B1/en not_active Expired - Lifetime
- 2004-03-19 AT AT04721850T patent/ATE337801T1/de not_active IP Right Cessation
- 2004-03-19 CN CNB200480007640XA patent/CN100525842C/zh not_active Expired - Lifetime
- 2004-03-19 WO PCT/EP2004/002874 patent/WO2004084962A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004084962A1 (en) | 2004-10-07 |
| EP1610831B1 (en) | 2006-08-30 |
| DE602004002202D1 (de) | 2006-10-12 |
| EP1610831A1 (en) | 2006-01-04 |
| CN100525842C (zh) | 2009-08-12 |
| ATE337801T1 (de) | 2006-09-15 |
| MXPA05009238A (es) | 2005-10-19 |
| TW200500046A (en) | 2005-01-01 |
| CN1761492A (zh) | 2006-04-19 |
| DE602004002202T2 (de) | 2007-01-04 |
| BRPI0408243B1 (pt) | 2015-03-17 |
| JP2006521431A (ja) | 2006-09-21 |
| JP4903038B2 (ja) | 2012-03-21 |
| BRPI0408243B8 (pt) | 2021-06-22 |
| US20060089611A1 (en) | 2006-04-27 |
| US7504551B2 (en) | 2009-03-17 |
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