BRPI0411235A - dispersão composta de partìculas de óxido de zinco em um meio de dispersão, óxido de zinco particulado, produto de filtro solar, e, uso de um óxido de zinco ou dispersão - Google Patents
dispersão composta de partìculas de óxido de zinco em um meio de dispersão, óxido de zinco particulado, produto de filtro solar, e, uso de um óxido de zinco ou dispersãoInfo
- Publication number
- BRPI0411235A BRPI0411235A BRPI0411235A BRPI0411235A BR PI0411235 A BRPI0411235 A BR PI0411235A BR PI0411235 A BRPI0411235 A BR PI0411235A BR PI0411235 A BRPI0411235 A BR PI0411235A
- Authority
- BR
- Brazil
- Prior art keywords
- zinc oxide
- dispersion
- volume
- particles
- sunscreen product
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/04—Compounds of zinc
- C09C1/043—Zinc oxide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/62—L* (lightness axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Nanotechnology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Biotechnology (AREA)
- Biophysics (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Medical Informatics (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Pharmacology & Pharmacy (AREA)
- Molecular Biology (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Cosmetics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
"DISPERSãO COMPOSTA DE PARTìCULAS DE óXIDO DE ZINCO EM UM MEIO DE DISPERSãO, óXIDO DE ZINCO PARTICULADO, PRODUTO DE FILTRO SOLAR, E, USO DE UM óXIDO DE ZINCO OU DISPERSãO". Uma dispersão contendo partículas de óxido de zinco, tendo um tamanho de particulas da dispersão de (i) diâmetro de partícula de volume médio na faixa de 70 a 130 nm, (ii) menos de 16% em volume de partículas, tendo um diâmetro de volume menor que 35 nm abaixo do diâmetro de partícula de volume médio, e (iii) mais de 84% em volume de partículas tendo um diâmetro de volume menor que 57 nm acima do diâmetro de partícula de volume médio. A dispersão de óxido de zinco pode ser utilizada em um produto de filtro solar que apresente tanto uma proteção efetiva contra UV, como uma transparência melhorada. O óxido de zinco é especialmente adequado para uso em combinação com o dióxido de titânio transparente.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0313432.7 | 2003-06-11 | ||
| GB0313432A GB0313432D0 (en) | 2003-06-11 | 2003-06-11 | Particulate zinc oxide |
| PCT/GB2004/002480 WO2004108599A1 (en) | 2003-06-11 | 2004-06-10 | Zinc oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0411235A true BRPI0411235A (pt) | 2006-07-11 |
| BRPI0411235B1 BRPI0411235B1 (pt) | 2021-03-09 |
Family
ID=27589840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0411235-0A BRPI0411235B1 (pt) | 2003-06-11 | 2004-06-10 | dispersão composta de partículas de óxido de zinco em um meio de dispersão, óxido de zinco particulado, produto de filtro solar, uso de um óxido de zinco particulado ou de uma dispersão |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7390355B2 (pt) |
| EP (1) | EP1631526B1 (pt) |
| JP (1) | JP4709142B2 (pt) |
| KR (1) | KR101118780B1 (pt) |
| CN (1) | CN100371250C (pt) |
| BR (1) | BRPI0411235B1 (pt) |
| CA (1) | CA2527234C (pt) |
| GB (1) | GB0313432D0 (pt) |
| RU (1) | RU2349617C2 (pt) |
| WO (1) | WO2004108599A1 (pt) |
| ZA (1) | ZA200509660B (pt) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0015381D0 (en) * | 2000-06-26 | 2000-08-16 | Acma Ltd | Particulate metal oxide |
| US9556376B2 (en) * | 2004-05-13 | 2017-01-31 | Baker Hughes Incorporated | Solids suspension with nanoparticle-associated viscoelastic surfactant micellar fluids |
| ATE415379T1 (de) * | 2005-04-05 | 2008-12-15 | Univ Hannover | Schwefel-modifiziertes zinkoxid der formel zn(1- y)m(y)o(1-x)s(x) (x=0.01-0.08, y=0-0,2) |
| DE102005062097A1 (de) * | 2005-12-22 | 2007-07-05 | Stada Arzneimittel Ag | Lichtschutzzubereitung mit Mikropigmenten |
| GB0610240D0 (en) | 2006-05-23 | 2006-07-05 | Sun Chemical Ltd | Dispersions of nano-sized materials |
| EP2027198A2 (en) * | 2006-06-15 | 2009-02-25 | CRODA INTERNATIONAL plc | Uv absorbing composition |
| EP2031048B2 (en) | 2007-08-31 | 2019-05-01 | The Procter and Gamble Company | Liquid acidic hard surface cleaning composition |
| US8784854B2 (en) | 2008-03-20 | 2014-07-22 | Amorepacific Corporation | Cosmetic product comprising UV-blocking cosmetic composition impregnated into expanded urethane foam |
| US20110223124A1 (en) * | 2008-10-07 | 2011-09-15 | Drovetskaya Tatiana V | Hair care compositions and methods |
| EP2243517A1 (de) * | 2009-04-20 | 2010-10-27 | Dr. Straetmans GmbH | Kosmetische oder dermatologische Zubereitung |
| CN102665666A (zh) | 2009-06-30 | 2012-09-12 | 陶氏环球技术有限责任公司 | 含防晒剂的可溶解膜 |
| AU2010340095B2 (en) | 2009-12-16 | 2016-09-29 | Dow Global Technologies Llc. | Sunscreen compositions incorporating methylcellulose as an SPF and/or PPD booster and methods |
| GB0922552D0 (en) | 2009-12-23 | 2010-02-10 | Croda Int Plc | Particulate titanium dioxide |
| WO2012135265A2 (en) | 2011-03-31 | 2012-10-04 | Rohm And Haas Chemicals Llc | Suncare compositions and methods |
| US9139737B1 (en) * | 2011-11-21 | 2015-09-22 | Nanophase Technologies Corporation | Multifunctional coated powders and high solids dispersions |
| US20140377197A1 (en) | 2011-12-22 | 2014-12-25 | Dow Global Technologies Llc | Suncare formulations and methods |
| JP2014231365A (ja) * | 2013-05-28 | 2014-12-11 | 凸版印刷株式会社 | ガスバリア性包装材料 |
| US9744111B2 (en) | 2014-07-11 | 2017-08-29 | Mary Kay Inc. | Sunscreen compositions and methods of their use |
| US9653373B2 (en) | 2015-04-09 | 2017-05-16 | Samsung Electronics Co., Ltd. | Semiconductor package including heat spreader and method for manufacturing the same |
| CN104843767B (zh) * | 2015-05-13 | 2017-04-12 | 湖南尔康制药股份有限公司 | 一种药用纳米氧化锌的制备方法 |
| US9883994B2 (en) | 2015-09-03 | 2018-02-06 | International Business Machines Corporation | Implementing organic materials in sunscreen applications |
| US10952942B2 (en) | 2015-09-03 | 2021-03-23 | International Business Machines Corporation | Plasmonic enhancement of zinc oxide light absorption for sunscreen applications |
| US10772808B2 (en) | 2015-09-03 | 2020-09-15 | International Business Machines Corporation | Anti-reflective coating on oxide particles for sunscreen applications |
| US10682294B2 (en) | 2015-09-03 | 2020-06-16 | International Business Machines Corporation | Controlling zinc oxide particle size for sunscreen applications |
| US9937112B2 (en) | 2015-09-03 | 2018-04-10 | International Business Machines Corporation | Doping of zinc oxide particles for sunscreen applications |
| US9883993B2 (en) | 2015-09-03 | 2018-02-06 | International Business Machines Corporation | Notch filter coatings for use in sunscreen applications |
| US9993402B2 (en) | 2015-09-03 | 2018-06-12 | International Business Machines Corporation | Sunscreen additives for enhancing vitamin D production |
| US10369092B2 (en) | 2015-09-03 | 2019-08-06 | International Business Machines Corporation | Nitride-based nanoparticles for use in sunscreen applications |
| WO2017069143A1 (ja) * | 2015-10-20 | 2017-04-27 | 凸版印刷株式会社 | コーティング液およびガスバリア性積層体 |
| US10092487B2 (en) | 2015-10-22 | 2018-10-09 | International Business Machines Corporation | Plasmonic enhancement of absorption in sunscreen applications |
| US10045918B2 (en) | 2015-10-22 | 2018-08-14 | International Business Machines Corporation | Embedding oxide particles within separate particles for sunscreen applications |
| US10076475B2 (en) | 2015-10-23 | 2018-09-18 | International Business Machines Corporation | Shell-structured particles for sunscreen applications |
| EP3480279A4 (en) * | 2016-06-30 | 2020-01-01 | Sakai Chemical Industry Co., Ltd. | ZINC OXIDE FLUORESCENT BODY, AND MANUFACTURING METHOD THEREOF |
| EP3624756B8 (en) * | 2017-05-17 | 2022-10-05 | VeganicSKN Limited | Sunscreen composition |
| CN107625656A (zh) * | 2017-09-12 | 2018-01-26 | 澳宝化妆品(惠州)有限公司 | 高稳定性和铺展性的氧化锌组合物及其制备方法和应用 |
| WO2020087121A1 (en) * | 2018-10-30 | 2020-05-07 | Advance NanoTek Ltd. | Anti-acne composition |
| KR102678104B1 (ko) * | 2018-11-19 | 2024-06-26 | 솔브레인 주식회사 | 폴리하이드록시스테아르산으로 표면개질된 세륨옥사이드 입자를 포함하는 자외선 차단제 조성물 및 이의 제조방법 |
| KR20220097948A (ko) * | 2019-11-05 | 2022-07-08 | 디에스엠 아이피 어셋츠 비.브이. | 점착성이 적은 자외선 차단 조성물 |
| US11672744B2 (en) * | 2020-07-02 | 2023-06-13 | Nanophase Technologies Corporation | Zinc oxide particles, photostable UV filters, and methods of use thereof |
| JPWO2023140123A1 (pt) * | 2022-01-21 | 2023-07-27 | ||
| US20260021026A1 (en) * | 2024-07-09 | 2026-01-22 | Formulated Solutions, Llc | Mineral formulation |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US536660A (en) * | 1895-04-02 | Feed-water heater | ||
| MY100306A (en) * | 1985-12-18 | 1990-08-11 | Kao Corp | Anti-suntan cosmetic composition |
| GB8829402D0 (en) * | 1988-12-16 | 1989-02-01 | Tioxide Group Plc | Dispersion |
| JPH02289506A (ja) * | 1989-02-08 | 1990-11-29 | Sakai Chem Ind Co Ltd | 化粧料用酸化亜鉛 |
| GB9121143D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Limited | Dispersions |
| GB9121153D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Ltd | Method of preparing sunscreens |
| JPH0725614A (ja) * | 1993-07-07 | 1995-01-27 | Kao Corp | 酸化亜鉛超微粒子及びその製造方法 |
| JPH083026A (ja) * | 1994-06-20 | 1996-01-09 | Toyo Ink Mfg Co Ltd | 化粧料 |
| US5575988A (en) * | 1995-04-07 | 1996-11-19 | Littlepoint Corp. | Combination sunscreen and insect repellent |
| FR2744914B1 (fr) * | 1996-02-15 | 1998-03-20 | Rhone Poulenc Chimie | Dispersion de dioxyde de titane, poudre a base de dioxyde de titane, leur utilisation dans les formulations cosmetiques |
| GB9616978D0 (en) * | 1996-08-13 | 1996-09-25 | Tioxide Specialties Ltd | Zinc oxide dispersions |
| JPH11106216A (ja) * | 1997-10-01 | 1999-04-20 | Kao Corp | 酸化亜鉛分散液及びこれを配合してなる化粧料 |
| JP2002539064A (ja) * | 1999-03-10 | 2002-11-19 | ナノグラム・コーポレーション | 亜鉛酸化物粒子 |
| GB9912002D0 (en) * | 1999-05-25 | 1999-07-21 | Acma Ltd | Metal oxide dispersions |
| GB0015381D0 (en) * | 2000-06-26 | 2000-08-16 | Acma Ltd | Particulate metal oxide |
| JP2002104822A (ja) * | 2000-09-29 | 2002-04-10 | Unitika Ltd | 分散性の良好な酸化亜鉛超微粒子水分散液およびその製造方法 |
| GB0130658D0 (en) * | 2001-12-21 | 2002-02-06 | Acma | Particulate metal oxide |
| AUPS080802A0 (en) * | 2002-02-27 | 2002-03-21 | Advanced Powder Technology Pty Ltd | A zinc oxide powder for use in a sunscreen composition |
| JP2004035632A (ja) * | 2002-07-01 | 2004-02-05 | Tayca Corp | 高い透明性と紫外線遮蔽能を有する無機酸化物分散体および分散方法 |
-
2003
- 2003-06-11 GB GB0313432A patent/GB0313432D0/en not_active Ceased
-
2004
- 2004-06-10 WO PCT/GB2004/002480 patent/WO2004108599A1/en not_active Ceased
- 2004-06-10 US US10/559,276 patent/US7390355B2/en not_active Expired - Lifetime
- 2004-06-10 JP JP2006516397A patent/JP4709142B2/ja not_active Expired - Fee Related
- 2004-06-10 CA CA2527234A patent/CA2527234C/en not_active Expired - Lifetime
- 2004-06-10 KR KR1020057023630A patent/KR101118780B1/ko not_active Expired - Fee Related
- 2004-06-10 BR BRPI0411235-0A patent/BRPI0411235B1/pt active IP Right Grant
- 2004-06-10 EP EP04742908.9A patent/EP1631526B1/en not_active Expired - Lifetime
- 2004-06-10 CN CNB2004800161718A patent/CN100371250C/zh not_active Expired - Lifetime
- 2004-06-10 RU RU2006100309A patent/RU2349617C2/ru active
-
2005
- 2005-11-29 ZA ZA200509660A patent/ZA200509660B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1631526B1 (en) | 2016-08-10 |
| KR20060025166A (ko) | 2006-03-20 |
| JP2006527160A (ja) | 2006-11-30 |
| KR101118780B1 (ko) | 2012-03-20 |
| CN100371250C (zh) | 2008-02-27 |
| JP4709142B2 (ja) | 2011-06-22 |
| CN1805902A (zh) | 2006-07-19 |
| US7390355B2 (en) | 2008-06-24 |
| CA2527234A1 (en) | 2004-12-16 |
| CA2527234C (en) | 2011-11-22 |
| ZA200509660B (en) | 2006-09-27 |
| US20060228310A1 (en) | 2006-10-12 |
| RU2006100309A (ru) | 2006-05-27 |
| WO2004108599A1 (en) | 2004-12-16 |
| EP1631526A1 (en) | 2006-03-08 |
| GB0313432D0 (en) | 2003-07-16 |
| BRPI0411235B1 (pt) | 2021-03-09 |
| RU2349617C2 (ru) | 2009-03-20 |
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