BRPI0411063A - processo para a produção de polipropileno usando catalisadores ziegler-natta de alto rendimento - Google Patents
processo para a produção de polipropileno usando catalisadores ziegler-natta de alto rendimentoInfo
- Publication number
- BRPI0411063A BRPI0411063A BRPI0411063-3A BRPI0411063A BRPI0411063A BR PI0411063 A BRPI0411063 A BR PI0411063A BR PI0411063 A BRPI0411063 A BR PI0411063A BR PI0411063 A BRPI0411063 A BR PI0411063A
- Authority
- BR
- Brazil
- Prior art keywords
- polypropylene
- production
- particles
- complex
- catalyst
- Prior art date
Links
- 239000004743 Polypropylene Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 6
- -1 polypropylene Polymers 0.000 title abstract 6
- 229920001155 polypropylene Polymers 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000000835 fiber Substances 0.000 abstract 3
- 239000002245 particle Substances 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 238000013019 agitation Methods 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920005594 polymer fiber Polymers 0.000 abstract 1
- 229920006254 polymer film Polymers 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
"PROCESSO PARA A PRODUçãO DE POLIPROPILENO USANDO CATALISADORES ZIEGLER-NATTA DE ALTO RENDIMENTO". A presente invenção refere-se a um processo para a produção de uma película ou fibra de polímero onde uma composição de polímero compreendendo um homo- ou copolímero de polipropileno é formado em uma película ou fibra, e onde o dito homo- ou copolímero de polipropileno é produzido em um processo que compreende a polimerização de monómeros de propileno ou monómeros de propileno e um ou mais tipos de comonómeros na presença de um catalisador de polimerização de olefina Ziegler-Natta de alto rendimento, catalisador que compreende um componente na forma de partículas tendo uma faixa de tamanho predeterminada que foi produzido em um processo compreendendo: a) preparação de uma solução de um complexo de um metal do grupo 2 e um doador de elétron através da reação de um composto do dito material com o dito doador de elétron ou um seu precursor em um meio de reação líquido orgânico, b) reação do dito complexo em solução com um composto de um metal de transição para produzir uma emulsão cuja fase dispersa contém mais de 50% em mol do metal do Grupo 2 no dito complexo, c) manutenção das partículas da dita fase dispersa dentro da faixa de tamanho média de 5 a 200 mícrons através de agitação na presença de um estabilizador de emulsão, e d) solidificação das ditas partículas e recuperação, opcionalmente lava gem das ditas partículas para se obter o dito componente de catalisador. A invenção refere-se ainda a produtos de polipropileno que podem ser obtidos através deste processo e ao uso de produtos de polipropileno na produção de películas ou fibras.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03012906A EP1484345A1 (en) | 2003-06-06 | 2003-06-06 | Process for the production of polypropylene using a Ziegler-Natta catalyst |
| PCT/EP2004/006053 WO2004111098A2 (en) | 2003-06-06 | 2004-06-04 | Process for the production of polypropylene using a ziegler-natta catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0411063A true BRPI0411063A (pt) | 2006-08-01 |
Family
ID=33155178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0411063-3A BRPI0411063A (pt) | 2003-06-06 | 2004-06-04 | processo para a produção de polipropileno usando catalisadores ziegler-natta de alto rendimento |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7465775B2 (pt) |
| EP (2) | EP1484345A1 (pt) |
| JP (1) | JP2006527271A (pt) |
| KR (1) | KR100990923B1 (pt) |
| CN (1) | CN1802392B (pt) |
| AU (1) | AU2004247364A1 (pt) |
| BR (1) | BRPI0411063A (pt) |
| CA (1) | CA2526144A1 (pt) |
| EA (1) | EA011642B1 (pt) |
| ES (1) | ES2536477T3 (pt) |
| WO (1) | WO2004111098A2 (pt) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1484345A1 (en) | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
| EP1717269A1 (en) | 2005-04-28 | 2006-11-02 | Borealis Technology Oy | Alpha-olefin homo-or copolymer compositions |
| EP1803743B1 (en) * | 2005-12-30 | 2016-08-10 | Borealis Technology Oy | Catalyst particles |
| EP1847555A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
| EP1862480B1 (en) * | 2006-05-31 | 2016-07-27 | Borealis Technology Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| ATE421760T1 (de) | 2006-07-10 | 2009-02-15 | Borealis Tech Oy | Elektrischer isolierfilm |
| PT2208749E (pt) * | 2006-07-10 | 2016-03-04 | Borealis Tech Oy | Películas de polipropileno orientadas biaxialmente |
| ATE427330T1 (de) | 2006-08-25 | 2009-04-15 | Borealis Tech Oy | Polypropylenschaumstoff |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| EP1941997B1 (en) * | 2006-12-18 | 2009-05-27 | Borealis Technology Oy | Terpolymer with high melting point |
| ATE424424T1 (de) | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
| EP1939227B1 (en) * | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
| RU2457290C2 (ru) * | 2007-03-26 | 2012-07-27 | Курарей Ко., Лтд. | Полипропиленовые волокна, способы их получения и их применение |
| DE602007001873D1 (de) * | 2007-05-08 | 2009-09-17 | Borealis Tech Oy | Folie zur elektrischen Isolierung |
| EP2030996A1 (en) | 2007-08-31 | 2009-03-04 | Borealis Technology Oy | Polyolefin compositions having improved optical and mechanical properties |
| EP2147939A1 (en) * | 2008-07-22 | 2010-01-27 | Borealis AG | Polypropylene composition with improved optics for film and moulding applications |
| EP2499175B2 (en) | 2009-11-11 | 2022-08-17 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| CN102666602B (zh) | 2009-11-11 | 2015-11-25 | 博瑞立斯有限公司 | 具有有利的电性能的可交联的聚合物组合物和电缆 |
| EP2499176B2 (en) | 2009-11-11 | 2022-08-10 | Borealis AG | Power cable comprising a polymer composition comprising a polyolefin produced in a high pressure process |
| CN102597093B (zh) | 2009-11-11 | 2015-01-07 | 博瑞立斯有限公司 | 电缆以及其生产方法 |
| KR101959473B1 (ko) | 2010-03-17 | 2019-03-18 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
| KR20130016285A (ko) | 2010-03-17 | 2013-02-14 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
| ES2385142T3 (es) | 2010-04-21 | 2012-07-18 | Borealis Ag | Composición de copolímero o propileno/1-hexeno con ventana de sellado amplia |
| EP2439238B1 (en) * | 2010-10-06 | 2012-12-05 | Borealis AG | Polypropylene with living hinge properties |
| EP2450910B1 (en) | 2010-11-03 | 2019-09-25 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| BR112013028282B1 (pt) | 2011-05-04 | 2021-07-06 | Borealis Ag | cabo de força de corrente direta (dc), processo para produção do mesmo e método para a redução, isto é, para a provisão de uma composição de um polímero de baixa condutibilidade elétrica de um cabo de força dc |
| EP2521137B1 (en) | 2011-05-04 | 2014-12-17 | Borealis AG | Polymer composition for electrical and communication devices |
| KR101891366B1 (ko) | 2011-05-04 | 2018-08-23 | 보레알리스 아게 | 전기 장치용 중합체 조성물 |
| US9978478B2 (en) | 2011-05-04 | 2018-05-22 | Borealis Ag | Polymer composition for electrical devices |
| EP2565221B2 (en) | 2011-08-30 | 2018-08-08 | Borealis AG | Process for the manufacture of a capacitor film |
| ES2727405T3 (es) * | 2011-12-30 | 2019-10-16 | Borealis Ag | Preparación de catalizadores de ZN PP libres de ftalato |
| WO2013148669A1 (en) | 2012-03-26 | 2013-10-03 | Freeslate, Inc. | Parallel reactor systems and methods for preparing materials |
| JP6030947B2 (ja) * | 2012-12-26 | 2016-11-24 | サン・トックス株式会社 | ポリオレフィン系無延伸多層フィルム |
| WO2014178897A1 (en) | 2013-04-30 | 2014-11-06 | Freeslate, Inc. | Methods for sampling from non-atmospheric vessels in a parallel reactor system |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US9593179B2 (en) | 2014-02-07 | 2017-03-14 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US9714302B2 (en) | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| WO2016066619A1 (en) | 2014-10-27 | 2016-05-06 | Borealis Ag | Polymer composition for cable applications with advantageous electrical properties |
| AU2016299098B2 (en) | 2015-07-30 | 2018-09-27 | Borealis Ag | Polypropylene composition with improved hot-tack force |
| US10385478B2 (en) | 2016-04-22 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | Process for forming a consumable filament |
| EP3445792B1 (en) * | 2016-04-22 | 2020-01-08 | Basell Poliolefine Italia S.r.l. | Propylene terpolymer for filament for 3d printer |
| CN110662773B (zh) * | 2017-06-30 | 2022-08-19 | 三井化学株式会社 | 丙烯系聚合物、其制造方法、丙烯系树脂组合物和成型体 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4181762A (en) * | 1976-03-10 | 1980-01-01 | Brunswick Corporation | Fibers, yarns and fabrics of low modulus polymer |
| EP0115940B2 (en) * | 1983-01-25 | 1997-03-19 | Mitsui Petrochemical Industries, Ltd. | Film-forming propylene copolymer, film thereof and process for production of the film |
| DE4202663A1 (de) * | 1992-01-31 | 1993-08-05 | Alkor Gmbh | Kunststoffolie auf der basis eines polypropylenterpolymerisates, verfahren zu deren herstellung und verwendung |
| US6184328B1 (en) * | 1994-09-07 | 2001-02-06 | Showa Denko Kabushiki Kaisha | Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production |
| JP3497080B2 (ja) * | 1994-05-12 | 2004-02-16 | 昭和電工株式会社 | プロピレン系重合体の重合用触媒成分の製法 |
| WO1995031490A1 (en) * | 1994-05-12 | 1995-11-23 | Showa Denko K. K. | Propylene polymer, process for producing the same, composition thereof, polymerization catalyst component, and process for producing the same |
| JPH08198913A (ja) * | 1995-01-26 | 1996-08-06 | Sumitomo Chem Co Ltd | ポリプロピレンフイルム |
| DE19813399A1 (de) * | 1998-03-26 | 1999-09-30 | Basf Ag | Statistische Propylencopolymerisate |
| FR2776660B1 (fr) | 1998-03-27 | 2000-05-12 | Parke Davis | Diazepino-indoles de phosphodiesterases iv |
| JP2003535178A (ja) * | 2000-05-31 | 2003-11-25 | バセル テクノロジー カンパニー ビー．ブイ． | 改善された衝撃強さと優れた光学特性を有するプロピレンポリマー組成物 |
| ATE328912T1 (de) * | 2001-06-20 | 2006-06-15 | Borealis Tech Oy | Herstellung eines katalysatorbestandteils zur olefinpolymerisation |
| EP1302486A1 (en) * | 2001-10-09 | 2003-04-16 | Borealis Technology Oy | Process for the production of propylene copolymers |
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| US7361720B2 (en) | 2002-10-07 | 2008-04-22 | Dow Global Technologies Inc. | Highly crystalline polypropylene with low xylene solubles |
| JP3885034B2 (ja) * | 2003-03-12 | 2007-02-21 | 東邦キャタリスト株式会社 | オレフィン類重合用固体触媒成分の調製方法 |
| EP1484345A1 (en) | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
-
2003
- 2003-06-06 EP EP03012906A patent/EP1484345A1/en not_active Withdrawn
-
2004
- 2004-06-04 CN CN2004800157074A patent/CN1802392B/zh not_active Expired - Fee Related
- 2004-06-04 BR BRPI0411063-3A patent/BRPI0411063A/pt not_active IP Right Cessation
- 2004-06-04 WO PCT/EP2004/006053 patent/WO2004111098A2/en not_active Ceased
- 2004-06-04 AU AU2004247364A patent/AU2004247364A1/en not_active Abandoned
- 2004-06-04 EP EP04736049.0A patent/EP1631601B1/en not_active Revoked
- 2004-06-04 CA CA002526144A patent/CA2526144A1/en not_active Abandoned
- 2004-06-04 ES ES04736049.0T patent/ES2536477T3/es not_active Expired - Lifetime
- 2004-06-04 KR KR1020057023424A patent/KR100990923B1/ko not_active Expired - Fee Related
- 2004-06-04 EA EA200501657A patent/EA011642B1/ru not_active IP Right Cessation
- 2004-06-04 US US10/559,484 patent/US7465775B2/en not_active Expired - Fee Related
- 2004-06-04 JP JP2006508279A patent/JP2006527271A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2004247364A1 (en) | 2004-12-23 |
| US7465775B2 (en) | 2008-12-16 |
| CN1802392B (zh) | 2010-10-13 |
| WO2004111098A2 (en) | 2004-12-23 |
| EA200501657A1 (ru) | 2006-06-30 |
| EP1631601B1 (en) | 2015-04-29 |
| KR100990923B1 (ko) | 2010-11-01 |
| JP2006527271A (ja) | 2006-11-30 |
| CN1802392A (zh) | 2006-07-12 |
| EA011642B1 (ru) | 2009-04-28 |
| EP1484345A1 (en) | 2004-12-08 |
| WO2004111098A3 (en) | 2005-08-04 |
| ES2536477T3 (es) | 2015-05-25 |
| EP1631601A2 (en) | 2006-03-08 |
| US20060235172A1 (en) | 2006-10-19 |
| KR20060028685A (ko) | 2006-03-31 |
| CA2526144A1 (en) | 2004-12-23 |
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