BRPI0413069A - processo e catalisador aperfeiçoados para produzir materiais de nanocarbono com alta seletividade e reduzidas temperaturas de reação - Google Patents

processo e catalisador aperfeiçoados para produzir materiais de nanocarbono com alta seletividade e reduzidas temperaturas de reação

Info

Publication number
BRPI0413069A
BRPI0413069A BRPI0413069-3A BRPI0413069A BRPI0413069A BR PI0413069 A BRPI0413069 A BR PI0413069A BR PI0413069 A BRPI0413069 A BR PI0413069A BR PI0413069 A BRPI0413069 A BR PI0413069A
Authority
BR
Brazil
Prior art keywords
catalyst
reaction temperatures
produce high
nanocarbon materials
high selectivity
Prior art date
Application number
BRPI0413069-3A
Other languages
English (en)
Inventor
Bhabendra Pradhan
Original Assignee
Columbian Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Columbian Chem filed Critical Columbian Chem
Publication of BRPI0413069A publication Critical patent/BRPI0413069A/pt

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Composite Materials (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

"PROCESSO E CATALISADOR APERFEIçOADOS PARA PRODUZIR MATERIAIS DE NANOCARBONO COM ALTA SELETIVIDADE E REDUZIDAS TEMPERATURAS DE REAçãO". A presente inenção refere-se a um sistema de nanofibras de carbono é sintetizado com pureza (acima de 95%), seletividade da morfologia do carbono muito altas e rendimento excepcionalmente alto. Um catalisador feito sob medida com um tamanho de partícula <243>10 nm e uma alta área superficial (>50 m¬ 2¬/g), proporciona seletividade morfológica mais alta. A reatividade dessas partículas de catalisador é mantida mesmo após 24 horas de reação de tal modo que o rendimento exceda 200 g de carbono por grama de catalisador. Os catalisadores que são chaves para os produtos e rendimentos obtidos são preparados de acordo com parâmetros específicos (distribuição de tamanho, composição e cristalinidade) especificados e via um processo de síntese por chama conforme ensinado na Patente Americana No. 6.132.653.
BRPI0413069-3A 2003-07-28 2004-04-20 processo e catalisador aperfeiçoados para produzir materiais de nanocarbono com alta seletividade e reduzidas temperaturas de reação BRPI0413069A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/628,842 US20050025695A1 (en) 2003-07-28 2003-07-28 Catalyst and process to produce nanocarbon materials in high yield and at high selectivity at reduced reaction temperatures
PCT/US2004/012136 WO2005016853A2 (en) 2003-07-28 2004-04-20 Improved catalyst and process to produce nanocarbon materials in high yield and at high selectivity at reduced reaction temperatures

Publications (1)

Publication Number Publication Date
BRPI0413069A true BRPI0413069A (pt) 2006-10-17

Family

ID=34103461

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0413069-3A BRPI0413069A (pt) 2003-07-28 2004-04-20 processo e catalisador aperfeiçoados para produzir materiais de nanocarbono com alta seletividade e reduzidas temperaturas de reação

Country Status (9)

Country Link
US (1) US20050025695A1 (pt)
EP (1) EP1654406A4 (pt)
JP (1) JP2007500121A (pt)
KR (1) KR20060052923A (pt)
CN (1) CN1833055A (pt)
AR (1) AR044387A1 (pt)
BR (1) BRPI0413069A (pt)
TW (1) TW200505788A (pt)
WO (1) WO2005016853A2 (pt)

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KR101443222B1 (ko) * 2007-09-18 2014-09-19 삼성전자주식회사 그라펜 패턴 및 그의 형성방법
MY160277A (en) 2009-04-17 2017-02-28 Seerstone Llc Method of producing solid carbon by reducing carbon oxides
KR101900758B1 (ko) * 2011-11-29 2018-09-20 한화에어로스페이스 주식회사 그래핀 합성용 금속 박막 및 이를 이용한 그래핀 제조 방법
US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
EP2838837A4 (en) 2012-04-16 2015-12-23 Seerstone Llc METHOD AND STRUCTURES FOR REDUCING CARBON OXIDES WITH IRON-FREE CATALYSTS
EP2838839B1 (en) 2012-04-16 2020-08-12 Seerstone LLC Method for producing solid carbon by reducing carbon dioxide
NO2749379T3 (pt) 2012-04-16 2018-07-28
WO2013158158A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Methods for treating an offgas containing carbon oxides
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
JP6284934B2 (ja) 2012-07-12 2018-02-28 シーアストーン リミテッド ライアビリティ カンパニー カーボンナノチューブを含む固体炭素生成物およびそれを形成する方法
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
JP6025979B2 (ja) 2012-07-13 2016-11-16 シーアストーン リミテッド ライアビリティ カンパニー アンモニアおよび固体炭素生成物を形成するための方法およびシステム
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
WO2014039509A2 (en) 2012-09-04 2014-03-13 Ocv Intellectual Capital, Llc Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media
MX382104B (es) 2012-11-29 2025-03-13 Seerstone Llc Reactores y métodos para producir materiales de carbono sólido.
EP3129135A4 (en) 2013-03-15 2017-10-25 Seerstone LLC Reactors, systems, and methods for forming solid products
US9586823B2 (en) 2013-03-15 2017-03-07 Seerstone Llc Systems for producing solid carbon by reducing carbon oxides
US9783416B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Methods of producing hydrogen and solid carbon
US9783421B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
EP3129321B1 (en) 2013-03-15 2021-09-29 Seerstone LLC Electrodes comprising nanostructured carbon
US20160130519A1 (en) * 2014-11-06 2016-05-12 Baker Hughes Incorporated Methods for preparing anti-friction coatings
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same

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Also Published As

Publication number Publication date
US20050025695A1 (en) 2005-02-03
EP1654406A4 (en) 2007-08-22
WO2005016853A3 (en) 2005-09-29
AR044387A1 (es) 2005-09-07
KR20060052923A (ko) 2006-05-19
TW200505788A (en) 2005-02-16
CN1833055A (zh) 2006-09-13
JP2007500121A (ja) 2007-01-11
EP1654406A2 (en) 2006-05-10
WO2005016853A2 (en) 2005-02-24

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE AS 6A, 7A E 8A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2159 DE 22/05/2012.