BRPI0408722A - sistema adequado como um catalisador e processo para a hidrocianação de compostos olefinicamente insaturados - Google Patents

sistema adequado como um catalisador e processo para a hidrocianação de compostos olefinicamente insaturados

Info

Publication number
BRPI0408722A
BRPI0408722A BRPI0408722-4A BRPI0408722A BRPI0408722A BR PI0408722 A BRPI0408722 A BR PI0408722A BR PI0408722 A BRPI0408722 A BR PI0408722A BR PI0408722 A BRPI0408722 A BR PI0408722A
Authority
BR
Brazil
Prior art keywords
olefinically unsaturated
hydrocyanation
catalyst
unsaturated compounds
radicals
Prior art date
Application number
BRPI0408722-4A
Other languages
English (en)
Inventor
Michael Bartsch
Robert Baumann
Gerd Haderlein
Miguel Angel Flores
Tim Jungkamp
Hermann Luyken
Jean Scheidel
Wolfgang Siegel
Ferenc Molnar
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0408722A publication Critical patent/BRPI0408722A/pt
Publication of BRPI0408722B1 publication Critical patent/BRPI0408722B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"SISTEMA ADEQUADO COMO UM CATALISADOR E PROCESSO PARA A HIDROCIANAçãO DE COMPOSTOS OLEFINICAMENTE INSATURADOS". Um sistema que é adequado para o uso como um catalisador para a hidrocianação de compostos olefinicamente insaturados, contendo a) Ni(0), b) Ni(0) como um composto de fixação complexo de ligando contendo fósforo trivalente, c) um ácido de Lewis e d) um composto da fórmula MR~ n~ em que M = A1 ou Ti, R = radicais alcóxi monovalentes idênticos ou diferentes, em que vários radicais alcóxi podem ser interligados em ponte, também no caso onde M = A1, R = radicais alquila idênticos ou diferentes em que vários radicais alquila podem ser interligados em ponte ou um ou vários radicais alquila podem ser ligados em ponte por um ou vários dos radicais alcóxi acima mencionados, n = valência de M. A invenção também diz respeito aos métodos para a hidrocianação de um composto olefinicamente insaturado na presença do dito sistema.
BRPI0408722-4B1A 2003-03-31 2004-03-24 sistema adequado como um catalisador e processo para a hidrocianaÇço de compostos olefinicamente insaturados BRPI0408722B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10314761A DE10314761A1 (de) 2003-03-31 2003-03-31 Als Katalysator für die Hydrocyanierung von olefinisch ungesättigten Verbindungen geeignetes System
PCT/EP2004/003103 WO2004087314A1 (de) 2003-03-31 2004-03-24 Als katalysator für die hydrocyanierung von olefinisch ungesättigten verbindungen geeignetes system

Publications (2)

Publication Number Publication Date
BRPI0408722A true BRPI0408722A (pt) 2006-03-07
BRPI0408722B1 BRPI0408722B1 (pt) 2013-08-27

Family

ID=32980901

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0408722-4B1A BRPI0408722B1 (pt) 2003-03-31 2004-03-24 sistema adequado como um catalisador e processo para a hidrocianaÇço de compostos olefinicamente insaturados

Country Status (16)

Country Link
US (1) US7550407B2 (pt)
EP (1) EP1610893B1 (pt)
JP (1) JP4611282B2 (pt)
KR (1) KR100975473B1 (pt)
CN (1) CN100364666C (pt)
AR (1) AR043781A1 (pt)
AT (1) ATE355902T1 (pt)
BR (1) BRPI0408722B1 (pt)
CA (1) CA2520571A1 (pt)
DE (2) DE10314761A1 (pt)
ES (1) ES2284000T3 (pt)
MX (1) MXPA05009437A (pt)
MY (1) MY140496A (pt)
PL (1) PL1610893T3 (pt)
TW (1) TW200502037A (pt)
WO (1) WO2004087314A1 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
US7385071B2 (en) * 2003-10-28 2008-06-10 Invista North America S.A.R.L. Hydrocyanation of pentenenitriles and/or 2-methyl-3-butenenitrile using promoters obtained from the chlorination of titanium-rich ores
ES2532982T3 (es) 2005-10-18 2015-04-06 Invista Technologies S.À.R.L. Proceso de preparación de 3-aminopentanonitrilo
WO2007109005A2 (en) 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
EP2146930A2 (en) 2007-05-14 2010-01-27 INVISTA Technologies S.à.r.l. High efficiency reactor and process
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
WO2009091771A2 (en) 2008-01-15 2009-07-23 Invista Technologies S.A R.L Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
FR2926816B1 (fr) * 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2943061B1 (fr) * 2009-03-13 2011-02-25 Rhodia Operations Composes organophosphores, systemes catalytiques comprenant ces composes et procede d'hydrocyanation ou d'hydroformylation utilisant ces systemes catalytiques
CN102471218B (zh) 2009-08-07 2014-11-05 因温斯特技术公司 用于形成二酯的氢化并酯化
ES2542430T3 (es) 2010-07-07 2015-08-05 Invista Technologies S.À.R.L. Proceso para hacer nitrilos

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US3496217A (en) * 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
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Also Published As

Publication number Publication date
BRPI0408722B1 (pt) 2013-08-27
WO2004087314A1 (de) 2004-10-14
EP1610893A1 (de) 2006-01-04
DE10314761A1 (de) 2004-10-14
PL1610893T3 (pl) 2007-07-31
US20060258874A1 (en) 2006-11-16
JP4611282B2 (ja) 2011-01-12
ATE355902T1 (de) 2007-03-15
DE502004003136D1 (de) 2007-04-19
ES2284000T3 (es) 2007-11-01
CN1767895A (zh) 2006-05-03
EP1610893B1 (de) 2007-03-07
MY140496A (en) 2009-12-31
AR043781A1 (es) 2005-08-10
JP2006521918A (ja) 2006-09-28
US7550407B2 (en) 2009-06-23
KR100975473B1 (ko) 2010-08-11
KR20050115327A (ko) 2005-12-07
MXPA05009437A (es) 2005-11-23
CA2520571A1 (en) 2004-10-14
TW200502037A (en) 2005-01-16
CN100364666C (zh) 2008-01-30

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/03/2004, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)