BRPI0410379A - fosfinas monodentadas contendo nitrogênio e seu uso em catálise - Google Patents

fosfinas monodentadas contendo nitrogênio e seu uso em catálise

Info

Publication number
BRPI0410379A
BRPI0410379A BRPI0410379-3A BRPI0410379A BRPI0410379A BR PI0410379 A BRPI0410379 A BR PI0410379A BR PI0410379 A BRPI0410379 A BR PI0410379A BR PI0410379 A BRPI0410379 A BR PI0410379A
Authority
BR
Brazil
Prior art keywords
nitrogen
catalysis
containing monodentate
monodentate phosphines
phosphines
Prior art date
Application number
BRPI0410379-3A
Other languages
English (en)
Inventor
Alexander Zapf
Mark Sundermeier
Ralf Jackstell
Mathias Beller
Thomas Riermeier
Axel Monsees
Uwe Dingerdissen
Original Assignee
Degussa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa filed Critical Degussa
Publication of BRPI0410379A publication Critical patent/BRPI0410379A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/10—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/08—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions not involving the formation of amino groups, hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D295/155—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6503—Five-membered rings
    • C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Quinoline Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

"FOSFINAS MONODENTADAS CONTENDO NITROGêNIO E SEU USO EM CATáLISE". A presente invenção refere-se a ligantes de fosfano monodentado contendo nitrogênio de fórmula (I) e ao seu uso em reações catalíticas, especialmente no aperfeiçoamento de compostos haloaromáticos.
BRPI0410379-3A 2003-05-16 2004-05-03 fosfinas monodentadas contendo nitrogênio e seu uso em catálise BRPI0410379A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10322408A DE10322408A1 (de) 2003-05-16 2003-05-16 Stickstoffhaltige monodentate Phosphine und deren Verwendung in der Katalyse
PCT/EP2004/004644 WO2004101581A2 (en) 2003-05-16 2004-05-03 Nitrogen-containing monodentate phosphines and their use in catalysis

Publications (1)

Publication Number Publication Date
BRPI0410379A true BRPI0410379A (pt) 2006-06-13

Family

ID=33394752

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0410379-3A BRPI0410379A (pt) 2003-05-16 2004-05-03 fosfinas monodentadas contendo nitrogênio e seu uso em catálise

Country Status (11)

Country Link
US (1) US7589081B2 (pt)
EP (1) EP1625133B1 (pt)
JP (1) JP4589329B2 (pt)
KR (1) KR20060013540A (pt)
CN (1) CN100486980C (pt)
BR (1) BRPI0410379A (pt)
CA (1) CA2525890A1 (pt)
DE (1) DE10322408A1 (pt)
IL (1) IL171943A0 (pt)
RU (1) RU2005139155A (pt)
WO (1) WO2004101581A2 (pt)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2580856A1 (en) 2004-09-20 2006-03-30 Xenon Pharmaceuticals Inc. Heterocyclic derivatives and their use as stearoyl-coa desaturase inhibitors
EP2316458A1 (en) 2004-09-20 2011-05-04 Xenon Pharmaceuticals Inc. Pyridazine derivatives for inhibiting human stearoyl-coa-desaturase
US7767677B2 (en) 2004-09-20 2010-08-03 Xenon Pharmaceuticals Inc. Heterocyclic derivatives and their use as stearoyl-CoA desaturase inhibitors
EP1799667B1 (en) 2004-09-20 2013-03-20 Xenon Pharmaceuticals Inc. Heterocyclic derivatives and their use as therapeutic agents
EP2289510A1 (en) 2004-09-20 2011-03-02 Xenon Pharmaceuticals Inc. Heterocyclic derivatives for the treatment of diseases mediated by stearoyl-coa desaturase enzymes
EP1804799B1 (en) 2004-09-20 2013-08-21 Xenon Pharmaceuticals Inc. Heterocyclic derivatives and their use as stearoyl-coa desaturase inhibitors
US7951805B2 (en) 2004-09-20 2011-05-31 Xenon Pharmaceuticals Inc. Heterocyclic derivatives and their use as mediators of stearoyl-CoA desaturase
EP2029138A1 (en) 2005-06-03 2009-03-04 Xenon Pharmaceuticals Inc. Aminothiazole derivatives as human stearoyl-coa desaturase inhibitors
DE102006042439A1 (de) * 2006-09-09 2008-03-27 Saltigo Gmbh Verfahren zur katalytischen Herstellung von aromatischen oder heteroaromatischen Nitrilen
CN102449030B (zh) 2009-05-27 2014-06-25 巴斯夫欧洲公司 用于有机半导体器件中的二酮基吡咯并吡咯聚合物
US8835579B2 (en) * 2009-05-27 2014-09-16 Basf Se Process for polymerising (hetero)aromatic compounds
DE102009029050A1 (de) 2009-08-31 2011-03-03 Evonik Oxeno Gmbh Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen
DE102010001364B4 (de) 2010-01-29 2014-10-16 Technische Universität Chemnitz Neue P,O-Ferrocene, deren Herstellung und Verwendung in katalytischen Reaktionen
KR101839636B1 (ko) 2010-05-19 2018-03-16 바스프 에스이 유기 반도체 소자에 사용하기 위한 디케토피롤로피롤 중합체
WO2012017005A2 (en) 2010-08-05 2012-02-09 Basf Se Polymers based on benzodiones
DE102010041821A1 (de) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden
DE102010043558A1 (de) 2010-11-08 2012-05-10 Evonik Oxeno Gmbh Verfahren zur Hydroformylierung von ungesättigten Verbindungen
WO2012164479A1 (en) 2011-05-30 2012-12-06 Basf Se Process for the production of polymers by using coupling reactions
WO2013050401A2 (en) 2011-10-04 2013-04-11 Basf Se Polymers based on benzodiones
DE102011089008B4 (de) 2011-12-19 2017-08-24 Evonik Degussa Gmbh Verfahren zur Herstellung von Estern aus Formiaten und olefinisch ungesättigten Verbindungen
EP2834284B1 (en) 2012-04-02 2017-05-10 Basf Se Phenanthro[9,10-b]furan polymers and small molecules for electronic applications
KR102079604B1 (ko) 2012-04-04 2020-04-08 바스프 에스이 디케토피롤로피롤 중합체 및 소분자
JP6207606B2 (ja) 2012-07-23 2017-10-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ジチエノベンゾフランポリマーおよび電子的な応用のための小分子
US9748487B2 (en) 2012-11-07 2017-08-29 Basf Se Polymers based on naphthodiones
EP2928940B1 (en) 2012-12-04 2021-03-03 CLAP Co., Ltd. Functionalized benzodithiophene polymers for electronic application
DE102013201665A1 (de) * 2013-02-01 2014-08-07 Evonik Industries Ag Phosphor-Liganden und Verfahren zur selektiven Ruthenium-katalysierten Hydroaminomethylierung von Olefinen
WO2014206863A1 (en) 2013-06-24 2014-12-31 Basf Se Polymers based on fused diketopyrrolopyrroles
EP2818493A1 (en) 2013-06-25 2014-12-31 Basf Se Near infrared absorbing polymers for electronic applications
CN103418438B (zh) 2013-08-22 2015-08-19 上海化工研究院 一种氮杂卡宾类钯催化剂及其制备方法和应用
US10093692B2 (en) 2013-09-18 2018-10-09 The Hong Kong Polytechnic University Phosphines, synthesis thereof and their use in catalysis
CN103755579A (zh) * 2014-02-25 2014-04-30 徐州宇家化工科技有限公司 一类高位阻叔胺的制备方法
CN104610355B (zh) * 2015-01-27 2017-01-11 华东师范大学 基于吲哚骨架的中心手性亚磺酰胺类单膦配体及制备方法
PL3272732T3 (pl) 2016-07-19 2020-03-31 Evonik Degussa Gmbh Sposób alkoksykarbonylowania etylenowo nienasyconych związków za pomocą ligandów monofosfinowych
CN106967443A (zh) * 2017-04-28 2017-07-21 烟台德润液晶材料有限公司 烷基环己基联苯腈类液晶化合物的制备方法
WO2019163732A1 (ja) * 2018-02-26 2019-08-29 住友化学株式会社 化合物及び着色樹脂組成物
JP7132017B2 (ja) 2018-02-26 2022-09-06 住友化学株式会社 化合物及び着色樹脂組成物
EP3765551A1 (en) 2018-03-12 2021-01-20 3M Innovative Properties Company Anion exchange membranes based on polymerization of long chain alpha olefins
US11702486B2 (en) 2018-03-12 2023-07-18 3M Innovative Properties Company Hydrocarbon polymers containing ammonium functionality
WO2019177968A1 (en) 2018-03-12 2019-09-19 3M Innovative Properties Company Cationic polymers for use as anion exchange polyelectrolytes
US11254777B2 (en) 2018-03-12 2022-02-22 3M Innovative Properties Company Nitrogen-containing multi-block copolymers and method of making
CN110317132B (zh) * 2019-07-26 2021-09-10 南京工业大学 一种苯丁酸钠的制备方法
CN110330427B (zh) * 2019-07-26 2021-09-10 南京工业大学 一种芬布芬的合成方法
CN113801161A (zh) * 2020-06-15 2021-12-17 华东师范大学 咪唑类配体衍生物及其制备和在丁二烯调聚反应中的应用

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10100708A1 (de) 2001-01-10 2002-07-11 Oxeno Olefinchemie Gmbh Neue N-Phenylpyrrolbisphosphanverbindungen und deren Metallkomplexe

Also Published As

Publication number Publication date
IL171943A0 (en) 2006-04-10
US20070123707A1 (en) 2007-05-31
WO2004101581A2 (en) 2004-11-25
CN1791606A (zh) 2006-06-21
CA2525890A1 (en) 2004-11-25
JP2007505945A (ja) 2007-03-15
EP1625133B1 (en) 2016-06-29
DE10322408A1 (de) 2004-12-02
WO2004101581A3 (en) 2005-03-03
RU2005139155A (ru) 2007-06-27
US7589081B2 (en) 2009-09-15
KR20060013540A (ko) 2006-02-10
JP4589329B2 (ja) 2010-12-01
CN100486980C (zh) 2009-05-13
EP1625133A2 (en) 2006-02-15

Similar Documents

Publication Publication Date Title
WO2004101581A3 (en) Nitrogen-containing monodentate phosphines and their use in catalysis
Cadierno et al. Synthesis and reactivity of α, β-unsaturated alkylidene and cumulenylidene Group 8 half-sandwich complexes
DE60031697D1 (de) Multidentat-phosphit-liganden, sie enthaltende katalytische zusammensetzungen und ihre verwendung in hydrocyanierungsreaktionen
BR0116744A (pt) Compostos de n-fenilpirrolbisfosfano e seus complexos de metais
ES2180335T3 (es) Ligandos y complejos para la hidrogenacion enantioselectiva.
ATE480548T1 (de) Adamantylgruppen enthaltende phosphanliganden, deren herstellung und ihre verwendung in katalytischen reaktionen
NL300736I1 (pt)
MY142506A (en) Trimerisation and oligomerisation of olefins using a chromium based catalyst
MXPA04001348A (es) NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS.
NO20030108L (no) Olefintrimerisering ved bruk av en katalysator innbefattende krom-, molybden- eller wolframkilde og en ligand inneholdende minst et fosfor-,arsen- eller antimonatom bundet til minst ±n (hetero)hydrokarbylgruppe
TR200100918T2 (tr) Aril ve heteroaril sübstitüentli üreler kullanılarak RAF kinazın inhibe edilmesi
BR0108679A (pt) Novos compostos
ID26775A (id) Hidroformilasi olefin-olefin menggunakan ligan-ligan bis (fosfor) tersangga
MY146079A (en) Tetraphosphorus ligands for catalytic hydroformylation and related reactions
DE60041409D1 (de) Multidentat-phosphit-liganden und ihre verwendung in katalytischen zusammensetzungen für hydrocyanierungsverfahren
AR048153A1 (es) Procedimiento continuo para la preparacion de pentenonitrilos lineales
BR0315869A (pt) Uso de compostos de complexos de metais como catalisadores de oxidação
TW200502037A (en) System suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds
MY130628A (en) Phosphorus containing ligands for metathesis catalysts
DK1047669T3 (da) Perfluor-N-alkylsulfonsyrederivater
AU2003255395A8 (en) Novel nickel-carbene, palladium-carbene and platinum-carbene complexes, their production and use in catalytic reactions
DE50102861D1 (de) Cycloaliphatisch-aromatische diphosphine und ihre verwendung in der katalyse
YU36104A (sh) Kristalna struktura fosfodiesteraza 5 i njihova upotreba
PL359409A1 (en) Compounds useful for the preparation of medicaments with phosphodiesterase iv inhibitory activity
IL143032A0 (en) Method for preparing tris (ether-amine)

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE AS 4A, 5A, 6A, 7A E 8A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2159 DE 22/05/2012.