BRPI0412529A - composições para estabilização de cor e método para produção das mesmas - Google Patents
composições para estabilização de cor e método para produção das mesmasInfo
- Publication number
- BRPI0412529A BRPI0412529A BRPI0412529-0A BRPI0412529A BRPI0412529A BR PI0412529 A BRPI0412529 A BR PI0412529A BR PI0412529 A BRPI0412529 A BR PI0412529A BR PI0412529 A BRPI0412529 A BR PI0412529A
- Authority
- BR
- Brazil
- Prior art keywords
- antioxidants
- producing
- color stabilization
- polyisocyanate
- antioxidant
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 230000006641 stabilisation Effects 0.000 title abstract 2
- 238000011105 stabilization Methods 0.000 title abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 6
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000005264 aryl amine group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- -1 hydrogen compound Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000008301 phosphite esters Chemical class 0.000 abstract 1
- 239000011527 polyurethane coating Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
"COMPOSIçõES PARA ESTABILIZAçãO DE COR E MéTODO PARA PRODUçãO DAS MESMAS". Uma composição de enrijecimento para utilização como um componente de uma composição de revestimento de poliuretano de dois estágios, compreendendo um poliisocianato, um catalisador para promoção da reação do poliisocianato com um composto de hidrogênio reativo e um ou mais antioxidantes selecionados a partir de: um primeiro antioxidante compreendendo um ou mais antioxidantes de fenol estericamente impedidos e antioxidantes de arilamina secundária, e um segundo antioxidante compreendendo um ou mais antioxidantes de organofosfito, exibe estabilidade de cor melhorada.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48717703P | 2003-07-14 | 2003-07-14 | |
| PCT/US2004/022759 WO2005089085A2 (en) | 2003-07-14 | 2004-07-14 | Improved color stability of isocyanates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0412529A true BRPI0412529A (pt) | 2006-09-19 |
| BRPI0412529B1 BRPI0412529B1 (pt) | 2015-11-24 |
Family
ID=34994136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0412529A BRPI0412529B1 (pt) | 2003-07-14 | 2004-07-14 | composições para estabilização de cor e método para produção das mesmas |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7297746B2 (pt) |
| EP (1) | EP1732965B1 (pt) |
| JP (2) | JP5112693B2 (pt) |
| CN (1) | CN101061067B (pt) |
| BR (1) | BRPI0412529B1 (pt) |
| CA (1) | CA2532294A1 (pt) |
| ES (1) | ES2450166T3 (pt) |
| PL (1) | PL1732965T3 (pt) |
| WO (1) | WO2005089085A2 (pt) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2898905B1 (fr) * | 2006-03-24 | 2008-05-09 | Rhodia Recherches & Tech | Composition polyisocyanate a proprietes anti-chocs ameliorees |
| US20090221728A9 (en) * | 2006-11-21 | 2009-09-03 | Basf Corporation | Method of making polyurethane foam |
| CN101641387B (zh) * | 2007-03-27 | 2014-01-15 | 巴斯夫欧洲公司 | 固化组合物 |
| FR2914309B1 (fr) * | 2007-03-27 | 2011-07-08 | Rhodia Recherches & Tech | Composition a base de (poly)isocyanate modifie et d'un solvant de type acetal ou cetone aliphatique,et utilisation de cette composition pour la fabrication de revetements |
| WO2011061314A1 (de) | 2009-11-23 | 2011-05-26 | Basf Se | Katalysatoren für polyurethanbeschichtungsmassen |
| EP2771376B1 (de) | 2011-10-28 | 2021-02-24 | Basf Se | Farbstabile härterzusammensetzungen enthaltend polyisocyanate (cyclo)aliphatischer diisocyanate |
| JP5924813B2 (ja) * | 2012-04-04 | 2016-05-25 | 関西ペイント株式会社 | 複層塗膜形成方法 |
| US9790399B2 (en) | 2013-07-23 | 2017-10-17 | Axalta Coatings Systems Ip Co. Llc | Clear coat component |
| CN104212160A (zh) * | 2014-09-18 | 2014-12-17 | 苏州市雄林新材料科技有限公司 | 一种高耐黄变型透明tpu薄膜及其制备方法 |
| JP6695112B2 (ja) * | 2015-08-31 | 2020-05-20 | 旭化成株式会社 | ポリイソシアネート組成物及びその製造方法 |
| EP3305824A1 (de) | 2016-10-07 | 2018-04-11 | Basf Se | Farbstabile härterzusammensetzungen enthaltend polyisocyanate (cyclo)aliphatischer diisocyanate |
| CN109790269B (zh) * | 2016-10-14 | 2022-06-14 | 旭化成株式会社 | 异氰酸酯组合物、异氰酸酯组合物的制造方法以及异氰酸酯聚合物的制造方法 |
| CN108017766B (zh) * | 2016-11-01 | 2020-12-01 | 中国石油化工集团公司 | 一种用于防止或减轻聚氨酯软泡变红的复合抗氧剂及其应用 |
| EP3431521A1 (de) * | 2017-07-20 | 2019-01-23 | Basf Se | Farbstabile härterzusammensetzungen enthaltend polyisocyanate (cyclo)aliphatischer diisocyanate |
| EP3336117A1 (de) * | 2017-09-20 | 2018-06-20 | Basf Se | Verfahren zur herstellung von in lösungsmitteln flockulationsstabilen polyisocyanaten von (cyclo)aliphatischen diisocyanaten |
| EP3336118A1 (de) * | 2017-09-20 | 2018-06-20 | Basf Se | Farbstabile härterzusammensetzungen enthaltend polyisocyanate (cyclo)aliphatischer diisocyanate |
| FR3078707B1 (fr) * | 2018-03-06 | 2020-12-25 | Vencorex France | Composition de polyisocyanates |
| EP3875513A1 (de) * | 2018-04-25 | 2021-09-08 | Covestro Intellectual Property GmbH & Co. KG | Ionisch hydrophilierte polyisocyanate und radikalfänger und/oder peroxidzersetzer |
| GB2579405B (en) | 2018-11-30 | 2022-09-14 | Si Group Switzerland Chaa Gmbh | Antioxidant compositions |
| KR102710406B1 (ko) * | 2019-08-23 | 2024-09-25 | 한화솔루션 주식회사 | 폴리이소시아네이트 조성물의 제조방법 |
| CN111129323B (zh) * | 2019-12-03 | 2022-09-09 | 深圳市华星光电半导体显示技术有限公司 | 显示面板、锡基钙钛矿发光器件及其制备方法 |
| CN110878033B (zh) * | 2019-12-05 | 2022-04-22 | 万华化学集团股份有限公司 | 一种功能型降色剂以及稳定二异氰酸酯产品的色号的方法 |
| CN115427473A (zh) * | 2020-01-30 | 2022-12-02 | 巴斯夫欧洲公司 | 包含水分散性聚异氰酸酯的颜色稳定的固化剂组合物 |
| CN116547331A (zh) | 2020-12-18 | 2023-08-04 | 巴斯夫欧洲公司 | 包含脂(环)族二异氰酸酯的多异氰酸酯的颜色稳定的固化剂组合物 |
| JP2024521009A (ja) * | 2021-04-26 | 2024-05-28 | ビーエーエスエフ ソシエタス・ヨーロピア | ジイソシアネート安定剤、その使用、及びジイソシアネート組成物 |
| CN114605287B (zh) * | 2022-03-31 | 2023-05-30 | 中国科学院过程工程研究所 | 一种用于提高非光气xdi稳定性的复配稳定剂及其制备方法和应用 |
| WO2026040074A1 (en) | 2024-08-23 | 2026-02-26 | Basf Se | Process for the provision of aliphatic polyisocyanurate |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2957A (en) | 1843-02-16 | Churn-dashee | ||
| US3715A (en) | 1844-08-23 | Machine eob sawing laths and clapboabds | ||
| US381A (en) | 1837-09-12 | Samuel nicolsonj of bo | ||
| US4297A (en) | 1845-12-06 | Improvement in pressing glass in molds | ||
| US472A (en) | 1837-11-23 | Improvement in horse-rakes | ||
| US362A (en) | 1837-08-18 | Tongs | ||
| US4065A (en) | 1845-06-02 | Arnold hosmer | ||
| US3A (en) | 1836-08-01 | 1836-08-11 | Thomas Blanchard | Machine for turning and wooden sheaves and pins for ships' tackle blocks and pulleys |
| US3069369A (en) | 1957-11-14 | 1962-12-18 | Monsanto Chemicals | Color stabilized polyethylene compounds |
| US2957903A (en) * | 1959-03-24 | 1960-10-25 | Du Pont | Stabilization of organic isocyanates |
| US3115465A (en) * | 1960-04-11 | 1963-12-24 | Ethyl Corp | Stabilized compositions of matter |
| GB923190A (en) | 1961-04-11 | 1963-04-10 | Ethyl Corp | Antioxidant compositions |
| BE672561A (pt) | 1964-12-01 | 1966-03-16 | ||
| US3535277A (en) * | 1967-06-05 | 1970-10-20 | Goodyear Tire & Rubber | Blends of phosphites and phenols and polymers stabilized therewith |
| IL30848A0 (en) | 1967-10-12 | 1968-12-26 | Diamond Shamrock Corp | Vinyl fluoride resinous compositions and method of stabilizing them |
| US3715381A (en) * | 1969-06-11 | 1973-02-06 | Allied Chem | Polyisocyanate compositions stabilized against discoloration |
| US3772218A (en) * | 1971-10-12 | 1973-11-13 | Scott Paper Co | Flexible,open-cell,non-discoloring polyurethane foam |
| JPS5337852B2 (pt) * | 1974-06-04 | 1978-10-12 | ||
| US4064157A (en) * | 1976-03-29 | 1977-12-20 | The Dow Chemical Company | Stabilization of polyisocyanates against discoloration |
| US4297472A (en) * | 1977-08-26 | 1981-10-27 | Mobay Chemical Corporation | Method of producing color stable thermoplastic polymethanes and products made thereby |
| US4305839A (en) | 1978-10-26 | 1981-12-15 | Carstab Corporation | Hydroxybenzophenones |
| JPS5918733A (ja) * | 1982-07-22 | 1984-01-31 | Sanyo Chem Ind Ltd | 表皮付ウレタンフオ−ム用コ−テイング剤 |
| JPS61126149A (ja) * | 1984-11-21 | 1986-06-13 | Kao Corp | ポリウレタン用複合安定剤 |
| US4740424A (en) | 1985-08-02 | 1988-04-26 | Minnesota Mining And Manufacturing Company | Curable composition having high tack and green strength |
| US4677154A (en) * | 1985-12-18 | 1987-06-30 | Basf Corporation | Stabilizer package for polyurethane comprising a substituted cresol and another costabilizer |
| US4814103A (en) * | 1988-02-18 | 1989-03-21 | Mobay Corporation | Color stable urethane prepolymer |
| EP0425710B1 (en) | 1989-05-16 | 1996-01-24 | Nippon Polyurethane Industry Co. Ltd. | Method of producing modified organic polyisocyanate |
| US4933374A (en) * | 1989-05-24 | 1990-06-12 | R. T. Vanderbilt Company, Inc. | Stabilizer compositions for polyols and polyurethane foam |
| DE4006976A1 (de) * | 1990-03-06 | 1991-09-12 | Basf Ag | Verfahren zur herstellung von mischungen aus diphenylmethan-diisocyanaten und polyphenyl-polymethylen-polyisocyanaten mit einer verminderten iodfarbzahl |
| DE59101819D1 (de) * | 1990-03-07 | 1994-07-14 | Bayer Ag | Stabilisierung von organischen Polyisocyanaten. |
| AU643883B2 (en) * | 1991-03-19 | 1993-11-25 | Mitsui Toatsu Chemicals Inc. | Stabilizing method of isocyanate compounds and isocyanate compositions stabilized thereby |
| US5194559A (en) * | 1991-03-25 | 1993-03-16 | Mitsui Toatsu Chemicals, Inc. | Optical urethane resins and plastic lenses comprising the same |
| US5182310A (en) * | 1991-07-25 | 1993-01-26 | Dow Chemical Company | Isocyanate-reactive composition and process for preparing a flexible polyurethane foam |
| JP2988755B2 (ja) * | 1991-09-09 | 1999-12-13 | 住友バイエルウレタン株式会社 | 芳香族イソシアネート化合物の着色防止法 |
| US5156762A (en) * | 1992-02-18 | 1992-10-20 | R. T. Vanderbilt Company, Inc. | Synergistic stabilizer compositions for polyols and polyurethane foam |
| JPH05345871A (ja) * | 1992-06-16 | 1993-12-27 | Kansai Paint Co Ltd | 硬化剤組成物 |
| WO1994019385A1 (en) | 1993-02-23 | 1994-09-01 | Shell Internationale Research Maatschappij B.V. | Process for preparation of stable, moulded thermoset polymers of cyclo-olefins and thermoset moulded polymers |
| DE4309141A1 (de) * | 1993-03-22 | 1994-09-29 | Bayer Ag | Neue zyklische Phosphorigsäureester, ein Verfahren zu deren Herstellung sowie deren Verwendung |
| US6624301B1 (en) * | 1995-03-25 | 2003-09-23 | Degussa Ag | Process for the preparation of (cyclo)aliphatic uretdiones of improved color quality |
| US5719229A (en) * | 1995-12-28 | 1998-02-17 | Bayer Corporation | Process for preparing solid elastomeric polyurethanes having reduced surface skinning |
| IN1997CH00157A (pt) | 1996-10-01 | 2006-06-09 | Recticel | |
| US5726240A (en) | 1996-11-25 | 1998-03-10 | Bayer Corporation | Reactivity stabilization of polymethylene poly(phenylisocyanates) |
| DE19735043A1 (de) | 1997-08-13 | 1999-02-18 | Bayer Ag | Verfahren zur Herstellung farbheller Uretdionpolyisocyanate |
| JP4044188B2 (ja) * | 1997-10-29 | 2008-02-06 | 旭化成ケミカルズ株式会社 | 水系コーティング組成物 |
| US6166128A (en) * | 1998-12-08 | 2000-12-26 | Bayer Corporation | Color reduction of polymethylene poly (phenylisocyanates) |
| US6291577B1 (en) * | 2000-04-11 | 2001-09-18 | Rhodia Inc. | Method for scavenging moisture in polyisocyanates and formulations thereof |
| JP2002097244A (ja) * | 2000-09-20 | 2002-04-02 | Nippon Polyurethane Ind Co Ltd | イソシアヌレート基含有ポリイソシアネートの製造方法 |
| EP1195395A1 (de) | 2000-10-06 | 2002-04-10 | Bayer Ag | Thermoplastisch verarbeitbare Polyurethanelastomere mit verbesserter Eigenfarbe |
| JP4533745B2 (ja) * | 2002-07-04 | 2010-09-01 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | ウレトジオン基を有する重付加生成物 |
-
2004
- 2004-07-14 JP JP2006520333A patent/JP5112693B2/ja not_active Expired - Lifetime
- 2004-07-14 WO PCT/US2004/022759 patent/WO2005089085A2/en not_active Ceased
- 2004-07-14 EP EP04821623.8A patent/EP1732965B1/en not_active Expired - Lifetime
- 2004-07-14 CN CN200480020126XA patent/CN101061067B/zh not_active Expired - Fee Related
- 2004-07-14 ES ES04821623.8T patent/ES2450166T3/es not_active Expired - Lifetime
- 2004-07-14 PL PL04821623T patent/PL1732965T3/pl unknown
- 2004-07-14 CA CA002532294A patent/CA2532294A1/en not_active Abandoned
- 2004-07-14 BR BRPI0412529A patent/BRPI0412529B1/pt not_active IP Right Cessation
- 2004-07-14 US US10/890,970 patent/US7297746B2/en not_active Expired - Lifetime
-
2012
- 2012-05-24 JP JP2012118685A patent/JP2012211325A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012211325A (ja) | 2012-11-01 |
| WO2005089085A2 (en) | 2005-09-29 |
| CN101061067A (zh) | 2007-10-24 |
| WO2005089085A3 (en) | 2007-02-01 |
| JP5112693B2 (ja) | 2013-01-09 |
| BRPI0412529B1 (pt) | 2015-11-24 |
| EP1732965B1 (en) | 2014-02-26 |
| EP1732965A2 (en) | 2006-12-20 |
| EP1732965A4 (en) | 2008-08-20 |
| ES2450166T3 (es) | 2014-03-24 |
| CA2532294A1 (en) | 2005-09-29 |
| JP2007535582A (ja) | 2007-12-06 |
| US20050020766A1 (en) | 2005-01-27 |
| CN101061067B (zh) | 2011-08-10 |
| US7297746B2 (en) | 2007-11-20 |
| PL1732965T3 (pl) | 2014-05-30 |
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